共查询到20条相似文献,搜索用时 31 毫秒
1.
Polysaccharide based graft copolymer (xanthan gum‐g‐4‐vinyl pyridine) was synthesized using potassium peroxymonosulphate/ascorbic acid redox initiator in inert atmosphere at 40°C. By studying the effect of the concentration of monomer, peroxymonosulphate (PMS), ascorbic acid (AA), xanthan gum (XOH), hydrogen ion along with effect of time and temperature on grafting characteristics: grafting ratio (%G), add on (%A), conversion (%C), efficiency (%E), homopolymer (%H), and rate of grafting (Rg), the reaction conditions for optimum grafting were determined. The optimum concentration of AA, H+ ion, 4‐VP for maximum grafting were found to be 10.0 × 10?3 mol dm?3, 2.5 × 10?2 mol dm?3, 10.0 × 10?3 mol dm?3, respectively. Maximum %G was obtained at minimum concentration of xanthan gum i.e., at 40.0 × 10?2 g dm?3 and at maximum concentration of PMS i.e., at 10.0 × 10?3 mol dm?3. The optimum temperature and time duration of reaction for maximum % of grafting were found to be 45°C and 120 min respectively. The synthesized graft copolymer was characterized by FTIR analysis. Thermogravimetric analysis showed that the xanthan gum‐g‐4‐vinyl pyridine is thermally more stable than pure gum. A probable mechanism was suggested for the graft copolymerization. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
2.
The graft copolymer of xanthan gum with methacrylic acid was synthesized in inert atmosphere by using Fentos reagent as a redox initiator. The effect of reaction conditions on grafting parameters [G(%), E(%), C(%), A(%), H(%), and Rg] was investigated. Similar trend was observed on increasing the concentration of ferrous ion and hydrogen peroxide from 4.0 to 20.0 × 10?3 mol dm?3 and 2.5 to 10 × 10?3 mol dm?3 respectively, i.e., initially grafting parameters increased and after a certain range of concentration grafting parameters showed decreasing trend. Hydrogen ion shows influenced result i.e., small increment of concentration in hydrogen ion presents much increment in percent of grafting. It was observed that the [G(%), E(%), C(%), A(%), and Rg] increased upto 6.67 × 10?2 mol dm?3 concentration of methacylic acid after that it decreased. Maximum G(%) was obtained at minimum concentration of xanthan gum i.e., at 40 × 10?2 g dm?3. The optimum temperature and time duration of reaction for maximum percentage of grafting were found to be 45°C and 150 min respectively. Thermogravimetric analysis showed that the xanthan gum‐g‐methacrylic acid is thermally more stable than pure gum. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
3.
This article describes the graft copolymerization of poly(methyl methacrylate) (PMMA) onto oil‐palm empty fruit bunches (OPEFBs) with a fiber length of less than 75 μm. The graft copolymerization was carried out under a nitrogen atmosphere by a free‐radical initiation technique in an aqueous medium. Hydrogen peroxide and ferrous ions were used as a redox initiator/cocatalyst system. The PMMA homopolymer that formed during the reaction was removed from the grafted copolymers by Soxhlet extraction. Determining the effects of the reaction period, reaction temperature, and monomer concentration on the grafting percentage was the main objective, and they were investigated systematically. The optimum reaction period, reaction temperature, monomer concentration, and initiator concentration were 60 min, 50°C, 47.15 × 10?3 mol, and 3.92 × 10?3 mol, respectively. The maximum percentage of grafting achieved under these optimum conditions was 173%. The presence of PMMA functional groups on OPEFB and the enormous reduction of the hydroxyl‐group absorption band in PMMA‐g‐OPEFB spectra provided evidence of the successful grafting reaction. The improvement of the thermal stability of PMMA‐g‐OPEFB also showed the optimal achievement of the grafting reaction of PMMA onto OPEFB. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
4.
A previously unreported graft copolymer of xanthan gum (XOH) with acrylic acid was synthesized and the reaction conditions were optimized using a potassium monopersulfate (PMS)/Fe2+ redox pair. Grafting ratio, add on, and conversion increase with an increase in the ferrous ion concentration (2.0 × 10?3 to 5.0 × 10?3 mol dm?3) and PMS concentration (1.0 × 10?3 to 4.0 × 10?3 mol dm?3). It was observed that grafting takes place efficiently when the acrylic acid concentration and temperature were 5.0 × 10?2 mol dm?3 and 35°C, respectively. Samples of xanthan gum and xanthan gum–g–acrylic acid were subjected to thermogravimetric analysis with the objective of studying the effect of grafting of acrylic acid on the thermal stability of xanthan gum. The graft copolymer was found to be more thermally stable than xanthan gum. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1341–1346, 2003 相似文献
5.
