模拟柴油机排气微粒的试验研究

为了改善柴油机排气微粒袋滤器性能试验的可控性及经济性，本文研制了一种微粒模拟装置，用以模拟柴油机的排气微粒。并采用气溶胶粒度电分析仪、扫描电镜、透射电镜等对模拟微粒影响柴油机微粒袋滤器性能的主要物理特性进行了测试，并与柴油机微粒的相应特性做了对比分析，证明所模拟的微粒具有与柴油机微粒相似的物理特性。因此可用本文研制的微粒模拟装置代替柴油机进行柴油机排气微粒袋滤器的性能试验。     

Emissions of a diesel engine using B20 and effects of hydrogen addition

The blended biodiesel with up to 20% biodiesel in petroleum diesel (B20) is considered nowadays as available in production. Previous studies investigating the effect of B20 on engine emissions led to some contradictory results. The present study continued the investigation on B20, 20% biodiesel (rapeseed methyl esters) blend effects and was also extended on B20 enriched with hydrogen. It was conducted on a conventional tractor diesel engine running alternatively with B20 and petroleum diesel at various speeds and full load and then, with the same fuels enriched with hydrogen, at 60% load and two speeds.     

Heat release and engine performance effects of soybean oil ethyl ester blending into diesel fuel

The engine performance impact of soybean oil ethyl ester blending into diesel fuel was analyzed employing heat release analysis, in-cylinder exergy balances and dynamometric tests. Blends with concentrations of up to 30% of soybean oil ethyl ester in volume were used in steady-state experiments conducted in a high speed turbocharged direct injection engine. Modifications in fuel heat value, fuel-air equivalence ratio and combustion temperature were found to govern the impact resulting from the addition of biodiesel on engine performance. For the analyzed fuels, the 20% biodiesel blend presented the best results of brake thermal efficiency, while the 10% biodiesel blend presented the best results of brake power and sfc (specific fuel consumption). In relation to mineral diesel and in full load conditions, an average increase of 4.16% was observed in brake thermal efficiency with B20 blend. In the same conditions, an average gain of 1.15% in brake power and a reduction of 1.73% in sfc was observed with B10 blend.     

Thermogravimetric analysis of soot emitted by a modern diesel engine run on catalyst-doped fuel

Understanding the mechanisms that affect catalytic activity in porous ceramic diesel particulate filters (DPF) at the temperature range 200 to 400°C is important for the successful modeling of the initiation and evolution of catalytic regeneration by use of fuel additives. This refers not only to the dry carbon particulate, but also to the volatile hydrocarbons adsorbed on it. In this paper, a detailed analysis of the hydrocarbon adsorption-desorption and oxidation behavior of diesel particulate emitted by a modern diesel engine and collected on a SiC diesel filter is performed by use of thermogravimetric and differential scanning calorimetry analysis (TGA-DSC). Non-isothermal tests were performed with samples collected directly from a ceramic filter connected to the exhaust system of the diesel engine running under low and medium speed and load operating conditions with and without fuel additive. Fuel additive concentration was varied to investigate its effect on the soot oxidation behavior. Based on the TGA data, the kinetic parameters of the soot oxidation reaction were calculated. The effect of volatile adsorbed hydrocarbons on the soot oxidation reaction was evaluated by comparing the calculated activation energies for samples collected from the center and the periphery of the filter at various exhaust temperatures prevailing at filter loading phase. In particular it was seen that the catalytic activity of the fuel additive is enhanced by the presence of the volatile organic components.     

