碱洗塔洗塔系统的优化

介绍了氯乙烯合成工段碱洗塔洗塔工艺流程,并针对存在的问题对其进行了优化升级,使碱洗塔自控洗塔、配碱,提高了系统的自动化控制水平,节约了水资源,也降低了废水处理系统的负荷,最大限度地提高了碱液的利用率,提高了工作效率,增加了经济效益,     

焦炉生产操作改进

介绍了焦炉生产中的改进措施,通过改进装煤方式,减少了装煤冒烟;配制新型填料,增强了炉体维护;改进了1M管的冲洗方式;改进炉顶水箱槽的高度;降低上升管底座的高度,杜绝连接处冒烟;改进装煤孔底座。通过采取这些改进措施,大大降低了生产成本,改善了职工的操作环境,降低了职工的劳动强度,提高了职工的工作效率,有效地保障了生产的平稳顺行。     

带式过滤机在多品种氢氧化铝生产中的应用

介绍了带式真空过滤机的工作原理及其在多品种氢氧化铝生产方面的应用情况,并对带式真空过滤机使用过程中存在的问题进行了改造。改造之后,提高了洗涤过滤效率,降低了滤饼水分,降低了能耗,提高了产量,确保了产品质量,取得了较好的经济效益。     

个性营销能否撑起陶瓷企业那片天

前些天在杂志上看到过一个故事,说的是中国人和犹太人的区别,一个犹太人建了一所加油站,生意很好,第二个犹太人来了,就在加油站旁边建了一座购物中心,生意同样很好,第三个犹太人来了,就在旁边又建了一座游乐场,生意照样很好,第四个犹太人来了,就开了一家4S店,生意也是好的不得了,第五个犹太人来了,他建的是公共卫生间,也赚到了钱。可是在我国呢,第一个人建了一个加油站,赚钱了,第二个人看到了,觉得有利可图,也建了一个加油站,结果第三个,第四个,     

高庄煤矿供热系统的改造

高庄煤矿针对原锅炉供热系统存在的问题进行了改造,拆除原锅炉,采用邻矿电厂的富余蒸气作热源,安装热交换器组。改造后保证了供热质量,节约了能源、资源,提高了矿区环境质量,降低了运行维护费用,节省了人力资源,减少了占地面积,节约了各项检查检测费用。     

2010年度工作会议

<正>2010年1月16日—17日,公司召开了2010年度工作会议。会议认真回顾总结了2009年的主要工作,分析了当前的形势和机遇,部署了2010年的工作任务。会上,公司董事长蒋明作了重要讲话,总经理毛绍融作了行政工作报告,党委副书记陈百河作了党委工作报告,副总     

患者住院费用明细在临床中的应用

住院费用明细的实施,让患者真正明白了医疗费用的每一笔开支,增加了医院的透明度,密切了医患关系,维护了医患双方的利益,赢得了患者及家属的信任,减少了医疗纠纷,树立了医院良好的社会形象。     

庄信万丰发布《铂金2009年年鉴》

据庄信万丰公司最近出版的《PLATINUM 2009》报道,2008年,全球铂金市场出现了11.7t的短缺,铂金的供应量下降了9.5%,达到了185.7t。汽车尾气净化催化剂行业对铂金的需求下降了8.2%,达到了118.3t。除去回收料,全球首饰行业对铂金原材料的需求下降了6.2%,达到了42.5t。     

焦炉生产操作改进

介绍了焦炉生产中的改进措施,通过改进装煤方式,减少了装煤冒烟;配制新型填料,增强了炉体维护;改进了1M管的冲洗方式;改进炉顶水箱槽的高度;降低上升管底座的高度,杜绝连接处冒烟;改进装煤孔底座.通过采取这些改进措施,大大降低了生产成本,改善了职工的操作环境,降低了职工的劳动强度,提高了职工的工作效率,有效地保障了生产的平...     

湿法除尘技术在三氯氢硅生产中的应用

分析了三氯氢硅生产过程中水冷器堵塞严重的原因,介绍了湿法除尘技术在三氯氢硅行业中的研究和应用.湿法除尘技术的应用有效地解决了冷凝系统的堵塞问题,使得整个生产系统实现长期稳定运行,不仅提高了生产效率,降低了生产成本,解决了频繁拆洗水冷器造成的现场污染,改善了工作环境,降低了劳动强度,同时杜绝了安全隐患.     

Computational Investigation of the Thermochemistry and Kinetics of Steam Methane Reforming Over a Multi-Faceted Nickel Catalyst

A microkinetic model of steam methane reforming over a multi-faceted nickel surface using plane-wave, periodic boundary condition density functional theory is presented. The multi-faceted model consists of a Ni(111) surface, a Ni(100) surface, and nickel step edge sites that are modeled as a Ni(211) surface. Flux and sensitivity analysis are combined to gain an increased understanding of the important reactions, intermediates, and surface facets in SMR. Statistical thermodynamics are applied to allow for the investigation of SMR under industrially-relevant conditions (e.g., temperatures in excess of 500 °C and pressures in excess of 1 bar). The most important surface reactions are found to occur at the under-coordinated step edge sites modeled using the Ni(211) surface as well as on the Ni(100) surface. The primary reforming pathway is predicted to be through C* + O* ?? CO* at high temperatures; however, hydrogen-mediated reactions such as C* + OH* ?? COH* and CH* + O* ?? CHO* are predicted to become more important at low temperatures. The rate-limiting reactions are predicted to be dissociative chemisorption of methane in addition to the aforementioned C?CO addition reactions.     

