Sensor for oxygen evaluation in concrete

This paper includes results from a research work carried out for developing and optimising a sensor to measure the limiting current of oxygen reduction in concrete.Platinum, stainless steel and carbon steel materials were tested as working electrodes in saturated Ca(OH)₂ solution. Linear correlations were obtained between the limiting currents of oxygen reduction and the oxygen concentration in solution.The measurements of the limiting current density due to oxygen reduction have been made in concrete specimens with a sensor consisting of platinum and stainless steel, as working electrodes, graphite, as a counter electrode, and activated titanium, as a reference electrode, under different conditions of water and oxygen accessibility to the concrete. The results show that this sensor detects oxygen content variations in the interstitial solution of the concrete, providing qualitative information about the evolution of oxygen availability in concrete.     

Comparison of curing compounds to reduce volume change from differential drying in concrete pavement

Curing compounds are used to retain moisture which promotes hydration to develop a tight microstructure. Because of the large surface-to-volume ratio of these structures, differential moisture loss can cause unwanted deflections, reduction in ride quality, and cracking. This paper quantitatively compares the effectiveness of different curing methods with an emphasis on curing compounds to resist moisture loss and subsequent volume changes caused by differential shrinkage. This work provides a quantitative comparison between different curing compounds, wet, sealed and no curing not made in previous publications. A performance-based cost analysis over the different curing compounds is also included. The result shows that the poly-alphamethylstyrene curing compound causes the lowest mass loss and subsequent deflections compared to the water–resin and water–wax-based curing compounds at equal coverage rates at equal costs. The work also shows that a double application of curing compound shows greater benefit than a single layer with the same volume for water–wax-based curing compounds. The results show that if adequate amounts of curing compounds are used then they are a useful curing method for members sensitive to differential drying such as concrete pavements.     

The effect of realistic curing temperature on the strength and E-modulus of concrete

The strength and E-modulus of concrete are decisive parameters when it comes to ultimate limit state design, serviceability limit state design, and early age crack assessment. The properties of concrete are generally determined in the laboratory under 20 °C isothermal conditions and then used as the basis for calculations under realistic temperature conditions. It is well-known, however, that the curing temperature affects both the rate of property development in concrete and the “final value” of a given property. The current study investigated the effect of a realistic temperature history on the compressive cube strength, the tensile strength, and the tensile E-modulus for two concretes, a reference concrete and a fly ash concrete. Concrete specimens were subjected to either (1) 20 °C isothermal curing conditions, or (2) realistic temperature curing conditions for 14 days and then 20 °C isothermal conditions, until they were tested after 28 and 91 days. Parallel tests performed in a Temperature-Stress Testing Machine were also used to evaluate the results. The reference concrete showed a general reduction in strength and E-modulus when subjected to a realistic curing temperature, whereas the fly ash concrete showed an 11% increase in the 28-day E-modulus when cured under realistic temperature conditions. Furthermore, in both isothermal and realistic curing temperature conditions, the fly ash concrete showed a pronounced property development beyond 28 days, which could not be described by the material model currently used.     

Accelerated carbonation and performance of concrete made with steel slag as binding materials and aggregates

Steel slag has been used as supplementary cementitious materials or aggregates in concrete. However, the substitution levels of steel slag for Portland cement or natural aggregates were limited due to its low hydraulic property or latent volume instability. In this study, 60% of steel slag powders containing high free-CaO content, 20% of Portland cement and up to 20% of reactive magnesia and lime were mixed to prepare the binding blends. The binding blends were then used to cast concrete, in which up to 100% of natural aggregates (limestone and river sands) were replaced with steel slag aggregates. The concrete was exposed to carbonation curing with a concentration of 99.9% CO₂ and a pressure of 0.10 MPa for different durations (1d, 3d, and 14d). The carbonation front, carbonate products, compressive strength, microstructure, and volume stability of the concrete were investigated. Results show that the compressive strength of the steel slag concrete after CO₂ curing was significantly increased. The compressive strengths of concrete subjected to CO₂ curing for 14d were up to five-fold greater than that of the corresponding concrete under conventional moist curing for 28d. This is attributed to the formation of calcium carbonates, leading to a microstructure densification of the concrete. Replacement of limestone and sand aggregates with steel slag aggregates also increased the compressive strengths of the concrete subjected to CO₂ curing. In addition, the concrete pre-exposed to CO₂ curing produced less expansion than the concrete pre-exposed to moist curing during the subsequent accelerated curing in 60 °C water. This study provides a potential approach to prepare concrete with low-carbon emissions via the accelerated carbonation of steel slag.     

