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1.
Food wastes are typically disposed of in landfills for convenience and economic reasons. However, landfilling food wastes increases the organic content of leachate and the risk of soil contamination. A sound alternative for managing food wastes is anaerobic digestion, which reduces organic pollution and produces biogas for energy recovery. In this study, anaerobic digestion of a common food waste, brown grease, was investigated using a pilot-scale, high-rate, completely-mixed digester (5.8 m3). The digestibility, biogas production and the impact of blending of liquid waste streams from a nearby pulp and paper mill were assessed. The 343-day evaluation was divided into 5 intensive evaluation stages. The organic removal efficiency was found to be 58 ± 9% in terms of COD and 55 ± 8% in terms of VS at a hydraulic retention time (HRT) of 11.6 ± 3.8 days. The removal was comparable to those found in organic solid digesters (45–60%), but at a much shorter HRT. Methane yield was estimated to be 0.40–0.77 m3-CH4@STP kg-VSremoved−1, higher than the typical range of other food wastes (0.11–0.42 m3-CH4@STP kg-VSremoved−1), with a mean methane content of 75% and <200 ppm of hydrogen sulfide in the biogas. The blending of selected liquid wastes from a paper mill at 10 vol% of brown grease slurry did not cause significant reduction in digester performance. Using a pseudo-first-order rate law, the observed degradation constant was estimated to be 0.10–0.19 d−1 compared to 0.03–0.40 d−1 for other organic solids. These results demonstrate that brown grease is a readily digestible substrate that has excellent potential for energy recovery through anaerobic digestion. 相似文献
2.
《International Journal of Hydrogen Energy》2019,44(6):3339-3346
Residual Chlorella sp. biomass obtained after anaerobic solid-state fermentation was used to produce bio-hythane. The residual biomass was pretreated using acid, thermal, and acid-thermal methods before their respective hydrolysates were used in dark fermentation followed by the methanogenesis of anaerobic digestion to produce hydrogen and methane, respectively. Pretreatment of the residual biomass using acid and thermal methods did not significantly increase reducing sugar production. However, a maximum reducing sugar content of 28.9 mg-reducing-sugar·g-biomass−1 was attained using an acid-thermal method, resulting in the highest hydrogen and methane yields of 12.5 and 81 mL·g-volatile-solid−1, respectively. This was equivalent to the total energy yield of 3.03 kJ·g-VS−1 or 4.6% energy recovery, based on the heating value of the residual biomass. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(64):27397-27420
Hydrogen energy plays an important role in solving the environmental problems caused by the fuel crisis and greenhouse gas emissions. However, hydrogen application on an industrial scale still requires technological advances, especially in choosing the best technological route for the recovery of renewable and cost-effective hydrogen. Therefore, this bibliometric review evaluated the research progress, trends, updates, and hotspots on hydrogen production from dark fermentation. The Web of Science© database was used to select the documents from 2000 to 2021, and the VOSviewer© and Bibliometrix softwares were used to carry out the bibliometric investigation. The results demonstrated that 3071 documents (2755 articles and 316 reviews) studied the hydrogen production from dark fermentation over the last 21 years. The number of publications exponentially increased in the last five years, which can be associated with the demand for new technologies to produce clean energy sources and decrease the environmental impacts caused by petroleum-based fuel. Keyword analysis revealed that the studies focused on the operational parameters, process optimization, pretreatment, and microbial community, aiming to increase the hydrogen yield during dark fermentation. Finally, this comprehensive review provides future directions for applying dark fermentation to produce hydrogen as a sustainable and renewable fuel in a biorefiney concept. 相似文献
4.
Sustainable clean energy is the top social, economic, and environmental agenda of political leaders, policy makers, enlightened business executives, and civil society in Asia. Strong economic growth in Asia has caused a great demand for energy which has resulted in an enormous increase in CO2 emissions. The association of Southeast Asian nations (ASEAN), India, China, South Korea and Japan are the most important regions in Asia as their economies have been growing steadily. These countries though heavily dependent on fossil fuels have stepped up their measures towards low-carbon society amid domestic affordability challenges and changing global mindset. This report highlights the current energy scenario in these countries and their effort towards an affordable and sustainable clean energy future. The energy policy to enhance energy security and improve environmental sustainability is also explicated in this article. 相似文献
5.
