镁合金激光表面熔覆技术

镁及镁合金具有良好的物理和力学性能，是一种极具发展潜力的材料，但镁合金的耐蚀性较差，采用激光表面熔覆技术，可显著提高其表面的耐蚀性。本文综述了镁合金激光表面熔覆技术。并对今后镁合金激光表面熔覆技术的发展作出展望。     

镁合金的激光表面处理技术

评述了激光表面熔凝、激光表面合金化和激光表面熔覆技术用于镁合金表面处理中提高其耐蚀性和耐磨性的机制,以及这些表面处理技术的研究现状。并探讨了激光表面处理技术在镁合金应用中存在的问题和该技术的发展前景。     

镁合金表面激光熔覆研究现状

总结了镁合金表面激光熔覆的特点,介绍了镁合金表面激光熔覆技术的处理工艺和熔覆体系及各种熔覆层的组织特征及性能的研究现状,提出了今后镁合金激光熔覆工艺的发展趋势.     

汽车用镁合金激光表面熔覆Al-Si合金涂层组织和性能研究

采用激光熔覆技术在汽车用镁合金表面制备Al-Si合金涂层,对Al-Si合金涂层的组织和性能进行研究。结果表明,Al-Si合金熔覆层组织主要为树枝晶,主要物相为Mg_2Al_3、Mg_(17)Al_(12)、Mg_2Si。镁合金激光表面熔覆Al-Si合金涂层硬度分为4个不同区域,分别为熔覆层、结合区、热影响区和镁基体,其中次表层硬度最高,基体层硬度最低。镁合金表面随着激光功率的增加,熔覆层耐磨性和耐腐蚀性能提高。随着激光功率的增加,耐磨性先增加后降低,耐蚀性逐渐提高。     

镁合金表面激光熔覆研究现状*

作为最轻的金属结构材料之一的镁合金,其较差的耐磨蚀性和低硬度限制了在工业中更为广阔的应用。激光熔覆涂层因具有稀释度小、组织致密、涂层与基体结合好等优点,可显著提高镁合金表面硬度和耐磨蚀性,获得密切关注,然而此方面缺乏系统的综述研究。以镁合金涂层材料的设计原则为出发点,首次从二元合金涂层、复合性增强涂层、非晶态合金涂层、高熵合金涂层、功能梯度涂层以及医用材料涂层6个方面,综述镁合金表面激光熔覆涂层材料设计体系,并分析每种涂层材料体系的性能特点。对镁合金在激光熔覆领域应用亟待解决的问题及未来发展方向进行展望,提出未来应结合超声振动技术、电磁搅拌技术、高频微锻造技术和等离子喷涂技术等辅助技术,协同高通量材料计算模拟,开发用于镁合金激光熔覆的新型高性能合金,为镁合金表面激光熔覆的涂层设计提供参考。     

激光在镁合金表面处理中的应用

综述了激光在镁合金表面处理中的应用现状。诸多实验表明,激光表面熔凝、合金化以及激光熔覆都可提高镁合金的硬度、耐摩擦和耐腐蚀等表面性能。镁合金激光表面处理技术具有宽广的应用前景。     

基于激光熔覆不锈钢涂层技术的工艺及腐蚀性研究

通过激光熔覆技术在Q235钢表面激光熔覆316L不锈钢涂层,研究了激光熔覆工艺参数对单道熔覆层几何尺寸及外观形貌的影响。对多道熔覆层的微观组织以及耐蚀性进行了分析。结果表明:激光电流对增大熔覆层高度、宽度和深度具有积极影响,而扫描速度是熔覆层成型尺寸的消极因素。通过耐蚀性实验得出不锈钢涂层的耐腐蚀性能高于基体的耐腐蚀性能。     

激光熔覆镍基合金的耐磨耐蚀性研究

用激光熔覆和火焰重熔方法在 35CrMo调质钢表面分别熔覆上一层Ni45、Ni35合金。用电化学方法和应力腐蚀试验测定了熔覆层耐蚀性。试验结果表明 ,激光熔覆层组织的耐磨性和抗腐蚀性较火焰重熔后组织的有很大提高。其中激光熔覆Ni45粉末的熔覆层组织的耐磨、耐蚀性最好     

