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1.
The kinetics of l-cystine hydrochloride reduction have been studied at a mercury-plated copper rotating disc electrode (RDE) and at a stationary mercury disc electrode (SMDE) in 0.1 mol dm−3 HCl at 298 K. The reduction of the disulphide is irreversible and hydrogen evolution is the major side reaction. In contrast to steady state electrode kinetic studies at a mercury drop electrode (which shows a well-defined limiting current), the mercury-plated Cu RDE shows overlap between disulphide reduction and hydrogen evolution. These effects are attributable to strong reactant adsorption with a calculated surface coverage close to 100%. A Tafel slope of −185 mV per decade is found with a cathodic transfer coefficient of 0.32 and a formal rate constant of 6.7 × 10−9 m s−1. The relative merits of steady state voltammetry at a mercury-plated copper RDE and linear sweep voltammetry at the SMDE are discussed, as is the mechanism of l-cysteine hydrochloride formation. 相似文献
2.
Composite G/PPy/PPy(La1−xSrxMnO3)/PPy electrodes made of the perovskite La1−xSrxMnO3 embedded into a polypyrrole (PPy) layer, sandwiched between two pure PPy films, electrodeposited on a graphite support were investigated for electrocatalysis of the oxygen reduction reaction (ORR). PPy and PPy(La1−xSrxMnO3) (0≤ x ≤0.4) successive layers have been obtained on polished and pretreated graphite electrodes following sequential electrodeposition technique. The electrolytes used in the electrodeposition process were Ar saturated 0.1 mol dm−3 pyrrole (Py) plus 0.05 mol dm−3 K2SO4 with and without containing a suspension of 8.33 g L−1 oxide powder. Films were characterized by XRD, SEM, linear sweep voltammetry, cyclic voltammetry (CV) and electrochemical impedance (EI) spectroscopy. Electrochemical investigations were carried out at pH 12 in a 0.5 mol dm−3 K2SO4 plus 5 mmol dm−3 KOH, under both oxygenated and deoxygenated conditions. Results indicate that the porosity of the PPy matrix is considerably enhanced in presence of oxide particles. Sr substitution is found to have little influence on the electrocatalytic activity of the composite electrode towards the ORR. However, the rate of oxygen reduction decreases with decreasing pH of the electrolyte from pH 12 to pH 6. It is noteworthy that in contrast to a non-composite electrode of the same oxide in film form, the composite electrode exhibits much better electrocatalytic activity for the ORR. 相似文献
3.
Electrochemical synthesis of polyaniline (PANI) on aluminum electrode from aqueous solution of 0.25 mol dm−3 aniline and 0.2 mol dm−3 sodium benzoate has been investigated under potentiodynamic and galvanostatic conditions. Initial corrosion behavior of aluminum and PANI coated aluminum electrode exposed to 3% NaCl has been investigated using electrochemical potentiodynamic and impedance spectroscopy technique (EIS). It was shown that PANI coating initially provide corrosion protection of aluminum, decreasing the corrosion current density at least 15 times. 相似文献
4.
Cobalt hydroxide film deposited on glassy carbon electrode for electrocatalytic oxidation of hydroquinone 总被引:3,自引:0,他引:3
The electrodeposition of cobalt hydroxide film on glassy carbon electrode was prepared by electrochemical method in an alkaline aqueous solution. The electrochemical behavior of hydroquinone on cobalt hydroxide film electrode has been investigated by using cyclic voltammetry and linear sweep voltammetry. The results showed that the film electrode has good electrocatalytic ability for the oxidation of hydroquinone to p-quinone. The recovery of hydroquinone from sample ranged from 94.7% to 102.9% and a rectilinear analytical curve for hydroquinone concentration from 5.0 × 10−6 to 1.25 × 10−4 mol/L was obtained. The detection limit was 5.0 × 10−7 mol/L and the relative standard deviation was 2.63%. Various factors affecting the electrocatalytic activity of cobalt hydroxide film were investigated. 相似文献
5.
