Gas-sensing property and mechanism of CaxLa1−xFeO3 ceramics

LaFEO₃ and Ca_xLa_1−xFeO₃ ceramic powders have been prepared by the coprecipitation method from La(NO₃)₃, Fe(NO₃)₃ and Ca(NO₃)₂ aqueous solutions. The orthorhombic perovskite phases of LaFeO₃ and Ca_xLa_1−xFeO₃ are characterized by X-ray diffraction patterns. The sensors fabricated with those powders have high sensitivity to alcohol. Partial substitution of La³⁺ in LaFeO₃ with Ca²⁺ can enhance the sensitivity of the materials to reducing gases. The resistance of an LaFeO₃ sensor in air, vacuum and alcohol-containing air has been measured. Complex impedance spectroscopy has been used to try and analyse the gas-sensing mechanism. According to the experimental results, it can be deduced that the surface adsorptive and lattice oxygen govern the sensing properties of LaFeO₃ and Ca_xLa_1−xFeO₃ ceramics.     

Correlation between carrier porous structure and gas-sensitive properties of thermocatalytic gas sensors

In order to determine the correlation between the gas-sensitive properties of the thermocatalytic gas sensor (TGS) and the porous structure of the carrier, two types of carriers have been investigated. Their sorptional parameters at different calcination temperatures have been studied. The parameters of the porous structure and the gas-sensitive properties of the TGS are characterized by measurements of benzene vapour adsorption and methane oxidation using methane/air mixtures, respectively. The obtained data indicate that the sensitivity of the TGS is related in some way with the structural parameters of the carrier (pore size and diameter distribution). Carriers must have a sorption capacity no less than 0.30 cm³ g⁻¹, surface area of 100–140 m² g⁻¹ and possess biporous pore-volume size distribution.     

An experimental study of Love-wave acoustic sensors operating in liquids

It has been shown that properly designed Love-wave acoustic sensors are very promising for sensing in gaseous and liquid environments because of their high sensitivity. Since Love-wave devices do not incur a radiative loss when used in a liquid, they have many potential applications in biosensing. We have successfully manufactured a range of 40 μm wavelength Love-wave devices based on SiO₂/ST-quartz, with the SiO₂ thickness ranging from 0 to 7.3 μm. The relationship of the mass-loading sensitivity to the thickness of the SiO₂ layer has been obtained experimentally. High sensitivity (≥ 300 cm⁻² g⁻¹) is achieved at an SiO₂ thickness between 3.5 and 6.5 μm. The Love-wave oscillators have operated efficiently in various liquids with excellent stability and low noise. In this paper, we report the experimental results for the devices operating in various liquids. The mass sensitivity, insertion loss, oscillation frequency stability, noise level, liquid viscous loading and acoustoelectric coupling have been studied. The influence of the thickness of the SiO₂ layer on some of these properties has also been investigated.     

High-resolution high-voltage sensor based on SAW

A surface acoustic wave (SAW)-based high-voltage sensor is described. The sensor consists of a SAW oscillator fabricated on a 10 mm × 10 mm 128° rotated Y-cut, X-propagating LiNbO₃ substrate. The voltage is applied to electrodes on the substrate, and the resulting electric field changes the propagation time of the SAW. The propagation time is directly related to the output frequency of the SAW oscillator. The high-voltage sensor offers a small-sized high-voltage measurement device with several attractive features: a high resolution (better than 0.2 V up to 2.4 kV, better than 0.4 V for higher voltages), a large range (−10 to +10 kV), a high input impedance (> 10¹³ ω) and a low input capacitance (< 10 pF). The sensitivity amounts to 16 Hz V⁻¹.     

Integrated optical pH sensor using replicated chirped grating coupler sensor chips

Integrated optical sensor chips suitable for high-resolution pH measurements are presented. The pH-sensitive swelling of a polymer membrane is detected by refractometry using a compact multi-channel sensor module. The signal transduction is achieved by means of chirped grating couplers which allow simple yet high functionality sensor modules to be built. The experiments have been performed with high sensitivity replicated polycarbonate TiO₂ waveguide sensor chips coated with an ultrathin photopatterned hydrogel membrane having functional groups which reversibly change from the neutral state to a charged state upon acidification. A resolution δpH <±1.1×10⁻⁴ in terms of the pH (at pH 7.5) has been obtained in a dual-channel module with size 10×10×10 cm³.     

