Collaborative monitoring of chlorine flavours in drinking water.

Sensory data have always been used by concerned citizens to evaluate environmental variables within volunteer monitoring initiatives. The work presented in this paper intends to explore the possibility of using human sensory data as a source of information to monitor environmental quality variables within a public participation context. A case study that uses untrained citizens to monitor chlorine flavour of tap water is presented. Two collaborative monitoring tests were developed: (1) the one-sample one-trial test and (2) the Chlorine@Home test. The tests intended to address the participatory context required by collaborative monitoring initiatives. The development of the collaborative tests was supported by two tests that were designed for a laboratory context and explored sensory methodologies. The sensory tests implemented were: (1) the paired comparison test, (2) the forced-choice triangle test (ASTM Method E679-04). The collaborative experiments showed that the ability to detect chlorine flavours on a participatory context was independent on chlorine concentrations. The use of sensors by citizens may be a way to increase the credibility of the information. Nevertheless, this case study suggested that more research should be carried out to explore ways to involve citizens while increasing data reliability.     

Benefits of pan-sharpened Landsat imagery for mapping small waterbodies in the Powder River Basin, Wyoming, USA

Pan‐sharpened Landsat imagery was used to map waterbodies of a wide variety of sizes in the Powder River Basin (PRB) in northcentral Wyoming, USA. Coal bed natural gas extraction activities have been intensive in the PRB over the past decade, with abundant co‐produced water being discharged into retention ponds and small ephemeral channels. Although land management agencies are tasked with monitoring these waterbodies, traditional field survey methods might not be feasible during rapid development. Remote‐sensing applications could be used in such cases. Although Landsat and similar medium‐resolution datasets do not have detailed spatial information at fine resolutions required to map small waterbodies, they do contain rich spectral information. Panchromatic data collected by satellites have an appropriate spatial resolution, but lack detailed spectral information. Thus, image fusion techniques were used to create a pan‐sharpened image, by merging multispectral (30‐m resolution) and panchromatic (15‐m) bands from Landsat 7 imagery. Both the original and the pan‐sharpened images were used to map waterbodies and estimate their area, being compared to photo‐interpretation results. The accuracy of mapping waterbodies with pan‐sharpened imagery was significantly higher than the original Landsat data for waterbodies ranging in size from 901 to 8100 m². Large reservoirs (>8100 m²) were very accurately mapped, both images producing identical results (96%). Neither image was able to suitably detect very small waterbodies (<900 m²). Detailed analysis within 901–3600 m² size category revealed that the benefits of pan‐sharpened imagery were most pronounced (25% higher accuracy) for mapping waterbodies ranging in size from 1801 to 2700 m².     

The stream evolution triangle: Integrating geology,hydrology, and biology

The foundations of river restoration science rest comfortably in the fields of geology, hydrology, and engineering, and yet, the impetus for many, if not most, stream restoration projects is biological recovery. Although Lane's stream balance equation from the mid‐1950s captured the dynamic equilibrium between the amount of stream flow, the slope of the channel, and the amount and calibre of sediment, it completely ignored biology. Similarly, most of the stream classification systems used in river restoration design today do not explicitly include biology as a primary driver of stream form and process. To address this omission, we cast biology as an equal partner with geology and hydrology, forming a triumvirate that governs stream morphology and evolution. To represent this, we have created the stream evolution triangle, a conceptual model that explicitly accounts for the influences of geology, hydrology, and biology. Recognition of biology as a driver leads to improved understanding of reach‐scale morphology and the dynamic response mechanisms responsible for stream evolution and adjustment following natural or anthropogenic disturbance, including stream restoration. Our aim in creating the stream evolution triangle is not to exclude or supersede existing stream classifications and evolutionary models but to provide a broader “thinking space” within which they can be framed and reconsidered, thus facilitating thought outside of the alluvial box.     