Impact of waste cooking oil in biodiesel blends on particle size distributions from a city-car engine

Using biodiesel as a blending component in diesel engine has demonstrated to reduce hydrocarbon and particulate matter emissions. Literature showed that biodiesel type, engine architecture and test conditions deeply affect performance and emission characteristics. Among suitable biodiesel fuels, waste cooking oil (WCO) is considered very attractive due to the reduced environmental impact without sacrificing engine performance.This paper aims at investigating how mixing ratio of biodiesel from WCO and mineral diesel affects the particle size distributions of a current state of art small displacement diesel engine.Experimental tests have been performed on an up-to date light common rail diesel engine. Its complete operative field has been investigated. The results obtained show that the use of biodiesel blends from WCO reduces the total number of particles emitted from the engine with respect to the diesel fuel; the reduction is more evident as the percentage of biodiesel in the blend increases. The number of particles in WCO biodiesel soot with diameter smaller than 10 nm is reduced as compared to diesel fuel; the same trend is observed for diameters larger than 200 nm; comparable particle numbers were obtained in the ultrafine range (Dp < 100 nm).     

Particulate characteristics of laser ignited hydrogen enriched compressed natural gas engine

Laser ignition (LI) is emerging as a strong technology to control the oxides of nitrogen (NOx) emissions from spark ignition (SI) engines without the need for any significant exhaust gas after-treatment and is an appropriate technology for meeting future emission norms in the automotive sector. In this study, particulate characteristics of LI engine fuelled with different compressed natural gas (CNG) and hydrogen mixtures [100% CNG, 10HCNG (10% v/v hydrogen with 90% v/v CNG), 30HCNG (30% v/v hydrogen with 70% v/v CNG), 50HCNG (50% v/v hydrogen with 50% v/v CNG) and 100% hydrogen] were investigated. Experiments were performed in a suitably modified single cylinder engine, which operated in LI mode at constant engine speed (1500 rpm) at five different engine loads (5, 10, 15, 20 and 25 Nm). Particulate characteristics were determined using an engine exhaust particle sizer (EEPS). Results showed that particle number concentration increased with increasing engine load. Number-size, surface area-size and mass-size distributions of particulates reflected that addition of hydrogen in the CNG improved particulate emission characteristics especially in nucleation mode particle (NMP) size range (10 nm < Dp < 50 nm). Among the test fuels, hydrogen-fuelled engine emitted the lowest number of particles. It was observed that the difference between particulate characteristics emitted by different test fuels reduced at higher engine loads. Significant contribution of lubricating oil in particulate emissions from both hydrogen as well as HCNG fuelled LI engine was an important finding of this study. Dominant contribution of larger particles (Dp > 50 nm) in total particle mass (TPM) was an important observation of this study. The qualitative correlation between total particle number (TPN) and TPM indicated that suitable fuel composition at different engine loads yielded cleaner exhaust from the LI engine. Overall, this study demonstrated that addition of hydrogen in CNG is advantageous from particulate reduction point of view, however, optimum fuel composition should be adjusted according to engine operating condition in order to reduce particulate emissions.     

Effect of diethyl ether additive in Jatropha biodiesel-diesel fuel blends on the variable compression ratio diesel engine performance and emissions characteristics at different loads and compression ratios

An investigational analysis was performed to assess the effect of diethyl ether (DEE) that acts as an oxygenated additive in Jatropha biodiesel and diesel fuel blends on the performance enhancement and emission reduction of a variable compression ratio (CR) diesel engine. The DEE (10% vol) is added to different concentration levels of Jatropha biodiesel (B5, B10, and B20). The Jatropha biodiesel (JME) is prepared by the transesterification reaction and DEE is prepared through acid distillation of ethanol. The various tests were conducted by varying the loads at 25%, 50%, 75%, and 100% (3, 6, 9, and 12 kg). The DEE was entirely miscible with diesel and Jatropha biodiesel, the addition of DEE increases the cetane and calorific value, kinematic viscosity of the fuel blends compared with neat diesel or Jatropha biodiesel. The results illustrate that at higher loads and CRs, the engine performance parameters such as brake thermal efficiency enhances and reduces the brake-specific fuel consumption for DEE-Jatropha biodiesel-diesel fuel blends. Blend A3 (10% DEE + 20% JME + 70% diesel) demonstrated an overall improvement in the engine performance parameters and emission characteristics compared with A1, A2, and diesel fuel blends. It is concluded that the DEE-JME-diesel fuel blend is a promising source of fuel for diesel engine at maximum load.     

