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1.
《塑料、橡胶和复合材料》2013,42(10):450-462
AbstractThe present study reports static and impact mechanical properties of jute fibre-based thermosetting composites using woven and flat braided jute fabrics. Tensile, three-point flexural and low-to-medium energy drop-weight impact tests were conducted and mechanical properties were evaluated to study their dependence upon surface modifications of the fibre materials due to bleaching and coating treatments. Full-bleaching (longer and rigorous) treatments improved interfacial bonding and tensile strength properties of the woven jute composites compared to unbleached and half-bleached counterparts. Bleaching treatments did not seem to improve the flexural strength of composites. Unbleached (natural) jute composites have relatively better flexural strength due to reduced microstructural waviness or fibre crimping to facilitate flexural failure. With coated jute yarns, the tensile properties of the resultant flat braided composites slightly degraded, whereas the flexural properties showed clear improvements. The changes in the mechanical properties were broadly related to the accompanying modifications and to the state of microstructural imperfections, namely fibre/matrix interfacial adhesion, severity of resin matrix shrinkage during the curing process, fibre/matrix debonding and distribution of disbonds within the matrix region, and also to the relative fibre filament density along the loading axis, in the cured composite structure. There was a clear indication that natural woven jute composites could be more effective in applications requiring better impact damage resistance, energy absorption capability and improved progressive crushing behaviour. 相似文献
2.
Using old newsprint (ONP) fibers as reinforcing filler in polyester (PE) composite has been studied. Using ONP fibers in PE composite resulted in a decrease in modulus of rupture (MOR) and an increase in modulus of elasticity (MOE) and tensile strength as compared with a neat PE composite. Also, water absorption and thickness swelling were increased as a result of using ONP fibers in the composite. Acetylation, steaming, and esterification (using maleic anhydride) of ONP fibers were performed to improve the dimensional stability of the produced composite. Acetylation and steaming of ONP fibers resulted in a decrease in the thickness swelling of the produced composites; MOR, MOE, and tensile strength were also decreased as a result of these treatments. Esterification of ONP fibers using maleic anhydride resulted in a decrease in thickness swelling of the produced composite and, at the same time, an increase in MOR, MOE, and tensile strength. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 2018–2023, 2001 相似文献
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《Polymer Composites》2017,38(7):1327-1334
Surface modification of jute fibers is necessary to improve the adhesion and interfacial compatibility between fibers and resin matrix before using fibers in polymer composites. In this study, dodecyl gallate (DG) was enzymatically grafted onto the jute fiber by laccase to endow the fiber with hydrophobicity. A hand lay‐up technique was then adopted to prepare jute/epoxy composites. Contact angle and wetting time measurements showed that the surface hydrophobicity of the jute fabric was increased after the enzymatic graft modification. The water absorption and thickness swelling of the DG‐grafted jute fabric/epoxy composite were lower than those of the other composites. The tensile and dynamic mechanical properties of the jute/epoxy composites were enhanced by the surface modification. Scanning electron microscopy images revealed stronger fiber–matrix adhesion in composites with modified fibers. Therefore, the enzymatic graft modification increased the fiber–matrix interface area. The fiber–matrix adhesion was enhanced, and the mechanical properties of the composites were improved. POLYM. COMPOS., 38:1327–1334, 2017. © 2015 Society of Plastics Engineers 相似文献
5.
