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天然气常压无催化剂部分氧化法造气试验 总被引:1,自引:1,他引:0
该厂在油头改为气头的改扩建工程中,进行了天然气常压无催化剂部分氧化法造气试验,试验结果表明此法工艺简单、技术可靠、投资少、见效快,具有经济效益、环境效益。 相似文献
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二氧化氯催化氧化处理农药废水的研究 总被引:1,自引:0,他引:1
对在常温常压下二氧化氯催化氧化法处理农药废水进行了实验研究和工程上的实际应用,并和没有放置催化剂时单纯的二氧化氯氧化进行对比。结果表明常温常压,在表面催化剂存在的条件下,二氧化氯催化氧化在处理高浓度农药废水中,化学需氧量(chemical oxygen demand,COD)的去除率达到75%,色度的去除率达到95%。 相似文献
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钢铁酸洗废液的回收利用研究 总被引:4,自引:0,他引:4
采用直接通空气法与直接通氯气法,将Fe^2 氧化为Fe^3 探讨了最佳转化条件,认定以pH值5.5、温度80℃、常压下通空气22h直接氧化为可行,并试制出产品铁红粉,回收率为77%。 相似文献
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本文以聚乙二醇和环氧丙烷为原料,用常压法合成了一系列“氧化丙烯-氧化乙烯-氯丙烯”嵌段共聚醚,对 进行了结构表征,对反应影响因素了探讨,并对产物的表面活性性能进行了测定研究。 相似文献
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常压法防老剂4020对NR胶料热氧老化的防护 总被引:2,自引:1,他引:2
研究了常压法防老剂 40 2 0对NR胶料的硫化特性、自由状态和应力状态下的热氧老化防护性能及氧化起始温度的影响。试验结果表明 ,常压法防老剂 40 2 0对NR胶料硫化特性的影响与防老剂A、D、40 10NA和高压法40 2 0相近 ;对NR胶料的热氧老化防护性能和氧化起始温度高于防老剂A、D和高压法 40 2 0 ,与防老剂 40 10NA相近 ;在NR胶料中常压法防老剂 40 2 0的用量以 0 5~ 1 5份为宜。 相似文献
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Yi Li Xiuli Zhang Hong He Yunbo Yu Tao Yuan Zhenyu Tian Jing Wang Yuyang Li 《Applied catalysis. B, Environmental》2009,89(3-4):659-664
The catalytic oxidation of volatile organic compounds (VOCs: ethanol, 1-propanol and 2-propanol) over Ag/Al2O3 catalyst under low and normal atmospheric pressure conditions has been studied with synchrotron vacuum ultraviolet (VUV) photoionization mass spectrometry (PIMS). The partial oxidation intermediates of the VOCs under different pressures were identified by PIMS and their photoionization efficiency (PIE) spectra. Alkene is preferentially formed under the low pressure conditions, while aldehyde and acid are favored under the normal atmospheric pressure conditions. In addition, the low pressure conditions are more suitable for observing the active intermediates, such as ethenol, ketene and propenal. The results indicate that the pressure has a significant effect on the oxidation pathway of VOCs over Ag/Al2O3 catalyst. 相似文献
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The effect of mixing and mass transfer on polysulphide generation by catalytic oxidation of sodium sulphide was studied using two batch‐operated reactors. One was a sparged reactor operated at atmospheric pressure and low mixing intensities (0.37 to 28 W/kg), the other was an unsparged pressurized reactor characterized by high mixing intensities (17 to 3100 W/kg). The reaction parameters examined included the impeller speed, sparged gas flowrate, oxygen partial pressure, and catalyst loading and type. In both reactors the maximum polysulphide yield, selectivity and rate of formation increased with increasing energy dissipation. Increased gas sparging increased the rate of reaction, but had little effect on either yield or selectivity. Increased oxygen partial pressure increased the rate of oxidation but decreased both the yield and selectivity. The type of catalyst dramatically affected the yield of polysulphide produced for a given set of reaction conditions with improved mixing increasing reaction rate, yield and selectivity. 相似文献
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Oscillatory reactions over nickel wires during the partial oxidation of methane were investigated in a tubular continuous flow reactor made of quartz at atmospheric pressure. A modified thermocouple was designed to measure the temperature while the interposed nickel coil worked as a catalyst. Significant effects on the oscillations were observed by varying the system temperature and the feed gas composition, and by cutting off one of the reactant gases temporarily. 相似文献
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Non-catalytic direct conversion of methane to valuable products was studied using non-equilibrium pulsed discharge under the conditions of ambient temperature and atmospheric pressure. Acetylene was produced with 95% selectivity and 52% methane conversion. An addition of oxygen, carbon dioxide and steam contributed significantly to suppress the carbon deposition and produced carbon monoxide as well as acetylene. Methane conversion increased with an increase in the pulse frequency while the product selectivity remained almost constant. The selectivity depended on the composition of the feed gas. The effect of the partial pressure of oxygen was examined, and it was found that the pulsed discharge would be able to produce synthesis gas by partial oxidation of methane. Carbon monoxide selectivity of 79% with methane conversion of 76% was obtained under the conditions of CH4/O2=25/25 cm3 min−1, gap distance of 10 mm and the frequency of 45 Hz. 相似文献
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Jian Xu Weisheng Wei Aizhen Tian Yu Fan Xiaojun Bao Changchun Yu 《Catalysis Today》2010,149(1-2):191-195
