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水相ATRP法合成聚羧酸类高效减水剂 总被引:5,自引:0,他引:5
以对苯乙烯磺酸钠、丙烯酸钠为原料,以2-溴丙酸为引发剂,采用原子转移自由基聚合(ATRP),在水相介质中室温条件下合成出聚羧酸类减水剂。通过红外光谱(FT-IR)、核磁共振(1H-NMR)等测试方法对聚合物的结构进行表征与分析,通过净浆流动度研究了反应时间和产物性能之间的关系。结果表明,成功地合成出了具有嵌段结构的聚羧酸类高效减水剂,并且当反应时间取24h时,产物的性能较好。 相似文献
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尹国英 《中国新技术新产品》2010,(23)
聚羧酸系减水剂作为一种新型的外加剂,具有减水率高、保塑性能好、水泥适应性强、混凝土收缩小等优点,但在掺入预拌混凝土的使用过程中,由于各种原因,引起混凝土的质量问题,合理选用使用原材料,提高聚羧酸类减水剂在预拌混凝土中的应用。 相似文献
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聚羧酸系减水剂的构性关系及其作用机理研究 总被引:2,自引:0,他引:2
聚羧酸系减水剂作为一种高性能减水剂,目前已成为国内外研究与发展的热点。概述了近几年国内外高效减水剂的研究与发展现状,阐述了聚羧酸系高效减水剂的分子结构、性能特点及作用机理,分子主链上阴离子基团越多及聚氧乙烯长侧链越长,聚羧酸系减水剂的分散性能和流动保持性能越好。聚羧酸系减水剂主要依靠聚氧乙烯长侧链的位阻效应和羧基及磺酸基的静电斥力来分散水泥颗粒。最后,提出了减水剂在应用中存在的问题并展望了其发展趋势。 相似文献
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聚羧酸类高效减水剂的研究进展 总被引:28,自引:0,他引:28
聚羧酸高效减水剂是高效减水剂的新品种,具有很多良好的使用性能。通过对近年来国内外的文献综合,讨论了反应单体,聚氧烷基链和端基的选择,聚合物相对分子质量及其分布,减水剂添加量等对减水剂性能的影响因素。 相似文献
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M. S. Hundal 《Design Studies》1991,12(4):227-231
The paper looks at the current research in computer-aided design at US universities. Design research in the US has increased dramatically in the last four years. The major sponsoring agencies for this research are named, as are the conferences and journals where the results of this research are presented. Emphasis is placed on research dealing with the design process itself. The areas of new design theories and methodologies, feature-based modelling, and knowledge-based CAD systems are included. Concurrent engineering is becoming a prominent research area. 相似文献
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Through analysis of articles published from 2000 to March 2014 in Automaton in Construction (AUTCON), an international research journal published by Elsevier, this paper summarizes the topics of research and the institutions worldwide where research was conducted in construction safety engineering and management. Seventy-one articles published during this time focused on Information Technology (IT) applications in this field were selected for analysis. The underlying research topics and their related IT implementations are discussed, and research trends in allied specialties are identified. 相似文献
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近年来,诞生于日本的感性(Kansei)研究越来越得到各国不同领域学者的关注。利用文献计量学的方法对Web of Science 数据库1998~2010年来收录的354篇相关文献进行了分析:通过对文献和作者的统计分析,探索了感性研究的发展现状;通过对文献作者提供的关键词的分析,构建了感性研究主题框架。结果表明:感性研究是一个具有较强发展潜力的新兴领域,日益呈现出跨行业、跨学科及多学科的研究特色。本研究成果对我国的感性研究具有一定的借鉴。 相似文献
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长余辉发光材料的研究进展 总被引:1,自引:0,他引:1
长余辉发光材料因其具有特殊的储能发光性能,是一类绿色环保型材料.综述了主要体系长余辉发光材料的研究历程,总结了长余辉材料的制备方法和余辉效应,概括了长余辉发光研究上存在的问题,提出了今后研究和应用的发展方向. 相似文献
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Pezhman Ghadimi Amir Hossein Azadnia Cathal Heavey Alexandre Dolgui Birkan Can 《国际生产研究杂志》2016,54(5):1443-1462
Sustainable development is currently being applied in most fields of research. Procurement, focused on the buyer–supplier dyad, is one such discipline where sustainability is being widely applied. This paper provides a review of these research studies, conducting a systematic content analysis in order to present the state of the art in this domain. The paper carries out a detailed review of articles in international scientific journals and well-known international conferences related to green and sustainable supplier selection published between 2008 and 2014 inclusive. Seven designed research questions are proposed and answered based on this bibliography. Interesting results are reported in each section and gaps in the current body of literature are identified. The purpose of this review is to provide important future directions and limitations in this research topic. 相似文献
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In the past 30 years various scientometric analyses have provided input data for research policy objectives of research institutions in the Netherlands. In this article we discuss several pioneering studies performed on behalf of the research councils for physics (FOM) and technical sciences (STW), which have played an important role in the early development of scientometrics in this country. The motives for these studies, the results and the influence on research policy are discussed. Relations to present themes in scientometric investigations are drawn. 相似文献
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This paper summarises a study designed to answer the following question: what are the benefits to Swedish society of road safety research in Sweden funded by the Swedish Transport Research Council and the programme for vehicle safety research during the period 1971-2004? The paper starts by discussing whether research can answer this question at all and explains why a well-controlled study was not feasible. A case study approach was selected, and five major research projects were examined in detail for the purpose of trying to estimate their effects on road safety. Estimates of safety effects were developed for four of the projects, indicating that road safety measures that were at least to some extent based on the findings of the research projects have made major contributions to reducing the number of road accident fatalities in Sweden. The estimates are not analytically rigorous and should be treated as qualified guesses only. Causal inferences are not possible. Nevertheless, if taken at face value, they show that the benefits to society of road safety research are large and outweigh by a wide margin the costs of the research, and of the road safety measures developed as a result of research. Thus, even if the estimated safety benefits exaggerate the true effects, the benefits of applied road safety research are likely to be greater than the costs of conducting this research and implementing road safety measures developed by research. 相似文献