Asli Demir Yoldas Seki Ebru Bozaci Mehmet Sarikanat Seckin Erden Kutlay Sever Esen Ozdogan 《应用聚合物科学杂志》2011,121(2):634-638
The effect of atmospheric air plasma treatment of jute fabrics on the mechanical properties of jute fabric reinforced polyester composites was investigated. The jute fabrics were subjected to different plasma powers (60, 90, and 120 W) for the exposure times of 1, 3, and 6 min. The effects of plasma powers and exposure times on interlaminar shear strength, tensile strength, and flexural strength of polyester based composites were evaluated. The greatest ILSS increase was about 171% at plasma power of 120 W and exposure time of 6 min. It is inferred that atmospheric air plasma treatment improves the interfacial adhesion between the jute fiber and polyester. This result was also confirmed by scanning electron microscopy observations of the fractured surfaces of the composites. The greatest tensile strength and flexural strength values were determined at 120 W for 1 min and at 60 W for 3 min, respectively. Moreover, it can be said that atmospheric air plasma treatment of jute fibers at longer exposure times (6 min) made a detrimental effect on tensile and flexural properties of jute‐reinforced polyester composites. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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Raw and dewaxed jute felt composites were prepared with resol and lignin modified phenol formaldehyde resin. Four different types of lignin modified resins were used by replacing phenol with lignin. The lignin modified resins were prepared from purified lignin obtained from paper industry waste black liquor. To investigate bonding between jute and resin, IR spectroscopy of jute felts and composites was carried out. The thermal stability of the composites was assessed by DSC and TGA. It was found that the lignin resin jute composite is thermally more stable than resol composite. XRD of jute felt and composite shows that the crystallinity of the jute fiber increases after composite preparation. The lignin resin composites were tested for water absorption and thickness swelling, and it was found that the results are comparable with those of resol jute composite. Composites prepared from lignin phenol formaldehyde resin with 50% phenol replacement has shown 75% tensile strength retention to that of pure resol jute composite. 相似文献
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Vijay Kumar Mahakur Sumit Bhowmik Promod Kumar Patowari Santosh Kumar 《乙烯基与添加剂工艺杂志》2023,29(2):330-342
With burgeoning environmental concerns worldwide, using natural fibers/fillers to produce composites rather than conventional fibers is on the rise. The current work focuses on the physical and thermomechanical characteristics of alkaline-treated jute filler-based epoxy composites. The composites have been prepared with different weight fraction of jute fillers (0%, 2.5%, 5%, 7.5%, 10%, and 12.5%) using hand layup process. The X-ray diffraction and Fourier transform infrared spectroscopy analysis observed that the alkali treatment of jute fillers improved the crystallinity and molecular structure, enhancing the interfacial and molecular bond between fillers and matrix. The mechanical characterizations of developed composites analyzed that the inclusion of treated jute fillers strengthened the tensile and flexural properties. The 5% filler-based composites have demonstrated maximum tensile strength (54.06 MPa) and modulus (3.12 GPa) with maximum flexural strength (67.55 MPa) and modulus (3.90 GPa). The viscoelastic characteristics of composites revealed that the 7.5% filler-based composite has the highest storage modulus (3.75 GPa), loss modulus (0.496 GPa), and glass transition temperature (91°C) due to greater interfacial interactions of molecules. The weight loss and degradation of composites analyzed with thermogravimetric analysis, and observed better thermal stability with treated jute fillers. The morphological analysis at fracture surfaces analyzed the brittle catastrophic failure of composites. Therefore, the finding produced better specific strength and stiffness with greater thermal stability for electronics equipment, packaging, and transportation. 相似文献
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The aim of this work is to assess the opportunity to use untreated waste office paper, alone and in combination with jute fabric, as a reinforcement in epoxy composites. Five different stacking sequences were manufactured and tested. Adding untreated waste office paper sheets has been revealed to increase both flexural and tensile strength of the neat resin and of the untreated jute fabric reinforced composites. The effect of the hybridization on tensile and flexural behavior has been evaluated through scanning electron microscopy observations and acoustic emission. The results confirm that waste office paper sheets can be used as a reinforcement for an epoxy resin, thus representing a viable alternative to paper recycling. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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Md. Ahmaruzzaman 《Polymer-Plastics Technology and Engineering》2013,52(8-9):1607-1629
