Pool boiling heat transfer to hydrocarbons and ammonia: A state-of-the-art review

Interest has grown in recent years to extend the use of hydrocarbons and ammonia as working fluids in refrigeration to new domains of application, despite their flammability. In the context of pool boiling heat transfer, this has created increasing research activities, particularly with regard to hydrocarbons. In contrast with this, only a few new experimental results have been added to the data set existing for ammonia in the literature. So this review will concentrate on hydrocarbons, while ammonia will be treated in a comparatively brief part.The review starts with the state-of-the-art that had been reached at about 1990. It continues with the data set for propane being taken as an example to highlight various reasons for the experimental data scatter that is found when different sources are compared for the same substance. In the main part, new results of 12 (aliphatic) hydrocarbons are discussed regarding the influence of heat flux q and reduced saturation pressure p^* = p_s/p_c on the heat transfer coefficient α, and also the variation in α₀ caused by the differences in the thermophysical properties of the 12 hydrocarbons at constant q₀ and . It is shown that the dependencies of the heat transfer coefficient α on heat flux q and reduced pressure p^*, and on the thermophysical properties of the various fluids at constant values q₀ and can be correlated by general semi-empirical functions with comparatively narrow limits of error that do not reach far beyond the experimental scatter occurring when different sources are compared for the same substance. Before treating ammonia in a final section, the review on hydrocarbons closes with short discussions for mixtures of hydrocarbons, for the bundle effect, and for the behaviour of enhanced tubes.     

Assessment of boiling heat transfer correlations in the modelling of fin and tube heat exchangers

A new way to assess the performance of refrigeration system models is presented in this paper, based on the estimation of cycle parameters, such as the evaporation temperature which will determine the validity of the method. This paper is the first of a series which will also study the influence of the heat transfer coefficient models on the estimation of the refrigeration cycle parameters. It focuses on fin and tube evaporators and includes the dehumidification process of humid air. The flow through the heat exchanger is considered to be steady and the refrigerant flow inside the tubes is considered one-dimensional. The evaporator model is discretised in cells where 1D mass, momentum and energy conservation equations are solved by using an iterative procedure called SEWTLE. This procedure is based on decoupling the calculation of the fluid flows from each other assuming that the tube temperature field is known at each fluid iteration. Special attention is paid to the correlations utilised for the evaluation of heat transfer coefficients as well as the friction factor on the air and on the refrigerant side. A comparison between calculated values and measured results is made on the basis of the evaporation temperature. The experimental results used in this work correspond to an air-to-water heat pump and have been obtained by using R-22 and R-290 as refrigerants.     

Experimental correlation of pool boiling heat transfer for HFC134a on enhanced tubes: Turbo-E

The objectives of this paper are to study the heat transfer characteristics for enhanced surface tubes in the pool boiling and to provide a guideline for the design conditions for the evaporator using HFC134a. The shape of tube surfaces, the wall superheat, and the saturation temperature are considered as the key parameters. Copper tubes (d_o = 19.05 mm) are treated with different helix angles and the saturation temperatures are controlled from 3 to 16 °C. It is found that the pool boiling heat transfer coefficient decreases with increasing the wall superheat. It is also found that boiling heat transfer coefficients for Turbo-II and Turbo-III are 1.5–3.0 times and 1.2–2.0 times higher than that for Turbo-I without the helix angle, respectively. The higher heat transfer performance from Turbo-II and Turbo-III can be explained by the “bubble detention” phenomenon on the surface without the helix angle for the Turbo-I. The experimental correlations for the pool boiling heat transfer on the present enhanced tubes without (Type I) and with the helix angle (Type II and Type III) are developed with the error bands of ±30%, respectively.     

Assessment of boiling and condensation heat transfer correlations in the modelling of plate heat exchangers

This paper studies refrigeration cycles in which plate heat exchangers are used as either evaporators or condensers. The performance of the cycle is studied by means of a method introduced in previous papers which consists of assessing the goodness of a calculation method by looking at representative variables such as the evaporation or the condensation temperature depending on the case evaluated. This procedure is also used to compare several heat transfer coefficients in the refrigerant side. As in previous works the models of all the cycle components are considered together with the heat exchanger models in such a way that the system of equations they provide is solved by means of a Newton–Raphson algorithm. Calculated and measured values of the evaporation and the condensation temperatures are also compared. The experimental results correspond to the same air-to-water heat pump studied in other papers and they have been obtained by using refrigerants R-22 and R-290.     