Unreported graft copolymer of N,N′‐dimethylacrylamide (DMA) with partially carboxymethylated guar gum (CmgOH) has been synthesized and the reaction conditions have been optimized for affording maximum grafting using a potassium peroxymonosulphate (PMS)/thiourea (TU) redox initiators under nitrogen atmosphere. The study of graft copolymerization has been performed to observe maximum value of grafting parameters except percentage of homopolymer by varying the concentrations of DMA, PMS, and TU. The grafting parameters increase continuously on increasing the concentration of DMA from 8 × 10?2 to 24 × 10?2 mol dm?3, PMS from 5 × 10?3 to 21 × 10?3 mol dm?3, and TU from 1.6 × 10?3 to 4.8 × 10?3 mol dm?3. The optimum temperature and time for grafting of DMA onto CmgOH were found to be 35°C and 120 min, respectively. The water‐swelling capacity of graft copolymer is investigated. Flocculation property for both coking and noncoking coals is studied for the treatment of coal mine waste water. The graft copolymer is characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
6.
Changhua Liu Xun Dai Jianguang Chen Yanqing Chen Xiaoli Guo Yuming Huang 《应用聚合物科学杂志》2009,113(4):2339-2345
The grafting of 4‐vinyl pyridine (4‐VP) onto konjac glucomannan (KGM) by ammonium persulfate (APS) as the initiator was studied in an acid aqueous solution under an inert atmosphere. The grafting ratio (G%) and grafting efficiency (E%) were evaluated comparatively. The dependence of these parameters on the initiator concentration, sulfuric acid concentration, ratio of monomer to KGM, temperature, and reaction time was also investigated. Under conditions of [KGM] = 1.00 g/L, [APS] = 1.00 × 10?2 mol/L, [4‐VP] = 9.32 × 10?2 mol/L, [H+] = 5.00 × 10?2 mol/L, temperature = 35°C, and time = 120 min, the optimum G% and E% were 307.27 and 52.75%, respectively. The proof of grafting was obtained from thermogravimetric analysis and infrared spectra. Preliminary research of the graft's adsorption capacity for heavy‐metal ions [Cr(VI), Cu(II), Pb(II), and Cd(II)] was done. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
7.
The graft copolymerization reaction of acrylamide onto guar gum with a vanadium(V)/mandelic acid redox pair was carried out in an N2 atmosphere. The optimum concentrations of vanadium(V), mandelic acid, hydrogen ions, acrylamide, and guar gum for the maximum percentage of grafting were 6.0 × 10?3, 2.0 × 10?2, 55.0 × 10?2, and 20.0 × 10?2 mol/dm3 and 110.1 × 10?2 g/dm3, respectively. The optimum time and temperature of reaction were 90 min and 35°C, respectively, and during the study of [H+] variation, a prompt change in the value of the grafting parameters was observed. The maximum percentage of swelling of the graft copolymer was achieved at room temperature in 1 h. Studies of the flocculation, viscosity, and metal‐ion absorption capacity were also performed. The synthesized graft copolymer was characterized by Fourier transform infrared spectroscopy and thermogravimetric analyses, which showed that the grafted guar gum was thermally more stable than the ungrafted guar gum. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
8.
A graft copolymer based on a polysaccharide (sodium salt of carboxymethylcellulose) and a vinyl monomer (acrylamide) has been synthesized in a nitrogen atmosphere, and its reaction conditions have been optimized for a better yield with ferrous sulfate and potassium bromate as a redox initiator. The effects of ferrous ion, bromate ion, hydrogen ion, sodium carboxymethylcellulose, and acrylamide along with the reaction time and temperature have been studied through the determination of the grafting parameters: the grafting ratio, add‐on, conversion, efficiency, homopolymer, and rate of grafting. The maximum yield has been found to occur when the acrylamide concentration is 8.0 × 10?2 mol/dm3, whereas the maximum conversion occurs at a minimum concentration of acrylamide, that is, at 3.0 × 10?2 mol/dm3. The grafting parameters have been found to increase with an increasing concentration of the redox initiator (Fe2+, from 2.0 × 10?3 to 10.0 × 10?3 mol/dm3; BrO, from 2.2 × 10?3 to 4.0 × 10?3 mol/dm3). The maximum efficiency occurs with a reaction time of 210 min. The rate of grafting has been found to be maximum up to 60 min; after that, it decreases rapidly. In this article, it is shown that the hydrogen ion leads to a very clear decrease in the grafting parameters as its concentration increases from 2.1 × 10?3 to 11.3 × 10?3 mol/dm3. Grafted gum and ungrafted gum have been characterized with Fourier transform infrared spectroscopy and thermogravimetric analysis. A probable mechanism has been suggested for graft copolymerization. It has been observed that the graft copolymer is thermally more stable than the parent backbone. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
9.
