The effect of pitting corrosion on fatigue life

Fatigue testing of pre‐pitted 2024‐T3 aluminium alloy specimens is performed in laboratory air at 22 °C and 40% RH to characterize the effect of pitting corrosion on fatigue life. Specimens, pre‐corroded in a 0.5 M NaCl solution from 48 to 384 h, have fatigue lives that are reduced by more than one order of magnitude after 384 h pre‐corrosion as compared to those of uncorroded specimens. The reduction in fatigue life is interpreted in terms of the influence of the time of exposure to the corrosive environment or pit size. The crack‐nucleating pit sizes, ranging from 20 to 70 μm, are determined from post‐fracture examinations by scanning electron microscopy. Fatigue lives are estimated using a fracture mechanics approach and are shown to be in good agreement with the actual data. A probabilistic analysis shows that the distribution of fatigue life is strongly correlated to the distribution in nucleating pit size.     

Corrosion fatigue short crack growth behaviour in a high strength steel

The influence of an aggressive environment (0.6 M, aerated NaCl solution) on short fatigue crack initiation and growth behaviour has been studied. The study involved three major test series, namely: air fatigue, corrosion fatigue, and intermittent air fatigue/corrosion fatigue. The above tests carried out under fully reversed torsional loading conditions at a frequency of 5 Hz, showed that it was the non-metallic inclusions which took part in crack initiation resulting from debonding at metal matrix/inclusion interface and pitting of inclusions in both air and corrosove environments, respectively. Short fatigue crack growth results in these two environments obtained by using plastic replication technique, indicated a large effect of microstructure i.e. prior austenite grain boundaries. The stage/stages at which the environmental contribution was dominant has been discussed by considering the results achieved from intermittent tests. However, the mechanisms involved in corrosion fatigue short crack growth have also been described in the light of results obtained from futher investigations carried out by conducting corrosion fatigue tests under applied cathodic potential conditions and tests on hydrogen pre-charged specimens under air fatigue and uniaxial tension conditions.     

Corrosion fatigue of BS 4360:50D structural steel in seawater

Research on through-thickness defects is reported for BS 4360:50D structural steel in air and in seawater; the results of experiments on the propagation of surface-breaking, semi-elliptic flaws under three-point bend loading are also presented. The mechanisms of corrosion fatigue crack growth of through-thickness and semi-elliptic cracks in seawater are considered, and the application of crack growth data to endurance tests on welded cruciform and tubular joints is discussed.     

A model of corrosion fatigue crack growth in ship and offshore steels

A model describing corrosion fatigue crack growth rate da/dN has been proposed. The crack growth rate is assumed to be proportional to current flowing through the electrolyte within the crack during a loading cycle. The Shoji formula for the crack tip strain rate has been assumed in the model. The obtained formula for the corrosion fatigue crack growth rate is formally similar to the author's empirical formulae established previously. The different effects of ΔK and the fatigue loading frequency f on da/dN, in region I as compared to region II of the corrosion fatigue crack growth rate characteristics can be described by a change of one parameter only: the crack tip repassivation rate exponent.     

Recent development in the fast corrosion fatigue analysis of offshore structures subject to random wave loading

In many areas of engineering, such as the offshore industry, welded steel joints are widely used as standard structural components. These joints are usually subject to long-term random wave loading and are therefore susceptible to fatigue damage. In many cases, the complex service loading is described by stress (or strain) power spectra, each representing a stationary sea state. These power spectra are obtained from hydrodynamic analysis or in situ monitoring. These will then be used in design calculations, feasibility studies or in-service assessment of fatigue damage on the structures.

Usually, the power spectra will have to be realized into real-time histories and then counted before fatigue analysis can be carried out. On many occasions where a large number of design options or joints need to be analysed, this process becomes very time consuming and expensive. The situation is further complicated by the calculations involving corrosion fatigue for joints in sea water.

