Exergy-method analysis of a two-stage vapour-compression refrigeration-plants performance

The behaviour of two-stage compound compression-cycle, with flash intercooling, using refrigerant R22, has been investigated by the exergy method. The condenser's saturation-temperature was varied from 298 to 308 K and the evaporator's saturation-temperature from 238 to 228 K. The effects of temperature changes in the condenser and evaporator on the plant's irreversibility rate were determined. The greater the temperature difference between either (i) the condenser and the environment, or (ii) the evaporator and the cold room, the higher the irreversibility rate. Any reduction in the irreversibility rate of the condenser gives approximately 2.40 times greater reduction in the irreversibility rate for the whole plant, and any reduction in the evaporator's irreversibility rate gives a 2.87 times greater mean reduction in the irreversibility rate of the whole plant. Because the changes in the temperatures in the condenser and the evaporator contribute so significantly to the plant's overall irreversibility, there is considerable scope for optimising the conditions imposed upon the condenser and evaporator.     

Energy and exergy analyses of a two‐stage vapour compression refrigeration system

In this paper exergy analysis of two‐stage vapour compression refrigeration (VCR) system has been carried out with an objective to evaluate optimum inter‐stage temperature (pressure) for refrigerants HCFC22, R410A and R717. A thermodynamic model based on the principles of mass, energy and exergy balances is developed for this purpose. The computed results illustrate the effects of evaporation and condensation temperatures, isentropic efficiencies of compressors, sub‐cooling of refrigerant and superheating of suction vapour on optimum inter‐stage saturation temperature (pressure). The optimum inter‐stage saturation temperatures (pressures) for HCFC22 and R410A are proximate to arithmetic mean of evaporation and condensation temperatures (AMT) when assuming superheating of suction vapour and non‐isentropic compression processes in low‐pressure and high‐pressure compressors. The optimum inter‐stage saturation temperatures (pressures) for HCFC22 and R410A are near to geometric mean of evaporation and condensation temperatures (GMT) when it is assumed that cycle involves the effects of sub‐cooling, superheating of suction vapour and non‐isentropic compression of the suction vapour. The optimum inter‐stage saturation temperature (pressure) for R717 is close to GMT irrespective of sub‐cooling, superheating of suction vapour and non‐isentropic compression in the cycle. The efficiency defects, computed corresponding to optimum inter‐stage temperature in condenser is higher in comparison to the other components. Finally, it is deduced that R717 is a better alternative refrigerant to HCFC22 than R410A in two‐stage VCR system. Copyright © 2009 John Wiley & Sons, Ltd.     

Thermodynamic analysis of subcooling and superheating effects of alternative refrigerants for vapour compression refrigeration cycles

This paper presents a computer‐based first law and exergy analysis applied to vapour compression refrigeration systems for determining subcooling and superheating effects of environmentally safe new refrigerants. Three refrigerants are considered: R134a, R407c and R410a. It is found that subcooling and superheating temperatures directly influence the system performance as both condenser and evaporator temperatures are affected. The thermodynamic properties of the refrigerants are formulated using artificial neural network (ANN) methodology. Six ANNs were trained to predict various properties of the three refrigerants. The training and validation of the ANNs were performed with good accuracy. The correlation coefficient obtained when unknown data were used to the networks were found to be equal or very near to 1 which is very satisfactory. Additionally, the present methodology proved to be much better than the linear multiple regression analysis. From the analysis of the results it is found that condenser and evaporator temperatures have strong effects on coefficient of performance (COP) and system irreversibility. Also both subcooling and superheating affect the system performance. This effect is similar for R134a and R407c, and different for R410a. Copyright © 2005 John Wiley & Sons, Ltd.     