Flow boiling of ammonia and hydrocarbons: A state-of-the-art review

A comprehensive review of flow boiling heat transfer, two-phase pressure drops and flow patterns of ammonia and hydrocarbons applied in air-conditioning, refrigeration and heat pump systems is presented in this paper. First, experimental studies of flow boiling of ammonia and hydrocarbons are addressed. Then, the prediction methods for flow boiling heat transfer, two-phase pressure drops and flow patterns are described. Next, comparisons of four flow boiling heat transfer and four two-phase pressure drop methods to the experimental data in smooth tubes derived from the available studies are presented. In addition, comparison of flow patterns to a flow map is presented. Based on the comparisons and analysis, recommendations on these methods are given. Furthermore, research needs on flow boiling and two-phase flow of ammonia and hydrocarbons have been identified. It is suggested that more experimental data be obtained through well conducted experiments and new prediction methods or modified ones based on the available methods be made for ammonia and hydrocarbons. In addition, the effect of oil on ammonia and hydrocarbon flow boiling and two-phase flow should be studied in order to have conclusive evidence of its effect.     

Boiling of ammonia/lubricant mixture on a horizontal enhanced tube in a flooded evaporator with inlet vapor quality

In a flooded evaporator of an ammonia vapor-compression refrigeration system, boiling commonly takes place with ammonia mixed with compressor lubricant and subjected to a vapor quality at the inlet of the evaporator. In the present study, flooded boiling tests of ammonia on an enhanced tube under simultaneous influence of a miscible lubricant and inlet quality were conducted. The results suggest that the boiling heat transfer coefficient increases with both saturation temperature and heat flux. The coefficient slightly increases or does not significantly vary with the inlet quality. The coefficient in general is decreased by adding lubricant to the refrigerant, but the coefficient does not necessarily decrease as the lubricant concentration increases. The lubricant effect is generally more significant than the inlet quality effect. A correlation was developed based on the present data for flooded boiling of lubricant/ammonia mixture on an enhanced horizontal tube under the influence of inlet quality.     

NH3 in-tube condensation heat transfer and pressure drop in a smooth tube

This paper presents an overview of the issues and new results for in-tube condensation of ammonia in horizontal round tubes. A new empirical correlation is presented based on measured NH₃ in-tube condensation heat transfer and pressure drop by Komandiwirya et al. [Komandiwirya, H.B., Hrnjak, P.S., Newell, T.A., 2005. An experimental investigation of pressure drop and heat transfer in an in-tube condensation system of ammonia with and without miscible oil in smooth and enhanced tubes. ACRC CR-54, University of Illinois at Urbana-Champaign] in an 8.1 mm aluminum tube at a saturation temperature of 35 °C, and for a mass flux range of 20–270 kg m⁻² s⁻¹. Most correlations overpredict these measured NH₃ heat transfer coefficients, up to 300%. The reasons are attributed to difference in thermophysical properties of ammonia compared to other refrigerants used in generation and validation of the correlations. Based on the conventional correlations, thermophysical properties of ammonia, and measured heat transfer coefficients, a new correlation was developed which can predict most of the measured values within ±20%. Measured NH₃ pressure drop is shown and discussed. Two separated flow models are shown to predict the pressure drop relatively well at pressure drop higher than 1 kPa m⁻¹, while a homogeneous model yields acceptable values at pressure drop less than 1 kPa m⁻¹. The pressure drop mechanism and prediction accuracy are explained though the use of flow patterns.     

Experimental investigation on convective heat transfer mechanism in a scroll compressor

This paper describes an experimental study on the convective heat transfer inside the scroll compressor. An experimental refrigeration system is composed with extensive instrumentations in the compressor that is operated at variable speeds. The 13 thermocouples installed inside the compressor monitor the temperatures of the scroll wrap during compression process of refrigerant. The temperature and the pressure of refrigerant at suction, and the pressure at discharge ports are measured, and applied to the numerical simulation as the operating condition parameters. The temperature measured at the discharge port is used to verify the simulation result with relevant heat transfer coefficient. This paper describes the effect of motion of the orbiting scroll on the convective heat transfer in the scroll wraps. Separate experiments are performed to investigate the heat transfer in such a peculiar physical condition. With this experimental result, the effect of the oscillation of the wall on the heat transfer is quantitatively analyzed and applied to the simulation of compression process in scroll compressor. The whole consecutive compression processes in the scroll compressor is simulated in detail by solving equations of mass and energy balance for the refrigerant. The modified heat transfer coefficient correlation considering the effect of motion of the orbiting scroll predicts the discharge temperature better than other typical heat transfer coefficients.     