The paper will start with a brief presentation of the fatigue analysis procedures for offshore welded joints and several existing models that were derived to bypass the laborious load history analysis mentioned above. More effort, however, will be concentrated on presenting the development of a new model. This model not only provides a more consistent and accurate prediction, but has also been adopted successfully for corrosion fatigue analysis.     

Stress corrosion and corrosion fatigue of metals in high temperature aqueous environments

The dissolved oxygen content of water influences the susceptibility of austenitic stainless steels and reactor pressure vessel steels to environment assisted cracking by raising the electrochemical potential. The relevance of this fact to the integrity of welded stainless steel constructions, deaerator vessels and reactor pressure vessels steels is discussed. In particulal, the use of slow strain rate test procedures involving applied electrochemical potential control is discussed as a means of assessing the susceptibility to cracking of materials in a range of aqueous environments.     

Effects of annealing and quenching on fatigue behaviour in type 444 ferritic stainless steel

In order to understand the effects of annealing and quenching on fatigue behaviour in type 444 stainless steel, fully reversed axial fatigue tests have been performed using smooth specimens of heat‐treated materials in laboratory air and 3%NaCl aqueous solution. Three materials subjected to different heat treatments, annealing at 960 and 1000 °C, and water‐cooling at 960 °C, were prepared. In laboratory air, the fatigue limit of the annealed specimens was lower than that of the as‐received specimen and decreased with increasing annealing temperature. The subsequent grain coarsening from the heat treatments was primarily responsible for the lower fatigue strength in the annealed specimens. The fatigue strength of the water‐cooled specimen was lower than that of the corresponding annealed specimen. In the annealed specimens, cracks were generated within ferritic grains, while in the water‐cooled specimen, at or near grain boundaries. In 3%NaCl solution, the fatigue strengths of all specimens decreased compared with those in laboratory air. Only in the water‐cooled specimens, crack initiation at grain boundary and intergranular crack growth were observed, indicating the most sensitive to corrosion environment.     

Pitting corrosion of steel tubes in an air preheater

Severe pitting corrosion of a carbon steel tube was observed in the air preheater of a power plant, which runs on rice straw firing. Approximately 1450 tubes were removed from Stage 3 of the preheater (air inlet and flue gas outlet) due to corrosion and local bursting. Samples from Stage 2 (where corrosion was low) and Stage 3 (severe corrosion) were taken and subjected to visual inspection, scanning electron microscopy (SEM), X-ray diffraction (XRD), microhardness measurement, and chemical and microstructural analysis. It was determined that extended non-operation of the plant resulted in the settlement of corrosive species on the tubes in Stage 3. The complete failure of the tube occurred due to diffusion of these elements into the base metal and precipitation of potassium and chlorine compounds along the grain boundaries, with subsequent dislodging of grains. The nonmetallic inclusions acted as nucleating sites for local pitting bursting. Nonuniform heat transfer in Stage 3 operation accelerated the selective corrosion of front-end tubes. The relatively high heat transfer in this stage resulted in condensation of some corrosive gases and consequent corrosion. Continuous operation of the plant with some precautions during assembly of the tubes reduced the corrosion problem.     

Growth behaviour of small surface fatigue cracks in AISI 304 stainless steel

A series of axial tensile fatigue tests (R = 0.1) was carried out to investigate the initiation and the growth behaviours of very small surface fatigue cracks under two different surface conditions (viz. smooth and pitted surfaces) of AISI 304 stainless steel at room temperature. This paper deals with both of the two approaches regarding the analysis of fatigue: the approach based on the concept of fracture mechanics and low cycle fatigue. In particular, both the initiation and growth of cracks and the coalescence of small cracks by fatigue in the specimen have been investigated by the methods of surface replicas and photomicrographs. Quantitative information such as the initiation period, growth and coalescence behaviours of small cracks, and crack growth properties were systematically obtained. The results show that the accurate determination of these parameters is critical for the application of fracture mechanics to fatigue life assessment.     

