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Two-component water reducible polyurethane coatings 总被引:22,自引:0,他引:22
Denise E. Fiori 《Progress in Organic Coatings》1997,32(1-4):65-71
Historically, polyurethane coatings have been formulated as two-component organic solvent based systems. These polyurethane coatings provide room temperature cure characteristics as well as an excellent combination of abrasion resistance, flexibility, adhesion, chemical resistance and appearance. However, the coatings industry is under increasing pressure to reduce the environmentally undesirable emission of volatile organic compounds (VOC). One way of doing this is to replace some or all of the organic solvent with water. However, in the case of isocyanate crosslinked polyurethane coatings this is not a straightforward matter due to the fact that unmodified isocyanates are not only reactive with water, but are hydrophobic and non-dispersible. 相似文献
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介绍了聚氨酯树脂地坪涂料的组成、特性、分类,综述了溶剂型、无溶剂型、水分散型和粉末型聚氨酯地坪涂料的发展和应用进展。 相似文献
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To prepare versatile polyurethane material suitable as insulating coatings, novel kinds of polyhydroxy compounds (PHCs) were prepared via transesterification reaction of poly(ethylene terphthalate), different molecular weight of poly(ethylene glycol)s (PEGs), and castor oil. The final networks were prepared via crosslinking of PHCs with a novel blocked isocyanate curing agent (BPI) made from trimethylol propane (TMP), toluene diisocyanate (TDI), and N‐methyl aniline (NMA). Polyols and curing agent were characterized by conventional methods and the curing condition was optimized via gel content measurements. Curing kinetic of the polyurethane network formation was investigated by differential scanning calorimetric method and the kinetic parameters were derived. Crosslink density of the samples was determined via equilibrium swelling method and by using Flory‐Rehner equations. Effects of crosslink density on electrical, physical, mechanical, and dynamic mechanical (DMTA) properties of the polyurethane coatings were investigated. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1222–1233, 2006 相似文献
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Haixia Yuan Weiyi Xing Hongyu Yang Lei Song Yuan Hu Guan Heng Yeoh 《Polymer International》2013,62(2):273-279
Phenolic foam exhibits outstanding flame, smoke and toxicity properties, good insulation properties and low production costs. However, the brittleness and pulverization of phenolic foam have severely limited its application in many fields. In this study, a novel phosphorus‐containing polyurethane prepolymer (DOPU) modifier was firstly synthesized, and then the foaming formula and processing of toughening phenolic foam modified with DOPU and glass fiber were explored. The structure and reactive behavior of prepolymer and phenolic resin were investigated using Fourier transform infrared spectroscopy. The effects of DOPU and glass fiber on the apparent density, compressive strength, bending strength and water absorption were investigated. The results suggested that the apparent density, compressive strength and bending strength of modified phenolic foam tended to increase irregularly with increasing content of DOPU. The addition of DOPU led to lower water absorption of glass fiber‐filled foam. Thermal stability and flame retardancy were examined using thermogravimetric analysis and limiting oxygen index (LOI) tests. It was found that foam with 3% DOPU and 0.5% glass fiber added exhibited good thermal stability and high char yields. The LOI value of modified phenolic foams decreased with increasing DOPU content, but it still remained at 41.0% even if the amount of modifier loaded was 10 wt%. © 2012 Society of Chemical Industry 相似文献
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Siloxane-semifluorinated polyurethane coatings were prepared for robust underwater application. Initially, acrylic polyol (FS-GPTACP)-containing fluoroalkoxysilane (1H,1H,2H,2H-Perfluorooctyltrimethoxysilane) pendant group was synthesized by the free-radical polymerization method. Different weight percentages of polydimethylsiloxane (0, 10, and 20 wt %) were added to the polyol to tune the mechanical and the surface energy of the coating. Subsequently, this polyol mixture was cured with 4, 4′-methylenebis(cyclohexyl isocyanate) (H12MDI) to prepare a series of siloxane-semifluorinated polyurethane–urea hybrid coatings (APUS 0%, APUS 10%, and APUS 20%). The synthesized coating showed low surface energy, hydrophobicity with exceptional water, and alkali resistance. Moreover, the coating displayed excellent mechanical properties with low pseudobarnacle adhesion strength. The coatings also showed nontoxicity against gram-positive and gram-negative bacterial strains. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47720. 相似文献