Tracking pollution and its sources in the catchment‐lake system of major waterbodies in Kazakhstan

The objective of the present study was to identify the sources and routes of entry of heavy metals and nutrients into several large waterbodies in the arid zone of Kazakhstan, namely Lake Balkhash and Samarkan and Shardara reservoirs. A data visualization method was used for this purpose. Statistical mapping, based on referencing coordinates of the material selection points, was performed with the Statistics 12.0 program. Matching statistical maps with the waterbody contours was performed in Adobe Photoshop. Maps of the spatial distribution of heavy metals (cadmium, nickel, cobalt, lead, zinc and copper) and nutrients were constructed for all three study waterbodies. Data visualization clearly illustrated the relationship between the distribution of pollutants in the study waterbodies, as well as the sources of anthropogenic pollution. Based on the mapping exercise, it was established that Cu and Zn entered the waterbodies mainly in agricultural waste waters, while Cd, Ni, Co, Pb and partly Zn entered the waterbodies mainly in industrial and surface run‐off. Nutrients enter the waterbodies mainly in river and municipal waters. The constructed maps demonstrate the role of the constant flow in the distribution of pollutants in the waters of Lake Balkhash. The results also indicate that statistical mapping is an effective tool for identifying the sources and routes of pollutant entry into waterbodies. The imposition of statistical maps on the contours of waterbodies of concern provides a mapping method allowing for more visually compelling data and information for a wide circle of users and managers.     

Invader amphipods Gmelinoides fasciatus (Stebbing, 1899) inhabiting distant waterbodies demonstrate differences in tolerance and energy metabolism under elevated temperatures

Gmelinoides fasciatus is a successful invasive amphipod (Amphipoda, Crustacea) that dispersed from Lake Baikal to various waterbodies. Here we studied whether Baikal conditions are optimal for G. fasciatus in terms of thermotolerance and investigated lethal temperatures, 70 kDa heat shock protein level, energy metabolism, and antioxidant defense of animals from three geographically distant waterbodies under changing temperatures. We used acute heat exposure to 28 °C to assess the median lethal times and gradual temperature increase from 6 °C to determine the lethal temperatures. Mortality under heat shock was explainable by the baseline content of Hsp70 that correlated with thermal history. But it was not the case under gradual temperature increase where Hsp70 levels became similar and the mortality pattern changed. The most thermotolerant amphipods from the Gulf of Finland demonstrated a higher amount of free glucose during the temperature increase that may be related to the higher salinity of this waterbody and less energy required for ion regulation. Even though concentrations of major physiological ions in Lake Baikal are lower than in Lake Ladoga, G. fasciatus from Ladoga was slightly more sensitive to the gradual temperature increase. This difference could be explained by the influence of high levels of humic and other potentially toxic substances in Lake Ladoga indicated by increased activities of catalase and glutathione S-transferase. Importantly, all G. fasciatus populations accumulated relatively low levels of lactate during the temperature increase, which may reflect the ability of this invasive species to effectively maintain aerobic metabolism under various conditions.     

Pretreatment chemistry for dual media filtration: model simulations and experimental studies.

Laboratory dual media filtration experiments were conducted (a) in direct filtration mode using model raw water moderate in turbidity and low in DOC, and (b) in conventional filtration mode treating water moderate in turbidity and high in DOC. Model simulations of filter performance for the removal of particles provided hypotheses for the experimental studies of dual media filtration. An increase in alum dose in direct filtration mode, while improving filter performance, also showed some disadvantages, including rapid development of head loss. Suboptimal dose in direct filtration significantly impaired the filter performance. In conventional mode, the effect of alum dose on the filter performance, while obvious, was not as dramatic as in direct filtration. Ripening indicated by particle counts occurred earlier than by turbidity and breakthrough of particle counts started earlier than breakthrough of turbidity, suggesting that turbidity can be used as a more conservative monitor of filter performance during the ripening period to minimise the risk of passage of small particles, while particle counts can be considered a more sensitive indicator of deteriorating filter performance during the breakthrough period. The lower sand layer served as a multiple barrier for particle when the performance of the anthracite layer was not effective.     

Microbiological water quality in a large in-building, water recycling facility.