A comparative study of water as a refrigerant with some current refrigerants

Water as a refrigerant (R718) is compared with some current natural (R717 and R290) and synthetic refrigerants (R134a, R12, R22, and R152a) regarding environmental issues including ozone depletion potential (ODP) and global warming potential (GWP), safety (toxicity and flammability), operating cost, refrigeration capacity and coefficient of performance (COP). A computer code simulating a simple vapour compression cycle was developed to calculate COPs, pressure ratios, outlet temperatures of the refrigerants from the compressor, and evaporator temperatures above which water theoretically yields better COPs than the other refrigerants investigated. The main difference of this study from other similar studies is that both evaporator temperature and condenser temperature are changed as changing parameters, but the temperature lift, which is the temperature difference between condenser and evaporator, are held constant and the irreversibility during the compression process is also taken into consideration by taking the isentropic efficiency different from 100%. It is found that for evaporator temperatures above 20°C and small temperature lift (5 K), R718 gives the highest COP assuming exactly the same cycle parameters. For medium temperature lifts (20–25 K), this evaporator temperature is above 35°C, whereas for even greater temperature lifts it decreases again. Furthermore, with increased values of polytropic efficiency, R718 can maintain higher COPs over other refrigerants, at lower evaporator temperatures. Copyright © 2005 John Wiley & Sons, Ltd.     

非共沸混合工质压缩制冷循环的不可避免(火用)损失

以非共沸混合工质替代 CFCS是比较有效的替代方案。通过对给定节点温差下的蒸发器和冷凝器内的温度匹配分析 ,提出利用调节非共沸混合工质的配比来优化蒸发器和冷凝器内的温度匹配 ,并可计算出循环的实际不可避免灯用损失 ,从而提出采用非共沸混合工质的蒸气压缩制冷循环的实际不可避免灯用损失的计算方法 ,并提出利用最佳配比和实际不可避免的灯用损失的计算 ,对各种非共沸混合工质对进行筛选 ,以进一步减少循环可避免的灯用损失 ,为优化蒸气压缩制冷循环 ,提高循环的性能奠定基础。     

Exergy analysis of a coal‐based 210 MW thermal power plant

In the present work, exergy analysis of a coal‐based thermal power plant is done using the design data from a 210 MW thermal power plant under operation in India. The entire plant cycle is split up into three zones for the analysis: (1) only the turbo‐generator with its inlets and outlets, (2) turbo‐generator, condenser, feed pumps and the regenerative heaters, (3) the entire cycle with boiler, turbo‐generator, condenser, feed pumps, regenerative heaters and the plant auxiliaries. It helps to find out the contributions of different parts of the plant towards exergy destruction. The exergy efficiency is calculated using the operating data from the plant at different conditions, viz. at different loads, different condenser pressures, with and without regenerative heaters and with different settings of the turbine governing. The load variation is studied with the data at 100, 75, 60 and 40% of full load. Effects of two different condenser pressures, i.e. 76 and 89 mmHg (abs.), are studied. Effect of regeneration on exergy efficiency is studied by successively removing the high pressure regenerative heaters out of operation. The turbine governing system has been kept at constant pressure and sliding pressure modes to study their effects. It is observed that the major source of irreversibility in the power cycle is the boiler, which contributes to an exergy destruction of the order of 60%. Part load operation increases the irreversibilities in the cycle and the effect is more pronounced with the reduction of the load. Increase in the condenser back pressure decreases the exergy efficiency. Successive withdrawal of the high pressure heaters show a gradual increment in the exergy efficiency for the control volume excluding the boiler, while a decrease in exergy efficiency when the whole plant including the boiler is considered. Keeping the main steam pressure before the turbine control valves in sliding mode improves the exergy efficiencies in case of part load operation. Copyright © 2006 John Wiley & Sons, Ltd.     