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Didier Arseguel Michel Baboulne 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1994,61(4):331-335
The degradation of phenol by a combination of horseradish peroxidase/hydrogen peroxide in the presence of talc, a natural abundant and low cost mineral, was investigated. Adsorption of the reaction products on the talc effectively protected the biocatalyst against contamination by oxidative products, thereby prolonging its catalytic action and leading to almost complete elimination of phenols in aqueous media. Suitable conditions for depollution of waste water containing phenolic substances were developed after optimization of various parameters (type and amount of talc, reaction duration). 相似文献
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Lingli Ni Shanshan Li Yongtao Liu Xiaowu Jiang Peng Cai Liangdong Feng Shizhong Zhang Xiaoyan Gao 《应用聚合物科学杂志》2021,138(36):50899
The development of eco-efficient and environmental friendly active anti-corrosion coatings for metallic substrates represents a fundamental milestone in many engineering applications. Herein, a new type of active corrosion protection coating was successfully synthesized simply based on waterborne polyurethane (WPU) and nanocontainer of Ce3+ modified palygorskite (Ce-PAL). Particularly, the nanocontainer of Ce-PAL was achieved via a facile and green process by cation exchange in water. Inductively coupled plasma atomic emission spectrometry (ICP) revealed that Ce3+ had successfully incorporated into PAL nanofibers with a loading amount of 10.334 g/kg. The salt immersion test, electrochemical potentiodynamic measurements and electrochemical impedance spectroscopy (EIS) demonstrated that the incorporation of Ce-PAL only with 2 wt% into WPU led to a significant improvement of their corrosion protection properties. Finally, according to the results of scanning electron microscopy with energy dispersive X-ray spectroscopy, the active anti-corrosion mechanism of Ce-PAL/WPU coating was proposed. 相似文献
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Trichloro modified polyester polyols were synthesized by two-step condensation reactions. An intermediate compound was synthesized by the esterification of trichloroacetic acid with trimethylolpropane in the first step. In the next step, polycondensation of the intermediate, 1,4-butanediol and trimethylolpropane with adipic acid was carried out. Two-component flame-retardant polyurethane coatings were prepared by blending these modified polyester polyols and polyisocyanate. The physical properties of these new coatings were comparable to non-flame-retardant coatings. They showed a drying time of 3–4 h and a pot life time of 10–13 h, which could belong to the flame-retardant coatings with long pot life times. Coating with 20 wt % trichloroacetic acid showed a self-extinguishing property in the vertical burning test. © 1998 John Wiley & Sons, Inc. J. Appl. Polym. Sci. 70: 913–920, 1998 相似文献
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Phenolic compounds in macadamia nuts and shells were identified, and their antioxidant activities were evaluated in refined
macadamia nut oil. Thin-layer chromatography of oil extracted from macadamia nut kernels and shells indicated the possible
presence of catechol, phrogallol, and 3,4,5-trihydroxy phenolic compounds. Four phenolic compounds were tentatively identified
as 2,6-dihydroxybenzoic acid, 2′-hydroxy-4′-methoxyacetophenone, 3′,5′-dimethoxy-4′-hydroxyacetophenone, and 3,5-dimethoxy-4-hydroxycinnamic
acid. Adding 0.01% of 2′-hydroxy-4′-methoxyacetophenone, 3′,5′-dimethoxy-4′-hydroxyacetophenone, or 3,5-dimethoxy-4-hydroxycinnamic
acid to the oil significantly increased the Rancimat induction time against the control (P<0.0001). At this concentration, 3′,5′-dimethoxy-4′-hydroxyacetophenone was the most effective compound added. Although induction
times of oils with 0.01%, 2,6-dihydroxybenzoic acid were not significantly different from the control, at 0.1% there was a