Climate is changing (WMO, Press release No. 695, 2003) and there is increasing evidence that this is due to human activity (IPCC, Climate Change 2001—The Scientific Basis, Cambridge University Press, Cambridge, 2001). One way to react is to reduce greenhouse gas emissions into the atmosphere. Although this approach generally does not cause much objection, disagreements do occur when concrete emission targets are to be set. Against this background, the following article provides an arithmetic approach for the determination of long-term emission targets where the US and the EU are studied as examples. 相似文献
6.
Devaraj Thiruselvi Ponnusamy Senthil Kumar Madhava Anil Kumar Chyi-How Lay Salma Aathika Yuvarani Mani D. Jagadiswary Anuradha Dhanasekaran Palaniyandi Shanmugam Subramanian Sivanesan Pau-Loke Show 《International Journal of Hydrogen Energy》2021,46(31):16734-16750
Renewable biogas production technology is an excellent method for eradication of greenhouse gas emission and thereby reducing global warming. This review discusses extensively on global biomass potential, energy need and method of satisfying the energy demand through sustainable techniques. One of the best alternative technological developments for the conversion of waste into useful energy is anaerobic digestion to produce biogas. It is recognized as one among leading green energy to manage the environmental and meet the current energy tasks to tackle globally. Generally, biogas can be utilized for cooking, heat and electricity generation. In order to extend the scope of application, traces of carbon dioxide, hydrogen sulphide has to be removed by several upgrading technologies to produce high purity methane (90%). This study discusses on biogas up-gradation using physical and chemical absorption, membrane separation, cryogenic separation, hybrid technology etc. Among the various up-gradation techniques, hybrid technology yields methane purity of 97%. In addition, this work reviews about benefits and problems in anaerobic integrated Solid Oxide Fuel Cell (SOFC) with latest real-world achievement in SOFC. Several SOFC systems with dynamic model development were reviewed based on efficiency of power generation. SOFC generates 45% more electricity than generator with heat engine. This review extends the scope for further research in biogas upgradation and global warming mitigation potential with carbon credits. 相似文献
7.
《International Journal of Hydrogen Energy》2019,44(29):14694-14706
Batch and continuous modes for bio-hydrogen production by co-digesting cassava starch wastewater with buffalo dung were investigated. Response surface methodology with central composite design was used to optimize the bio-hydrogen production conditions. A hydrogen production potential of 1787 mL H2/L was achieved under optimal conditions of 2.84 g/L of NaHCO3, an initial pH of 6.77 and a total chemical oxygen demand (tCOD)/total nitrogen ratio of 42.36. A continuous stirred tank reactor was operated under the optimum conditions from batch mode to investigate the effects of hydraulic retention time (HRT) of 72, 60 and 48 h on hydrogen production. The highest hydrogen content, hydrogen production rate and hydrogen yield of 33%, 839 mL H2/L.d and 16.90 mL H2/g-CODadded, respectively, were achieved at a HRT of 60 h. The predominant hydrogen producer under the optimal conditions in batch mode was Clostridium sp. while Clostridium sp., Megasphaera sp. and Chloroflexi sp. were observed in the continuous hydrogen production mode at an optimal HRT. 相似文献
8.
Effect of thermal, chemical and thermo-chemical pre-treatments to enhance methane production 总被引:1,自引:0,他引:1
Rashad Rafique Tjalfe Gorm Poulsen Abdul-Sattar Nizami Zaki-ul-Zaman Asam Jerry D. Murphy Gerard Kiely 《Energy》2010,35(12):4556-4561
The rise in oil price triggered the exploration and enhancement of various renewable energy sources. Producing biogas from organic waste is not only providing a clean sustainable indigenous fuel to the number of on-farm digesters in Europe, but also reducing the ecological and environmental deterioration. The lignocellulosic substrates are not completely biodegraded in anaerobic digesters operating at commercial scale due to their complex physical and chemical structure, which result in meager energy recovery in terms of methane yield. The focus of this study is to investigate the effect of pre-treatments: thermal, thermo-chemical and chemical pre-treatments on the biogas and methane potential of dewatered pig manure. A laboratory scale batch digester is used for these pre-treatments at different temperature range (25 °C-150 °C). Results showed that thermo-chemical pretreatment has high effect on biogas and methane potential in the temperature range (25–100 °C). Maximum enhancement is observed at 70 °C with increase of 78% biogas and 60% methane production. Thermal pretreatment also showed enhancement in the temperature range (50–10 °C), with maximum enhancement at 100 °C having 28% biogas and 25% methane increase. 相似文献
9.