Performance and exergetic analysis of vapor compression refrigeration system with an internal heat exchanger using a hydrocarbon,isobutane (R600a)

Hydrocarbons (HCs) are excellent refrigerants in many ways such as energy efficiency, critical point, solubility, transport and heat transfer properties, but they are also flammable, which causes the need for changes in standards, production and product. There are increasing number of scientists and engineers who believe that an alternative solution, which has been overlooked, may be provided by using HCs. The main objective of this study is to perform energy and exergy analyses for a vapor compression refrigeration system with an internal heat exchanger using a HC, isobutene (R600a). For a refrigeration capacity of 1 kW and cold chamber temperature of 0°C, energy and exergy balances are taken into account to determine the performance of the refrigeration system. Energy and exergy fluxes are determined, and irreversibility rates are calculated for every component of the system. It is seen that the compressor has the highest irreversibility rate, and the heat exchanger has the lowest. Also from the result of the analysis, it is found that condenser and evaporator temperatures have strong effects on energetic and exergetic performances of the system such as coefficient of performance (COP), efficiency ratio (τ), exergetic efficiency (ξ) and irreversibility rate. Copyright © 2008 John Wiley & Sons, Ltd.     

Sustainability with prospective refrigerants

This paper first presents a brief historical summary of the recent past and current status of refrigerants, and then proceeds to suggest a simple Second Law‐based approach using the ideal vapor compression refrigeration cycle to estimate a refrigerant's performance potential. The resulting performance rankings are then supplemented by additional rankings of the exergy losses in the compressor and in the condenser. These methodologies are then applied to several refrigerants: three natural refrigerants (ammonia, propane, and isobutane), five conventional single‐component halocarbon refrigerants, two conventional blends of halocarbon refrigerants, and three newer refrigerants (fluorinated propene isomers). Generally speaking, the lower pressure refrigerants have better COP and lesser volumetric cooling capacity than the higher pressure refrigerants; whereas, the lower pressure refrigerants have higher penalty factor (measure of condenser exergy losses) than the higher pressure refrigerants. The analyses presented in this paper suggest that to minimize a refrigeration system's overall impact on the environment, the choice of refrigerant should not necessarily be based on a single criterion but rather should be chosen based on the particular application. Copyright © 2013 John Wiley & Sons, Ltd.     

Exergetic performance assessment of a variable‐speed R404a refrigeration system

The goal of this study is to carry out exergy analyses for an experimental variable‐speed refrigeration system working with R404a in order to determine irreversibility rates and exergetic efficiencies of system components and the overall system. For this aim, an experimental refrigeration system was designed with a frequency inverter mounted on compressor electric motor. Controlling the rotational speed of the compressor with a frequency inverter is one of the best methods to vary the capacity of the refrigeration system. The experiments were made for different compressor electric motor frequencies. The results showed that at low‐frequency values, irreversibility rates of the system decreased and exergetic efficiencies were increased. In addition, the major irreversibility occurs in the compressor by 61.47–61.83% followed by condenser by 17.00–16.52%, evaporator by 12.39–13.73% and expansion valve by 6.24–6.76% for different compressor frequencies. Copyright © 2009 John Wiley & Sons, Ltd.     

Thermo‐economic optimization of superheating and sub‐cooling heat exchangers in vapor‐compressed refrigeration system

In this study, superheating and sub‐cooling heat exchangers in vapor‐compressed refrigeration system are analyzed from thermodynamics and economical (refrigeration system operation cost, investment cost) viewpoints. Using four different refrigerants (R22, R502, R134a and R404a), the temperature of condenser at the interval of (35–55°C) and temperature of evaporator at the interval of (?10 to 10°C) have been obtained from the calculation process. The second law analysis (analysis of irreversibility) of a refrigeration system is carried out and then the whole system is optimized thermo‐economically. As a result of calculations, optimum superheating and sub‐cooling temperatures of heat exchanger (superheating, sub‐cooling) areas corresponding to these temperatures are obtained. Copyright © 2007 John Wiley & Sons, Ltd.     