Jute fiber composites were prepared with novolac and coal, phenolated-oxidized super clean coal (POS), petroleum vacuum residue (XVR)–modifiedphenol-formaldehyde (novolac) resin. Five different type of resins, i.e., coal, POS, and XVR-modified resins were used by replacing (10% to 50%) with coal, POS, and XVR. The composites thus prepared have been characterized by tensile strength, hardness, thermogravimetric analysis (TGA), Fourier-transfer infrared (FT-IR), water absorption, steam absorption, and thickness swelling studies. Twenty percent POS-modified novolac composites showed almost the same tensile strength as that of pure novolac composites. After 30% POS incorporation, the tensile strength decreased to 25.84 MPa from 33.96 MPa in the case of pure novolac resin composites. However, after 50% POS incorporation, the percent retention of tensile strength was appreciable, i.e., 50.80% retention of tensile strength to that of pure novolac jute composites. The tensile strength of coal and XVR-modified composites showed a trend similar to that shown by POS-modified novolac resin composites. However, composites prepared from coal and XVR-modified resin with 50% phenol replacement showed 25.4% and 42% tensile strength retention, respectively, compared to that of pure novolac jute composites. It was found that the hardness of the modified composites slightly decreased with an increase in coal, POS, and XVR incorporation in the resin. The XVR-modified composites showed comparatively lower steam absorption than did coal or POS-modified composites. The thermal stability of the POS-modified composites was the highest among the composites studied. The detailed results obtained are being reported. 相似文献
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Epoxy resin of bisphenol-C-formaldehyde (EBCF) was synthesized and its structure was confirmed by FTIR and 1HNMR techniques. Untreated jute and a 4 % sodium hydroxide-treated jute composites of EBCF, araldites (GY508 and GY6010) and their hybrid composites were fabricated by hand layup technique followed by compression-molding technique. Mechanical, electrical and water absorption behavior of the composites was studied by standard test methods. The composites showed good mechanical and electrical properties, excellent hydrolytic stability and almost identical water absorption tendency. To some extent, alkali-treated jute composites displayed improved mechanical properties and water absorption tendency. EBCF-based jute and hybrid composites showed comparable mechanical and electrical properties and water absorption behavior with araldite-based composites. Among jute–EBCF, jute–araldite and their hybrid composites, J–EBCF showed the highest impact strength (26 kg m?2), Barcol hardness (34), volume resistivity (2.7 × 10?11 Ω cm) and diffusivity (7.19 × 10?13 m2 s?2). J–GY-1 showed the highest tensile strength (43.7 MPa), flexural modulus (4.26 GPa), % equilibrium water absorption (19.36 %) and equilibrium water absorption time (480 h). Good mechanical and electrical properties and excellent hydrolytic stability of both types of the composites suggested their usefulness for low load-bearing housing, and electrical and marine applications. Thus, EBCF has found its commercial importance as that of the commercial araldite resins. 相似文献
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Biocomposites developed from wheat gluten using water without any chemicals as plasticizer and jute fibers as reinforcement have much better flexural and tensile properties than similar polypropylene composites reinforced with jute fibers. Wheat gluten is an inexpensive and abundant co‐product derived from renewable resources and is biodegradable but non‐thermoplastic. Previous attempts at developing biocomposites from wheat gluten have used plasticizers such as glycerol or chemical modifications to make gluten thermoplastic. However, plasticizers have a considerably negative effect on the mechanical properties of the composites and chemical modifications make wheat gluten less biodegradable, expensive and/or environmentally unfriendly. In the research reported, we developed composites from wheat gluten using water as a plasticizer without any chemicals. Water plasticizes wheat gluten but evaporates during compression molding and therefore does not affect the mechanical properties of the composites. The effect of composite fabrication conditions on the flexural, tensile and acoustic properties was studied in comparison to polypropylene composites reinforced with jute fibers. Wheat gluten composites had flexural strength (20 MPa), tensile strength (69 MPa) and tensile modulus (7.7 GPa) values approximately twice those of polypropylene composites. Water is an effective plasticizer for wheat gluten and could be used to develop various types of inexpensive and biodegradable wheat gluten‐based thermoplastics. Copyright © 2011 Society of Chemical Industry 相似文献
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In this study, the jute/polypropylene nonwoven reinforced composites were prepared using film stacking method. The surface of jute fibers was modified using alkali treatment. These alkali treated jute fiber nonwoven composites were analyzed for their tensile and flexural properties. Increasing the amount of jute fibers in the nonwovens has improved the mechanical properties of their composites. The effect of stacking sequence of preferentially and nonpreferentially aligned nonwovens within the composites was also investigated. The flexural and tensile moduli of composites were found to be significantly enhanced when nonwovens consisting of preferentially and nonpreferentially aligned jute fibers were stacked in an alternate manner. The existing theoretical models of tensile modulus of fiber reinforced composites have been analyzed for predicting the tensile modulus of nonwoven composites. In general, a good agreement was obtained between the experimental and theoretical results of tensile modulus of nonwoven composites. POLYM. COMPOS., 35:1044–1050, 2014. © 2013 Society of Plastics Engineers 相似文献