Sensitivity differences in Chroma,Hue, and Lightness from several classical threshold datasets

A check of the weighting functions proposed by the CIE Technical Committee 1-29 (TC1-29) [Color Res. Appl. 18 , 137–139 (1993)] has been carried out using pairs of samples with only a threshold difference in chroma, hue, or lightness. Experimental results with object and aperture colors were used and some parametric factors can be appointed: the dependence of ΔC* on C* appears to be about two times stronger for related color versus the aperture color mode; and the ΔH* dependence on C*, weak but significant for related colors, becomes insignificant for aperture colors. the hue-angle dependences of ΔH* after correction for C* and the dependences of ΔL* on L* or C* are found not significant for aperture colors. After normalization of the five different datasets employed, the results achieved are in overall good agreement and support the proposal of the CIE TC1-29.     

Additive-Free Enzymatic Phosphorylation and Ligation of Artificial Oligonucleotides with C-Nucleosides at the Reaction Points

We report enzymatic phosphorylation and additive-free ligation of DNAs containing unnatural C-nucleotide residues through the action of T4 polynucleotide kinase and T4 DNA ligase. The artificial units are each made up of an alkynyl deoxyribose component and one of the unnatural nucleobases D * , T * , G * , and C * , corresponding—from a viewpoint of hydrogen-bonding patterns—to natural A, T, G, and C, respectively. Phosphorylation progressed quantitatively at the 5′-end in the cases of all of the artificial units in the chimeric DNAs. Ligation also smoothly progressed at the 5′-end in the cases of the D* and G* nucleotide residues, but only negligibly in those of their T* and C* counterparts. Chemical redesign of the last two units successfully improved the ligation efficiency, so that enzymatic ligation worked well for all of the artificial units in every 3′-natural ⋅ 5′-artificial, 3′-artificial ⋅ 5′-natural, and 3′-artificial ⋅ 5′-artificial terminal combination at the nicks.     

Plasma Modified Membrane for Daily Recovery of Oil from Repeated Frying Operation with Frequent Oil Replenishment

Sunflower oil was used for deep frying of potatoes at 170 ± 5 °C and for 8 h per day for 5 days in a fryer with an automatic oil filtration system. Three different frying operations were performed: operation (OP)-1, OP-2 and OP-3; that correspond to the oil unfiltered at the end of each frying day, the oil filtered through the fryer's own filter (passive filtration) and the oil firstly subjected to passive filtration and then filtered through a polyethersulfone membrane modified with hexamethyldisiloxane via radio frequency plasma (75 W-5 min, discharge power–time), respectively. The performance of each operation was investigated in terms of free fatty acids (FFA), conjugated dienoic acids (CD), TOTOX value, total polar content (TPC), Hunter color, viscosity, fatty acid composition, and tocopherol content. The results showed that OP-3 could decrease FFA, CD, TOTOX, TPC, L*a*b* value, viscosity and linoleic acid (18:2)/palmitic acid (16:0) ratio in 29.6, 11.7, 25, 30.8, 6.1*11.3*20.8*, 7.8, 12.2 %, respectively, compared to the unfiltered oil (OP-1). Regenerated oil from OP-3 had a frying life approximately 17 h more than oils from both OP-1 and OP-2.     

Insights into the Genetic Variations of Human Cytochrome P450 2C9: Structural Analysis,Characterization and Comparison

Cytochromes P450 (CYP) are one of the major xenobiotic metabolizing enzymes with increasing importance in pharmacogenetics. The CYP2C9 enzyme is responsible for the metabolism of a wide range of clinical drugs. More than sixty genetic variations have been identified in CYP2C9 with many demonstrating reduced activity compared to the wild-type (WT) enzyme. The CYP2C9*8 allele is predominantly found in persons of African ancestry and results in altered clearance of several drug substrates of CYP2C9. The X-ray crystal structure of CYP2C9*8, which represents an amino acid variation from arginine to histidine at position 150 (R150H), was solved in complex with losartan. The overall conformation of the CYP2C9*8-losartan complex was similar to the previously solved complex with wild type (WT) protein, but it differs in the occupancy of losartan. One molecule of losartan was bound in the active site and another on the surface in an identical orientation to that observed in the WT complex. However, unlike the WT structure, the losartan in the access channel was not observed in the *8 complex. Furthermore, isothermal titration calorimetry studies illustrated weaker binding of losartan to *8 compared to WT. Interestingly, the CYP2C9*8 interaction with losartan was not as weak as the CYP2C9*3 variant, which showed up to three-fold weaker average dissociation constant compared to the WT. Taken together, the structural and solution characterization yields insights into the similarities and differences of losartan binding to CYP2C9 variants and provides a useful framework for probing the role of amino acid substitution and substrate dependent activity.     