The Thames Water recycling plant at the Millennium Dome, London, reclaimed three sources of water: greywater from the washbasins, rainwater from the Dome roof and groundwater from a borehole on site. These were pre-treated separately, and the mixed stream filtered using ultrafiltration and reverse osmosis membranes. Monitoring for indicator microorganisms was undertaken throughout the plant and in the reclaimed water distribution system, as well as ad-hoc monitoring for the presence of pathogens in the raw waters. Treatment to the level of ultrafiltration was more than adequate to produce a water quality meeting existing worldwide reclaimed water guidelines for toilet flushing. Owing to the excellent quality of the water leaving the plant, no significant microbiological growth was observed in the reclaimed water distribution system during the year. The raw greywater exhibited a higher faecal bacterial load than the rainwater and groundwater, as predicted from more human contact (i.e. hand washing). Environmental strains of Legionella were observed in the three raw greywater samples analysed for pathogens, as was Cryptosporidium, Giardia and faecal enterococci. The rainwater had relatively high levels of faecal bacteria, probably of avian origin. Giardia was detected in one rainwater sample confirming the potential for this water source to contain pathogens.     

Water chemistry gradient in a degraded bog area.

Surface and ground water was sampled in a degraded bog area 36 times during 1993 - 2003 at Five representative points: point E (natural area with Sphagnum as the main vegetal cover), point W (boundary between the natural and degraded areas), point W' (area installed with vinyl sheeting), point WW (area where Sasa thrives), and point NC (area with naturally formed ditches). Analysis of variance (ANOVA) was conducted for parameters measured in surface water and ground water at 0.5, 1.0, 1.5, and 2.0 m depths. "Sampling point" (i.e. locations along the degradation gradient) accounted for most of the variation in surface and ground water chemistry. It accounted for 30-80% of the total variation in pH, electrical conductivity, ammonia, dissolved nitrogen, major cations (Na+, K+, Ca2+, Mg2+), alkalinity and dissolved organic carbon. "Year" accounted for more variation in nitrate, nitrite, chloride, and sulfate than the sampling point did, but the variation in dissolved reactive phosphorus and dissolved phosphorus concentrations was not based on any of the calculated variables.     

Appraisal and optimization of agricultural water use in large irrigation schemes: II. Applications

In this paper, the theoretical approach presented in Part I is demonstrated by means of case studies on the irrigation schemes of Rio Mendoza and Rio Tunuyán in the Province of Mendoza, Argentina. The object of the case studies was the determination of optimal allocation of surface water to reduce the use of groundwater. Current and optimal conjunctive allocation of ground and surface water is studied by means of the developed simulation and optimization models.The second case study was designed on the basis of the experience gathered during the first one: each step of the case studies is compared. The comparison between the two case studies illustrates how to apply the proposed approach when the amount and quality of available data are different. For the more detailed Rio Tunuyán study, we determined the following physical characteristics of all terminal nodes: on-farm rotational intervals, mean water application depth, actual soil water storage capacity, crop water requirements, depth of groundwater table, aquifer transmissivity, and efficiency of groundwater use.The performance of the entire system is sensitive to changes in the water application depth, as it was shown by a simulation study.The application of our optimization approach to the conjunctive use of ground- and surface water showed that the total water requirements over a year can be met by a reassignment of water that reduces the total costs of a great amount.     

Appraisal and optimization of agricultural water use in large irrigation schemes: I. Theory

A new approach on the functioning of an irrigation scheme has been presented. A mathematical representation of the irrigation system based on measured system properties, such as losses due to percolation and to poor management, in only a part of the system is used. This mathematical representation is termed an equivalent irrigation network. The merit of this approach is that it reduces the number of required streamflow measurements.When water amounts are measured for a number of paths in the irrigation network, so-called path efficiencies are obtained. The path efficiency is a measure of the amount of water lost along the way. The numerical model that simulates the operation of the irrigation system is based on the path efficiencies. This simulation model in turn is used to calculate different objective functions, corresponding with different optimization goals, like uniform water distribution, minimum groundwater extraction, minimum cost of water supply.This paper gives the theoretical background of the approach. The application to an actual irrigation scheme will be discussed in a second paper.     