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In this study, randomly oriented short jute/bagasse hybrid fiber‐reinforced epoxy novolac composites were prepared by keeping the relative volume ratio of jute and bagasse of 1:3 and the total fiber loading 0.40 volume fractions. The effect of jute fiber hybridization and different layering pattern on the physical, mechanical, and thermal properties of jute/bagasse hybrid fiber‐reinforced epoxy novolac composites was investigated. The hybrid fiber‐reinforced composites exhibited fair water absorption and thickness swelling properties. To investigate the effect of layering pattern on thermomechanical behavior of hybrid composites, the storage modulus and loss factor were determined using dynamic mechanical analyzer from 30 to 200°C at a frequency of 1 Hz. The fracture surface morphology of the tensile samples of the hybrid composites was performed by using scanning electron microscopy. The morphological features of the composites were well corroborated with the mechanical properties. Thermogravimetric analysis indicated an increase in thermal stability of pure bagasse composites with the incorporation of jute fibers. The incorporation of hybrid fibers results better improvement in both thermal and dimensional stable compared with the pure bagasse fiber composites. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers 相似文献
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Bisphenol‐C‐formaldehyde‐toluene‐2,4‐di isocyanate polyurethane (PU) has been synthesized at room temperature and used for the fabrication of jute and jute–rice husk/wheat husk hybrid composites. PU–jute and PU–jute–RH/WH composites were prepared under pressure of 30.4 MPa at room temperature for 8 h, while PU–jute–RH/WH composites were prepared under same pressure at 110°C for 5 h. PU–jute composite has good tensile strength and flexural strength (50–53 MPa), while PU–jute–RH/WH hybrid composites have moderate tensile strength (9–11 MPa) and a fairly good flexural strength (15–31 MPa). Composites possess 1.1–2.2 kV electric strength and 0.94–1.26 × 1012 ohm cm volume resistivity. Water absorption in PU–jute composite is different in water (9.75%), 10% HCl (12.14%), and 10% NaCl (6.05%). Equilibrium water uptake time in salt environment is observed 96 h, while in pure water and acidic environments it is 192 h. In boiling water equilibrium water content and equilibrium time are found to be 21.7% and 3 h, respectively. Water absorption increased 2.2 times in boiling water, whereas equilibrium time reduced 64 times. Thus, PU–jute composite has excellent hydrolytic stability against boiling water, 10% HCl, and 10% NaCl solutions. Fairly good mechanical and electrical properties and excellent hydrolytic stability of composites signify their usefulness for low cost housing units and in electrical and marine industries. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2363–2370, 2006 相似文献
15.
Effect of lactic acid chain length on thermomechanical properties of star‐LA‐xylitol resins and jute reinforced biocomposites
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Arash Jahandideh Nima Esmaeili Kasiviswanathan Muthukumarappan 《Polymer International》2017,66(7):1021-1030
Star‐shaped bio‐based resins were synthesized by direct condensation of lactic acid (LA) with xylitol followed by end‐functionalizing of branches by methacrylic anhydride with three different LA chain lengths (3, 5 and 7). The thermomechanical and structural properties of the resins were characterized by 13C NMR, Fourier transform IR spectroscopy, rheometry, DSC, dynamic mechanical analysis (DMA), TGA and flexural and tensile tests. An evaluation of the effect of chain length on the synthesized resins showed that the resin with five LAs exhibited the most favorable thermomechanical properties. Also, the resin's glass transition temperature (103 °C) was substantially higher than that of the thermoplast PLA (ca 55 °C). The resin had low viscosity at its processing temperature (80 °C). The compatibility of the resin with natural fibers was investigated for biocomposite manufacturing. Finally, composites were produced from the n5‐resin (80 wt% fiber content) using jute fiber. The thermomechanical and morphological properties of the biocomposites were compared with jute‐PLA composites and a hybrid composite made of the impregnated jute fibers with n5 resin and PLA. SEM and DMA showed that the n5‐jute composites had better mechanical properties than the other composites produced. Inexpensive monomers, good thermomechanical properties and good processability of the n5 resin make the resin comparable with commercial unsaturated polyester resins. © 2017 Society of Chemical Industry 相似文献
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Khurshid Malik Faiz Ahmad Nurul Azhani Yunus Ebru Gunister Saad Ali Ali Raza 《应用聚合物科学杂志》2023,140(5):e53421
This research investigates the physical and mechanical properties of hybrid composites made of epoxy reinforced by kenaf and flax natural fibers to investigate the hybridization influences of the composites. Pure and hybrid composites were fabricated using bi-directional kenaf and flax fabrics at different stacking sequences utilizing the vacuum-assisted resin infusion method. The pure and hybrid composites' physical properties, such as density, fiber volume fraction (FVF), water absorption capacity, and dimensional stability, were measured. The tests of tensile, flexural, interlaminar shear and fracture toughness (Mode II) were examined to determine the mechanical properties. The results revealed that density remained unchanged for the hybrid compared to pure kenaf/epoxy composites. The tensile, flexural, and interlaminar shear performance of flax/epoxy composite is improved by an increment of kenaf FVF in hybrid composites. The stacking sequence significantly affected the mechanical properties of hybrid composites. The highest tensile strength (59.8 MPa) was obtained for FK2 (alternative sequence of flax and kenaf fibers). However, FK3 (flax fiber located on the outer surfaces) had the highest interlaminar shear strength (12.5 MPa) and fracture toughness (3302.3 J/m2) among all tested hybrid composites. The highest water resistance was achieved for FK5 with the lowest thickness swelling. 相似文献