Metallic thin-film thermocouple for thermoelectric microgenerators

A new metallic thin-film thermocouple orientated towards thermoelectric microgenerators has been developed. It consists of a 3 μm thick NiCr/SiO₂/Sb multilayer structure sputter deposited onto a thermally oxidized silicon substrate. A relative Seebeck coefficient of _ab = 76 μV K⁻¹ and an optimal figure of merit of z_ab = 0.08 × 10⁻³ K⁻¹ have been measured for this material combination. Both parameters are very close to the theoretical values.     

Simulation and fabrication of piezoresistive membrane type MEMS strain sensors

Two piezoresistive (n-polysilicon) strain sensors on a thin Si₃N₄/SiO₂ membrane with improved sensitivity were successfully fabricated by using MEMS technology. The primary difference between the two designs was the number of strips of the polysilicon patterns. For each design, a doped n-polysilicon sensing element was patterned over a thin 3 μm Si₃N₄/SiO₂ membrane. A 1000×1000 μm² window in the silicon wafer was etched to free the thin membrane from the silicon wafer. The intent of this design was to fabricate a flexible MEMS strain sensor similar in function to a commercial metal foil strain gage. A finite element model of this geometry indicates that strains in the membrane will be higher than strains in the surrounding silicon. The values of nominal resistance of the single strip sensor and the multi-strip sensor were 4.6 and 8.6 kΩ, respectively. To evaluate thermal stability and sensing characteristics, the temperature coefficient of resistance [TCR=(ΔR/R₀)/ΔT] and the gage factor [GF=(ΔR/R₀)/] for each design were evaluated. The sensors were heated on a hot plate to measure the TCR. The sensors were embedded in a vinyl ester epoxy plate to determine the sensor sensitivity. The TCR was 7.5×10⁻⁴ and 9.5×10⁻⁴/°C for the single strip and the multi-strip pattern sensors. The gage factor was as high as 15 (bending) and 13 (tension) for the single strip sensor, and 4 (bending) and 21 (tension) for the multi-strip sensor. The sensitivity of these MEMS sensors is much higher than the sensitivity of commercial metal foil strain gages and strain gage alloys.     

Determination of reduced glutathione using an amperometric carbon paste electrode chemically modified with TTF–TCNQ

The development of an amperometric sensor for the determination of reduced glutathione (GSH) is described. The sensor is based on tetrathiafulvalene–tetracyanoquinodimethane (TTF–TCNQ) incorporated into the graphite powder/Nujol oil matrix. The electrooxidation of GSH was monitored amperometrically at 200 mV versus SCE (saturated calomel electrode). The amperometric response of the sensor was linearly proportional to the GSH concentration between 20 and 300 μmol l⁻¹, in 0.1 mol l⁻¹ phosphate buffer (pH 8.0), containing 0.1 mol l⁻¹ KCl and 0.5 mmol l⁻¹ Na₂H₂EDTA, as supporting electrolyte.

The detection limit, considering signal/noise ratio equal three, was 4.2 μmol l⁻¹ for GSH and the repeatability obtained as relative standard deviation was of 5.1% for a series of 10 successive measurements.     

Development of a bienzyme system based on sugar–lectin biospecific interactions for amperometric determination of phenols and aromatic amines

Bienzyme electrode with horseradish peroxidase (HRP) and glucose oxidase (GOD) multilayers was constructed based on sugar–lectin biospecific interactions for amperometric determination of phenolic compounds and aromatic amines. Atomic force microscopy (AFM) was applied to monitor the uniform layer-by-layer assembly of concanavalin A (Con A) and HRP or GOD on polyelectrolyte precursor film-modified Au electrode. Substituted phenolic compounds and aromatic amines could be determined with in situ generation of H₂O₂ by GOD-catalyzed oxidation of glucose. The parameters of the biosensor including the number of assembled HRP and GOD layer, and the concentrations of glucose were optimized. The linear range for the determination of catechol and p-phenyldiamine was 6.0–60.0 μmol L⁻¹ and 7.6–68.4 μmol L⁻¹ with detection limit of 0.9 μmol L⁻¹ and 0.4 μmol L⁻¹, respectively. The biosensor possessed high sensitivity and fast response for phenolic compounds and 95% of the maximum response could be reached in about 3 s. Glucose, ascorbic acid, tartaric acid, citric acid and starch exhibited no interference for the detection. The biosensor presented high stability due to the design for in situ generation of H₂O₂ with bienzyme system.     