Optimal allocation of water resources in large river basins: I. Theory

The major purpose of this paper is to present the useful techniques in the optimal allocation of water resources (OAWR) and to demonstrate using water resources applications how these methods can be conveniently employed in practice for systematically studying both simple and complex water resources problems. Formal modelling techniques in multiobjective decision-making provide many benefits to professionals working in water resources and elsewhere. A new Large-system Hierarchical Dynamic Programming (LHDP) method to solve the model can be carried out to ascertain the consequences of meaningful parameter changes upon the optimal or compromise solution.As a case study, the techniques and methods are applied to the OAWR of the Yellow River Basin (YRB) of China. The next paper shares with the reader recent research results on the OAWRYRB.Notation L _i inflows from the trunk stream in the subregioni. - S _i run-off volume of the river sectioni. - Q _i net inflows of intervals in the subregioni. - W _i volumes of water drawn the trunk stream ofi into subdistricti. - H _i volumes of water returning to the trunk stream in the subdistricti. - B _i(W _i) the maximum net benefits (in hundred million yuan) from the annual-water consumption ofW _iin subregioni. - W _ik the annual-water consumption (in hundred million m³) of sectorK in subregioni, k = 1, 2, 3, 4. - B _ik(W _ik the maximum net benefits (in hundred million yuan) from the annual consumptionW _ikof sectork in subregioni. - BS _i(S _i) the maximum net benefits (in hundred million yuan) obtained from the optimal allocation of the run-off volumeS _iof river trunki among different sectors within the months of a year.     

Importance of biotic interactions in large rivers: an experiment with planktivorous fish,dreissenid mussels and zooplankton in the St. Lawrence River

Physical conditions are usually considered pre‐eminent in controlling river plankton, but biotic interactions may be important in slackwater areas. To begin testing this general hypothesis, we conducted a 12‐day, predator–prey experiment in 3500 litre mesh enclosures in a slackwater area of the St. Lawrence River using planktivorous, juvenile yellow perch (Perca flavescens) and Dreissena mussels. Results generally supported our hypotheses that: (1) perch would directly suppress large zooplankton via predation but benefit microzooplankton through indirect interactions; and (2) dreissenids would directly depress rotifer densities via predation and have indirect negative effects on macrozooplankton. Based on gut contents of experimental fish, cladocera were the principal prey of smaller yellow perch (c. 46–50 mm), followed by copepods, ostracods, and rotifers. Larger juvenile perch (c. 67–73 mm) fed almost exclusively on copepods and ostracods. Densities of calanoid copepodids, nauplii, and some cyclopoid copepods (Diacyclops thomasi) were significantly depressed by perch, and adult Eurytemora affinis (99% of adult calanoids) essentially disappeared from fish enclosures. Despite being a favourite prey item of small perch, densities of the small cladoceran Bosmina (Sinobosmina) spp. were significantly higher when fish were present (150% greater than control densities on Day 12). Densities of the very abundant rotifer Polyarthra were >300% greater in fish enclosures than controls by Day 12, and the rotifers Synchaeta and predaceous Ploesoma were significantly more abundant in the presence of perch. Increases in rotifers and cladocera suggest indirect, positive effects of fish related to significantly higher phytoplankton biomass or decreased densities of predaceous copepods. Densities of eight of ten zooplankton groups examined declined significantly when mussels were present, and calanoid copepodids also declined but not significantly. Chlorophyll‐a concentrations were slightly lower in mussel enclosures. This evidence suggests biotic interactions play important roles among potamoplankton in slackwater habitats, but river‐wide implications of these findings require further study. Copyright © 2003 John Wiley & Sons, Ltd.     

Water exchange in a large river–lake system: Modeling,characteristics and causes

River–lake water exchange reflects hydrological connectivity and the dynamic relationship between the river and the lake. The water exchange is crucial for lake level variation, downstream river discharge and the ecosystem. To figure out the water exchange between the Yangtze River and Poyang Lake, a data‐driven model was established based on the support vector regression and genetic algorithm technique. Nine scenarios were set with different river–lake hydrological conditions, divided into two categories: single‐element change scenarios, where only the river conditions or only the lake conditions changed, and combined scenarios, where both elements changed simultaneously. The model could accurately simulate the river–lake water exchange variations. Scenario simulation results show that increasing the river flow or lowering the lake level could cause a decrease in the lake outflow. Conversely, decreasing river flow or raising the lake level could cause an increase in lake outflow. Changing lake conditions have a stronger impact on the water exchange variation than changing river conditions if the change percentages of the situation indicator values are the same. Similarly, lake level increase has a stronger impact on the water exchange variation than lake level decrease. The combined scenarios indicate the additive effect of the corresponding single‐element change scenarios, with a clear linear relationship between their lake outflow changes. This study provides an efficient model for simulating complex hydrological flow relationships in river–lake systems, and supports the management of the Yangtze River and Poyang Lake by providing the characteristics and causes of the river–lake water exchange.     

