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以Triton X-100/正己醇/环己烷/水制成W/O微乳反胶团体系,通过测定体系的电导率和观察液晶相的出现确定相点绘制了各体系的拟三元相图,研究了温度、盐浓度和油相组分对W/O微乳液体系稳定性的影响.实验发现助表面活性剂与表面活性剂的配比对微乳液的稳定性有显著影响.随着温度的升高,W/O微乳液稳定区域减小,可通过升高温度对微乳液进行破乳;与以纯环己烷为油相的体系相比,油相中含有少量正己烷的体系具有更优异的性质.所得结果为利用该W/O微乳液体系制备纳米颗粒提供了基础数据. 相似文献
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基于相图法的W/O型微乳液体系稳定性分析 总被引:4,自引:0,他引:4
以辛基苯基聚氧乙烯醚(TX-10)、十二烷基磺酸钠(SDS)和十六烷基三甲基溴化铵(CTAB)为表面活性剂,以正戊醇、正己醇和正庚醇为助表面活性剂,以正戊烷为油相,制备了油包水型(W/O)微乳液.用相图法分析了微乳液体系的热力学稳定性,计算了水核半径的大小,并考察了影响微乳液W/O区域范围的各种因素.结果表明:这几种微乳液体系在实验条件下能自发形成:微乳液的水核半径处于纳米量级,可作为制备纳米粒子的超微反应器;以TX-10为表面活性剂时,水核可以包容更多的水分子,微乳液的W/O区域较大;而以CTAB为表面活性剂时,由于其极性头之间的空间和静电排斥作用强,微乳液的W/O区域最小;以硝酸镧溶液作为分散相时,微乳液的W/O区域变化较小;随着温度的升高,微乳液的W/O区域显著减小. 相似文献
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探讨了用于制备氧化铈纳米粒子的反相微乳体系组成及稳定性,以溴化十六烷基三甲基铵/正丁醇/环己烷/水构成了用于制备纳米氧化铈的W/O微乳液,通过测定体系的电导率的方法确定相点,绘制了溴化十六烷基三甲基铵和正丁醇-环己烷-水反相微乳区拟三元相图.结果表明,表面活性剂与助表面活性剂质量比,即溴化十六烷基三甲基铵与正丁醇的质量比等于1.6时为制备纳米粒子的最佳值,加入硝酸铈会使微乳液的区域减小,随着温度的升高微乳区域略微减小.按实验确定的条件,制备出纳米氧化铈,XRD分析结果表明,纳米氧化铈粒径为19~22 nm. 相似文献
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采用非离子表面活性剂吐温-80,以石油醚为油相,正丁醇为助表面活性剂来制备微乳液。用稀释法测定并计算了Tween-80/石油醚/正丁醇/水体系O/W型微乳的结构参数。测量微乳液体系在15~30℃温度范围内的pH及电导,考察温度对微乳液体系的影响。向微乳液体系中加入PVP,测量体系的电导和接触角,考察水溶性高分子对微乳液体系的影响。结果表明微乳液体系的电导随温度的上升而变大,相同温度时,加入PVP会使体系的电导变大,接触角变小。 相似文献
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4 微乳剂
早在20世纪40年代,Hoar和Schulman等人发现油-水混合物借助表面活性剂可以自发地形成透明的分散体系,由于所形成的液滴粒径非常小,后来将这种体系命名为微乳液.此后证明,它是一个热力学上稳定的、均相的水包油型乳液可溶体系,加工的微乳液剂型即为微乳剂.
微乳液存在3种结构类型,即O/W型、W/O型和双连续相结构(也称为中间相微乳型).这3种类型可以在一定条件下互相转变[10].农药上的微乳剂大都为以水为连续相的O/W型乳液. 相似文献
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The preparation of biocompatible microemulsions of soybean oil in systems made of anionic surfactant, oleic acid, water, and
several glycols was considered. The selected glycols were ether derivatives (methyl, ethyl, dimethyl, and diethyl ether) of
ethylene glycol and diethylene glycol. The study was performed using pseudoternary phase diagrams in which the three apexes
were occupied by soybean oil, a combination of surfactant/oleic acid, and a combination of water/glycol, respectively. The
widest regions of microemulsions were obtained for systems containing methyl ether and especially ethyl ether of both ethylene
glycol and diethylene glycol. The two latter compounds allowed the preparation of oil-in-water, bicontinuous, and water-in-oil
microemulsions with final surfactant contents of 3–4%. 相似文献
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In this study the effect of an anionic surfactant (sodium dodecyl sulfate SDS) and oils (hydrocarbons: C12–C16) on the formation
and phase behavior of the systems of oil/monoacylglycerols (MAG):SDS/propylene glycol/water has been investigated. The effects
of the surfactant mixture on the phase behavior and the concentration of water or oil in the systems were studied at three
temperatures (50, 55, 60 °C). Electrical conductivity measurement, FT-IR spectroscopy and differential scanning calorimetry
methods were applied to determine the structure and type of the microemulsions formed. The dimension of microemulsion droplets
was characterized by dynamic light scattering. It has been stated that the concentration of SDS has a strong influence on
the shape and extent of the microemulsion areas. Addition of an ionic surfactant to the mixture with MAG promotes an increase
in the area of microemulsion formation in the phase diagrams, and these areas of the isotropic region change with the temperature.