Current and future prospects of enhanced heat transfer in ammonia systems

In the last decade a moderate headway has been made in the application of enhanced surface heat exchangers in ammonia refrigeration systems. This has been a result of the persistent issue of ozone and global warming which has resulted in keen interest in natural refrigerants such as ammonia that has played a prominent role in the refrigeration industry for years, particularly in the field of food, beverage and marine. The only drawback with ammonia is the toxicity; hence, if smaller heat exchangers could be introduced in order to reduce ammonia charge, this negative aspect about ammonia can be addressed to a great extent. In order to achieve this goal, novel and compact heat exchangers with enhanced surfaces have to be introduced. This paper presents an over view of the status of ammonia as a refrigerant and discusses the present and the future trends in the development of compact heat exchangers for use in ammonia refrigeration.     

Heat transfer characteristics of flat plate finned-tube heat exchangers with large fin pitch

The objective of this study is to provide experimental data that can be used in the optimal design of flat plate finned-tube heat exchangers with large fin pitch. In this study, 22 heat exchangers were tested with a variation of fin pitch, number of tube row, and tube alignment. The air-side heat transfer coefficient decreased with a reduction of the fin pitch and an increase of the number of tube row. The reduction in the heat transfer coefficient of the four-row heat exchanger coil was approximately 10% as the fin pitch decreased from 15.0 to 7.5 mm over the Reynolds number range of 500–900 that was calculated based on the tube diameter. For all fin pitches, the heat transfer coefficient decreased as the number of tube row increased from 1 to 4. The staggered tube alignment improved heat transfer performance more than 10% compared to the inline tube alignment. A heat transfer correlation was developed from the measured data for flat plate finned-tubes with large fin pitch. The correlation yielded good predictions of the measured data with mean deviations of 3.8 and 6.2% for the inline and staggered tube alignment, respectively.     

Two-phase flow heat transfer of CO2 vaporization in smooth horizontal minichannels

Experiments were performed on the convective boiling heat transfer in horizontal minichannels with CO₂. The test section is made of stainless steel tubes with inner diameters of 1.5 and 3.0 mm and with lengths of 2000 and 3000 mm, respectively, and it is uniformly heated by applying an electric current directly to the tubes. Local heat transfer coefficients were obtained for a heat flux range of 20–40 kW m⁻², a mass flux range of 200–600 kg m⁻² s⁻¹, saturation temperatures of 10, 0, −5, and −10 °C and quality ranges of up to 1.0. Nucleate boiling heat transfer contribution was predominant, especially at low quality region. The reduction of heat transfer coefficient occurred at a lower vapor quality with a rise of heat flux, mass flux and saturation temperature, and with a smaller inner tube diameter. The experimental heat transfer coefficient of CO₂ is about three times higher than that of R-134a. Laminar flow appears in the minichannel flows. A new boiling heat transfer coefficient correlation that is based on the superposition model for CO₂ was developed with 8.41% mean deviation.     

An experimental study on heat transfer and pressure drop characteristics of carbon dioxide during gas cooling process in a horizontal tube

The heat transfer coefficient and pressure drop during gas cooling process of CO₂ (R744) in a horizontal tube were investigated experimentally. The experiments are conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and a gas cooler (test section). The water loop consists of a variable speed pump, an isothermal tank, and a flow meter. The refrigerant, circulated by the variable-speed pump, condenses in the inner tube while water flows in the annulus. The gas cooler of tube diameter is 6000 mm in length, and it is divided into 12 subsections.The pressure drop of CO₂ in the gas cooler shows a relatively good agreement with those predicted by Blasius's correlation. The local heat transfer coefficient of CO₂ agrees well with the correlation by Bringer–Smith. However, at the region near Pseudo-critical temperature, the experiments indicate higher values than the Bringer–Smith correlation. Based on the experimental data presented in this paper, a new correlation to predict the heat transfer coefficient of supercritical CO₂ during in-tube cooling has been developed. The majority of the experimental values are within 18% of the values predicted by the new correlation.     