表面改质及强化技术

熔覆材料对铝合金激光熔覆性能的影响;镁合金表面冷喷涂铝合金的界面扩散行为;TiCCo.3No.7）／铁基复合耐磨熔覆层激光熔覆;汽缸缸套激光重熔处理工艺研究;表面纳米化焊接接头组织和结构;     

表面改质及强化技术

熔覆材料对铝合金激光熔覆性能的影响;镁合金表面冷喷涂铝合金的界面扩散行为;TiCCo.3No.7）／铁基复合耐磨熔覆层激光熔覆;汽缸缸套激光重熔处理工艺研究;表面纳米化焊接接头组织和结构;     

Laser Surface Engineering of Magnesium Alloys: A Review

Magnesium (Mg) and its alloys are well known for their high specific strength and low density. However, widespread applications of Mg alloys in structural components are impeded by their insufficient wear and corrosion resistance. Various surface engineering approaches, including electrochemical processes (plating, conversion coatings, hydriding, and anodizing), gas-phase deposition (thermal spray, chemical vapor deposition, physical vapor deposition, diamond-like coatings, diffusion coatings, and ion implantation), and organic polymer coatings (painting and powder coating), have been used to improve the surface properties of Mg and its alloys. Recently, laser surface engineering approaches are attracting significant attention because of the wide range of possibilities in achieving the desired microstructural and compositional modifications through a range of laser?Cmaterial interactions (surface melting, shock peening, and ablation). This article presents a review of various laser surface engineering approaches such as laser surface melting, laser surface alloying, laser surface cladding, laser composite surfacing, and laser shock peening used for surface modification of Mg alloys. The laser?Cmaterial interactions, microstructural/compositional changes, and properties development (mostly corrosion and wear resistance) accompanied with each of these approaches are reviewed.     

钛合金表面激光熔覆的研究进展

钛合金具有优异的物理化学性能,其在航空航天行业中被广泛应用.但钛合金的低硬度和低耐磨性能使它的应用受到了限制.激光熔覆因其熔覆层与基体结合力强,无污染等优点成为钛合金表面改性研究热点之一.钛合金表面熔覆具有不同特性的熔覆材料来提高钛合金表面的相应性能.介绍国内外钛合金激光熔覆的研究现状和发展趋势.     

Research progress of laser cladding self-fluxing alloy coatings on titanium alloys

Laser cladding is a new surface modification technology,and is widely used for fabricating wear and corrosion resistant composites coatings. Self-fluxing alloys have many advantages,such as excellent properties of deoxidizing and slagging,high wear resistance,low melting point and easy cladding,and are often used in laser cladding to improve wear and corrosion resistance of titanium and its alloys. In this paper,the recent development of Ni-based and Co-based self-fluxing alloy coatings which includes the influence of rare earth and ceramic particles in coatings are summarized. Besides,the effects of processing parameters,such as laser power and scanning speed,on coatings are reviewed. Finally,the trend of development in the future is forecasted.     

镁合金表面耐蚀改性技术

镁及镁合金是一种极具发展潜力的轻质结构材料，但镁合金的耐蚀性较差，因此进行适当的表面处理以提高镁合金的耐蚀性能已成为目前研究的热点。微弧氧化、激光表面处理、离子注入、物理气相沉积(PVD)及等离子体注入沉积(IBAD)是近年来兴起的镁合金表面耐蚀强化新技术，这几种技术在处理镁合金耐蚀性方面已取得了一定的成果。综述了目前国内外应用这几种方法提高镁合金耐蚀性方面的研究现状，并展望了其应用前景。     