Faraj A. Abu‐Ilaiwi Mansor B. Ahmad Nor Azowa Ibrahim Mohamad Zaki Ab. Rahman Khairul Zaman Md. Dahlan Wan Md. Zin Wan Yunus 《应用聚合物科学杂志》2003,88(10):2499-2503
Methyl methacrylate (MMA) was successfully grafted onto rubber‐wood fiber in a free‐radical solution polymerization initiated by ferrous ion and hydrogen peroxide. The effects of the reaction parameters (reaction temperature, reaction period, influence of hydrogen peroxide, ferrous ammonium sulfate, and monomer concentrations) were investigated. The grafting percentage showed dependency on H2O2, Fe2+, and monomer concentrations, as well as reaction temperature and reaction period. The optimum reaction temperature was determined to be about 60°C and the reaction period was 60 min. The optimum concentration of H2O2 was 0.03M and optimum amounts of Fe2+ and MMA were 0.26 mmol and 2.36 × 10?2 mol, respectively. Poly(methyl methacrylate) (PMMA) homopolymer was removed from the graft copolymer by Soxhlet extractor using acetone. The presence of PMMA on the fiber was shown by FT‐IR spectroscopy and gravimetric analysis. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2499–2503, 2003 相似文献
10.
Graft copolymerization of 4‐vinylpyridine (4‐VP) onto guar gum (GOH) using potassium monopersulfate (PMS)/thioacetamide (TAA) as a redox pair was studied in an aqueous medium under inert atmosphere. The concentration of potassium monopersulfate and thioacetamide should be 1.0 × 10?2 and 5.0 × 10?3 mol dm?3, respectively, for highest grafting ratio and efficiency. Efficient grafting was observed at 19.25 × 10?2 and 4.87 × 10?2 mol dm?3 concentration of 4‐vinylpyridine and sulfuric acid, respectively. The optimum temperature for grafting is 30°C. As the time period of reaction is increased, the grafting ratio increases, whereas efficiency decreases. The plausible mechanism of grafting has been suggested. A sample of guar gum and guar‐ g‐4‐vinylpyridine were subjected to thermogravimetric analysis with the objective of studying the effect of grafting 4‐vinylpyridine on the thermal stability of guar gum. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2380–2385, 2002 相似文献
11.
A pH‐sensitive porous chitosan membrane prepared via surface grafting copolymerization in supercritical carbon dioxide
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
We report the successful grafting copolymerization of acrylic acid (AA) on a crosslinked porous chitosan membrane in supercritical carbon dioxide at pressures ranging from 13 to 25 MPa with the use of benzyl peroxide (BPO) as the reduction–oxidation free radical initiator. The effects of reaction pressure, initiator concentration, monomer concentration, reaction temperature and reaction time on grafting yield (GY) were investigated. GY initially increases and then decreases with increasing polymerization temperature and AA and BPO concentrations. The optimum grafting conditions to obtain maximum GY are as follows: 8 h reaction time, 80 °C reaction temperature, 3.05 × 10?2 g mL?1 AA concentration, 3 × 10?3 g mL?1 BPO concentration and 16 MPa reaction pressure. The water flux of the grafted chitosan membranes decreases with pH from 2 to 7, even at considerably low GY (0.95 wt%). A novel and green modification method has been developed for the preparation of biopolymer‐based membranes. © 2014 Society of Chemical Industry 相似文献
12.