Detailed axial temperature distribution has been studied in a two-stage process for catalytic partial oxidation of methane to syngas, which consists of two consecutive fixed bed reactors with oxygen or air separately introduced. The first stage of the reactor, packed with a combustion catalyst, is used for catalytic combustion of methane at low initial temperature. While the second stage, filled with a partial oxidation catalyst, is used for the partial oxidation of methane to syngas. A pilot-scale reactor packed with up to 80 g combustion catalyst and 80 g partial oxidation catalyst was employed. The effects of oxygen distribution in the two sections, and gas hourly space velocity (GHSV) on the catalyst bed temperature profile, as well as conversion of methane and selectivities to syngas were investigated under atmospheric pressure. It is found that both oxygen splitting ratio and GHSV have significant influence on the temperature profile in the reactor, which can be explained by the synergetic effects of the fast exothermic oxidation reactions and the slow endothermic (steam and CO2) reforming reactions. Almost no change in activity and selectivity was observed after a stability experiment for 300 h. 相似文献
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Meshcheryakov V. D. Kirillov V. A. 《Theoretical Foundations of Chemical Engineering》2002,36(5):466-471
Variants of the Fischer–Tropsch producer-gas conversion into liquid hydrocarbons are analyzed under the assumption that thermodynamic equilibrium is attained in the reactions occurring in the biomass gasification. When the raw material is wood waste, the optimum variant of the process involves partial biomass oxidation by atmospheric oxygen with tail-gas recycling after the separation of liquid hydrocarbons. Before mixing with fresh producer gas, the hydrocarbons contained in the tail gas are reformed on a nickel catalyst. 相似文献
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The influence of an inert gas on the separation performances of a dense polymeric membrane module working under partial vacuum on the downstream side, such as possibly encountered in gas permeation, vapor permeation or pervaporation, has been investigated through an experimental and theoretical study. A whole range of situations on the downstream side, covering ideal vacuum pumping (i.e. zero downstream pressure under leak free conditions) to inert gas sweeping under atmospheric pressure has been tested. A theoretical framework, previously developed for single permeant situation has been extended to the multicomponent case. The separation of methanol and 2-propanol by a dense silicone rubber membrane confirms the ability of this simple modelling strategy to offer quantitative predictions of the permeate composition under variable downstream pressure and inert gas flowrate conditions. Based on this observation, the implications of an inert gas contribution on pervaporation or gas separation operation are discussed, particularly in relationship to the global energy consumption of the system or to analytical devices making use of a gas sweep. 相似文献
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本文针对我国以天然气为原料的小型合成氨厂采用的常压间歇蒸汽转化制气方法热效率低、能耗高等问题,提出采用加压空气部分氧化—深冷除氮的生产工艺改造这类小型氨厂。 相似文献
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The effect of gas phase O2 and reversibly adsorbed oxygen on the decomposition of CH4 and the surface state of a Ni/Al2O3 catalyst during partial oxidation of CH4 were studied using the transient response technique at atmospheric pressure and 700°C. The results show that, when the catalyst
surface is completely oxidized under experimental conditions, only a small amount of CO and H2 can be produced from non‐selective oxidation of CH4 by reversibly adsorbed oxygen which is more active in oxidizing CH4 completely than NiO via the Rideal–Eley mechanism and both the conversions of CH4 and O2 and the selectivities to CO and H2 are very low. Therefore, keeping the catalyst surface in the reduced state is the precondition of high conversion of CH4 and high selectivities to CO and H2. The surface state of the catalyst decides the reaction mechanism and plays a very important role in the conversions and
selectivities of partial oxidation of CH4. During partial oxidation of CH4, no oxygen species but a small amount of carbon exists on the catalyst surface, which is favorable for maintaining the catalyst
in the reduced state and the selectivity of CO. The results also indicate that direct oxidation is the main route for partial
oxidation of CH4, and the indirect oxidation mechanism is not able to gain dominance in the reaction under the experimental conditions.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献