Estela Tapia-Venegas Juan Esteban Ramirez Andrés Donoso-Bravo Lorena Jorquera Jean-Phillipe Steyer Gonzalo Ruiz-Filippi 《International Journal of Hydrogen Energy》2013
The objective of this study was to evaluate the production of hydrogen in a two-stage CSTR system – both reactors having the same volume – and compare its performance with a conventional one-stage process. The lab-scale two-stage and one-stage systems were operated at five pHs and five hydraulic retention time (HRTs). The maximum volumetric hydrogen productivity and yield obtained with the two-stage system were 5.8 mmol L−1 h−1 and 2.7 mol H2 mol glucose−1, respectively, at an HRT of 12 h and pH 5.5. Overall, the two-stage system showed, at steady state, a better performance that the one-stage system for all the evaluated pHs. However, a comparison between the one-stage system, operating at 6 h of HRT, and the first reactor of the two-stage system at the same HRT did not show any significant difference, highlighting the positive impact of having a two-stage process. The determination of the ratio between the experimental measured H2 in the gas phase and the theoretical H2 generated in the liquid phase (discrepancy factor) indicated that an important part of the hydrogen produced in the first reactor was transferred into the second reactor instead of being desorbed in the headspace. Therefore, the improving of hydrogen production in the two-stage system is rather attributed to the increased transfer of hydrogen from liquid to gas than an actual total hydrogen production increase. 相似文献
10.
The influence of plant litter-compost of the hot rotten-phase as additional inoculum for anaerobic batch digestion of sugar beet silage (SBS) was studied. Four simultaneously driven batch-fermenters were inoculated with sewage sludge. Two of the fermenters were inoculated additionally with the same amount of organics by compost of the hot rotten-phase. Two of the fermenters were mesophilic (40 °C) and the other two were thermophilic (60 °C). The impact on the gas production rate and gas yield was observed to be boosted for thermophilic (60 °C) and only a minor effect of 6–13% for mesophilic (40 °C) digestion. The gas yield increased considerably up to 26.5% at 60 °C (batch). Also the methane content increased from 57.4% to 62.3% by adding compost (continuously run mesophilic digestion). Fluorescence In Situ Hybridization (FISH) indicated that a microbial effect was responsible for the observed stimulation of gas production rates, but not simply by increasing the bacterial counts. By analysing each fermenter for its mineral and trace element content a mineralic effect could be excluded. However, the bacterial counts by FISH of 10 different groups were somewhat ambiguous. But an effect on the presence of Chloroflexi could be demonstrated. They nearly doubled to 15–16% by supplementation with compost. Furthermore, under thermophilic conditions, the added compost induced a significant shift in the microbial composition towards hydrogenotrophic Methanobacteriales. The suggestive conclusion drawn is that this explicitly increase in hydrogenotrophic activity could alone or in combination with accompanying fermentative bacteria forces the microbial food chain towards stimulation of methane generation. 相似文献
11.
The halophyte species Sea Aster (Tripolium pannonicum) was grown with different concentrations of artificial seawater. In a second experiment, T. pannonicum was cultivated with a nutrient solution containing different concentrations of NaCl. This halophyte biomass was used to determine the biogas production potential. According to the findings, it is possible to produce high yields of methane using biomass from halophytes cultivated in the presence of salt. Biogas and methane yield are influenced by the salt content of the plant tissue, however, high concentrations of salt in the anaerobic reactors itself inhibit the biogas and methane production. The highest methane yield is obtained using plant substrates grown at 22.5 g L−1 sea-salt with a value of 313 cm3 g−1 of VS. When treating T. pannonicum with different concentrations of NaCl, biogas and methane yields are highest when using plant substrates grown at 30 g L−1 to produce values of 554 cm3 g−1 of VS and 447 cm3 g−1 of VS, respectively. Other research was carried out to study the effect of sodium on the biogas and methane yields using substrate from T. pannonicum cultured under non-saline conditions and adding different amounts of NaCl to the anaerobic reactors. Adding NaCl to the reactors decreases the biogas and methane production but using a salt-adapted inoculum increases the biogas yield in comparison to the non-adapted inoculum. 相似文献
12.