Transcritical CO2 refrigerator and sub‐critical R134a refrigerator: A comparison of the experimental results

This paper describes experiments comparing a commercial available R134a refrigeration plant subjected to a cold store and a prototype R744 (carbon dioxide) system working as a classical ‘split‐systems’ to cool air in residential applications in a transcritical cycle. Both plants are able to develope a refrigeration power equal to 3000 W. The R744 system utilizes aluminium heat exchangers, a semi‐hermetic compressor, a back‐pressure valve and a thermostatic expansion valve. The R134a refrigeration plant operates using a semi‐hermetic reciprocating compressor, an air condenser followed by a liquid receiver, a manifold with two expansion valves, a thermostatic one and a manual one mounted in parallel, and an air cooling evaporator inside the cold store. System performances are compared for two evaporation temperatures varying the temperature of the external air running over the gas‐cooler and over the condenser. The refrigeration load in the cold store is simulated by means of some electrical resistances, whereas the air evaporator of the R744 plant is placed in a very large ambient. The results of the comparison are discussed in terms of temperature of the refrigerants at the compressor discharge line, of refrigerants mass flow rate and of coefficient of performance (COP). The performances measured in terms of COPs show a decrease with respect to the R134a plant working at the same external and internal conditions. Further improvements regarding the components of the cycle are necessary to use in a large‐scale ‘split‐systems’ working with the carbon dioxide. Copyright © 2009 John Wiley & Sons, Ltd.     

三级复叠式制冷系统低温级制冷剂的应用分析

为研究三级复叠制冷系统中低温循环制冷剂替代的可行性方案,采用R1150/R170/R717、R50/R170/R717和R14/R170/R717三种工质组合,对三级复叠式制冷系统的高低温循环压缩机的排气温度、压缩机输入功率、COP、热力学完善度、系统的■效率、■损失以及系统中各个部件■损失所占比例随蒸发温度的变化进行热力学分析。研究结果表明:不同蒸发温度下均存在最佳中间循环冷凝温度,使COP值最大。蒸发温度由-100.0℃升高到-80.0℃时,R1150/R170/R717的■损失最小,COP、热力学完善度和■效率最大。R1150/R170/R717的COP由0.60增大到0.82。R1150/R170/R717的COP比R14/R170/R717的COP高3.47%～4.49%。主要的■损失部件是冷凝器,冷凝器的■损失所占比例随蒸发温度的升高而升高。推荐在三级复叠式制冷系统中采用R1150/R170/R717制冷剂组合方案,研究结果为三级复叠式制冷系统工质组的选择提供理论依据。     

Theoretical analysis of LiBr/H2O absorption refrigeration systems

A computational model is developed for the parametric investigation of single‐effect and series flow double‐effect LiBr/H₂O absorption refrigeration systems. The effects of generator, absorber, condenser, evaporator and dead state temperatures are examined on the performance of these systems. The parameters computed are coefficient of performance (COP), exergy destruction rates, thermal exergy loss rates, irreversibility and exergetic efficiency. The results indicate that COP and exergetic efficiency of both the systems increase with increase in the generator temperature. There exist different optimum values of generator temperature for maximum COP and maximum exergetic efficiency. The optimum generator temperature is lower corresponding to maximum exergetic efficiency as compared to optimum generator temperature corresponding to maximum COP. The effect of increase in absorber, condenser and evaporator temperatures is to decrease the exergetic efficiency of both the systems. The irreversibility is highest in absorber in both systems. Copyright © 2009 John Wiley & Sons, Ltd.     

Performance analysis of a waste‐heat‐powered thermodynamic cycle for multieffect refrigeration

A multieffect refrigeration system that is based on a waste‐heat‐driven organic Rankine cycle that could produce refrigeration output of different magnitudes at different levels of temperature is presented. The proposed system is integration of combined ejector–absorption refrigeration cycle and ejector expansion Joule–Thomson (EJT) cooling cycle that can meet the requirements of air‐conditioning, refrigeration, and cryogenic cooling simultaneously at the expense of industrial waste heat. The variation of the parameters that affect the system performance such as industrial waste heat temperature, refrigerant turbine inlet pressure, and the evaporator temperature of ejector refrigeration cycle (ERC) and EJT cycles was examined, respectively. It was found that refrigeration output and thermal efficiency of the multieffect cycle decrease considerably with the increase in industrial waste heat temperature, while its exergy efficiency varies marginally. A thermal efficiency value of 22.5% and exergy efficiency value of 8.6% were obtained at an industrial waste heat temperature of 210°C, a turbine inlet pressure of 1.3 MPa, and ejector evaporator temperature of 268 K. Both refrigeration output and thermal efficiency increase with the increase in turbine inlet pressure and ERC evaporator temperature. Change in EJT cycle evaporator temperature shows a little impact on both thermal and exergy efficiency values of the multieffect cycle. Analysis of the results clearly shows that the proposed cycle has an effective potential for cooling production through exploitation of lost energy from the industry. Copyright © 2014 John Wiley & Sons, Ltd.     