Effects of super plasticizer and curing conditions on properties of concrete with and without fiber

In this study, effects of super plasticizer (SP) and curing conditions on properties of concrete with and without fiber were investigated. In the concrete mixtures, Portland cement, artificial aggregate, SP and steel fibers were used. SP in concrete mixtures was used with ratios of 1.0%, 1.5%, and 2.0% by weight of cement and so C25 concrete was produced with and without fiber. Specimens were cured under two different curing conditions being continuous moist curing and open-air curing. Produced concrete with and without fiber were compared with each other as well as with Portland cement concrete. The highest compressive and flexural strength were obtained with 1.0% and 1.5% SP fiber reinforced concrete, respectively.     

The permeability of fly ash concrete

Oxygen permeability tests were carried out on plain ordinary Portland cement (OPC) and fly ash concretes at three nominal strength grades. Prior to testing the concretes were subjected to a wide range of curing and exposure conditions. The results emphasize the importance of adequate curing to achieve concrete of low permeability, especially when the ambient relative humidity is low. In addition, the results demonstrate the considerable benefit that can be achieved by the use of fly ash in concrete. Even under conditions of poor curing, fly ash concrete is significantly less permeable than equal-grade OPC concrete, the differences being more marked for higher-grade concretes. Attempts were made to correlate strength parameters with permeability but it is concluded that neither the strength at the end of curing nor the 28-day strength provides a reliable indicator of concrete permeability. A reliable correlation was established between the water to total cementitious material ratio [w/(c+f)] and the permeability of concretes subjected to a given curing and exposure regime.     

A site study of durability indexes for concrete in marine conditions

The paper describes an investigation into the validity of durability index tests when used in a site situation and to evaluate the effectiveness of site curing methods. Concretes manufactured and cured under site conditions in a warm, humid coastal environment were investigated using recently developed durability index tests.Three blended binders (GGBS, FA and CSF) were used to cast a series of wall and slab elements. The elements were cured using practical site methods currently employed in the industry. Cores were extracted at early (28-day) and later (120-day) ages and used to determine the durability index properties.The results indicated that it is possible to manufacture, place and cure site concrete to achieve acceptable durability properties. Full wet curing proved to be the most effective method, as expected. While variation in potential durability properties existed at early age (28 days) between site and wet cured samples, at a later age (120 days) the variations had reduced such that, in practical and general terms, the different site curing methods were virtually indistinguishable. It was clear that environmental curing continues after 28 days provided climatic conditions are conducive for this to occur. Thus, on-going environmental curing largely governs the potential durability. To develop a concrete durability performance specification, it is imperative that a system is developed to quantify the effects of the environment on potential durability.     

The effect of mineral admixtures on the properties of high-performance concrete

The paper presents a laboratory study on the influence of two mineral admixtures, silica fume (SF) and fly ash (FA), on the properties of superplasticised high-performance concrete. Assessment of the concrete mixes was based on short- and long-term testing techniques used for the purpose of designing and controlling the quality of high-performance concrete. These include compressive strength, porosity, oxygen permeability, oxygen diffusion and chloride migration. Measurements were carried out after curing at 20% and 65% relative humidity up to the age of 1 yr. The results, in general, showed that mineral admixtures improved the properties of high-performance concretes, but at different rates depending on the binder type. While SF contributed to both short- and long-term properties of concrete, FA required a relatively longer time to get its beneficial effect. In the long term, both mineral admixtures slightly increased compressive strength by about 10%, but contributed more to the improvement of transport properties of concretes.     