Aspects of the biology of Labeo cylindricus (Pisces: cyprinidae) in Lake Baringo,Kenya

Aspects of the biology of Labeo cylindricus from Lake Baringo were investigated, based on experimental beach seining and gillnetting between August and October 2007. The length–weight relationship indicated the species exhibited positive allometric growth (b = 3.7083), with a condition factor (K) of 0.84 ± 0.0298 S.D. Males dominated fish catches, with an adult sex ratio of males/females of 1:1.7. The fish length‐at‐50% maturity (Lm50) was 127.7 and 126.1 mm total length (TL) for males and females, respectively. Fish age and growth were determined from sagittal otoliths considered to be from the young‐of‐the‐year. Clear circuli observed in the otoliths were used to determine fish age in days. Validation by oxytetracycline marking indicated that a single growth increment (1.1 ± 0.1 SE) is formed daily on fish otoliths. Fish length (TL mm) was correlated significantly with age (in days), TL = 1.398 Age + 26.523 (r² = 0.91). Fish growth was subsequently estimated to be 1.398 mm day^?1. The weights and ages (in days) of fish exhibited a significant (P < 0.05) power relationship defined by the equation: W = 0.0003 Age^2.5804 (r² = 0.88). The results of this study provide parameters that, if appropriately monitored, can be used to predict responses of fish populations in Lake Baringo and elsewhere to human interventions (exploitation) and natural environmental change.     

Temporal and spatial variation of physical, biological, and chemical parameters in a large waste stabilisation pond, and the implications for WSP modelling.

The spatial and temporal variation of physical, chemical, and biological parameters was determined, in summer and winter, at nine sites in a large (112 ha) waste stabilisation pond (WSP) at the Bolivar Wastewater Treatment Plant. Each site was extensively sampled over the course of one day, with the nine sites sampled over successive days at exactly the same times of day, progressing in the direction of bulk flow through the pond. Analyses of covariance were used to test the independent impact of site and climate on the way in which the mean values and stratification gradient of the physical, chemical, and biological parameters varied diurnally at each site. In both winter and summer studies there was a very strong correlation at all sites between changes in temperature, pH and dissolved oxygen (DO). Mean pond temperatures were higher in summer than winter, and thermal stratification was more common in summer. In summer, during the day at each site, concentrations of chlorophyll-a, DO, suspended solids and pH increased with higher solar radiation levels. This relationship was less evident in winter. There was no systematic depth or temporal variation identified in either the summer or winter study for the broad range of chemical parameters measured. Mean values for these parameters, and to a lesser extent their stratification gradients, increased by varying extents throughout the day at the different sites in both summer and winter, irrespective of changes in climate when the different sites were sampled. Sites nearer the inlet to the WSP recorded lower NH4N and higher NO2N and NO3N concentrations than the rest of the WSP. This was indicative of nitrification. Somewhat surprisingly, high DO concentrations were also recorded at these sites near the inlets. Computational fluid dynamics (CFD) modelling, incorporating the predominant wind conditions, offers a rationale for these observations. Recirculation was evident, which may increase the residence time for the slow growing autotrophic nitrifying bacteria and recirculate oxygen rich water around these sites - conditions which would enhance nitrification. Understanding the effect of these variations, overlaid by the influence of hydraulic and temporal scenarios, assists in developing a mechanistic understanding of pond operation.     

Entrainment of endangered sturgeon by a large water diversion: Rescue,enumeration, and conservation opportunities