Energy,exergy and exergoeconomic analysis of a steam power plant: A case study

The objective of this paper is to perform the energy, exergy and exergoeconomic analysis for the Hamedan steam power plant. In the first part of the paper, the exergy destruction and exergy loss of each component of this power plant is estimated. Moreover, the effects of the load variations and ambient temperature are calculated in order to obtain a good insight into this analysis. The exergy efficiencies of the boiler, turbine, pump, heaters and the condenser are estimated at different ambient temperatures. The results show that energy losses have mainly occurred in the condenser where 306.9 MW is lost to the environment while only 67.63 MW has been lost from the boiler. Nevertheless, the irreversibility rate of the boiler is higher than the irreversibility rates of the other components. It is due to the fact that the combustion reaction and its high temperature are the most significant sources of exergy destruction in the boiler system, which can be reduced by preheating the combustion air and reducing the air–fuel ratio. When the ambient temperature is increased from 5 to 24°C, the irreversibility rate of the boiler, turbine, feed water heaters, pumps and the total irreversibility rate of the plant are increased. In addition, as the load varies from 125 to 250 MW (i.e. full load) the exergy efficiency of the boiler and turbine, condenser and heaters are increased due to the fact that the power plant is designed for the full load. In the second part of the paper, the exergoeconomic analysis is done for each component of the power plant in order to calculate the cost of exergy destruction. The results show that the boiler has the highest cost of exergy destruction. In addition, an optimization procedure is developed for that power plant. The results show that by considering the decision variables, the cost of exergy destruction and purchase can be decreased by almost 17.11%. Copyright © 2008 John Wiley & Sons, Ltd.     

Exergy analysis of ejector‐refrigeration cycle using water as working fluid

Exergy is based on the second law of thermodynamics and is the only rational basis for evaluating the system performance. The aim of this paper is to study in detail the irreversibilities in the steam‐ejector refrigeration system. The influence of the cycle parameters is analysed on the basis of the first and second law and the results indicated the components with the greater irreversibility. A better quality of the ejector has more effect on the system performance than the better quality of other components, because the ejector at first and the condenser at second have the greater exergy loss of the system. For the refrigeration system the maximum coefficient of performance varying between 0.4 to 0.6 and the second law efficiency remains close to 0.17 for generator pressure 6 bar, condenser temperature 44–50°C and evaporator temperature 4–8°C. Also the study showed that the second law analysis quantitatively visualizes losses within a system and gives clear trends for optimization. Copyright © 2005 John Wiley & Sons, Ltd.     

Performance study on the evaporation and pressure drop of low‐temperature refrigerant blends in porous media

An experimental investigation on the performance of different low‐temperature refrigerant blends is presented in this work. Five different low‐temperature refrigerant blends are put on display to replace the R22 refrigerant, which has a high ozone depletion potential. These five blends are R404A, R407C, R410A, R417A, and R422A. Different performance studies have been performed on these alternative refrigerants to replace R22. A comparative experimental performance study is performed during the evaporation of these refrigerant blends in porous media. A porous metallic heat transfer medium is used with different porosities (40%, 43%, and 45%) in the evaporator during the test experiments. The evaporator superheat and the condenser subcool are maintained constant throughout the experiments at 8°C (±0.5°C) and 6°C (±0.5°C), respectively. The condensing temperature is kept constant at 38.5°C, and the mean evaporating temperatures were selected to be from ?33 to ?18°C. The effect of the above‐mentioned given operating conditions on the compressor discharge temperature, evaporation pressure drop, evaporation capacity, and coefficient of performance of these five low‐temperature refrigerant blends has been analyzed for different porosities. This experimental study showed that the refrigerant R422A can give a similar or greater performance to R22 and R404A with a global warming effect and zero ozone depleting potential.     