生物柴油对直喷式柴油机燃烧和排放的影响

列举了生物柴油的基本物化特性。介绍了生物柴油对直喷式柴油机燃烧和排放的影响。相比普通柴油,燃用生物柴油可以减少CO、CO_2、SO_2、HC、微粒以及碳烟的排放且不会影响柴油机工作性能。采用EGR、乳化油、多次喷射及微粒捕捉器等措施可以进一步降低使用生物柴油的微粒和NOx排放。生物柴油作为一种可再生的替代能源,以其良好的环境效应受到越来越多的关注。     

柴油机微粒袋滤器的试验研究

本将袋滤技术用于柴油机生粒排放控制，根据柴油机的工作特点，研制了一结构较为紧凑的柴油机微粒袋滤器，在４８５Ａ柴油机台架上重点对柴油机的微粒质量排放特性，袋滤器的过滤效率、阻力及清灰效果进行了试验考察。结果证实，柴油机的质量排放浓度在高、低速工况下较高而在中等转速下较低，袋滤器的微粒捕集效率在不同工况下均高于９０％；袋滤器的清灰系统在整个试验期间能有效地工作而无故障。     

Effect of induction on exhaust gas recirculation and hydrogen gas in compression ignition engine with simarouba oil in dual fuel mode

Biofuels extracted from non-edible oil is sustainable and can be used as an alternative fuel for internal combustion engines. This study presents the performance, emission and combustion characteristic analysis by using simarouba oil (obtained from Simarouba seed) as an alternative fuel along with hydrogen and exhaust gas recirculation (EGR) in a compression ignition (CI) engine operating on dual fuel mode. Simarouba biofuel blend (B20) was prepared on volumetric basis by mixing simarouba oil and diesel in the proportion of 20% and 80% (v/v), respectively. Hydrogen gas was introduced at the flow rate of 2.67 kg/min, and EGR concentration was maintained at 30% of total air introduction. Performance, combustion and emission characteristics analysis were examined with biodiesel (B20), biodiesel with hydrogen substitution and biodiesel, hydrogen with EGR and were compared with neat diesel operation. Results indicate that BTE of the engine operating with biodiesel B20 was decreased when compared to neat diesel operation. However, introducing hydrogen along with B20 blend into the combustion chamber shows a slight increase in the BTE by 1%. NO_x emission was increased to 18.13% with the introduction of hydrogen than that of base fuel (diesel) operation. With the introduction of EGR, there is a significant reduction in NO_x emission due to decrease in in-cylinder temperature by 19.07%. A significant reduction in CO, CO_2, and smoke emissions were also noted with the introduction of both hydrogen and EGR. The ignition delay and combustion duration were increased with the introduction of hydrogen, EGR with biodiesel than neat diesel operation. Hence, the proposed biodiesel B20 with H₂ and EGR combination can be applied as an alternative fuel in CI engines.     

Effect of an emission-reducing soluble hybrid nanocatalyst in diesel/biodiesel blends on exergetic performance of a DI diesel engine

The present study was set to explore the effect of a novel soluble hybrid nanocatalyst in diesel/biodiesel fuel blends on exergetic performance parameters of a DI diesel engine. Experiments were carried out using two types of diesel/biodiesel blends (i.e., B5 and B20) at four concentrations (0, 30, 60 and 90 ppm) of the hybrid nanocatalyst, i.e., cerium oxide immobilized on amide-functionalized multiwall carbon nanotubes (MWCNT). Furthermore, the exergy analysis was performed at five different loads and two engine speeds. The results obtained revealed that the exergetic parameters were profoundly influenced by engine speed and load. In general, increasing engine speed and load increased the magnitude of the destructed exergy. Moreover, the exergy efficiency increased by increasing engine load, while it decreased by elevating engine speed. However, the applied fuel blends had approximately similar exergetic efficiency and sustainability index. Interestingly, a remarkable reduction in emissions was obtained by incorporating the soluble catalyst nanoparticles to the diesel/biodiesel blends. Thus, it could be concluded that the diesel/biodiesel blends containing amide-functionalized MWCNTs-CeO₂ catalyst might substitute the use of pure diesel fuel without any unfavorable change in the exergetic performance parameters of the DI engines.     

