HVAF-ARC涂层在电站锅炉省煤器防护中的研究

本文采用HVAF-ARC喷涂系统制造的NiCrTi活性功能涂层.研究电站锅炉省煤器防护涂层的金相组织研究、SEM检测、X射线衍射以及涂层显微硬度.     

超音速电弧喷涂不锈钢涂层结构及性能的研究

运用超音速电弧喷涂系统,通过光学显微镜,电子扫描显微镜和拉伸试验法对３Ｃｒ１３涂层的组织结构和性能进行了研究,结果表明,超音速电弧喷涂的颗粒细小,涂层表面光滑,组织致密,结合强度和硬度高,可广泛地应用于零件和设备的表面耐磨,耐蚀强化处理与机械零件加工尺寸超差的恢复等。     

高速电弧喷涂FeAlCrNi-Cr3C2涂层的组织与相结构研究

采用粉芯丝材高速电弧喷涂技术制备了FeAlCrNi-Cr3C2涂层,并研究了涂层的组织和相结构.结果表明:涂层具有致密的层状结构,扁平颗粒小,氧化物膜细小,硬质点相分布均匀,孔隙率低;在涂层中存在着多种结构复杂的组织和化合物相,包括单立方结构基体相FeAl、Fe3Al、AlNi,AlNi;硬质相Cr3C2、Fe3C及AlFe3C0.5;氧化物相FeO·Al2O3、Cr2O3、少量六方结构的α-Al2O3和面心立方结构的γ-Al2O3以及面心立方结构的FeO·Cr2O3;某些区域还存在面心立方结构的γ-(Fe,Ni).     

高速电弧喷涂铁基Cr3C2复合涂层的显微组织

采用高速电弧喷涂技术将自制的铁基Cr3C2粉芯丝材在20钢上制备复合涂层,采用SEM、TEM、XRD等研究了涂层的显微组织和物相结构。结果表明：涂层与基体结合紧密,具有致密的层状结构,颗粒扁平细小,孔隙率低,具有较高的显微硬度;在涂层中存在着多种结构复杂的组织和化合物相,其中α-Fe为基体相,主要硬质相为（Fe,Cr）23C6、（Fe,Cr）7C3,另外还有FeCr2O4、Cr2O3等氧化物相,其中某些物相之间存在着平行的晶体学取向关系。     

超声深滚法提高电弧喷涂3Cr13涂层性能

利用超声深滚(Ultrasonic deeprolling,UDR)技术对钢基体电弧喷涂3Cr13涂层进行表面复合强化处理,旨在改善涂层的综合性能。采用扫描电镜、应力仪及球—盘式摩擦磨损试验机等设备检测和分析UDR工艺对该涂层孔隙率、表面粗糙度、残余应力、显微硬度、摩擦学性能等的影响。结果表明,UDR工艺使该涂层的孔隙率从5.1%降为2.3%;表面粗糙度Ra由40μm以上降为2.4μm;表面残余压应力由8MPa提高到257MPa;涂层显微硬度提高约45%,涂层摩擦学性能得到了明显提高。且Bragg衍射峰明显宽化、左移、峰强增大,这表明涂层晶粒明显细化、晶格畸变,且形成晶向平行表面的板织构。同时分析和讨论UDR工艺对提高3Cr13涂层性能的影响机理。     

瓦楞辊表面等离子喷涂Cr2O3涂层性能研究

利用等离子喷涂技术在瓦楞辊材料42CrMo合金钢表面涂镀Cr2O3硬质涂层,以期提高材料表面耐磨性能.用显微硬度仪测试涂层的硬度,用MFT-4000型高速往复摩擦磨损试验机对涂层进行耐磨性能试验.并用扫描电镜(SEM)、X光衍射仪(XRD)分析了涂层的截面形貌和相结构.结果表明:等离子喷涂Cr2O3涂层后试样表面硬度达到HV1 184.1,试样表面摩擦因数减小,抗磨损性能大幅提高.     