Dinesh Kumar Mishra Jasaswini Tripathy Madan Mohan Mishra Kunj Behari 《应用聚合物科学杂志》2008,110(6):3455-3463
The optimum conditions for grafting N‐vinyl‐2‐pyrrolidone onto dextran initiated by a peroxydiphosphate/thiourea redox system were determined through the variation of the concentrations of N‐vinyl‐2‐pyrrolidone, hydrogen ion, potassium peroxydiphosphate, thiourea, and dextran along with the time and temperature. The grafting ratio increased as the concentration of N‐vinyl‐2‐pyrrolidone increased and reached the maximum value at 24 × 10?2 mol/dm3. Similarly, when the concentration of hydrogen ion increased, the grafting parameters increased from 3 × 10?3 to 5 × 10?3 mol/dm3 and attained the maximum value at 5 × 10?3 mol/dm3. The grafting ratio, add‐on, and efficiency increased continuously with the concentration of peroxydiphosphate increasing from 0.8 × 10?2 to 2.4 × 10?2 mol/dm3. When the concentration of thiourea increased from 0.4 × 10?2 to 2.0 × 10?2 mol/dm3, the grafting ratio attained the maximum value at 1.2 × 10?2 mol/dm3. The grafting parameters decreased continuously as the concentration of dextran increased from 0.6 to 1.4 g/dm3. An attempt was made to study some physicochemical properties in terms of metal‐ion sorption, swelling, and flocculation. Dextran‐g‐N‐vinyl‐2‐pyrrolidone was characterized with infrared spectroscopy and thermogravimetric analysis. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
13.
The study of graft copolymerization of methyl methacrylate, acrylonitrile, and acrylamide onto both defatted and bleached jute fibers using the ferrous ammonium sulfate / H2O2 redox initiator system has been made. To determine the optimum conditions of grafting, the effects of concentrations of ferrous ammonium sulfate, monomer, H2O2; time and temperature on percentage of graft yield have been studied. Acrylamide was found to graft onto the fiber only at a fixed ferrous ammonium ion concentration (5 × 10?4M). Kinetic studies showed that the rates of grafting follow the second-order mechanism. The activation energies of the reactions were found to be 3.351 and 2.53 kcal/mol in the methyl methacrylate and acrylonitrile systems, respectively. The grafted fibers have been characterized by thermogravimetric analysis, IR spectroscopy, and XRD studies. 相似文献
14.
The effect of reaction conditions on the grafting parameter during grafting of acrylamide onto guar gum has been studied using peroxydiphosphate–metabisulphite redox pair at 35 °C. Grafting ratio, efficiency and add‐on all increase as the concentrations of peroxydiphosphate and acrylamide increase up to 40.0 × 10−3 mol dm−3 and 40.0 × 10−2 mol dm−3, respectively. It has been observed that the optimum concentrations of metabisulphite and guar gum for obtaining high grafting ratio, efficiency, add‐on and conversion are 6.0 × 10−3mol dm−3 and 91.7 × 10−2 g dm−3, respectively. © 2000 Society of Chemical Industry 相似文献
15.
Poly(ethylene terephthalate) (PET) films were grafted with n-vinyl-2-pyrrolidone (n-VP) using an azobisisobutyronitrile (AIBN) initiator. Films were pre-treated in dimethyl sulfoxide (DMSO) for 1 h at 140°C before the polymerization reaction was carried out. Variations of graft yield with time, temperature, initiator, and monomer concentrations were investigated. The optimum temperature and polymerization time was found to be 70°C and 4 h, respectively. Increasing monomer concentration from 0.28 to 1.22M and initiator concentration from 1.77 × 10−3 to 4.20 × 10−3M enhanced the percent grafting. The effects of monomer and initiator diffusion on PET films were also studied. The overall activation energy for grafting was calculated as 11.5 kcal/mol. Further changes in properties of PET films such as water-absorption capacity and intrinsic viscosity were determined. The grafted films were characterized with FTIR and scanning electron microscopy (SEM). © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 1437–1444, 1997 相似文献
16.
Graft copolymers of sodium alginate (NaAlg) with itaconic acid (IA) were prepared in aqueous solution using ceric ammonium nitrate (CAN) as the redox initiator under N2 atmosphere. The carboxylic acid groups of IA were neutralized with sodium hydroxide before grafting process. Grafted copolymers as sodium salts (NaAlg‐g‐PIA) were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, intrinsic viscosity measurement, differential scanning calorimetry, and thermogravimetric analysis. The graft yield (GY %) of the graft copolymer and the grafting efficiency (GE %) of the reaction were evaluated comparatively. The effects of the reaction variables such as the reaction time, temperature, percentage of NaAlg, monomer and initiator concentrations on these parameters were studied. It was observed that GY% and GE% increased and then decreased with increasing concentrations of IA and polymerization temperature. The optimum grafting conditions for maximum GY were obtained with a reaction time of 5 h, reaction temperature of 30°C, IA concentration of 0.23 M, CAN concentration of 9.12 × 10?2 M and percentage of NaAlg 0.5 g/dL. The overall activation energy for the grafting was also calculated to be 1135 cal/mol. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
17.