Bundle effect of ammonia/lubricant mixture boiling on a horizontal bundle with enhanced tubing and inlet quality

Shell-side heat transfer coefficients of individual tubes for ammonia/lubricant mixture boiling on a 3 × 5 enhanced tube bundle were measured, enabling a detailed study of tube bundle effect under the influences of inlet quality, concentration of miscible lubricant (co-polymer of polyalkylene glycol, PAG), saturation temperature, and heat flux. Tests were conducted in the range of heat flux from 3.2 to 32.0 kW/m², simulated inlet quality from 0.0 to 0.4, saturation temperature from −13.2 to +7.2 °C, and lubricant concentration from 0 to 10%. The data show that bundle effect is more significant at a higher saturation temperature. Most of the data in the bottom row are lower than the single-tube heat transfer coefficient data at a low saturation temperature. Lubricant renders the heat transfer coefficient lower in lower rows and higher in higher rows, therefore a larger range of data variation.     

Mass transfer characteristics of a structured packing for ammonia rectification in ammonia–water absorption refrigeration systems

In ammonia–water absorption refrigeration systems a purification process of the vapours produced in the generator is required. One type of equipment to carry out the purification process is a packed column. However, detailed experimental studies at the normal operating conditions found in ammonia–water absorption refrigeration systems have not been found. An experimental facility has been designed and built to study the ammonia–water rectification in packed columns. Experimental tests have been performed at the normal operating conditions found in the high-pressure stage of a small power ammonia–water absorption refrigeration system. In this paper, the experimental set-up is described and experimental results of the height equivalent to a theoretical plate (HETP) and the volumetric mass transfer coefficient of a rectifying section with the Sulzer BX packing are presented. The HETP values and the experimental mass transfer coefficients are compared with different data and correlations proposed in the literature; it has been found that the differences are appreciable.     

Effect of bulk lubricant concentration on the excess surface density during R134a pool boiling

This paper investigates the effect that the bulk lubricant concentration has on the non-adiabatic lubricant excess surface density on a roughened, horizontal flat pool-boiling surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for pure R134a and three different mixtures of R134a and a polyolester lubricant (POE). A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of an R134a/POE lubricant mixture on a test surface. The lubricant is preferentially drawn out of the bulk refrigerant/lubricant mixture by the boiling process and accumulates on the surface in excess of the bulk concentration. The excess lubricant resides in an approximately 40 μm layer on the surface and influences the boiling performance. The lubricant excess surface density measurements were used to modify an existing dimensionless excess surface density parameter so that it is valid for different reduced pressures. The dimensionless parameter is a key component for a refrigerant/lubricant pool-boiling model given in the literature. In support of improving the boiling model, both the excess measurements and heat transfer data are provided for pure R134a and three R134a/lubricant mixtures at 277.6 K. The heat transfer data show that the lubricant excess layer causes an average enhancement of the heat flux of approximately 24% for the 0.5% lubricant mass fraction mixture relative to pure R134a heat fluxes between 5 and 20 kW/m². Conversely, both 1 and 2% lubricant mass fraction mixtures experienced an average degradation of approximately 60% in the heat flux relative to pure R134a heat fluxes between approximately 4 and 20 kW/m². This study is an effort toward generating data to support a boiling model to predict whether lubricants degrade or improve boiling performance.     

Experimental study of turbulent single-phase flow and heat transfer inside a micro-finned tube

Single-phase heat transfer and pressure drop characteristics of a commercially available internally micro-finned tube with a nominal outside diameter of 7.94 mm were studied. Experiments were conducted in a double pipe heat exchanger with water as the cooling as well as the heating fluid for six sets of runs. The pressure drop data were collected under isothermal conditions. Data were taken for turbulent flow with 3300 ≤ Re ≤ 22,500 and 2.9 ≤ Pr ≤ 4.7. The heat transfer data were correlated by a Dittus–Boelter type correlation, while the pressure drop data were correlated by a Blasius type correlation. The correlation predicted values for both the Nusselt number and the friction factors were compared with other studies. It was found that the Nusselt numbers obtained from the present correlation fall in the middle region between the Copetti et al. and the Gnielinski smooth tube correlation predicted Nusselt number values. For pressure drop results, the present correlation predicted friction factors values were nearly double that of the Blasius smooth tube correlation predicted friction factors. It was also found that the rough tube Gnielinski and Haaland correlations can be used as a good approximation to predict the finned tube Nusselt number and ffriction factor, respectively, in the tested Reynolds number range.     

