共查询到19条相似文献,搜索用时 109 毫秒
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非离子型表面活性剂TO的合成韩俐伟,王俊峰.吴青,李丽君SYNTHESISOFNON-IONSURFACEACTTVEAGENTTO通过对造纸废液妥尔油进行化学反应分离或采用薄膜闪蒸分离,提取脂肪酸、树脂酸与环氧乙烷反应,合成一种新型非离子表面活性剂... 相似文献
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制备了一种耐温抗盐高性能表面活性剂NHJ,并经试验评价了NHJ表面活性剂界面张力性能、耐温抗盐性能、表面张力性能、与地层水适应性能及洗油性能。评价结果表明,w(NHJ)0.3%溶液可使原油界面张力降低到10-2 mN/m数量级,抗温性能达80℃,抗矿化度达8×104 mg/L,抗Ca2+达4 000 mg/L,w(NHJ)0.3%溶液表面张力为21.24 mN/m,与地层水具有良好适应性,洗油率达到45%。 相似文献
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以二乙醇胺与顺丁烯二酸酐为原料合成了超支化不饱和聚(酰胺-酯)(HP)。通过琥珀酸单十二酰胺磺酸与HP端羟基的酯化反应得到阴-非离子型超支化表面活性剂(HPSA),用FTIR、~1HNMR和GPC对其结构进行了表征,并对HPSA的临界胶束浓度、表/界面张力、润湿性能、高温高盐下抗老化性能、乳化性能及驱油能力进行了测定。结果表明:HPSA具有较低的临界胶束质量浓度(0.162 g/L)、较好的表/界面活性(γ_(CMC)=25.1 mN/m,δ_(CMC)=0.077 mN/m)及抗老化性能[ρ(NaCl)=2×10~(5 )mg/L,150℃时,老化15 d表面张力约为25 mN/m]。润湿性能结果表明:HPSA具有较好的润湿性能以及润湿反转性能。乳化性能结果说明:HPSA乳化性能与十二烷基磺酸钠相当,但其乳化抗盐能力[ρ(Na Cl)=8×10~(4 )mg/L,ρ(CaCl_2)=1×10~(4 )mg/L]较十二烷基磺酸钠优异。填砂管驱油实验结果表明:注入体积为0.5PV时,0.3 g/L的HPSA可在水驱基础上提高采收率约5.3%。HPSA可以作为高温高盐油田驱油剂使用。 相似文献
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双子型表面活性剂是两个结构相同或不同的表面活性剂分子通过联接基团连接而成分子.其中至少含有两个疏水链和两个亲水基团(离子或极性基团),双子表面活性剂的特殊结构使得其性质也比较特殊,如低的CMC、较好的润湿性、更好的分散力、溶解性、泡沫力和相行为等优良的性能日,使得其广泛应用于杀菌、环保、造纸、选矿、采油等方面。 相似文献
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以三氯氧磷、二元醇(酚)、正十二醇为原料,合成了4种双十二烷基双磷酸酯(HDP,DGDP,BDP,PDP)。产物经无水乙醇重结晶提纯后,通过IR、1HNMR、质谱和电位滴定进行了结构表征。25℃时,它们的电离常数分别为:2.76×10-5mol/L(HDP),3.940×10-4mol/L(DGDP),1.595×10-4mol/L(BDP),4.255×10-3mol/L(PDP)。20℃时,它们的临界胶束浓度分别为:3.5×10-4mol/L(HDP),9.0×10-4mol/L(DGDP),1.1×10-3mol/L(BDP),1.3×10-3mol/L(PDP);在临界胶束浓度处的表面张力分别为:30.38 mN/m(HDP),34.49 mN/m(DGDP),35.31 mN/m(BDP),36.14 mN/m(PDP)。差热分析表明,4种产物的分解温度分别为:231℃(BDP),251℃(HDP),227℃(PDP),249℃(DGDP);初熔温度分别为:87℃(BDP),80℃(HDP),97℃(PDP),72℃(DGDP)。 相似文献
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居贝特表面活性剂的合成和表面性质研究 总被引:1,自引:1,他引:0
以短碳链辛醇为起始原料制备了具有Guerbet结构的十六烷基失水甘油醚(Ⅰ)和具有Guerbet结构的十六烷基聚氧乙烯醚(EO)3的失水甘油醚(Ⅱ)以及它们对应的阳离子和两性离子表面活性剂(Ⅲ~Ⅵ)。Ⅲ~Ⅵ表面活性剂的结构如下:N-(3-支链十六烷氧基-2-羟丙基)-N,N,N-三甲基氯化铵(Ⅲ),N-〔3-支链十六烷基聚氧乙烯醚(EO)3-2-羟丙基〕-N,N,N-三甲基氯化铵(Ⅳ),N-(3-支链十六烷氧基-2-羟丙基)-N,N-二甲基羧酸甜菜碱(Ⅴ),N-〔3-支链十六烷基聚氧乙烯醚(EO)3-2-羟丙基〕-N,N-二甲基羧酸甜菜碱(Ⅵ)。通过硅胶柱色谱分离和重结晶,对所得6种化合物进行了纯化。用IR、1HNMR和ESI-MS鉴定了Ⅰ~Ⅵ的结构。并对Ⅲ~Ⅵ的表面张力进行了测定。结果表明,由于这些表面活性剂具有独特的Guerbet亲油基结构,使其具有较低的CMC(10-5~10-6mol/L)和γCMC(25~27 mN/m),有良好的表面活性和应用潜力。 相似文献
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酯基Gemini型季铵盐表面活性剂的合成与性能 总被引:2,自引:0,他引:2
合成了一系列酯基Gemini型季铵盐表面活性剂烷基-α,ω-双(二甲基酰氧乙基溴化铵),标记为II-m-n(m=12,14;n=3,4,6);采用红外光谱和核磁共振进行结构表征.测定了相关的性能,结果表明,酯基Gemini型季铵盐表面活性剂具有很强的胶束生成能力,其临界胶束浓度(cmc)为2.63×10-4~ 4.17×10-4 mol·L-1(m=12)及2.88×10-5~ 4.46×10-5 mol·L-1(m=14),分别比相应的单季铵盐表面活性剂的临界胶束浓度低两个数量级;其泡沫稳定性、乳化性能和杀菌性明显优于相应的单季铵盐表面活性剂. 相似文献