The graft copolymerization of methyl methacrylate onto silk fibers was investigated in aqueous solution using the Mn(IV)–oxalic acid redox system. The copolymerization reaction was carried out under a variety of conditions such as different monomer, initiator, oxalic acid, acid concentrations, and temperatures. The graft yield increases with increasing initiator concentration up to 5 × 10?2M, and with further increase of the initiator concentration it decreases. The graft yield also increases with increasing sulfuric acid concentration up to 15 × 10?2M, and decreases thereafter. The rate of grafting also increases with increase in oxalic acid concentration up to 1.5 × 10?2M and 84.592 × 10?2M, respectively, and thereafter the rate of grafting shows down. The effect of temperature, solvents, and salts on graft yield has also been investigated and a plausible rate expression has been derived. 相似文献
18.
Isotactic polypropylene fiber (IPP) was graft‐copolymerized using 2‐vinyl pyridine (2‐VP) and styrene (sty) as the monomers by the mutual irradiation method in air. The percentage of grafting was determined as a function of various reaction parameters and it was found that the maximum grafting of 2‐VP (114%) and sty (76%) was obtained at an optimum dose of 1.08 × 104 and 0.64 × 104 Gy using 1.8 × 10−2 mol of 2‐VP and 4.3 × 10−2 mol of sty, respectively. The graft copolymers were characterized by differential scanning calorimetric analysis and isolation of the grafted chains from the grafted iPP samples. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2959–2969, 1999 相似文献
19.
To improve water wettability of polyurethane (PU), graft copolymerization with acrylic acid (AA) and crotonic acid (CA) was performed using a benzoyl peroxide (BO) initiator. The grafting reaction was carried out by placing the membranes in aqueous solutions of AA and CA at constant temperatures. Variations of graft yield with time, temperature, initiator, and monomer concentrations were investigated. The optimum temperature, polymerization time, monomer, and initiator concentrations for AA were found to be 70°C; 3 h; 1.5 M; 5.0 × 10?2 M, and for CA 70°C; 1 h; 1.5 M; 4.0 × 10?2 M, respectively. The grafting membranes were characterized by FTIR spectroscopy and scanning electron microscopy (SEM) analysis, and the effect of grafting on equilibrium water content (EWC) of PU membranes was obtained by swelling measurements. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 2690–2695, 2001 相似文献
20.
Dinesh Kumar Mishra Jasaswini Tripathy Abhishek Srivastava Peeyoosh Kant Pandey Kunj Behari 《应用聚合物科学杂志》2009,113(4):2429-2439
The aim of this study was to examine the synthesis of a graft copolymer of chitosan and methacrylic acid (MAA) by free‐radical polymerization with a potassium peroxymonosulfate/cyclohexanone (CY) redox system in an inert atmosphere. The optimum reaction conditions affording maximum grafting ratio (%G), grafting efficiency (%E), add on (%A), and conversion (%C) were determined. The grafting parameters were found to increase with increasing concentration of MAA up to 24 × 10?2 mol/dm3, but thereafter, these parameters decreased. With increasing concentration of peroxymonosulfate from 0.6 × 10?2 to 1.2 × 10?2 mol/dm3, %G, %A, and %E increased continuously. All of these grafting parameters increased with increasing concentration of CY up to 1.2 × 10?2 mol/dm3, but beyond this concentration, the grafting parameters decreased. With various concentrations of chitosan from 0.6 to 1.4 g/dm3, the maximum %G, %A, and %E were obtained at 1.4 g/dm3. %G, %A, and %C decreased continuously with various concentrations of hydrogen ions from 2 × 10?3 to 6 × 10?3 mol/dm3. The grafting parameters increased with increasing temperature up to 35°C, but thereafter, these parameters decreased. With increasing time period of reaction from 60 to 180 min, %G, %A, and %E increased up to 120 min, but thereafter, these parameters decreased. The graft copolymer was characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献