This study investigated the effect of a specific adsorption ion, copper (II) ion, on the kinetics of the charge transfer reaction at a LiMn2O4 thin film electrode/aqueous solution (1 mol dm−3 LiNO3) interface. The zeta potential of LiMn2O4 particles showed a negative value in 1 × 10−2 mol dm−3 LiNO3 aqueous solution, while it was measured as positive in the presence of 1 × 10−2 mol dm−3 Cu(NO3)2 in the solution. The presence of copper (II) ions in the solution increased the charge transfer resistance, and CV measurement revealed that the lithium insertion/extraction reaction was retarded by the presence of small amount of copper (II) ions. The activation energy for the charge transfer reaction in the solution with Cu(NO3)2 was estimated to be 35 kJ mol−1, which was ca. 10 kJ mol−1 larger than that observed in the solution without Cu(NO3)2. These results suggest that the interaction between the lithium ion and electrode surface is a factor in the kinetics of charge transfer reaction. 相似文献
6.
A colloidal silver nanoparticles (CSNs) chemically modified electrode was prepared and its application to the electroanalysis of Cytochrome c (Cyt. c) was studied. The CSNs were prepared by reduction of AgNO3 with NaBH4, and were stabilized by oleate. They could be efficiently immobilized on the surface of a silver electrode. The result showed that the CSNs could clearly enhance the electron transfer process between Cyt. c and the electrode compared with bulk silver electrode. Linear sweep voltammetric measurement of Cyt. c at the chemical modified electrode indicated that the oxidative peak current of Cyt. c was linear to its concentration ranging from 8.0 nmol L−1 to 3.0 μmol L−1 with the calculated detection limit was about 2.6 nmol L−1. The direct electrochemistry of Cyt. c was also studied by cyclic voltammetry. 相似文献
7.
David Hernández-Santos 《Electrochimica acta》2005,50(9):1895-1902
In the present work, the influence of several metals (Co, Ru, Pd, Os, Pt, Cu, Pb), deposited on a carbon paste electrode, towards silver electrodeposition was tested. First, adequate conditions for the electrodeposition of metals on the electrode were found. Then, the cyclic voltammograms registered (silver deposition curves and analytical signals) showed that Co, Cu, Pt and Pd were able to accelerate silver electrodeposition. Finally, a valid methodology for the detection of cisplatin was established. It is based on the deposition of silver on a Pt (from cisplatin) modified electrode and the analytical signal corresponds to the anodic stripping of the deposited silver. A limit of detection of 3.2 × 10−9 mol dm−3 (1 ng cm−3) cisplatin was obtained. 相似文献
8.
The membrane electrode assembly (MEA) studied was constituted with a gas diffusion electrode (E-TEK) impregnated with Nafion® solution which was assembled with a Nafion® 117 cation exchange membrane under heat and pressure. The MEA was used as anode in a membrane electrolysis (ME) cell with the objective to regenerate HCl and NaOH from NaCl. Current efficiency for hydrogen oxidation was determined and its value is 100%, which indicates that the only reaction occurring at the anode is the oxidation of hydrogen. Current-potential curves, recorded in different conditions, showed a linear variation in the range 0-3000 A m−2 when hydrochloric acid concentration is below 2 mol dm−3. In this case, the overvoltage was shown to be mainly due to the ohmic drop in the membrane and in the layer where Nafion® impregnation was performed. MEA overvoltage necessary to reach 3000 A m−2 current density was about 0.12 V. For high HCl concentration (6-8 mol dm−3), the MEA overvoltage increased sharply with current density due to the adsorption of chloride anions on platinum catalyst. 相似文献
9.
Biotin was incorporated into dioleoyl phosphatidylcholine (DOPC) monolayers as dioleoyl phosphatidylethanolamine (DOPE)-biotin, DOPE-caproyl-biotin and DOPE-polyethylene glycol (PEG)-biotin. Experiments were carried out in electrolyte KCl (0.1 mol dm−3) buffered with 0.001 mol dm−3 phosphate buffer to pH 6.9. Bovine serum albumin (BSA), avidin, biotinylated anti-haemoglobin (IgG) and haemoglobin were added to the solution. The frequency dependence of the complex impedance of the coated electrode surfaces was estimated between 65,000 and 0.1 Hz at potentials −0.4 V versus Ag/AgCl 3.5 mol dm−3 KCl. The capacitance of the monolayers was measured at 75 Hz between potentials −0.4 and −1.1 V. Both non-specific and specific binding of the soluble proteins to DOPC gave rise to the occurrence of low frequency relaxations in the impedance data. The non-specific binding of BSA to DOPC can be suppressed by the incorporation of DOPE-PEG into the DOPC monolayer. The nature of the effect of specific binding of neutravidin to biotin on the impedance data depended on the positioning of the biotin group in relation to the DOPC monolayer surface. Successive binding of proteins to the biotin and then to each other gave rise to an increase in the significance of low frequency relaxations in the impedance data respectively. 相似文献
10.