R245fa有机朗肯循环余热发电系统火用分析

以低品位热能驱动的有机朗肯循环发电系统,是实现将低品位热能转变为电能,进而提高热力系统总体热效率,降低污染排放的有效途径之一。本文建立了低品位热能发电系统火用分析模型,对以R245fa为工质的温度低于383.15 K的低品位热能有机朗肯循环余热发电系统进行了火用分析,得到了各环节的能量转换效率并确定了对系统性能影响最大的环节;通过改变蒸发器和冷凝器的压降和传热系数值,分析了主要换热设备的设计和运行性能参数对系统火用效率、热效率和发电量的影响趋势,提出了低品位热能发电系统的优化方向。     

Thermoeconomic optimization for a finned‐tube evaporator configuration of a roof‐top bus air‐conditioning system

This paper presents a methodology of a design optimization technique that can be useful in assessing the best configuration of a finned‐tube evaporator, using a thermoeconomic approach. The assessment has been carried out on a direct expansion finned‐tube evaporator of a vapor compression cycle for a roof‐top bus air‐conditioning (AC) system at a specified cooling capacity. The methodology has been conducted by studying the effect of some operational and geometrical design parameters for the evaporator on the entire cycle exergy destruction or irreversibility, AC system coefficient of performance (COP), and total annual cost. The heat exchangers for the bus AC system are featured by a very compact frontal area due to the stringent space limitations and structure standard for the system installation. Therefore, the current study also takes in its account the effect of the variation of the design parameters on the evaporator frontal area. The irreversibility due to heat transfer across the stream‐to‐stream temperature difference and due to frictional pressure drops is calculated as a function of the design parameters. A cost function is introduced, defined as the sum of two contributions, the investment expense of the evaporator material and the system compressor, and the operational expense of AC system that is usually driven by an auxiliary engine or coupled with the main bus engine. The optimal trade‐off between investment and operating cost is, therefore, investigated. A numerical example is discussed, in which a comparison between the commercial evaporator design and optimal design configuration has been presented in terms of the system COP and evaporator material cost. The results show that a significant improvement can be obtained for the optimal evaporator design compared with that of the commercial finned‐tube evaporator that is designed based on the conventional values of the design parameters. Copyright © 2007 John Wiley & Sons, Ltd.     

An examination of exergy destruction in organic Rankine cycles

The exergy topological method is used to present a quantitative estimation of the exergy destroyed in an organic Rankine cycle (ORC) operating on R113. A detailed roadmap of exergy flow is presented using an exergy wheel, and this visual representation clearly depicts the exergy accounting associated with each thermodynamic process. The analysis indicates that the evaporator accounts for maximum exergy destroyed in the ORC and the process responsible for this is the heat transfer across a finite temperature difference. In addition, the results confirm the thermodynamic superiority of the regenerative ORC over the basic ORC since regenerative heating helps offset a significant amount of exergy destroyed in the evaporator, thereby resulting in a thermodynamically more efficient process. Parameters such as thermodynamic influence coefficient and degree of thermodynamic perfection are identified as useful design metrics to assist exergy‐based design of devices. This paper also examines the impact of operating parameters such as evaporator pressure and inlet temperature of the hot gases entering the evaporator on ORC performance. It is shown that exergy destruction decreases with increasing evaporator pressure and decreasing turbine inlet temperatures. Finally, the analysis reveals the potential of the exergy topological methodology as a robust technique to identify the magnitude of irreversibilities associated with real thermodynamic processes in practical thermal systems. Copyright © 2008 John Wiley & Sons, Ltd.