Partial hydrogenation and hydrogen induction: A comparative study with B20 operation in a turbocharged CRDI diesel engine

Numerous studies explored the possibility and effective strategies for supplementing hydrogen along with fossil or biofuels on internal combustion engines. Hydrogen is also being employed for formulating fuels such as hydrogen compressed natural gas in the gaseous form and hydrogenated biofuels in the liquid form. The present study evaluates (i) hydrogen usage on the fuel formulation and (ii) investigates the engine operation of an automotive turbocharged diesel engine operated with karanja biodiesel blended diesel (B20) as a reference fuel. Existing literature outlines that biodiesel blends possess lower energy content and emit higher nitric oxide (NO) emission than fossil diesel. The present research paper partially hydrogenates karanja biodiesel using an autoclave reactor with a palladium catalyst to increase the saturation levels and mitigate the biodiesel-NO penalty. Besides, the drop in energy release of B20 is compensated through the provision of hydrogen induction along the intake manifold. The hydrogen flow rates to the turbocharged engine are maintained at a fixed energy share of 10%. Both biodiesel and hydrogenated biodiesel were blended on a volume basis (20%) with fossil diesel (80%) and are designated as B20 and HB20, respectively. The test results reveal that HB20 effectively mitigates the biodiesel-NO penalty with a maximum reduction of 29.8% compared to B20. Further, hydrogen induction yielded a significant improvement (23.7%) in fuel consumption with HB20 relative to B20 without hydrogen addition. The compounding effect of hydrogen usage on the engine operation and fuel formulation exhibited a better performance and emission trade-off at mid load conditions.     

The effect of biodiesel and bioethanol blended diesel fuel on nanoparticles and exhaust emissions from CRDI diesel engine

Biofuel (biodiesel, bioethanol) is considered one of the most promising alternative fuels to petrol fuels. The objective of the work is to study the characteristics of the particle size distribution, the reaction characteristics of nanoparticles on the catalyst, and the exhaust emission characteristics when a common rail direct injection (CRDI) diesel engine is run on biofuel-blended diesel fuels. In this study, the engine performance, emission characteristics, and particle size distribution of a CRDI diesel engine that was equipped with a warm-up catalytic converters (WCC) or a catalyzed particulate filter (CPF) were examined in an ECE (Economic Commission Europe) R49 test and a European stationary cycle (ESC) test. The engine performance under a biofuel-blended diesel fuel was similar to that under D100 fuel, and the high fuel consumption was due to the lowered calorific value that ensued from mixing with biofuels. The use of a biodiesel–diesel blend fuel reduced the total hydrocarbon (THC) and carbon monoxide (CO) emissions but increased nitrogen oxide (NO_x) emissions due to the increased oxygen content in the fuel. The smoke emission was reduced by 50% with the use of the bioethanol–diesel blend. Emission conversion efficiencies in the WCC and CPF under biofuel-blended diesel fuels were similar to those under D100 fuel. The use of biofuel-blended diesel fuel reduced the total number of particles emitted from the engine; however, the use of biodiesel–diesel blends resulted in more emissions of particles that were smaller than 50 nm, when compared with the use of D100. The use of a mixed fuel of biodiesel and bioethanol (BD15E5) was much more effective for the reduction of the particle number and particle mass, when compared to the use of BD20 fuel.     