Observation of fatigue damage in structural steel by scanning atomic force microscopy

Fatigue slip bands and plastic deformation around fatigue microcracks were observed by scanning atomic force microscopy. In fatigue slip bands, extrusions were observed but intrusions were not detected. Large extrusions were found in slip bands whose traces at specimen surface were almost perpendicular to the loading axis. Microcracks propagated under mixed mode condition of Mode I, Mode II, and Mode III.     

Multi‐axial fretting fatigue behaviour of 35CrMoA steel

The fretting fatigue behaviours in 35CrMoA steel were investigated under conditions of the various contact pressure and the same maximum equivalent stress of cyclic multi‐axial loading. The specimens were characterized by optical microscopy and scanning electron microscopy. Results showed that the fretting fatigue life has complex variation with the increase of contact pressure. The different contact pressure also played very important role in fretting wear model and various wear scars were formed. The influence of them at the fretting surface on the fretting fatigue life was finally discussed by the comparison of the experimental and numerical analysis results.     

The effects of saline aqueous corrosion on fatigue crack growth rates in 316 grade stainless steels

A study of fatigue crack propagation rates of 316 grade stainless steels in air and in an aqueous saline environment was carried out in an attempt to assess the fatigue properties encountered when such materials are used as surgical implants. The effects of variables such as temperature, pH, oxygenation level, bulk electrode potential, mean stress, frequency and stress waveform on the Paris crack growth law parameters were determined. Corrosion fatigue effects were observed in the aqueous saline environment, and a mechanism to describe this effect is proposed.     

Corrosion fatigue behaviour of a 15Cr‐6Ni precipitation‐hardening stainless steel in different tempers

Systematic fatigue experiments, including both high‐cycle axial fatigue (S–N curves) and fatigue crack growth (FCG, da/dN–ΔK curves), were performed on a precipitation‐hardening martensitic stainless steel in laboratory air and 3.5 wt% NaCl solution. Specimens were prepared in three tempers, i.e. solution‐annealed (SA), peak‐aged (H900) and overaged (H1150) conditions, to characterize the effects of ageing treatment on the corrosion fatigue (CF) resistance. S–N results indicated that fatigue resistance in all three tempers was dramatically reduced by the aqueous sodium chloride environment. In addition, the smooth‐surface specimens in H900 temper exhibited longer CF lives than the H1150 ones, while those in SA condition stood in between. However, for precracked specimens, the H1150 temper provided superior corrosive FCG resistance than the other two tempers. Comparison of the S–N and FCG curves indicated that early growth of crack‐like defects and short cracks played the major role in determining the CF life for smooth surface. The differences in the CF strengths for the S–N specimens of the given three tempers were primarily due to their inherent differences in resistance to small crack growth, as they were in the air environment.     

Initiation and propagation behaviour of fatigue cracks in hard-shot peened Type 316L steel in high cycle fatigue

Observations of fatigue crack growth behaviour were made during rotating‐bend testing of hard‐shot peened Type 316L steel. From the results of these observations, the crack that developed in the axial direction was observed and the mechanism of the fatigue crack properties was clarified as follows: (1) Small circumferential surface fatigue cracks were detected at 60% of the fatigue lifetime. These cracks propagated very slowly in both the circumferential and radial directions. (2) When a radial crack reached a depth of between 150 and 350 μm, axial fatigue cracks were formed. (3) In the next stage, either the radial or the axial fatigue cracks continued propagating, or an inwards growing radial crack formed from the axial crack. (4) In the final stage, the circumferential surface crack began to grow rapidly and resulted in fracture. (5) The fracture type of hard‐shot peened Type 316L is a particular type of surface fracture.     