The winemaking process generates many by-products besides wastewater, mainly grape marcs, grape stalks, and wine lees. Anaerobic digestion is particularly suitable to treat winery waste because of its high content of nutrient-rich organic matter and for its noticeable energetic potential. To date, only results from mesophilic tests have been extensively reported. In this study, potential methane production and kinetic constants were determined by batch trials under thermophilic conditions and compared with mesophilic values already reported in literature. Grape marcs and wine lees appeared to be the most promising substrates with an estimated potential of 0.34 and 0.37 Nm3CH4/kgVSfed, respectively, while grape stalks generated only 0.13 Nm3CH4/kgVSfed. In order to assess the feasibility of a continuous anaerobic digestion process, a lab-scale semi-continuous reactor was constructed. Because of the consumption of buffer capacity, the biological process was difficult to control. On the other hand, biogas was produced when working with a hydraulic retention time of 40 d and with previously fermented grape marcs; a specific biogas production of 0.29 Nm3/kgVSfed was observed. The results of the continuous tests were used to calculate the potential energy recovery from grape marcs produced in Italy (808 thousands of tons per year) in terms of heat and electricity; about 245 GWh of heat and 201 GWh of electricity per annum could be generated in Italian scenario. 相似文献
13.
Ivet Ferrer Marianna Garfí Enrica Uggetti Laia Ferrer-MartíEnric Velo 《Biomass & bioenergy》2011,35(5):1668-1674
Low-cost tubular digesters originally developed in tropical regions have been adapted to the extreme weather conditions of the Andean Plateau (3000-4000 m.a.s.l.). The aim of this study was to characterise biogas production in household digesters located at high altitude, operating under psychrophilic conditions. To this end, two pilot digesters were monitored and field campaigns were carried out in two representative digesters of rural communities. Digesters’ useful volume ranged between 2.4 and 7.5 m3, and hydraulic residence time (HRT) between 60 and 90 days. The temperature inside the digester’s greenhouse ranged between 20 and 25 °C. Treating cow manure, a specific biogas production around 0.35 m3 kgVS−1 was obtained, with some 65% CH4 in biogas. In order to fulfil daily requirements for cooking and lighting, biogas production should be enhanced without increasing implementation costs as not to impede the expansion of this technology at household scale. In this sense, HRT below 60 days and OLR above 1 kgVS m−3 day−1 should be investigated to decrease digesters’ volume (i.e. costs) and increase biogas production rate. The adaptation of conventional gas burners to biogas characteristics can also contribute in improving the efficiency of the system. 相似文献
14.
Trace element requirements of agricultural biogas digesters during biological conversion of renewable biomass to methane 总被引:3,自引:0,他引:3
The availability of trace metals as micro-nutrients plays a very significant role on the performance and stability of agricultural biogas digesters, which are operated with energy crops, animal excreta, crop residues, organic fraction of municipal solid wastes or any other type of organic waste. The unavailability of these elements in biogas digesters is probably the first reason of poor process efficiency without any other obvious reason, despite proper management and control of other operational and environmental parameters. However, trace metal requirements of biogas digesters operated with solid biomass are not often reported in literature. Therefore, the aim of this article is to review the previous and current literature about the trace metal requirements of anaerobic biogas digesters operated with solid organic substrates for production of methane. 相似文献
15.
Anaerobic digestion (AD) has the potential to contribute to greenhouse gas emissions reductions, improve energy security, increase generation of decentralised renewable electrical and thermal energy, produce low-impact fertiliser and enhance adherence to the principles of proximity as well as self-sufficiency in waste treatment, in energy generation and in resource use. Financial viability is scrutinised investigating optimal logistic pre-conditions such as catchment area or plant size. Given that a breakthrough in deployment does not only depend on technical aspects, the relative importance and magnitude of the necessary incentives is discussed. The influence of policy instruments is studied by devising different incentive scenarios for the United Kingdom. Substantial and predictable rewards for renewable electricity and heat are essential to harness the full potential of AD in addition to the current emphasis on landfill tax. A possible configuration of energy supply companies as a crucial vehicle to bring anaerobic digestion to market is highlighted. 相似文献
16.
