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The Al-Si alloy matrix composite reinforced by γ-Al2O3 particles was produced by adding NH4AlO(OH)HCO3(AACH) into molten Al-Si alloy at 850℃. During stirring γ-Al2O3 particles are formed by the decomposing reaction of AACH. It is found that the γ-Al2O3 particles distribute more uniformly in the matrix by adding AACH than by adding γ-Al2O3 directly. The wear tests show that the volume loss of the unreinforced Al-Si alloy matrix is about 3 times larger than that of the γ-Al2O3 reinforced composites and that of the composites fabricated by adding γ-Al2O3 is larger than that by adding AACH. 相似文献
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The 1.0%Al2O3/Cu (mass fraction) composite was prepared by hot pressing (HP), then treated by rolling to get a full density. The microstructures and the micro area element distribution of the composite were analyzed by SEM. The density, electric conductivity and tensile strength were also investigated. The experimental results show that the alumina particles are more dispersed and become smaller through a single-pass rolling. The pore existing in the composite is eliminated or closed under the rolling force. The relative density increases from 98.4% to 99.2%. The electric conductivity increases from 88.9%IACS to 91.2%IACS. The tensile strength is increased by 47% from 300 MPa to 440 MPa. 相似文献
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Al2O3/TiAl composites were fabricated by PAXD (pressure-assisted exothermic dispersion) method. The effects of Nb205 content on the microstructure and mechanical properties of the composites were investigated. The results show that the ultimate phases of the composite consist of TiAl, Ti3Al, Al2O3 and a small amount of NbA13. SEM reveals that a submicron γ+(α2/γ) dual phases structure can be presented after sintered at 1 200 ℃, Furthermore, with the increase of Nb205 content, the ratio of TiAl to Ti3Al phase decreases correspondingly, the grains of the corflposites are remarkably refined, and the produced Al2O3 particles are uniformly dispersed. When 6% Nb205 is added, the composite has the best comprehensive properties. It exhibits a Vickers hardness of 4.77 GPa and a bending strength of 642 MPa. Grain-refinement and dispersion-strengthening are the main strengthening mechanisms. 相似文献
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The thermodynamic data of pure Ag and Y were calculated. The phase constitution, composition of micro-region and microstructures of Ag-Y alloy after internal oxidation were investigated by X-ray diffractometry(XRD), energy dispersion spectrometry(EDS) and scanning electron microscopy(SEM). The results show that the internal oxidation behavior of Ag-Y alloy is feasible from the view of thermodynamics. The upper limit of oxygen partial pressure of Ag-Y alloy oxidation is a function of temperature. Two phases (Ag and Y2O3) appear in Ag-Y alloy after the internal oxidation. The surface of Ag-Y alloy is convex because of the volume expansion of oxide in the alloy and the composition of the convex part is Ag. In Ag-Y2O3 sintered bulk Y2O3 particles are distributed inhomogeneously and conglomerated seriously, but they are dispersed uniformly in the Ag matrix after severe plastic deformation. 相似文献
