共查询到20条相似文献,搜索用时 13 毫秒
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In recent years considerable progress has been made in electronic packaging substrate technology. The future need of miniaturization of devices to increase the signal processing speed calls for an increase in the device density requiring the substrates to be designed for better thermal, mechanical and electrical efficiency. Fast signal propagation with minimum delay requires the substrate to possess very low dielectric constant. Several glasses and glassceramic materials have been identified over the years which show good promise as candidate substrate materials. Among these, borophosphate and borophosphosilicate glass-ceramics have been recently identified to have the lowest dielectric constant (3.8). Sol-gel processing has been used to synthesize borosilicate, borophosphosilicate and borophosphate glasses and glass-ceramics using inexpensive boron oxide and phosphorus pentoxide precursors. Preliminary results of the processing of these gels and the effect of volatility of boron alkoxide and its modification on the gel structure are described. X-ray diffraction, differential thermal analysis and Fourier transform-infrared spectroscopy have been used to characterize the as-as-prepared and heat-treated gels. 相似文献
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A. Abdel-Kader A. A. Higazy M. M. Elkholy 《Journal of Materials Science: Materials in Electronics》1991,2(4):204-208
A range of TeO2-P2O5 and Bi2O3-TeO2-P2O5 glass systems were prepared. The optical absorption spectra were measured in the spectral range 300–800 nm and it was found that the fundamental absorption of these glasses is dependent on the glass composition. The optical energy gap of binary glasses increases with increasing TeO2 content while the addition of Bi2O3 to TeO2-P2O5 decreases the optical energy gap. The absorption edges of these glasses arise from direct forbidden transitions and occur at photon energies in the range of 2.17 to 2.97 eV for TeO2-P2O5 glasses and 2.63 to 2.32 eV for Bi2O3-TeO2-P2O5 glasses depending on their composition. 相似文献
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ThexB2O3 · (20-x) P2O5 · 80SiO2 (in mol%) glass films withx=0, 10 and 20 have been prepared from metal alkoxides by carrying out the coating in a dry atmosphere. These coating films have shown a larger value of load at scratch and a smaller shrinkage during heat-treatment by replacing P2O5 in the films with B2O3. It has been found that B2O3 more effectively reduces the glass transition temperature of SiO2 glass than P2O5. The concentrations of sodium ions, which migrated from soda-lime-silica glass substrates during the film formation, were higher in phosphosilicate and borophosphosilicate films than in borosilicate and pure silica films. This finding should be ascribed to the gettering effects of phosphorus for sodium ions. 相似文献
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在锌硼硅玻璃中添加0%~20%(wt)的超细部分稳定氧化锆粉体,分别采用熔融法和烧结法制备氧化锆/锌硼硅微晶玻璃。通过对实验现象的观测与分析,发现采用烧结法可以较好地制备氧化锆/锌硼硅微晶玻璃。采用X射线衍射仪观测玻璃样品中的晶相组成,用烧结点试验仪测试微晶玻璃的半球温度,通过维氏硬度计在玻璃表面的压痕尺寸计算微晶玻璃的韧性。结果表明,在ZnO-B2O3-SiO2玻璃中添加部分稳定超细ZrO2后,微晶玻璃的烧结温度升高,韧性得到很大的改善。 相似文献
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A. Abdel-Kader A. A. Higazy M. M. Elkholy 《Journal of Materials Science: Materials in Electronics》1991,2(3):157-163
The infrared absorption spectra of the vitreous TeO2-P2O5 and Bi2O3-TeO2-P2O5 systems are studied in the spectral region of 4000 to 200 cm–1. Absorption bands in this range are assigned. The midband wavenumber and the absorption intensity for the attributed bands are found to be strongly and systematically dependent on glass composition. Quantitative analysis was also attempted to justify our attribution of the observed bands. 相似文献
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Yajun Qi Zhiqiang Wang Shangru Zhai Shuwen Jiang Hai Lin 《Materials Science-Poland》2014,32(3):414-418
The influence of ZnO substitution by 0–12 wt.% Na2O on the properties of ZnO-Sb2O3-P2O5-Na2O glasses has been investigated. The structure and properties of the glasses with the composition of (13.86-x)ZnO-57.93Sb2O3-28.21P2O5?x Na2O (x = 0–12 wt.%) were characterized by infrared spectra (IR), X-ray diffraction and differential thermal analysis (DTA). The results of IR indicated an increase in the intensity of symmetric vibrations of P-O-P bond, which was confirmed by the improvement of water durability with the increasing amount of Na2O in the range of 0–10 wt.%. Substitution of 10 wt.% Na2O led to the weight loss of the glass to 5.93 mg/cm?2 after immersion in deionized water at 50 °C for 24 h. The results of XRD showed that the ability of crystallization decreased, indicating the good thermal stability of the glass. The glass containing 8 wt.% Na2O had the best properties in every respect and might be an alternative to lead based glasses for the applications, providing further composition improvement. 相似文献
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