Characteristics analysis for total volatile organic compounds emissions of methanol-diesel fuel

To study the characteristics of volatile organic compounds (VOCs) emissions from an engine fueled with methanol diesel, an experiment compared with petroleum diesel (0# diesel) and biodiesel was carried out on a Xichai 4CK diesel engine test bench by the solid phase adsorption-thermal desorption-gas chromatography mass spectrometry method. In this experiment, methanol-diesel (20 vol.% methanol), petroleum diesel and biodiesel were analyzed through the sampling system, which consists of Tenax TA adsorption tubes, flow sampling pump, the capillary gas chromatography–mass spectrometry (CGC/MS), etc. The experimental results demonstrate that total volatile organic compounds (TVOC) emissions of methanol diesel are lower than petroleum diesel but higher than biodiesel at maximum power, and that TVOC emissions of methanol diesel reduce with the rise of load but increase when the rotation speed of engine gets faster. And benzene and toluene are two main components of TVOC emissions of methanol diesel, accounting for more than 70% at rated power. Therefore, this study can provide a theoretical basis for popularization and development of methanol-diesel fuel in the future, meanwhile, contributing to make relative regulations and standards to control its emissions.     

Potential and challenges for large-scale application of biodiesel in automotive sector

Biodiesel is receiving serious attention globally as a potential alternative fuel for replacing mineral diesel, partially or fully. In this review paper, most prominent methods of biodiesel production commercially, life-cycle analysis and economic issues related to biodiesel, engine performance, combustion and emission characteristics including particulate, engine compatibility issues and effect of biodiesel usage on engine component wear and lubricating oil are comprehensively discussed. Majority of biodiesel produced globally is via base-catalyzed transesterification process since this is a low temperature and pressure process, having high conversion rates without intermediate steps, and it uses inexpensive materials of construction for the plant. Catalyst types (alkaline, acidic or enzymatic), catalyst concentration, molar ratio of alcohol/oil, reaction temperature, moisture content of reactants, and free fatty acid (FFA) content of oil are the main factors affecting biodiesel (ester) yield from the transesterification process. Substantial reduction in particulate matter (PM), total hydrocarbons (THC) and carbon monoxide (CO) emissions in comparison to mineral diesel, and increased brake specific fuel consumption (BSFC) and oxides of nitrogen (NO_X) emissions are reported by most researchers using unmodified compression ignition (CI) engines. This review covers several aspects, which are not covered by previous review articles, such as effect of biodiesel on unregulated emissions, effect of biodiesel on carbon deposits, wear of key engine components, and lubricating oil in long-term endurance studies. It emerges from literature review that even minor blends of biodiesel help control emissions and ease pressure on scarce petroleum resources without sacrificing engine power output, engine performance and fuel economy. This review underscores that future studies should focus on optimization of fuel injection equipment and hardware modifications to develop dedicated biodiesel engines, improve low temperature performance of biodiesel fuelled engines, develop new biodiesel compatible lubricating oil formulations and special materials for engine components before implementing large-scale substitution of mineral diesel by biodiesel globally.     

氢气／柴油发动机NOx和微粒排放特性的数值模拟

在柴油引燃氢气／柴油发动机中,氢气的引入会对氢气／空气混合气氛围中的柴油雾化特性和燃烧特性产生直接的影响,进而对发动机的排放产生影响．应用改进的KIVA．3V程序,对氢气／柴油发动机的N0x和微粒排放特性进行了模拟研究,分析了氢气的引入对氢气／柴油发动机N0。和微粒排放的影响．结果表明：低负荷时,氢气替代部分柴油后,发...     