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The electrodeposited Y2O3-dispersed γ-Ni+γ-Ni3Al coatings on Ni substrates were developed by the conversion of electrodeposited Ni-Al-Y2O3 films with dispersed AI microparticles in Ni matrix into Ni3Al by vacuum annealing at 800 ℃ for 3 h. For comparison, Y2O3-free γ-Ni+γ'-Ni3Al coatings with a similar AI content were also prepared by vacuum annealing the electrodeposited microparticle-dispersed composite coatings of Ni-AI under the same condition. SEM and TEM characterizations show that the electrodeposited Y2O3-dispersed γ+γ' coatings exhibit finer grains, a more homogeneous distribution of γ', and a narrowed γ' phase spacing compared with the electrodeposited Y2O3-free γ-γ' coatings. The oxidation at 1 000 ~C shows that the addition of Y2O3 significantly improves the oxidation resistance of the electrodeposited γ+γ'coatings. The effect of Y2O3 particles on the microstructure and oxidation behavior of the electrodeposited γ+y' coatings was discussed in detail. 相似文献
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The electrodeposited Y2O3-dispersed γ-Ni γ'-Ni3Al coatings on Ni substrates were developed by the conversion of electrodeposited Ni-Al-Y2O3 films with dispersed Al microparticles in Ni matrix into Ni3Al by vacuum annealing at 800 ℃ for 3 h. For comparison, Y2O3-free (γ-Ni γ'-Ni3Al coatings with a similar Al content were also prepared by vacuum annealing the electrodeposited microparticle-dispersed composite coatings of Ni-Al under the same condition. SEM and TEM characterizations show that the electrodeposited Y2O3-dispersed γ γ' coatings exhibit finer grains, a more homogeneous distribution of γ', and a narrowed γ' phase spacing compared with the electrodeposited Y2O3-free γ γ' coatings. The oxidation at 1 000 ℃ shows that the addition of Y2O3 significantly improves the oxidation resistance of the electrodeposited γ γ'coatings. The effect of Y2O3 particles on the microstructure and oxidation behavior of the electrodeposited γ γ' coatings was discussed in detail. 相似文献
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QUShoujiang GENGLin MENGQingchang FENGAihan LEITingquan 《稀有金属(英文版)》2005,24(1):95-99
A 20 vol.% SiCp/Al composite was fabricated by squeeze casting, of which a new process for fabricating the preform was used by blending Al powder and SiC particulates with average diameters of 10 and 3.5μtm, respectively. The microstructure of the as-cast and the hot-rolled composite was investigated by using TEM, EDS, and SEM, and their tensile properties were measured at room temperature. The results show that the ultimate tensile strength and ultimate elongation of the hot-rolled composite are 80% and 140% higher than those of the as-cast one. The TEM observation result indicates that there are high density of dislocations and dislocation tangles in the hot-rolled composite. Al2O3 layers in the composite resuiting from the surface oxidation of the aluminum powders were damaged to spherical particles during hot rolling. All the results indicate that hot-rolling can improve the mechanical properties of the composite and, therefore, engineering components of the 20 vol.% SiCp/Al composite can be produced by squeeze casting followed by hot-rolling. 相似文献
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The effect of sintering process and ZrO2 contents on formation of intragranular ZrO2 in Al2O3 matrix was investigated with α-Al2O3 micro-powders and ZrO2 nano-powders as original materials. It is found that the secondphase particles coalesce with the growth of matrix grains during sintering. The process conditions that benefit the growth of matrix grains benefit the formation of intragrains. The formation procedure of intragrains could be described as follows. At first, the particles are driven to agglomerate during densification of the matrix. Some particles move along with the migration of the matrix grain boundaries and tend to further gather, then become intergrains. Those gripped between the matrix grain boundaries become intragrains during the growth of matrix grains. 相似文献