Scaled rotation regularization

A new regularization method - a scaled rotation - is proposed and compared with the standard linear regularized discriminant analysis. A sense of the method consists in the singular value decomposition S=TDT′ of a sample covariance matrix S and a use of the following representation of an inverse of the covariance matrix S⁻¹=T(D+λI)⁻¹T ′. For certain data structures the scaled rotation helps to reduce the generalization error in small learning-set and high dimensionality cases. Efficacy of the scaled rotation increases if one transforms the data by y=(D+λI)^−1/2T ′x and uses an optimally stopped single layer perceptron classifier afterwards.     

A fibre-optic oxygen sensor based on contact charge-transfer absorption

A fibre-optic oxygen (O₂) sensor monitoring at a wavelength of 400 nm has been successfully developed for the determination of gaseous O₂. Its working principle is based on the contact charge-transfer absorption of N,N-dimethyl-p-toluidine and O₂. The response to changes in O₂ concentrations is reversible and in good agreement with the Beer-Lambert law. The response and recovery times are 12 and 26 min, respectively. The sensor can detect a wide range of O₂ concentrations, ranging from 4.3 to 100% O₂. The precision is 1.45% (n=5) in a gas mixture of 95% O₂ in N₂ and the limit of detection is 4.3% O₂ (3σ_b). The sensor is stable with a 0.53% change in sensitivity per hour. There is a 0.25% °C⁻¹ decrease of the sensitivity of the sensor to O₂ in the range 20–34°C. Water vapour and nitrogen dioxide interfere slightly, whereas hydrogen sulphide and hydrogen chloride have moderate interference on the sensor. However, chlorine and sulphur dioxide seriously interfere with the sensor.     

Four-moduli set (2, 2−1, 2+2−1, 2+2−1) simplies the residue to binary converters based on CRT II

A multiplier-free residue to binary converter architecture based on the Chinese remainder theorem II (CRT II) [1] is presented. The paper also includes a binary to residue converter. This is achieved by introducing a new moduli set (2, 2ⁿ − 1, 2ⁿ + 2ⁿ⁻¹ − 1, 2ⁿ⁺¹ + 2ⁿ − 1) for RNS application. The complexity of conversion has been greatly reduced using CRT II with the new moduli set. The proposed hardware architecture replaces the necessary multiplication by shift-left operations. A similar hardware architecture is presented for the binary to residue conversion.     

Computerized formal solutions of dynamical systems with two degrees of freedom and an application to the Contopoulos potential—II : The near-resonance case

The article describes the periodic solutions of the Contopoulos system for the case of near-resonant frequencies (ω₂² = 1 and ω = 1 − ε²² The Lindstedt method is used throughout with all the literal algebraic manipulations being computerized so that all expansions are carried to the fourth order in the small parameter ε.

It is shown that each of the two normal modes of oscillation has a bifurcation (really trifurcation) point which moves towards the origin when the exact resonance is approached, explaining why the one-to-one resonant Contopoulos system has six modes of periodic oscillations near the origin, rather then the usual number of two.

We give a single Lindstedt-type literal expansion which is valid for the three intersecting families of periodic solutions. This expansion contains two constants, A and D, representing the direct and retrograde circulations C⁺ and C⁻ when both constants are non-zero and the vertical normal mode family when A = 0.

The verifications of the analytical results by numerical integrations are also given.     

Development of a highly sensitive and selective optical chemical sensor for batch and flow-through determination of mercury ion

A very sensitive, highly selective and reversible optical chemical sensor (optode) for mercury ion is described. The sensor is based on the interaction of Hg²⁺ with 2-mercapto-2-thiazoline (MTZ) in plasticized PVC membrane incorporating a proton-selective chromoionophore (ETH5294) and lipophilic anionic sites (sodium tetraphenylborate, NaTPB). The membranes were cast onto glass substrates and used for the determination of mercury ion in aqueous solutions by batch and flow-through methods. The sensor could be used in the range 2.0 × 10⁻¹⁰ to 1.5 × 10⁻⁵ M (0.04 ng mL⁻¹ to 3 μg mL⁻¹) Hg²⁺ with a detection limit of 5.0 × 10⁻¹¹ M and a response time of <40 s. It can be easily and completely regenerated by dilute nitric acid solution. The sensor has been incorporated into a home-made flow-through cell for determination of mercury ion in flowing streams with improved sensitivity, precision and detection limit. The sensor showed excellent selectivity for Hg²⁺ with respect to several common alkali, alkaline earth and transition metal ions. The results obtained for the determination of mercury ion in river water samples using the proposed optode was found to be comparable with the well-established cold-vapor atomic absorption method.     