The Bonnet Carre' Spillway diverts water from the Mississippi River through a floodway into brackish Lake Pontchartrain to reduce river stages at New Orleans and prevent flood damage. Pallid Sturgeon Scaphirhynchus albus, a federally listed species under the Endangered Species Act, and Shovelnose Sturgeon Scaphirhynchus platorynchus, listed under the Similarity of Appearance rule, are entrained through the spillway structure and become trapped in the canals and shallow lakes. The two species of sturgeon were identified according to a suite of morphomeristic characters, not genetically, and were therefore noted as either Shovelnose Sturgeon or presumed Pallid Sturgeon. Rescue efforts were undertaken to return the entrained sturgeon back into the Mississippi River. This article describes the environmental and operational conditions that influence entrainment risk, catch, and potential impacts on the population. Five openings and corresponding rescue operations occurred between 2008 and 2019 after each spillway closure. A total of 70 days with a crew number ranging from 6 to 12 were expended to collect 57 Pallid Sturgeon, four of which were dead, and 362 Shovelnose Sturgeon, 83 of which were dead, after the five openings that spanned 240 total days. More sturgeon were entrained at higher water temperatures, with a greater number of bays opened for longer durations. Recovery of sturgeon is initially high but over time declines as sturgeon are depleted from the floodway, stranded in isolated waterbodies in the floodway, and/or displaced further downstream into Lake Pontchartrain during longer openings. Sturgeon that cannot find their way back to the floodway are unlikely to be rescued. Recent population studies indicate that only a small proportion of the Lower Mississippi River total population is entrained. However, this does not take into account those individuals entrained but not captured and the potential impacts if more frequent openings of the structure were to continue in the future. Conservation recommendations are provided to increase catch efficiency and recovery of the endangered sturgeon.     

The role of soil chemistry in wine grape quality and sustainable soil management in vineyards.

Abstract This study aimed to establish if there is any evidence that soil mineralogical and/or chemical composition influence the composition and quality of wine grapes. In the initial phase of the study, soils and grapes were sampled in two riesling vineyards in South Australia. Soils were analysed for a wide range of total major and trace elements; soil cation extracts and grape juices were analysed for 27 trace elements by ICP-MS and ICP-AES. The results show that grape juice properties such as Baumé and titratable acidity (TA) are clearly correlated with several plant-available trace elements in the soil. Most notable of these are Ca, Sr, Ba, Pb and Si. Soil clay content also plays a (lesser) role. The cations Ca, Sr, Ba and Pb are closely similar to one another in their relationships to Baumé and TA, strongly indicating that the correlations are real. It is evident from our results that soil cation chemistry does indeed have an influence on wine grape composition. Such knowledge has the potential to be used in better tailoring grape varieties to soils, and in managing--or modifying--soils for optimum viticultural results and better wines in a more sustainable way.     

南通地区地下水循环与水化学时空变化规律研究

过去数十年来,江苏南通地区地下水水化学特征发生了较大的变化。为探明其水化学演化及时空变化规律,对南通地区地下水开展了野外调查取样及水化学测试分析,并利用Surfer8.0软件绘制出研究区域内浅层和深层地下水TDS、Cl-等值线图。研究结果表明,该区的浅层地下水含水层和深层地下水含水层属于不同的地下水循环系统。水化学显示2001~2007年间地下水咸化程度达到最高峰,全区咸化情况普遍严重;在空间上,总体浅层地下水由中西部内陆向东部沿海逐渐由淡水变为微咸水、咸水,西北部远海地区和中部南通地区地下水水质较好,咸化较严重的区域主要集中在东部沿海尤其是东南角沿海和海晏镇一带。     

Mapping bottom substrate in Illinois waters of Lake Michigan: Linking substrate and biology

Habitat plays an essential role in shaping aquatic communities yet limited information on the type and distribution of bottom features is available in the form of detailed maps. This is especially apparent in large systems where obtaining such information can be both expensive and challenging. Current maps of Lake Michigan substrate are very general and lack suitable detail of substrate composition and geographic extent of rocky areas. This limits our ability to link biological processes, such as fish spawning, to nearshore habitat and makes it difficult to target structurally complex habitats for sampling. We compiled substrate information gathered over 72 years for Illinois waters and incorporated it into a GIS framework to generate more complete documentation of sediment type and particle size distribution in southwestern Lake Michigan. Sediment data for 1682 sites were standardized to phi units; natural neighbor interpolation was used during GIS analysis to predict sediment type in areas lacking data. Predicted sediment values based on this interpolation had a significant positive relationship with observed sediment values (R² = 0.92). Further, we linked existing fishery (yellow perch Perca flavescens) data with newly generated substrate information to identify potential associations between spawning site selection and habitat. Tagging data indicated that substrate quality affected the likelihood of yellow perch returning to their release sites in subsequent spawning seasons; higher fidelity was associated with larger, coarser substrate. The generated map will be a useful tool to enhance our understanding of habitat's importance in the Great Lakes, particularly when linked with fishery data.