激光熔覆制备高熵合金涂层的研究进展

激光熔覆技术具有高的冷却速度、低的稀释率、涂层与基体冶金结合等优点,采用激光熔覆技术制备耐磨性和耐腐蚀好的高熵合金涂层是近几年高熵合金领域的研究热点之一。首先概括了激光熔覆技术制备的高熵合金体系及组织结构特征,大多高熵合金涂层以固溶相为主,少数合金涂层形成了非晶相,与熔炼制备高熵合金块体材料相比,涂层组织具有均匀、细小致密等特点。然后介绍了涂层的性能特征,涂层具有较高的硬度、良好的耐磨性,同时指明高耐磨性涂层不仅具有高的硬度,同时还需要具有一定的塑韧性。涂层合金中大多包含有Al、Cr、Si和Co等形成稳定氧化膜的元素,呈现优异的抗腐蚀性能。随后重点概述了合金元素（Al、Mo、V、Ti、B、Ni、Nb和Cu等）、熔覆工艺参数（激光功率、扫描速度和预制层粉末厚度）和热处理工艺对涂层组织结构和性能的影响规律。其中,熔覆工艺参数对涂层组织结构和性能的影响研究相对较少,将是未来研究的重点内容之一。最后对激光熔覆技术制备高熵合金涂层存在的问题和未来的研究方向做了展望。     

镁及其合金表面处理研究现状

镁及其合金由于具有优良的性能而得到了广泛应用,但由于该合金非常活跃,很容易被腐蚀,而使其应用也受到了限制,因此可以通过适当的表面处理方法来改善镁合金的耐腐蚀性能.较系统地综述了镁合金表面处理的研究现状,介绍了以电镀和化学镀为主要内容的金属镀层处理,以普通阳极氧化和微弧氧化为主要内容的阳极氧化法以及化学转化法和高能束技术在镁合金表面处理中的应用.经这些方法处理后镁合金的耐蚀性得到了明显提高.     

Investigation of Wear and Corrosion Protection of AlSi20 Coatings Produced by Plasma Spraying and Laser Cladding on AZ31B

Magnesium and magnesium alloys are the lightest structural materials with an approximate density of 1.7 g/cm² (density of aluminum ~2.7 g/cm²). Due to poor corrosion and wear resistance properties, they need to be coated for usage in service conditions under corrosive and tribological loads. AlSi20 was found to be a suitable coating material to improve the wear and corrosion protection properties of magnesium alloys. Within this work, AlSi20 coatings were applied by plasma spraying, laser cladding, and a combination of both processes. First, the coatings are characterized by their microhardness and residual stresses formed within the coating during the different coating processes. Then, these coatings were investigated regarding corrosion resistance in 3.5% sodium chloride solution in a three-electrode setup to obtain electrochemical corrosion characteristics. Abrasive wear was investigated using a pin-on-disk tribometer and the abrasion rate was calculated. Resistance against shock loads was tested by applying a cyclic load at 50 Hz to investigate the resistance against impact stresses.     

高熵合金高能束增材制造及性能的研究进展

高熵合金（HEA）是目前材料和工程科学领域的研究热点。HEA不同于传统合金，由多种主要元素组成，因此HEA成分数量可能大大超过传统合金。HEA因其独特“近/等摩尔比”的成分构成，具备高硬度、抗氧化、抗腐蚀、耐高温、耐磨等优异的性能。增材制造（AM）与HEA结合可制备出高强度、高塑性、高度复杂几何体的金属零件。本文探讨了目前广泛使用的选区电子束熔化技术（SEBM）、选区激光熔化技术（SLM）、激光熔覆技术（LC）以及等离子熔覆技术（PC）。前两者用于制备块状HEA，后两者用于制备涂层HEA。SEBM制备的HEA延展性好，不易开裂；SLM制备的HEA成形精度、强度、表面光洁度高；LC制备的HEA熔覆层稀释度极低，组织致密；PC制备的HEA熔覆层几乎无气孔、无裂纹。本文系统总结了4种不同AM方法的技术特点，以及制备的HEA相较于传统铸造技术在微观结构特征、力学和耐腐蚀性能方面的优势，并详细介绍其内在机理。本文为开发AM制备高熵合金的前沿技术提供理论思路。     

Laser Cladding of an Al-11.7Wt%Si Alloy on ZM5 Magnesium Alloy to Enhance the Corrosion Resistance

MG and its alloys are widely used in aerospace andautomotive in industry.Its poor corrosion resistancerestricts application of Mg alloy.Laser cladding andlaser surface melting are advantageous processes forimprovement of the corrosion resistance of themagnesium alloy[1-2].In the present study,lasercladding of an Al-11.7Wt%Si alloy with two differentthickness on ZM5die cast alloy was performed withCC>2laser with different powder thickness.1.Experimental ProcedureDie cast plates of ZM5Mg a…