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The extruded Mg-12Gd-3Y-0.4Zr alloy sheets were rolled from 30 mm to 2.3 mm at 723 K by electric heated rollers,and then different heat treatments were performed to improve their properties.The microstructures and tensile properties of the alloy sheets were investigated,including as-rolled,annealed and T5 treated.The experimental results show that the grains are effectively refined by the rolling process,and the strength of the rolled alloy is greatly enhanced.The annealed alloy exhibits lower strength a... 相似文献
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An Al2O3 protective coating on magnesium alloy AZ31 was prepared by a repeated direct sol-gel process annealing at 300℃and a composite coating was also deposited using Al2O3 particles dispersed sol followed by phosphating treatment and annealing at 300℃.The morphologies,structures and critical adhesive loads as well as corrosion properties of the coatings were comparatively investigated by scanning electron microscopy(SEM),X-ray diffractometry(XRD),nanoscratch test and electrochemical measurement.The results show that the composite coating has a more uniform,crack-free layer and improved adhesion to the substrate as compared with that of the repeated direct sol-gel coating owing to its lower heat strain.The main phases in both coatings consist ofγ-Al2O3 andδ-Al2O3 derived from annealed alumina sol,and the composite coating has an anticorrosion performance which is superior to that of the repeated direct sol-gel coating. 相似文献
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混合稀土对Cu-Al合金薄板内氧化组织和性能的影响 总被引:1,自引:1,他引:0
采用内氧化工艺,以工业N2中余氧为氧源,在950℃使Cu-Al-RE合金薄板内氧化成功制备了Al2O3/Cu复合材料,并对其显微硬度、电导率进行测试,用透射电子显微镜(TEM)对内氧化生成相和微观亚结构进行了分析.结果表明,与未添加混合稀土相比,Cu-Al-0.05(Ce+Y)合金950℃×2h内氧化层深度增加了22.8%,表现出明显的稀土催渗作用;TEM分析表明,在铜基体上弥散分布着大量细小均匀的γ-Al2O3颗粒;适晕添加混合稀土改善了合金的导电性,提高了合金的显微硬度,添加0.05%(Ce+Y)的Cu-Al-RE内氧化后综合性能最优. 相似文献
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Effects of composite scale on high temperature oxidation resistance of Fe-Cr-Ni heat resistant alloy
Fe-Cr-Ni heat resistant alloys with aluminum and silicon addition, alone and in combination, were melted using an intermediate frequency induction furnace with a non-oxidation method. By the oxidation weight gain method, the oxidation resistances of the test alloys were determined at 1,200 ℃ for 500 hours. According to the oxidation weight gains, the oxidation kinetic curves were plotted and the functions were regressed by the least squares method. The results show that the oxidation kinetic curves follow the power function of y = axb (a0,0相似文献
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Li Guobin 《中国有色金属学会会刊》1999,9(3)
1 INTRODUCTIONPurecopperanditsalloyshavegoodelectricalandheatconductivityandpoormechanicalpropertiessothattheycannotoftenmeettheneedsofmodernindustry.Intheconditionofkeepinghighconductivity,howtoimprovethemechanicalproperties,especiallyhotstrengthan… 相似文献
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纳米γ-Al2O3的溶胶-凝胶法制备及表征 总被引:1,自引:0,他引:1
异丙醇铝为先驱体,异丙醇为溶剂,乙酰乙酸乙酯为螯合剂,聚乙二醇(PEG1000)为分散剂,硝酸为胶溶剂,采用溶胶-凝胶法制备了纳米γ-Al2O3.并采用DTA/TG,XRD,TEM等测试技术对纳米γ-Al2O3粉体进行表征.结果表明,通过溶剂、螯合剂、分散剂和胶溶剂的协同效应,在750℃煅烧条件下,γ-Al2O3粒子形貌为针状结构,长度为20~30 nm;在900℃煅烧条件下,γ-Al2O3粒子形貌为颗粒状,平均晶粒尺寸为10 nm左右;纳米γ-Al2O3粒子尺寸均一、分散性良好. 相似文献
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运用等离子喷涂技术在7005铝合金表面制备Al2O3-40%TiO2纳米结构颗粒增强镍基合金复合涂层,分析其微观结构,研究其在不同载荷和速度条件下的摩擦磨损性能。结果表明:复合涂层主要由γ-Ni、α-Al2O3、γ-Al2O3和金红石型-TiO2等相组成,其摩擦因数和磨损失重较镍基合金涂层显著降低。在轻载3 N 时,复合涂层磨损表面的接触应力较低,主要发生微观切削磨损;当载荷上升至6~12 N时,接触应力高于磨损表面的弹性极限应力,复合涂层的磨损机理变为多次塑变磨损、微观脆性断裂磨损和磨粒磨损。随着速度的增大,磨损表面的接触温度逐渐升高,复合涂层以多次塑变磨损、疲劳磨损和粘着磨损为主。 相似文献
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Cu-Al合金内氧化产物及其体积分数的测定 总被引:4,自引:0,他引:4
利用萃取方法研究了Cu-Al合金的内氧化产物及其晶 体结构,测定了Al2O3的体积分数.分析表明该方法简单、有效,既可用于内氧化的动 力学研究,又可利用其进行定性定量分析,本实验条件下Cu-Al2O3复合材料的增强体以 晶内纳米γ-Al2O3为主,含有一定量的界面θ-Al2O3和α-Al2O3. 相似文献