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The synthesis of a homologous series of alanine-based surfactants, namely sodium salts of n-alkanesulfonamido-2-propanoic acids in which n-alkane is n-dodecane, n-tetradecane, n–hexadecane, and n-octadecane having the formula RSO2NHCH (CH3)COO?Na+, is described. The starting materials used were a mixture of secondary positional isomers of n-alkanesulfonyl chlorides obtained by photosulfochlorination reaction using sulfuryl chloride and a catalyst. Surface properties of the aqueous solutions of the synthesized surfactants, including the critical micelle concentration and minimal surface tension δmin, were determined using surface tension measurements at 25 °C. The surface excess Γ and minimum area per molecule (A min) where calculated using the Gibbs equation. The foaming power was also determined by the Bartsh method, and the R 5 parameter was calculated to estimate the stability of the foam formed. The results obtained were compared to those of a commercial surfactant, sodium dodecylsulfate, and a series of synthesized glycine-based surfactants. The results obtained clearly show that the alanine-based surfactants possess good surface properties. The investigations highlight the influence on the surface properties of the addition of a methyl group in the hydrophilic part. 相似文献
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A series of novel dissymmetric gemini cationics surfactants was synthesized by three-step reactions. The dissymmetric gemini
surfactants contain a dodecanoic acid dimethylethylamine ester as the constant cationic part on one side of the hydroxypropyl
center and a similar other cationic part, but with a different acid length (from octanoic to palmitic), on the other side.
The critical micelle concentration (CMC) and the effectiveness of surface tension reduction (γ
CMC) were determined. The surface tension measurements of dissymmetric gemini surfactants showed good water solubility, and low
CMC had great efficiency in lowering the surface tension and a strong adsorption at the air/water interface. The CMC was observed
to increase initially with the increase of the ester bond alkyl group. They also showed good foaming properties and wetting
capabilites. 相似文献
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A series of novel dissymmetric gemini surfactants, [C m H2m+1COOC2H4(CH3)2N(CH2)3N(CH3)2C2H4OOCC n H2n+1]Br2 was synthesized and symbolized as m-s–n. The Krafft temperatures and surface tension curves of the dissymmetric gemini surfactants were measured using an electrical conductivity method and a drop volume method. The low Krafft temperatures indicate very good solubility of these esterquat gemini surfactants. With the increasing numbers of carbon atoms in the hydrophobic alkyl chain, the critical micelle concentration (CMC) and the minimum surface area (A min) decrease, and the efficiency of surface tension reduction (pc20) increases. With the same numbers of carbon atoms in the hydrophobic alkyl chain, the dissymmetric gemini surfactant has a lower CMC and a smaller A min than the corresponding symmetric gemini surfactant due to the enhanced hydrophobic interactions. 相似文献