粒径对超细空心镍球光吸收性能的影响

用自催化还原法制备不同粒径的超细窄心镍球,用场发射扫描电镜和透射电镜观察空心镍球的形貌,并通过粒度分析仪和X-Ray衍射仪等对其粒径对光吸收性能的影响进行研究.结果表明,在紫外一近红外区,随着粒径减小,镍球的光吸收性能明显增强;纳米尺寸的镍球在紫外光区的吸收特性与大粒径镍球明显不同,前者在375 am处产生一个吸收峰;而在中红外区域,空心镍球具有很弱的光吸收能力.经过氧气气氛下热处理后,空心镍球的晶粒尺寸变大,其在紫外一近红外区域的光吸收减弱,纳米级的空心镍球,原来在375 nm的吸收峰移到了440 nm,这可能是由于晶粒尺寸增大所致.     

Thermal property measurements of metal injection moulded Inconel 625 and Inconel 718 using combined thermal analysis techniques

ABSTRACT

The high-temperature thermal properties of powder metallurgy derived superalloys have not been reported in the literature. In this study, the coefficient of thermal expansion (CTE), specific heat and thermal diffusivity of metal injection moulded (MIM) Inconel 625 and Inconel 718 were measured. Measurements of wrought Nickel 200 were also made to verify the methods. These thermal property measurements were made in the range of room temperature to 1000–1200°C using dilatometry, differential scanning calorimetry and laser flash analysis. Thermal conductivity of all three materials was calculated using the measured diffusivity, specific heat and CTE. All the MIM results were compared to published data for the wrought form of these alloys and found to be in close agreement outside of phase transition regions.     

Environmental effects on cellular photosensitization: correlation of phototoxicity mechanism with transient absorption spectroscopy measurements

The presence of actin in eukaryotic nuclei and chromosomes, and especially in higher plant nuclei and chromosomes, has not been well established. We detected actin in meristematic cells of Allium cepa with indirect immunofluorescence technique and observed bright fluorescence in the intact nuclei and chromosomes, indicating that actin is present in the nuclei and chromosomes of the higher plant. We labeled sections of the meristematic cells of A. cepa with immunogold technique, gold particles were found over the whole nuclei and a number of gold particles were concentrated in condensed chromatin and nucleoli, confirming the results of the immunofluoresence observations. We treated the nuclei and chromosomes of A. cepa with DNase I and 2M NaCl and obtained DNA- and histone-depleted nuclei and chromosomes. Indirect immunofluorescence tests showed that the DNA- and histone-depleted nuclei and chromosomes reacted positively with the anti-actin antibodies. These results demonstrate that actin exists not only in intact nuclei and chromosomes, but also in DNA- and histone-depleted nuclei and chromosomes of the plant. In addition, our immuno-fluorescence tests indicate that tropomyosin is present in the nuclei and chromosomes of A. cepa.     

Determination of refractive index and absorption coefficient of iron- oxide-bearing slags

The refractive index and absorption coefficient of amorphous Fe₂O₃-SiO₂-CaO-Al₂O₃ slags have been determined at room temperature as functions of the basicity of [mass pct CaO]/[mass pct SiO₂] and the Fe₂O₃ concentration. The refractive index has been measured by an ellipsometer at 546 nm, and the absorption coefficient has been determined from transmittance measured by a spectrophotometer in the wavelength range of 350 to 1000 nm. The refractive index increases with increasing basicity of [CaO]/[SiO₂] and the Fe₂O₃ concentration. On the other hand, with decreasing basicity of [CaO]/[SiO₂], the absorption coefficient is increased in the near-infrared region, and the absorption edge by the charge transfer band is shifted to a shorter wavelength. With increasing Fe₂O₃ concentration, the absorption coefficient is increased in the measured wavelength range, and the absorption edge by the charge transfer band is shifted to a longer wavelength. These dependences of refractive index and absorption coefficient on the basicity and the Fe₂O₃ concentration are discussed.     

火焰原子吸收法测定钨铁中铜量

研究了用草酸 -过氧化氢分解样品 ,并探讨了酸度、干扰离子对测定结果的影响 ,提出了用火焰原子吸收光谱法测定钨铁中铜量     

CO2吸收模型中容积传质系数的确定

气泡微细化是“原位机械搅拌法铁水炉外脱硫技术”的关键.气液传质系数是研究气液吸收过程的基本参数.本文根据相似性原理建立水模型实验装置,并通过测定NaOH吸收CO2的速率来研究气泡微细化过程,同时根据吸收原理定量计算出容积传质系数Ak及CO2气体利用率η.当溶液pH值从12降低到9的过程中,容积传质系数为2.938×10 4m3/s,本实验所用CO2的利用率的公式可简化为:η=18.98/Qt.本论文的研究结果可为进一步研究吸收速率提供理论依据.