Effect of drying conditions on autogenous shrinkage in ultra-high performance concrete at early-age

This experimental study investigated the effects of drying conditions on the autogenous shrinkage of ultra-high performance concrete (UHPC) at early-ages. UHPC specimens were exposed to different temperatures, namely, 10, 20 and 40°C under a relative humidity (RH) ranging from 40 to 80%. The effects of using a shrinkage-reducing admixture (SRA) and a superabsorbent polymer (SAP) as shrinkage mitigation methods were also investigated. The results show that autogenous and drying shrinkage are dependent phenomena. Assuming the validity of the conventional superposition principle between drying and autogenous shrinkage led to overestimating the actual autogenous shrinkage under drying conditions; the level of overestimation increased with decreasing RH. Both SRA and SAP were very effective in reducing autogenous shrinkage under sealed conditions. However, SRA was efficient in reducing drying shrinkage under drying conditions, while SAP was found to increase drying shrinkage. Generally, results indicate that adequate curing is essential for reducing shrinkage in UHPC even when different shrinkage mitigation methods are applied.     

Effect of curing methods on strength and durability of concrete under hot weather conditions

This paper reports the results of a research study conducted to evaluate the effect of curing methods on the mechanical properties of ordinary Portland cement (OPC) and Silica Fume Cement (SFC) concretes. Slab and beam specimens were prepared and cured by covering them with wet burlap or applying a curing compound under field conditions. Four types of curing compounds, namely water-, acrylic-, and bitumen-based and coal tar epoxy, were applied on the concrete specimens. The curing compounds were applied immediately after casting or after an initial period of burlap curing. The effect of the selected curing regime on the properties of OPC and SFC concrete specimens was evaluated by measuring compressive strength, water-absorption and chloride permeability. The strength and durability characteristics of both OPC and SFC concrete specimens cured by applying the selected curing compounds were similar or better than that of concrete specimens cured by covering with wet burlap. Though no significant change in strength could be noted due to the curing methodology; however, its effect was noticeable on the durability. The best performance was shown by concrete specimens cured by applying the bitumen-based curing compound followed by those cured by applying coal tar epoxy, acrylic-based or water-based curing compound. The initial period of water curing, prior to the application of the curing compound, was also noted to be beneficial in increasing the durability of concrete.     

Asphalt concrete rutting predicted using the PEDRO model

This paper presents a theoretical viscoelastic approach, called PEDRO (PErmanent Deformation of asphalt concrete layers for ROads), for predicting rut formation in asphalt concrete materials subjected to traffic loading. Input data are traffic parameters, asphalt concrete viscosity and asphalt layer thickness. Vertical strains that cause rutting in the pavement were estimated using the PEDRO approach. A large-size type of wheel tracking machine, which has the capability to subject asphalt concrete slabs to different loadings, has been used to study the effects of wheel load and tyre pressure. Rut development in the slabs under various loading conditions was predicted. The approach has shown reasonable results as regards predicting densification and shear rutting in the tested asphalt concrete slabs.     

Shrinkage of plain and silica fume cement concrete under hot weather

Supplementary cementing materials (SCMs) are widely used these days to improve the durability of concrete. Silica fume has gained world wide acceptance due to its high pozzolanic reactivity compared to other SCMs. While silica fume cement concrete has several advantages over other blended cement concretes its main draw back is increased plastic and drying shrinkage, particularly under hot weather conditions. This paper reports results of a study conducted to assess these properties of plain and silica fume cement concrete specimens cast and cured in the field under hot weather conditions. The effect of specimen size and method of curing on plastic and drying shrinkage and some of the mechanical properties of silica fume and plain cement concrete specimens were evaluated. Results indicated that the type of cement significantly affected both the plastic and drying shrinkage of concrete in that these values in the silica fume cement concrete specimens were more than those in the plain cement concrete specimens. As expected, the shrinkage strains in both the plain and silica fume cement concrete specimens cured by continuous water-ponding were less than that in similar concrete specimens cured by covering them with wet burlap. The results point to the importance of selecting a good quality silica fume and good curing for avoiding cracking of concrete due to plastic and drying shrinkage, particularly under hot weather conditions.     