Experimental characterization of the rectification process in ammonia–water absorption systems with a large-specific-area corrugated sheet structured packing

In this paper, the mass transfer performance of a large-specific-area corrugated sheet structured packing for ammonia–water absorption refrigeration systems (AARS) is reported. An experimental facility was used to test the performance of the packing. Experimental results of the temperature, ammonia concentration and mass flow rate of the rectified vapour are presented and discussed for different operating conditions including reflux ratio values from 0.2 to 1. The volumetric vapour phase mass transfer coefficient is calculated from the measured data and compared with different correlations found in the literature. A new correlation is proposed which was fitted from the experimental data. Finally, a comparison is made between the actual packing height used in the experimental setup and the height required to obtain the same ammonia rectification in AARS with different packings previously tested by the authors.     

Modelling of the heat exchangers of a small capacity, hot water driven, air-cooled H2O–LiBr absorption cooling machine

General models for the design of the heat exchangers (absorber, generator, condenser and evaporator) of a prototype of an air-cooled absorption chiller of 2 kW for air-conditioning using the pair H₂O–LiBr have been developed. An absorption machine of such characteristics has been constructed to be used as a test facility for validating the results obtained from the mathematical models developed. The discrepancies considering the heat exchanged between numerical results and experimental data are under 15% in most cases for all these components except the condenser, where the discrepancies are higher. The conclusions reported will lead to: (i) future improvements of the mathematical simulation models and (ii) improvements in the experimental infrastructure.     

Experimental analysis of ammonia condensation on smooth and integral-fin titanium tubes

This paper reports on the experimental research conducted to study the condensation of ammonia on smooth and integral-fin (32 fpi) titanium tubes of 19.05 mm outer diameter. Experiments were carried out at saturation temperatures of 30, 35, 40 and 45 °C and wall subcoolings from 1 to 8 °C. The results show that the condensation coefficients on the smooth tubes are well predicted by the Nusselt theory with an average error of +0.66% and within a deviation between −6.6% and +8.3%. The enhancement factors provided by the integral-fin tubes range from 0.77 to 1.22. The low enhancement factors are due to the high condensate retention between fins, which brings about flooded fractions of the tube perimeter from 62.9% to 73.2%, and the low thermal conductivity of titanium. The Briggs and Rose [1994. Effect of fin efficiency on a model for condensation heat transfer on a horizontal, integral-fin tube. Int. J. Heat Mass Transfer 37, 457–463.] model, which accounts for the conduction in the fins, predicts the experimental data with a mean overestimation of 20%. The analysis of the partial thermal resistances in the overall heat transfer process points out the convenience of enhancing the outside ammonia condensation when high water velocities are considered inside the tubes.     

Forced convective boiling heat transfer of R-410A in horizontal minichannels

Convective boiling heat transfer experiments were performed in horizontal minichannels with binary mixture refrigerant, R-410A. The test section is made of stainless steel tubes with inner diameters of 1.5 mm and 3.0 mm and with lengths of 1500 mm and 3000 mm, respectively, and is uniformly heated by applying electric current directly to the tubes. Local heat transfer coefficients were obtained for a heat flux range of 10–30 kW m⁻², a mass flux range of 300–600 kg m⁻² s⁻¹, and quality ranges of up to 1.0. The experimental results were mapped on Wang et al.'s (C.C. Wang, C.S. Chiang, D.C. Lu, Visual observation of two-phase flow pattern of R-22, R-134a, and R-407C in a 6.5-mm smooth tube, Experimental, Thermal and Fluid Science 15 (1997) 395–405) and Wojtan et al.'s (L. Wojtan, T. Ursenbacher, J.R. Thome, Investigation of flow boiling in horizontal tubes: part I – a new diabatic two-phase flow pattern map, International Journal of Heat and Mass Transfer 48 (2005) 2955–2969) flow pattern maps to observe the flow regimes. Laminar flow appears in flow with minichannels. A new boiling heat transfer coefficient correlation based on the superposition model for R-410A was developed with 11.20% mean deviation; it showed a good agreement between the measured data and the calculated heat transfer coefficients.