A systematic investigation of the influence of Ti/[IrO2-Nb2O5] electrode composition ([IrO2]=40, 45 and 50 mol%) on electrochemical ozone production (EOP), was conducted in 3.0 mol dm−3 H2SO4 in the presence and absence of 0.03 mol dm−3 KPF6. “In situ” characterisation revealed all oxide layer presented similar structures, except for the 50 mol% IrO2 nominal composition which showed a higher porosity/roughness. The introduction of KPF6 in the electrolyte resulted in an inhibition of the oxygen evolution reaction (OER) at high current densities, improving ozone generation efficiency at i > 0.4 A cm−2, while reducing overpotential for OER. When normalised for the area, the ozone current efficiency presented a good performance of the system. However, improvement of the electrode service life is necessary in order to support the drastic conditions observed during EOP. 相似文献
11.
A new SiO2/SnO2 carbon ceramic composite was prepared by the sol-gel method, and its potential application in electrochemistry as a novel electrode material has been studied. The prepared xerogel was structurally and electrochemically characterized by scanning electron microscopy coupled to energy dispersive spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction and cyclic voltammetry. The composite was pressed in a rigid disk-shape and used as a conductive substrate to immobilize a water-soluble organic-inorganic hybrid polymer, 3-n-propyl-4-picolinium chloride silsesquioxane. The oxidation of nitrite was studied on this polymer film coated electrode in aqueous solution using cyclic voltammetry and differential pulse voltammetry. This modified electrode exhibited a better defined voltammetric peak shifted negatively about 60 mV. The linear detection limit found for nitrite was from 1.3 × 10−5 to 1.3 × 10−3 mol l−1 and the detection limit was 3.3 × 10−6 mol l−1. 相似文献
12.
The deposition and stripping processes of lead and copper and cadmium ions over the wide concentrations range of 1 × 10−5 to 5 × 10−9 M, have been studied at mercury film deposited on wax impregnated carbon paste electrode, using cyclic voltammetry, linear sweep anodic stripping voltammetry and differential pulse anodic stripping voltammetry. The carbon paste electrode modified with the mercury film was characterized for its physical and electrochemical properties. The parameters of deposition and stripping processes of the analytes have been investigated using standard solution of the metal ions at various concentrations and different supporting electrolytes and different pH. The linear sweep anodic stripping has been adopted for the determination of analytes at higher concentration whereas the analytes at lower concentrations were determined using DPASV. The DPASV behavior for the ions studied dependent on concentrations of the analyte as well as on the time used in the pre-concentration step. The method developed using standard solutions have been successfully applied for the determination of Cu(II), Pb(II) and Cd(II) in Fin Fish muscles and water samples. 相似文献
13.
Kanchan M. Samant Vrushali S. Joshi Geeta Sharma Sudhir Kapoor Santosh K. Haram 《Electrochimica acta》2011,(5):2081
We report the electrodics of methanol oxidation on Pt-multiwalled carbon nanotube composites (Pt-f-MWCNTs), prepared by γ-radiolysis of K2PtCl6 in the presence of HOOC-functionalized multiwalled carbon nanotubes. The electrocatalytic activity for the methanol oxidation was studied using cyclic and linear sweep voltammetric techniques on the stationary indium tin oxide and rotating gold disc electrodes, respectively. Higher values of oxidative (anodic) current were obtained using Pt-f-MWCNTs compared to the polycrystalline Pt electrode. This phenomenon is attributed to the synergistic effect of oxy groups on MWCNTs, which alleviate CO poisoning. The electrodics of the reaction at various temperatures was studied using linear sweep voltammetry (LSV) on a rotating disc gold electrode, modified with the composite. From the Koutecky-Levich plots, the standard rate constant (k0) was determined to be 7.9 ± 1.9 × 10−8 cm s−1. 相似文献
14.