第聂泊——3型爆炸喷涂设备技术性能研究

爆炸喷涂是一种先进的热喷涂技术。本文论述了第聂泊－３型爆炸喷涂设备的工作原理和工作过程，爆炸喷涂技术特点，分析研究了几种常用涂层性能。揭示其广阔的应用前景。     

第聂泊-3型爆炸喷涂设备技术性能研究

爆炸喷涂是一种先进的热喷涂技术．本文论述了第聂泊-3型爆炸喷涂设备的工作原理和工作过程，爆炸喷涂技术特点，分析研究了几种常用涂层性能，揭示其广阔的应用前景．     

高速火焰喷涂Fe-Al/Cr3C2复合涂层的摩擦学特性

运用高速火焰喷涂方法，选用自主研发的Fe-Al／CrsC2喷涂材料，在20钢基体上制备了复合涂层。利用XRD分析了涂层的相组成，利用SEM分析了涂层表面以及磨损表面形貌，对涂层进行了EDAX分析，并对涂层的摩擦学特性进行了研究。结果表明：高速火焰喷涂Fe-Al／Cr3C2复合涂层中主要相包括Fe3Al、Cr3C2和α-Fe相，涂层的磨损率随温度的升高而下降，具有很好的抗高温磨损性能。     

爆炸喷涂Cr3C2／25NiCr涂层抗微动磨损性能的研究

研究爆炸喷涂Cr3C2/25NiCr涂层的抗微动磨损性能.结果表明,爆炸喷涂Cr3C2/25NiCr涂层的层间氧化物含量和孔隙率低,组织致密,结合强度高,涂层的抗接触疲劳性能得到有效改善,抗微动磨损能力比K417镍基合金和等离子喷涂层显著提高.     

一种柱塞件的设计与火焰热喷涂加工

针对化工工业中的零件“柱塞”，因其工作环境恶劣，性能要求高，对其结构进行了重新设计，对生产工艺进行了进一步研究，采用了火焰热喷涂技术，使产品取得了良好的使用效果及经济效益。     

Wear and friction characteristics of atmospheric plasma sprayed Cr3C2–NiCr coatings

ABSTRACT

The present work focuses on investigating the wear and friction characteristics of the Atmospheric Plasma Sprayed Cr₃C₂-NiCr coatings deposited onto the surface of die steel material. The as-sprayed specimens were characterized. The coating porosity, bond strength and microhardness values were evaluated. Wear tests were performed on the high-temperature pin-on-disc tribometer at room temperatures, 400°C and 800°C under two loads as 25N and 50N in the laboratory. The wear mechanisms of all the worn-out samples were studied by scanning electron microscopy (SEM) technique. The specific wear rates and the coefficient of friction values were analyzed. The developed coating showed better wear resistance than its uncoated counterpart. The coefficient of friction values for coated specimens decreased at elevated temperatures. At room temperatures, the wear mode was observed to be adhesive and further at elevated temperatures of testing, the wear mode was observed to be the combination of oxidative, adhesive and abrasive.     

Performance in Resistance to Surface Fatigue for Cr3C2–25%NiCr Coatings by Plasma Spray and CDS Spray

Three Cr₃C₂–25%NiCr coatings, prepared by Air Plasma Spray (APS)-Ar/H₂, APS-Ar/He and Continuous Detonation Spraying CDS, have been tested on a double-point-contact fatigue-test machine to examine their surface fatigue limit. Results show that the CDS coating exhibits the best performance in resistance to contact fatigue, while the other two coatings tested in our study are unacceptable as fatigue-resistant materials. On the basis of SEM observations, different failure mechanisms for the coatings are suggested. The fatigue limit of the Cr₃C₂–25%NiCr coatings decreases with the reduction of coating thickness, and the causes for the phenomenon have been discussed.     

Cr3C2/镍基合金等离子堆焊层的组织及耐磨性能

采用光学显微镜、扫描电镜、X射线衍射仪以及磨损试验机等,研究了加入不同量的Cr3C2对等离子堆焊镍基合金堆焊层组织和耐磨性能的影响.结果表明:纯镍基合金堆焊层组织主要是由γ(Ni,Fe)、CrB和M7(C,B)3等物相构成,且存在着明显的成分偏析;加入Cr3C2以后,合金层中出现了Cr3C2相,且使堆焊层枝晶破碎,组织变细,成分偏析减弱直至消失;Cr3C2颗粒的加入,提高了堆焊层的磨粒磨损性能,且随其加入量的增加,耐磨性逐渐提高;当加入量达到30%时,耐磨性最好,随后耐磨性开始降低.     