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《Polymer Composites》2017,38(10):2212-2220
Sandwich composites based on coir fiber nonwoven mats as core material were manufactured by Vacuum Assisted Resin Transfer Molding technique. Mechanical and physical properties of produced coir/polyester and coir‐glass/polyester composites were assessed. Samples were evaluated according to their reinforcement contents, resin contents, areal density, and thickness. Tests on physical properties revealed that coir‐glass/polyester sandwich structure has the lowest values of thickness swelling, water absorption and moisture contents compared with coir/polyester composite. Mechanical tests such as tensile strength, open‐hole tensile strength, and flexural strength were also performed on all samples. Coir‐glass/polyester sandwich structure showed significant increase in tensile strength of 70 MPa compared with 8 MPa of coir/polyester composite. Introducing two skins of fiber glass woven roving to coir/polyester increased its flexural strength from 31.8 to 131.8 MPa for coir‐glass/polyester. POLYM. COMPOS., 38:2212–2220, 2017. © 2015 Society of Plastics Engineers 相似文献
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Jute slivers were acetylated in pilot scale following a no catalyst‐no solvent method at 120°C for 2 h. The weight % gain was found to be 11.37. Different jute boards were pressed under heat and pressure using acetylated jute sliver and urea formaldehyde resin. Neutral salt (NaCl), acid salt (NH4Cl), and melamine powder were used separately for curing urea formaldehyde. For comparison purposes, control boards were also prepared using nonacetylated slivers. The boards were tested for water soaking, cyclic water soaking, and cyclic humidity to see the effect of acetylation on dimensional stabilization. This chemical modification was found to improve the dimensional stability to a great extent for NaCl and NH4Cl cured boards and to a less extent for a melamine‐cured one. Tensile and flexural strengths were tested by Instron before and after the cyclic tests. Retention values were found to be as high as 60% after cyclic water tests for acetylated boards and the same was as low as 24% for control boards. Dynamic parameters, such as storage flexural modulus (E′), loss flexural modulus (E"), and loss factor or damping efficiency (tan δ) were determined in a fixed‐frequency mode. Dynamic mechanical study revealed that tan δ peaks were lowered due to increased bulkiness of the fiber after acetylation and thus restricted mobility. A tiny additional peak was also visible at ∼90°C beside the main peak at ∼125°C for boards with modified slivers. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 935–944, 1999 相似文献
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Natural fiber composite laminates are nowadays used in structural application such as aerospace, automobile and in sports goods because of their high strength to weight ratio and renewability. Hence the study of mechanical behaviors of natural fiber composites is very important in using these composite laminates for such specific applications. This project aims at identifying the mechanical properties of hybrid natural Jute/Kenaf fiber. The major drawbacks in natural fiber are its Resin incompatibility. Surface treatment of fiber is made to improve the interfacial bonding between the fiber and resin and to reduce the moisture absorption. Laminates are fabricated using Hand lay-up technique. Mechanical properties such as tensile, flexural, and Impact test for jute/kenaf hybrid laminates were obtained. Specimen preparation and Mechanical property testing were carried out as per ASTM standards. Micro structures of the different layer of hybrid specimens are scanned by the Scanning Electron Microscope. 相似文献
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The natural fiber reinforced biodegradable polymer composites were prepared with short jute fiber as reinforcement in PLA (Poly lactic acid) matrix. The short jute fiber is successively treated with NaOH at various concentrations (5%, 10%, and 15%) and H2O2. The composites were prepared with untreated and treated short jute fibers at different weight proportions (up to 25%) in PLA and investigated for mechanical properties. The results showed that the composite with successive alkali treated jute fiber at 10% NaOH and H2O2 with 20% fiber loading has shown 18% higher flexural strength than neat PLA and untreated jute/PLA composite. The flexural modulus of the composite at 25% fiber loading was 125% and 110% higher than that of composites with untreated fibers and neat PLA, respectively. The impact strength of composite with untreated fibers at higher fiber weight fraction was 23% high as compared to neat PLA and 26% high compared to composite with treated fibers. The water absorption was more for untreated jute/PLA composite at 25% fiber loading than all other composites. The composite with untreated fibers has high thermal degradation compared with treated fibers but lower than that of pure PLA matrix. The enzymatic environment has increased the rate of degradation of composites as compared to soil burial. Surface morphology of biodegraded surfaces of the composites were studied using SEM method. POLYM. COMPOS., 37:2160–2170, 2016. © 2015 Society of Plastics Engineers 相似文献