混凝土养护期间HRB400钢筋钝化行为研究

为了研究HRB400钢筋在模拟养护阶段混凝土孔隙液中表面钝化膜的生长过程,采用3种电化学测试技术(开路电位、电化学阻抗谱、动电位极化曲线)研究钢筋表面钝化膜的性能随着浸泡时间的变化特征,此外通过XPS对稳定钝化膜的成分与结构进行分析。结果表明,同传统钢筋材料一样,HRB400钢筋在模拟混凝土养护条件的溶液中展现出良好的耐蚀性能,浸泡5 d后便能够生成稳定钝化膜。XPS分析发现钢筋钝化膜为双层结构,内层以二价铁离子化合物为主,外层主要由三价铁离子化合物组成。     

Effects of shrinkage reducing admixture in shrinkage compensating concrete under non-wet curing conditions

The practice of using expansive agents has been recommended to manufacture shrinkage-compensating concrete provided that an adequate wet curing is carried out. On the other hand, more recently the use of shrinkage reducing admixture (SRA) has been suggested to improve concrete performance in terms of lower risk of cracking related to drying shrinkage.However, neither expansive agent nor SRA, when used separately, can definitively and safely avoid the risk of cracking caused by drying shrinkage in real concrete structures under the practical conditions of curing on many job-sites.This paper shows the advantages of the combined use of SRA and CaO-based expansive agent to produce shrinkage-compensating concrete even in the absence of an adequate wet curing.     

Effect of curing parameters on CO2 curing of concrete blocks containing recycled aggregates

In this study, a CO₂ curing process was adopted in order to promote rapid strength development of concrete blocks containing recycled aggregates. The influence of several factors associated with the curing conditions on the curing degree and compressive strength of the concrete blocks were investigated, including curing time, temperature, relative humidity, pressure and post-water curing after the pressurized CO₂ curing (PCC) process. In addition a flow-through CO₂ curing (FCC) method at ambient pressure was also used. The results of the PCC experiments showed that, considerable curing degree and compressive strength were attained during the first 2 h of CO₂ curing, and a prolonged curing time yielded slower gains. The variations of temperature from 20 °C to 80 °C and relative humidity from 50% to 80% had limited impacts on PCC; but the effects of CO₂ gas pressure on the curing degree and compressive strength were more pronounced. The post-water curing after pressurized CO₂ curing allowed the concrete blocks to attain further strength gain but its effectiveness was inversely proportional to the CO₂ curing degree already attained. The FCC experimental results indicated that although a lower curing degree and slower strength development at the early age were observed, after 24 h of curing duration, they were comparable to those obtained by the PCC method. To assess the thermal stability of the concrete blocks, the optimum CO₂ curing regime was adopted for preparing the concrete blocks with recycled aggregates, and the CO₂ cured specimens exhibited better fire resistance than the water-cured ones at 800 °C.     

Assessment of the surface permeation properties of recycled aggregate concrete

The water permeability, air permeability and surface permeability of recycled aggregate concrete (RAC) are compared with those of a control concrete made with natural aggregate. The study shows that the permeation properties of RAC depend on mix-design, conditions of curing and drying of samples. Relationships between permeability and other physical characteristics of concrete such as water absorption capacity and diffusivity are discussed. According to the criteria existing for ordinary concrete made with natural aggregate, RAC could be classified as being of moderate quality rather than poor quality. The testing methodology shows that some of the techniques used to measure the permeability of RAC need to be modified in order with the distinctive characteristics of this material.     