The oxidative behavior of antibiotic roxithromycin standard was studied at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry and differential pulse voltammetry. It was found that the value of the oxidative peak of pure roxithromycin at 0.81 V vs. SCE in 0.05 M NaHCO3 at a scan rate of 50 mV s−1 is a linear function of the concentration in a range 0.10006-0.654 mg cm−3. It was also found that peak current density at 0.75 V vs. SCE at a scan rate of 2 mV s−1, pulse amplitude of 25 mV and pulse time of 0.1 s exhibits linear dependence on the concentration of roxithromycin from 0.1006 to 0.476 mg cm−3. Roxithromycin as a content of solid dosage form and urine was quantitatively determined and the obtained results were checked by HPLC. 相似文献
15.
A novel electrochemical methanol sensor based on a catalytic electrode of palladium-nickel/silicon nanowires (Pd-Ni/SiNWs) is presented in this paper. Scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and electrochemical methods are employed to investigate the Pd-Ni/SiNWs electrode materials. These nanocomposite materials exhibit a highly ordered, wire-like structure with a wire length of ∼50 μm and a wire diameter ranging from 100 to 300 nm. The substrate has good electrocatalytic activity towards the oxidation of methanol in alkaline solutions. The performances of the prototype sensor are characterized by cyclic voltammetry and fixed potential amperometry techniques. In a 1 mol L−1 KOH solution containing different methanol concentrations, the sensor exhibits a good sensitivity of 1.96 mA mmol−1 L cm−2 with R2 = 0.99 and the corresponding detection limit of 18 μmol L−1 (signal-to-noise ratio = 3, S/N = 3) for cyclic voltammetry. Meanwhile, the electrode also displays a sensitivity of 0.48 mA mmol−1 L cm−2 with R2 = 0.98 and the corresponding detection limit of 25 μmol L−1 (S/N = 3) for a fixed potential amperometry at −0.3 V versus an Ag/AgCl reference electrode. The results demonstrate that the Pd-Ni/SiNWs catalytic electrode has potential as an efficient and integrated sensor for methanol detection. 相似文献
16.
A new gold nanoparticles-modified electrode (GNP/LC/GCE) was fabricated by self-assembling gold nanoparticles to the surface of the l-cysteine-modified glassy carbon electrode. The modified electrode showed an excellent character for electrocatalytic oxidization of uric acid (UA) and ascorbic acid (AA) with a 0.306 V separation of both peaks, while the bare GC electrode only gave an overlapped and broad oxidation peak. The anodic currents of UA and AA on the modified electrode were 6- and 2.5-fold to that of the bare GCE, respectively. Using differential pulse voltammetry (DPV), a highly selective and simultaneous determination of UA and AA has been explored at the modified electrode. DPV peak currents of UA and AA increased linearly with their concentration at the range of 6.0 × 10−7 to 8.5 × 10−4 mol L−1 and 8.0 × 10−6 to 5.5 × 10−3 mol L−1, respectively. The proposed method was applied for the detection of UA and AA in human urine with satisfactory result. 相似文献
17.
Electrochemical sensor for sulfite determination based on a nanostructured copper-salen film modified electrode 总被引:1,自引:0,他引:1
Tony R.L. Dadamos 《Electrochimica acta》2009,54(19):4552-1258
The electrochemical preparation described herein involved the electrocatalytic oxidation of sulfite on a platinum electrode modified with nanostructured copper salen (salen = N,N′-ethylenebis(salicylideneiminato)) polymer films. The complex was prepared and electropolymerized at a platinum electrode in a 0.1 mol L−1 solution of tetrabutylammonium perchlorate in acetonitrile by cyclic voltammetry between 0 and 1.4 V vs. SCE. After cycling the modified electrode in a 0.50 mol L−1 KCl solution, the estimated surface concentration was found to be equal to 2.2 × 10−9 mol cm−2. This is a typical behavior of an electrode surface immobilized with a redox couple that can usually be considered as a reversible single-electron reduction/oxidation of the copper(II)/copper(III) couple. The potential peaks of the modified electrode in the electrolyte solution (aqueous) containing the different anions increase with the decrease of the ionic radius, demonstrating that the counter-ions influence the voltammetric behavior of the sensor. The potential peak was found to be linearly dependent upon the ratio [ionic charge]/[ionic radius]. The oxidation of the sulfite anion was performed at the platinum electrode at +0.9 V vs. SCE. However, a significant decrease in the overpotential (+0.45 V) was obtained while using the sensor, which minimized the effect of oxidizable interferences. A plot of the anodic current vs. the sulfite concentration for chronoamperometry (potential fixed = +0.45 V) at the sensor was linear in the 4.0 × 10−6 to 6.9 × 10−5 mol L−1 concentration range and the concentration limit was 1.2 × 10−6 mol L−1. The reaction order with respect to sulfite was determined by the slope of the logarithm of the current vs. the logarithm of the sulfite concentration. 相似文献
18.