Influence of Genetic Variations on Levels of Inflammatory Markers of Healthy Subjects at Baseline and One Week after Clopidogrel Therapy; Results of a Preliminary Study

We aimed to assess the association between the most common polymorphisms of cytochrome P450 (CYP) epoxygenases on the plasma levels of inflammatory markers in a population of healthy subjects. We also sought to determine whether CYP2C19*2 polymorphism is associated with the anti-inflammatory response to clopidogrel. In a population of 49 healthy young males, the baseline plasma levels of inflammatory markers including C-reactive protein, haptoglobin, orosomucoid acid, CD-40 were compared in carriers vs. non-carriers of the most frequent CYP epoxygenase polymorphisms: CYP2C9*2, CYP2C9*3, CYP2C19*2, CYP2C8*2 and CYP2J2*7. Also, the variation of inflammatory markers from baseline to 7 days after administration of 75 mg per day of clopidogrel were compared in carriers vs. non-carriers of CYP2C19* allele and also in responders vs. hypo-responders to clopidogrel, determined by platelet reactivity tests. There was no significant association between epoxygenase polymorphisms and the baseline levels of inflammatory markers. Likewise, CYP2C19* allele was not associated with anti-inflammatory response to clopidogrel. Our findings did not support the notion that the genetic variations of CYP epoxygenases are associated with the level of inflammatory markers. Moreover, our results did not support the hypothesis that CYP2C19*2 polymorphism is associated with the variability in response to the anti-inflammatory properties of clopidogrel.     

Compatibility of Dye Mixtures

The dyeing behaviour of a number of dye mixtures on three types of fibre has been studied by the method based on assessment of colour build up under practical dyeing conditions, as well as under ideal conditions. Some a*b* and L*C*_ab diagrams are constructed for both the conditions. These diagrams give valuable information about the dyeing behaviour of the dye mixtures. The technique reported in this paper will prove useful to a practical dyer for determining the compatibility of dyes in mixtures.     

Manifestations of stereoelectronic interactions in 1JC-H one-bond coupling constants

Two-electron/two-orbital hyperconjugative interactions depend on the relative orientation of bonds and lone pairs in a molecule and are also inversely proportional to the energy difference between the interacting orbitals. Spectroscopic manifestations of stereoelectronic interactions are particularly useful experimental signatures of these effects which can be utilized for testing molecular models. Empirical observations together with theoretical interpretations in cyclohexane and six-membered heterocycles confirm the relevance of sigma C-H ax --> sigma* C-H ax , n X --> sigma* C-H ax (X = O or N), sigma C-S --> sigma* C-H eq , beta-n O --> sigma* C-H eq , sigma C(2)-H ax --> pi* CY (Y = O, S, or CH 2), and sigma C(2)-H ax --> sigma* S-O ax two-electron/two-orbital stereoelectronic interactions that weaken the acceptor (or donor) C-H bonds and attenuate the Fermi contribution to the one-bond (13)C- (1)H coupling constants.     

Effect of classification by competitive neural network on reconstruction of reflectance spectra using principal component analysis

The best way to describe a color is to study its reflectance spectrum, which provide the most useful information. Different methods were purposed for reflectance spectra reconstruction from CIE tristimulus values such as principal components analysis. In this study, the training samples were first divided into 3, 6, 9, and 12 subgroups by creating a competitive neural network. To do that, L*a*b*, L*C*h or L*a*b*C*h were introduced to neural network as input elements. In order to investigate the performance of reflectance spectra reconstruction, the color difference and RMS between actual and reconstructed data were obtained. The reconstruction of reflectance spectra were improved by using a six or nine‐neuron layer with L*a*b* input elements. © 2016 Wiley Periodicals, Inc. Col Res Appl, 42, 182–188, 2017     

Optimizing the design of nanostructures for improved thermal conduction within confined spaces

Maintaining constant temperature is of particular importance to the normal operation of electronic devices. Aiming at the question, this paper proposes an optimum design of nanostructures made of high thermal conductive nanomaterials to provide outstanding heat dissipation from the confined interior (possibly nanosized) to the micro-spaces of electronic devices. The design incorporates a carbon nanocone for conducting heat from the interior to the exterior of a miniature electronic device, with the optimum diameter, D0, of the nanocone satisfying the relationship: D02(x) ∝ x1/2 where x is the position along the length direction of the carbon nanocone. Branched structure made of single-walled carbon nanotubes (CNTs) are shown to be particularly suitable for the purpose. It was found that the total thermal resistance of a branched structure reaches a minimum when the diameter ratio, β* satisfies the relationship: β* = γ-0.25bN-1/k*, where γ is ratio of length, b = 0.3 to approximately 0.4 on the single-walled CNTs, b = 0.6 to approximately 0.8 on the multiwalled CNTs, k* = 2 and N is the bifurcation number (N = 2, 3, 4 ...). The findings of this research provide a blueprint in designing miniaturized electronic devices with outstanding heat dissipation.PACS numbers: 44.10.+i, 44.05.+e, 66.70.-f, 61.48.De.