It was shown that the presence in the systems of a surfactant more hydrophilic than MAG caused an increase in water content
in the microemulsions. It was found that, depending on temperature and concentration of the surfactant mixture, it was possible
to obtain a W/O type microemulsion with a dispersed particles size distribution ranging from 20 to 50 nm and containing about
17–38% water in the system. Among different alkanes (from C12 to C16), hexadecane embedded microemulsions showed a maximum
water solubilization capacity. 相似文献
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Nonionic microemulsions containing triglycerides and fatty acid esters as lipophilic components have been studied. The phase
inversion temperature (PIT) of the systems was determined by a conductometric method. Partial phase diagrams were constructed
in the phase inversion temperature range. Water solubilization capacity of the nonionic surfactant systems studied was dependent
on surfactant and oil types in analogy to ordinary hydrocarbon systems. The PIT:s increased with increased molecular weight
for both esters and triglycerides. 相似文献
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For oil sand extractions with microemulsions it is important to disperse large quantities of light hydrocarbons in an aqueous medium. Fundamental studies on the properties of 2-butoxyethanol (BE) and diethylmethylamine (Et2McN) in water suggest that these two liquids could be more effective cosurfactants than the usual alcohols used for this purpose. The phase diagrams of microemulsions using BE and Et2MeN as cosurfactants, combined with typical ionic and non-ionic surfactants and typical aliphatic and aromatic hydrocarbons, were therefore investigated and compared with microemulsions based on n-butanol. Although the phase diagrams depend significantly on the nature of the surfactant and of the oil, the monophasic region generally increases with the cosurfactant in the order n-butanol < Et2McN < BE. With the active mixture BE-cetyltrimethylammonium bromide, temperature has little effect on the phase diagram and NaCl generally destabilizes the microemulsion. 相似文献
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The effect of type of self-assembled system and pH on the efficiency of corrosion inhibition of carbon-steel surfaces 总被引:1,自引:0,他引:1
Erileide Cavalcanti Roberto Alcides de Oliveira Wanderley Neto Carlos Alberto Martínez-Huitle José Luís Cardozo Fonseca Tereza Neuma de Castro Dantas Alexandre Gurgel 《Progress in Organic Coatings》2013
In this work, three surfactants were used in the preparation of self-assembled systems to inhibit acidic corrosion on API5LX Gr X52 carbon-steel surfaces: CTAB (a cationic surfactant), SDS (an anionic surfactant), and C12E9 (a non-ionic surfactant). These surfactants were used in the form of aqueous solutions and in microemulsions. Pseudoternary diagrams were constructed using aqueous phases consisting of 0.5 M NaCl at pH = 2, 4 and 7, butan-1-ol as co-surfactant and kerosene as oil phase. The values of c.m.c., maximum surface excess, minimum surfactant cross-sectional area and free energy of micellization were determined using surface tensiometry. The distinct effects of pH and type of self-assembled system on the efficiency of corrosion inhibition have been elucidated by electrochemical techniques (polarization and Tafel curves). It has been demonstrated that these parameters can significantly affect the results, which depend largely on the mechanism of aggregate adsorption on the metal surface and droplet stability. By establishing the optimal conditions, excellent corrosion efficiencies were found for these systems, even at low surfactant concentrations. 相似文献
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Reverse water/oil (w/o) microemulsions composed of epoxy resin (EP) (the oil phase) and nonionic surfactant and ammonia aqueous solutions (the water phase) were used in the synthesis of SiO2/EP nanocomposites. The stability of reverse microemulsion was evaluated by measuring water solubilization of the microemulsion. Effects of surfactant type and content, ammonia concentration and temperature on the water solubilization were systematically investigated. Higher water solubilization capacity was obtained by nonionic surfactant TX‐100 compared with other two surfactants, Span‐80 and Tween‐80. Ammonia concentration of 5 wt% and preparation temperature at 35°C were favorable for forming a stable microemulsion and enabling the subsequent hydrolysis and condensation reaction of inorganic precursor tetraethoxysilane (TEOS). SiO2/ epoxy nanocomposites were prepared via in situ polymerization of TEOS within the nanoscale reverse microemulsion “water pool”. FTIR, SEM, and universal testing machine were used to characterize the structural and mechanical properties of the composite. The results revealed that the optimal mechanical properties were obtained at 3 wt% TEOS content. Compared with neat epoxy resin, the tensile and flexural strength of the composite were 40% and 12% higher, respectively. The formation of the silica structure in the hybrid was investigated with FTIR. The SEM and optical observations showed a ductile fracture morphology and good miscibility between inorganic and organic phases. POLYM. COMPOS., 35:1388–1394, 2014. © 2013 Society of Plastics Engineers 相似文献
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Olive oil microemulsions as a biomimetic medium for enzymatic studies: Oxidation of oleuropein 总被引:1,自引:0,他引:1
Microemulsions consisting of olive oil as the non-polar solvent, lecithin as surfactant, 1-propanol as cosurfactant, and water
were prepared. The choice of the compositions of the microemulsions used was based on the pseudo-ternary phase diagrams of
the system determined at 30°C, for different weight ratios of lecithin/olive oil. Lecithin solubilization and water incorporation
in these microemulsion systems was limited. Tyrosinase, an oxidizing enzyme present in olives, was successfully incorporated
in the water core of these microemulsions. Enzymatic oxidation of oleuropein, the most abundant olive phenolic compound, in
the restricted aqueous environment of olive oil microemulsions was studied. Formation of oleuropein oxidation products was
followed spectrophotometrically at 30°C for several minutes. An absorption maximum was observed at 415 nm. When the enzymatic
reaction was considered at different tyrosinase and oleuropein concentrations, a rapid inactivation of the enzyme was observed.
Addition of l-proline as a coupling reactor did not succeed in preventing enzyme inactivation in the microemulsions, probably owing to
substrate localization and product accumulation around the entrapped enzyme molecules in the micellar interface. 相似文献