Porous TiO2 nanowire microsphere constructed by spray drying and its electrochemical lithium storage properties

Porous TiO₂ nanowire microspheres with greatly decreasing agglomeration were successfully prepared by spray drying of hydrothermal reaction suspension, followed by calcination at 350°C. The as‐obtained nanowire microspheres with TiO₂‐B structure reach an initial discharge capacity 210 mAh g^?1 with an irreversible capacity 25 mAh g^?1 at a current density of 20 mA g^?1. For the 450°C‐calcined one with anatase TiO₂ crystal structure, the initial discharge capacity is 245 mAh g^?1 but with a much higher irreversible capacity of 80 mAh g^?1. The hierarchical porous structure in the 350°C‐calcined TiO₂ nanowire microspheres collapsed at 450°C, annihilating the main benefit of nanostructuring. Microsc. Res. Tech. 77:170–175, 2014. © 2013 Wiley Periodicals, Inc.     

Nanoparticle suspension preparation using the arc spray nanoparticle synthesis system combined with ultrasonic vibration and rotating electrode

This study aims to investigate the use of a new nanoparticle preparation method, i.e., the arc spray nanoparticle synthesis system (ASNSS) combined with ultrasonic vibration and rotating electrode, to prepare TiO₂ nanoparticle suspension. For the proposed new method of nanoparticle suspension preparation, this study has designed four different process modes of experimentation for comparison, in order to obtain suspended nanoparticles with smaller particle size and relatively good dispersion. This study discusses the process modes with different settings of variables including peak current, pulse duration, breakdown voltage, temperature of the dielectric fluid and amplitude of ultrasonic vibration, in order to determine the better conditions for the preparation of TiO₂ nanoparticles suspension. The Transition Electron Microscope (TEM) image of the experiment result shows that TiO₂ nanoparticles prepared by the ultrasonic vibration assisted vacuum arc spray process has an average particle size of less than 10 nm.     

高速电弧喷涂FeAlCrNi-Cr3C2涂层的组织与相结构研究

采用粉芯丝材高速电弧喷涂技术制备了FeAlCrNi-Cr3C2涂层,并研究了涂层的组织和相结构.结果表明涂层具有致密的层状结构,扁平颗粒小,氧化物膜细小,硬质点相分布均匀,孔隙率低;在涂层中存在着多种结构复杂的组织和化合物相,包括单立方结构基体相FeAl、Fe3Al、AlNi,AlNi;硬质相Cr3C2、Fe3C及AlFe3C0.5;氧化物相FeO·Al2O3、Cr2O3、少量六方结构的α-Al2O3和面心立方结构的γ-Al2O3以及面心立方结构的FeO·Cr2O3;某些区域还存在面心立方结构的γ-(Fe,Ni).     

Computational fluid dynamics analysis of MQL spray parameters and its influence on superalloy grinding

The application of emulsion for combined heat extraction and lubrication requires continuous monitoring of the quality of emulsion to sustain a desired grinding environment; this is applicable to other grinding fluids as well. To sustain a controlled grinding environment, it is necessary to adopt an effectively lubricated wheel–work interface. The present work aims to develop a numerical model to replicate the mist formation in minimum quantity lubrication (MQL) grinding using a fluent-based computational fluid dynamics (CFD) flow solver. The MQL parameters considered for this study are air pressure and the mass flow rate. Simulation of the atomization under turbulent conditions was done in a discrete phase model (DPM) owing to the fact that oil mass flow rates are very low and oil acts as a discrete medium in air. Jet velocity and droplet diameters were also obtained under different input conditions to find the optimum value of air pressure and mass flow rate of oil to achieve the desired results (lower cutting force and surface roughness) in MQL grinding of superalloy (Inconel 751). It is seen that medium size (around 16.3 µm) of droplet plays a significant role in improved performance by the way of reduction in cutting force and surface roughness.