The influence of poisoning of Pt catalyst by CO on the kinetics and mechanism of H2 oxidation reaction (HOR) at Pt/C electrode in 0.5 mol dm−3 HClO4, saturated with H2 containing 100 ppm CO, was examined with rotating disc electrode (RDE) at 22 °C. Commercial carbon black, Vulcan XC-72 was used as support, while Pt/C catalyst was prepared by modified polyol synthesis method in an ethylene glycol (EG) solution. The kinetically controlled current (Ik) for the HOR at Pt/C decreases significantly at CO coverage (ΘCO) > 0.6. For ΘCO < 0.6 the HOR takes place through Tafel-Volmer mechanism with Tafel reaction as rate-determining step at the low CO coverage, while Volmer step controls the overall reaction rate at the medium CO coverage. When CO coverage is higher then 0.6, Heyrovsky-Volmer mechanism is operative for the HOR with Heyrovsky as the rate-determining step (rds). 相似文献
19.
Iolana Campestrini 《Electrochimica acta》2010,55(17):4970-527
A bismuth-film electrode for use in cathodic electrochemical detection was employed in order to quantify sulfadiazine in pharmaceutical formulations. The bismuth film was deposited ex situ onto a glassy carbon substrate. Analysis of two sulfa drugs was carried out by differential-pulse voltammetry in 0.05 mol L−1 Britton-Robinson pH 4.5 solution. Sulfadiazine reduction was observed at −0.74 V vs. Ag/AgCl in one well-resolved irreversible reduction peak. The analytical curve with two slopes was obtained in the concentration range of 3.2-97.0 μmol L−1. The detection limit was 2.1 μmol L−1 for concentrations of 3.2-20.0 μmol L−1 (r = 0.9949) and 12.2 μmol L−1 for concentrations between 20.0 and 97.0 μmol L−1 (r = 0.9951). Recovery studies carried out with both sulfadiazine samples gave values from 93.6 to 109.3%. The accuracy of the results supplied by the bismuth-film electrode was compared to those obtained by the standard amperometric titration method. The relative error between them was lower than 2.0%. 相似文献
20.
Margarita Stoytcheva Roumen Zlatev Benjamin Valdez Lubomir Petkov 《Electrochimica acta》2009,54(6):1721-1727
An electrochemical biosensor for organophosphorus (OP) pesticides trace level concentrations determination was developed and characterized. It integrates a hybrid biorecognition element consisting of immobilized Arthrobacter globiformis and free acetylcholinesterase (ACh) with a Clark type oxygen probe transducer. The bacteria convert the ACh-generated choline to betaine with oxygen consumption measured as a Clark probe current change. This change representing the sensor response correlates to the concentration of the OP pesticides inhibiting the Ach-catalyzed acetylcholine hydrolysis to choline. The conditions for maximal sensor response to choline were optimized according to the methodology of design of experiments. The analytical performances of the enzyme substrate determination in a wide concentration range (0.1-20 μmol dm−3 of acetylcholine) and different ACh activities were established. It was demonstrated that the biosensor ensures reproducible, accurate and reliable chlorophos quantification reaching a limit of detection (LOD) of 1 nmol dm−3 and a sensitivity of 0.0252 μA/p(mol dm−3) under optimal experimental conditions. The biosensor response time is 200 s and the storage stability is tL50 = 49 days for the bacterial membrane at ambient temperature. The device is reusable, the bacterial membrane being not affected by OP. The biosensor was applied to chlorophos determination in contaminated milk. 相似文献