Effects of distribution of lightweight aggregates on internal curing of concrete

This study investigates the effects of spatial distribution of lightweight aggregates (LWAs) on internal curing of concrete. As replacements for normal aggregates, different sizes and amounts of natural pumice LWAs were used as water reservoirs to provide internal curing in mitigating autogenous deformation. Water in the pre-soaked LWAs flows into cement paste during hydration and provides internal curing to counteract the RH loss due to self-desiccation of binding paste. The results show that variations in the autogenous strain of concrete can be evaluated in terms of LWA–LWA proximity. The protected paste volume approach, previously used for air-entrained concrete, is applied to calculate the internally-cured volume of paste. The results show that the experimental rate of mitigation of autogenous strain for different series of concrete specimens, with respect to the reference concrete, gave the best-fitted values at water flow distance of 1 mm. The results indicate that the protected paste volume in internal curing can be determined by calculating the water-entrained volume using image analysis.     

Curing and the durability of OPC,fly ash and blast-furnace slag concretes

This paper presents preliminary results of a research project into the influence of moist curing on the potential durability of concrete. Durability is characterized by measuring the oxygen permeability and water absorption at various depths in the covercrete. Concretes containing plain OPC, an OPC-FA blend and an OPC-GGBS blend were used. A range of strength grades was tested for each of these binder types. Concretes were exposed to moist curing conditions for 1, 3, 7 and 28 days before being tested at 28 days after casting. The main conclusions are: (i) moist curing has a marked influence on the potential durability of concrete and (ii) a relatively greater influence on durability can be effected by extending the duration of early-age moist curing rather than decreasing the binder/water ratio.     

Effect of steel fiber on the mechanical properties of oil palm shell lightweight concrete

This paper reports the results of a study conducted to investigate the effect of low volume content of steel fiber on the slump, density, compressive strength under different curing conditions, splitting tensile strength, flexural strength and modulus of elasticity of a grade 35 oil palm shell (OPS) lightweight concrete mixture. The results indicate that an increase in steel fiber decreased the workability and increased the density. All the mechanical properties except the modulus of elasticity (E) improved significantly. The 28 day compressive strength of steel fiber OPS lightweight concrete in continuously moist curing was in the range of 41–45 MPa. The splitting tensile/compressive and the flexural/compressive strength ratio for plain OPS concrete are comparable with artificial lightweight aggregate. The (E) value measured in this study was about 15.5 GPa on average for all mixes, which is higher than previous studies and is in the range of normal weight concrete. Steel fiber can be used as an alternative material to reduce the sensitivity of OPS concrete in poor curing environments.     

Moisture distribution in drying ordinary and high performance concrete cured in a simulated hot dry climate

Adequate moisture is very important during early age of portland cement concrete. The Single Point Magnetic Resonance Imaging technique was used to study the effects of various lengths of moist curing, and the use of curing compound, on the amount and distribution of evaporable water during drying of ordinary and high performance concrete. The specimens subjected to six different curing regimes, were cast in triplicate for a total of 72. After moist curing at 38°C, the specimens were subjected to uniaxial drying in an environmental chamber at 38°C and 40% relative humidity that simulated hot dry climate conditions. As the specimens were drying, Magnetic Resonance Imaging was used to study the evaporable water distribution, non-destructively and with millimetric resolution. The Magnetic Resonance Imaging profiles indicated a reduced moisture loss with increasing length of moist curing. Extended moist curing was especially beneficial for the two self-compacting concrete mixtures, particularly for the cover concrete. In all mixtures the use of curing compound was only marginally better than one day moist curing, but was significantly better than air curing, particularly for the cover concrete. The moisture diffusivity was evaluated from the transient moisture distribution profiles using the Boltzmann transformation method. The results indicated a strong dependence of the moisture diffusivity on the moisture content when above 80% saturation, whereas below this value it remains almost constant. The moisture diffusivity is significantly reduced with increased moist curing period.