Evaluating combustion,performance and emission characteristics of diesel engine using karanja oil methyl ester biodiesel blends enriched with HHO gas

With a specific end goal to take care of the worldwide demand for energy, a broad research is done to create alternative and cost effective fuel. The fundamental goal of this examination is to investigate the combustion, performance and emission characteristics of diesel engine using biodiesel blends enriched with HHO gas. The biodiesel blends are gotten by blending KOME obtained from transesterification of karanja oil in various proportions with neat diesel. The HHO gas is produced by the electrolysis of water in the presence of sodium bicarbonate electrolyte. The constant flow of HHO gas accompanied with biodiesel guarantees lessened brake specific fuel consumption by 2.41% at no load and 17.53% at full load with increased the brake thermal efficiency by 2.61% at no load and 21.67% at full load contrasted with neat diesel operation. Noteworthy decline in unburned hydrocarbon, carbon monoxide, carbon-dioxide emissions and particulate matter with the exception of NO_x discharge is encountered. The addition of EGR controls this hike in NO_x with a slight decline in the performance characteristics. It is clear that the addition of HHO gas with biodiesel blends along with EGR in the test engine improved the overall characterization of engine.     

Determination of ecological efficiency in internal combustion engines: The use of biodiesel

This paper evaluates and quantifies the environmental impact from the use of some renewable fuels and fossils fuels in internal combustion engines. The following fuels are evaluated: gasoline blended with anhydrous ethyl alcohol (anhydrous ethanol), conventional diesel fuel, biodiesel in pure form and blended with diesel fuel, and natural gas. For the case of biodiesel, its complete life cycle and the closed carbon cycle (photosynthesis) were considered. The ecological efficiency concept depends on the environmental impact caused by CO₂, SO₂, NO_x and particulate material (PM) emissions. The exhaust gases from internal combustion engines, in the case of the gasoline (blended with alcohol), biodiesel and biodiesel blended with conventional diesel, are the less polluting; on the other hand, the most polluting are those related to conventional diesel. They can cause serious problems to the environment because of their dangerous components for the human, animal and vegetable life. The resultant pollution of each one of the mentioned fuels are analyzed, considering separately CO₂, SO₂, NO_x and particulate material (PM) emissions. As conclusion, it is possible to calculate an environmental factor that represents, qualitatively and quantitative, the emissions in internal combustion engines that are mostly used in urban transport. Biodiesel in pure form (B100) and blended with conventional diesel as fuel for engines pollute less than conventional diesel fuel. The ecological efficiency for pure biodiesel (B100) is 86.75%; for biodiesel blended with conventional diesel fuel (B20, 20% biodiesel and 80% diesel), it is 78.79%. Finally, the ecological efficiency for conventional diesel, when used in engines, is 77.34%; for gasoline, it is 82.52%, and for natural gas, it is 91.95%. All these figures considered a thermal efficiency of 30% for the internal combustion engine.     

Improvement of emission reduction in nano additive Simarouba glauca biodiesel blends

In this paper discussed about the emission profile from nano additive blended biodiesel. It is observed that minimum carbon dioxide was emitted in the presence of zinc oxide blends when compared to B20 and diesel. The hydrocarbon emission for the diesel and B20 was higher than that of the B20ZnO50 and B20ZnO100 blended fuels. The higher oxide of nitrogen emissions was observed with the B20ZnO50 and B20ZnO100 blended fuels at all engine loads when compared to B20 and diesel.     

Effect of ethanol blending with biodiesel on engine performance and exhaust emissions in a CI engine

The use of biodiesel as an alternative diesel engine fuel is increasing rapidly. However, due to technical deficiencies, they are rarely used purely or with high percentages in unmodified diesel engines. Therefore, in this study, we used ethanol as an additive to research the possible use of higher percentages of biodiesel in an unmodified diesel engine. Commercial diesel fuel, 20% biodiesel and 80% diesel fuel, called here as B20, and 80% biodiesel and 20% ethanol, called here as BE20, were used in a single cylinder, four strokes direct injection diesel engine. The effect of test fuels on engine torque, power, brake specific fuel consumption, brake thermal efficiency, exhaust gas temperature, and CO, CO₂, NO_x and SO₂ emissions was investigated. The experimental results showed that the performance of CI engine was improved with the use of the BE20 especially in comparison to B20. Besides, the exhaust emissions for BE20 were fairly reduced.