significant difference from the control (P<0.0001). The activity was the same as that of 2′-hydroxy-4′-methoxyacetophenone at 0.1%. 相似文献
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以具有代表性的外墙纯丙乳液为基础,对国内外著名厂商的各类助剂进行平行试验,对各牌号的助剂进行考评得出数据。 相似文献
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Xuechuan Wang Yuqiao Fu Peiying Guo Longfang Ren Haijun Wang Taotao Qiang 《应用聚合物科学杂志》2013,130(4):2671-2679
The isocyanate‐terminated polyurethane pre‐polymer (PPU) was synthesized via the step‐growth polymerization approach by using polycarbonate diol (PCDL, Mn = 2000) and isophorone disocyanate (IPDI) as monomers, dibutyltin dilaurate (DBTDL) as the catalyst. Subsequently, the hyperbranched polyurethane (HBPU) was synthesized by graft copolymerization using PPU, hyperbranched poly(amide–ester) polyol (HPAE) and 1,4‐butanediol (BDO). The molecular structure of HBPU was characterized by means of FTIR, 1H‐NMR, and 13C‐NMR. It was observed that HBPU was synthesized as anticipated. The thermal and mechanical properties, the microstructure, and morphologies of the filmed HBPU and LPU (linear polyurethane) were tested, respectively. The filmed HBPU, revealed better thermal stability, and higher Tg accompanied with lower viscosity than those of filmed LPU. Additionally, the mechanical experiment showed that the filmed HBPU exhibited enhanced mechanical properties because it contained certain amounts of HPAE. Compared with its linear analog (LPU) specimen, the tensile strength of the filmed HBPU containing 10 wt % HPAE increased by 1.9 times (up to 28.15 MPa), and its elongation at break increased by 1.5 times (up to 543.8%), resulting from the dual effects of the hydrogen bonding and the crosslinking density in the HBPU system. The morphologies of filmed HBPU were characterized by means of WAXD and SEM, which indicated that increasing the content of HPAE lowers the crystallinity of HBPU. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2671–2679, 2013 相似文献
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采用原位聚合的方法在锑掺杂氧化锡/氧化钛复合材料(TIO)上包覆一层完整的聚苯胺(PANI)膜,成功制备了PANI/TIO复合材料,将其作为水性聚氨酯涂料的填料,制备了水性聚氨酯导电涂料。利用X射线粉末衍射、透射电镜、红外光谱等分析方法对复合材料进行表征,利用涂层机械性能测试对导电涂料进行了测试。同时得到了制备PANI/TIO三元复合材料的最佳工艺条件:苯胺(An)包覆量为15%、m(An)/m[磺基水杨酸(SSA)]=0.4、m(An)/m[过硫酸铵(APS)]=3。在最佳工艺条件下,得到的PANI/TIO复合材料体积电阻率为15.3Ω·cm。实验结果表明:当填料比为15%时涂层机械性能最佳,硬度为2B、耐冲击力为50 cm、附着力为1级、涂层表面电阻为3.56×105Ω/m2,该导电涂料有较好的应用前景。 相似文献
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Himadri S. Karmakar Ravi Arukula Apparao Thota Ramanuj Narayan Chepuri R. K. Rao 《应用聚合物科学杂志》2018,135(6)
We report the superior corrosion‐resistant properties of conducting polyurethane networks of polyaniline (PANI), poly‐m‐aminophenol (PmAP), and poly‐o‐anisidine (PoA) coated on mild steel panels. These networks were prepared by blending conducting polyanilines with isocyanate‐containing prepolyurethanes. Free‐standing polyurethane films were obtained after a moisture cure for several days to ensure complete reaction of the excess isocyanate. The films were electrochemically active with conductivity in the range of 10?2 to 10?3 S/cm. The solution blends and formed films were characterized by infrared, ultraviolet, thermogravimetric analysis, and differential scanning calorimetry. Electrochemical corrosion studies of the coated films on mild steel panels showed excellent corrosion protection in the following order: PU‐PANI > PU‐PmAP > PU‐PoA. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45806. 相似文献
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Two-component waterborne polyurethane (2K WBPU) coatings were prepared using a silicone-modified acrylic emulsion as the hydroxyl
component, and hydrophilically-modified polyisocyanate as the curing agent. The effects of the levels of silicone monomer
and hydroxyl values on the film properties of the 2K WBPU coatings were investigated. Infrared spectroscopy characterized
its structure. Scanning electron microscopy (SEM), thermo-gravimetric analysis (TGA), and differential scanning calorimetry
(DSC) were used to study the surface morphology and the thermal stability of the film. The results showed that the performance
of the coatings and the thermal stability of the film of 2K WBPU were improved after silicone modification. 相似文献
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非均相Fenton催化法是去除水中难降解有机污染物的一种重要高级氧化技术,近些年以其效率高、污染少、材料来源广泛而受到人们更多的重视。介绍了现今主要的非均相Fenton催化降解酚类化合物的催化剂研究进展,包括零价铁、Fe3O4、Fe2O3、以碳、黏土、柱撑黏土、沸石、介孔二氧化硅等为载体的催化剂。最后提出了三个非均相Fenton反应的研究方向。 相似文献