On the corrosion fatigue crack initiation model and expression of metallic notched elements

In the present study, attempts are made to extend the application of the mechanical model for the fatigue crack initiation (FCI) and the FCI life formula of metallic notched elements in laboratory air to those in the corrosive environment. The test results and analysis of the corrosion FCI (CFCI) life of aluminum alloys and Ti---6A1---4V show that the expression of the CFCI life obtained by modifying the FCI life formula in laboratory air can give a good fit to the test results of the CFCI life. The salt water (3.5% NaCl) environment has no effects on the CFCI resistant coefficient compared with the FCI resistant coefficient in laboratory air. However, 3.5% NaCl environment greatly decreases the CFCI threshold of aluminum alloy, but has little effect on the CFCI threshold of Ti---6A1---4V. The loading frequency ranging from 1 Hz to 10 Hz has no appreciable effect on the CFCI life, and thus, the CFCI threshold of aluminum alloys investigated. Hence, the expression for the CFCI life of metallic notched elements proposed in this study is a better one, which reveals a correlation between the CFCI life and the governing parameters, such as, the geometry of the notched elements, the nominal stress range, the stress ratio, the tensile properties and the CFCI threshold. However, this new expression of the CFCI life needs to be verified by more test results.     

The effect of overload on the fatigue crack growth behaviour of 304 stainless steel in hydrogen

Fatigue crack growth (FCG) behaviour and its characteristics following tensile overloads were investigated for AISI 304 stainless steel in three different atmospheres; namely dry argon, moist air and hydrogen. The FCG tests were performed by MTS 810 servohydraulic machine. CT specimens were used for the tests and crack closure measurements were made using an extensometer. FCG rates of 304 stainless steel at both dry argon and moist air atmospheres have shown almost the same behaviour. In other words, the effect of moisture on FCG of this material is very small. However, in a hydrogen atmosphere, the material showed considerably higher crack growth rate in all regimes. In general, for all environments, the initial effect of overloads was to accelerate the FCG rate for a short distance (less than a mm) after which retardation occurred for a considerable amount of time. The main causes for retardation were found as crack blunting and a long reinitiation period for the fatigue crack. Regarding the environmental effect, the overload retardation was lowest in a hydrogen atmosphere. This low degree of retardation was explained by a hydrogen embrittlement mechanism. In a general sense, hydrogen may cause a different crack closure mechanism and hydrogen induced crack closure has come in to the picture. Scanning electron microscope and light microscope examinations agreed well with the above results.     

Pit morphology characterization and corrosion fatigue crack nucleation analysis based on energy principle

Pit always changes its shape and size during corrosion fatigue. The actual morphology of pit is an outcome of the interaction between the variation in the elastic energy, surface energy and electrochemical energy stored in the cyclically stressed solid. In this paper, a two‐variable semi‐elliptical model is proposed to depict the pit's growing morphology. The critical condition for corrosion fatigue crack nucleation is deduced according to dislocation theory, and the influences of some important factors on critical pit size and crack nucleation life are discussed.     

Experimental investigations on the growth of small fatigue cracks in naval steel

The concept of damage tolerance is now largely employed to evaluate the fatigue life of structures. However, part of this fatigue relies on the initiation and growth of small cracks. The fatigue behaviour of a naval structural steel (S355NL) was investigated. In order to characterize the behaviour of short and long cracks, tests were performed under constant amplitude loading for several load ratios between –1.0 and 0.5. A major part of fatigue life is constituted by short crack initiation and propagation.     

Observation of hydrogen effects on fatigue crack growth behaviour in an 18Cr-8Ni austenitic stainless steel

The hydrogen effect on crack growth behaviour in a type 304 austenitic stainless steel was investigated and the following results were obtained. The crack growth rate in hydrogen gas is accelerated compared with that in air. In order to clarify the mechanism of the acceleration, the growth behaviours of a crack propagating in a grain and propagating along the boundary to be a fracture facet were investigated. Slip behaviour, opening displacement and fractography showed that the slip-off mechanism in fatigue crack growth is valid even in hydrogen gas. Hydrogen mainly affects slip behaviour such that slip bands concentrate at a crack tip and result in acceleration of the growth rate. The facets are not significantly responsible for the acceleration. The ratio of facets to the entire area is low, and a crack nearly compensates for the temporary acceleration by the facets with subsequent deceleration.