Pyroelectric thin-film sensor array

Pyroelectric thin-film point detectors and 1 × 12 arrays have been fabricated and characterized. They consist of sol-gel-deposited PZT thin-film elements on micromachined Si₃N₄/SiO₂ membranes. The measured current and voltage response as a function of modulation frequency of a 1 × 12 array element is compared with finite-element calculations. Voltage responsivities of almost 3000 V W⁻¹ in vacuum and 800 V W⁻¹ in air have been achieved for 0.4 mm × 0.9 mm elements. Some point detectors have been completely packaged and correct operation in a movement detection system has been demonstrated.     

A simple solution to the l optimization problem

It is pointed out in this brief paper that the l¹ optimization problem min_{Q ε lqp¹} | H − U * Q * V |₁, H ε l_mn¹, U ε l_mq¹, V ε l_pn¹ can be solved in one step rather than two. The solution of the dual problem is obviated by the direct solution of the primal problem via linear programming. The method here is applicable to finite-dimensional problems or approximating finite-dimensional problems, in the general case.     

Thermal expansion of Chromium (Cr) to melting temperature

In situ x-ray data on molar volumes of chromium have been collected over the temperature range from 300 K to melting. The sample was heated to melting by passing an electrical current through the sample (the technique of electrical resistance wire heating). The sample consists of a tungsten wire as a heater and a mixture of Cr and W powder, which is placed in a hole of 250 μm diameter. Tungsten was used as an internal standard for temperature determination. In order to prevent the specimen from oxidation, the experiments were carried out in an argon flow. Unit cell parameters of Cr at different temperatures were calculated using (110), (200), (211), and (220) reflections. Precision of determination of lattice parameter is 10⁻⁴ A at 300 K and 5 10⁻⁴ A at 2000 K. Thermal expansion of Cr increases rapidly at temperatures higher than 1200 K. The linear thermal expansion () of chromium between 300 and 2130 K is given by: = 1.220(5) 10⁻⁵ − 1.150(6) 10⁻⁸ T + 1.132(8) 10⁻⁶ T² − 0.507(7)/T² (T, K). In our experiments, Cr melted between 2120 and 2150 K.     

Fabrication of improved piezoresistive silicon cantilever probes for the atomic force microscope

This paper describes an improved design for a monolithic silicon atomic force microscope (AFM) probe using piezoresistive sensing. The probe is V shaped, with a sharp tip at the free end and two piezoresistors at the root, and is fabricated using silicon-on-insulator (SOI) starting material. The maximum sensitivity of the AFM probe is measured to be 4.0(± 0.1) × 10⁻⁷ Å⁻¹, which is larger than that of the previous parallel-arm piezoresistive AFM probe. The measured results are in reasonable agreement with the values predicted by theory. The minimum detectable force and minimum detectable deflection of the AFM probes are predicted to be 1.0 × 10⁻¹⁰ N and 0.29 Å_r.m.s., respectively, using a Wheatstone bridge arrangement biased at a voltage of ± 5 V and bandwidth of 10 Hz–1 kHz.     

On the type of a polynomial f, when f(0)f−f(0)f is a monomial

A polynomial is said to be of type (p₁, p₂, p₃) relative to a directed line in the complex plane if, counting multiplicities, it has p₁ zeros to the left of, p₂ zeros on, and p₃ zeros to the right of the line. In this paper we determine explicitly the types of all polynomials belonging to a very restricted (but infinite) family of polynomials. A polynomial ƒ belongs to this family if and only if its coefficients are such that the polynomial ƒ^*(0)ƒ(z)−ƒ(0) ƒ^*(z) is a monomial; here ƒ^* denotes the reflection of ƒ in the directed line.

A special case of the present result appeared in an earlier publication.