Modeling the performance of the anaerobic phased solids digester system for biogas energy production
A process model was developed to predict the mass and energy balance for a full-scale (115 t d−1) high-solids anaerobic digester using research data from lab and pilot scale (1-3000 kg d−1 wet waste) systems. Costs and revenues were estimated in consultation with industry partners and the 20-year project cash flow, net present worth (NPW), simple payback, internal rate of return, and revenue requirements were calculated. The NPW was used to compare scenarios in order to determine the financial viability of using a generator for heat and electricity or a pressure swing adsorption unit for converting biogas to compressed natural gas (CNG).The full-scale digester consisted of five 786 m3 reactors (one biogasification reactor and four hydrolysis reactors) treating a 50:50 mix (volatile solids basis) of food and green waste, of which 17% became biogas, 32% residual solids, and 51% wastewater. The NPW of the projects were similar whether producing electricity or CNG, as long as the parasitic energy demand was satisfied with the biogas produced. When producing electricity only, the power output was 1.2 MW, 7% of which was consumed parasitically. When producing CNG, the system produced 2 hm3 y−1 natural gas after converting 22% of the biogas to heat and electricity which supplied the parasitic energy demand. The digester system was financially viable whether producing electricity or CNG for discount rates of up to 13% y−1 without considering debt (all capital was considered equity), heat sales, feed-in tariffs or tax credits. 相似文献
17.
In the United States, the response of the federal government to the global initiative of reduction of emissions of CO2 has been limited. With the Kyoto Protocol having entered into force in February 2005, there will be renewed international pressure on the United States for action. Concurrently, the US economy, growing modestly, is characterized by large current account and budget deficits. This situation calls for garnering additional revenue through repealing of the recent tax cuts. An option available is to impose a modest carbon tax. The rationale of such a tax is that it would address the twin objectives of additional revenue and reduction of emissions. 相似文献
18.
Animesh S. Deval Harita A. Parikh Abudukeremu Kadier K. Chandrasekhar Ashok M. Bhagwat Anil K. Dikshit 《International Journal of Hydrogen Energy》2017,42(2):1130-1141
A two-chambered microbial fuel cell (MFC), which can function on the self-driven bio-electrogenic activity operated on anaerobically digested distillery waste (ADDW) i.e. wastewater post anaerobic digestion was designed and fabricated in the laboratory. MFC was evaluated for production of bioelectricity with a simultaneous reduction in the carbon content. Using a surface response methodology with a Box-Behnken design (BBD), operating conditions such as the concentration of antifoam, pH, and resistance were optimized and it was found that the pH and resistance were optimum at 8.3 and 1000 Ω, respectively with no antifoam in the system. Under optimum conditions, 31.49 Wm?3 was generated, and 60.78 ± 0.95% total organic carbon was degraded. We revealed that the fermentative bacteria generated organic acids mainly acetate from dextrose present in ADDW and electrogenic bacteria oxidized acetate in a successive manner to generate electrons, which was confirmed by gas chromatography. The development of biofilm analyzed by scanning electron microscope (SEM) was found to be crucial in the transfer of electrons directly to the anode and was confirmed by cyclic voltammetry experiments. Identification of bacteria from biofilm by both culture and denaturing gradient gel electrophoresis methods found bacteria belonging to phylum Firmicutes and γ-proteobacteria. The study of successive nature of bacterial metabolism to generate electricity could play an important role in the production of electricity in a continuous mode of operation using MFCs fed with ADDW for further reduction of carbon content post anaerobic digestion for the benefit for the environment. Thus MFC can be used as a complementary technology to anaerobic digestion. 相似文献
19.
Three renewable energy technologies (RETs) were analyzed for their feasibility for a small off-grid research facility dependent on diesel for power and propane for heat. Presently, the electrical load for this facility is 115 kW but a demand side management (DSM) energy audit revealed that 15–20% reduction was possible. Downsizing RETs and diesel engines by 15 kW to 100 kW reduces capital costs by $27 000 for biomass, $49 500 for wind and $136 500 for solar.The RET Screen International 4.0® model compared the economical and environmental costs of generating 100 kW of electricity for three RETs compared to the current diesel engine (0 cost) and a replacement ($160/kW) diesel equipment. At all costs from $0.80 to $2.00/l, biomass combined heat and power (CHP) was the most competitive. At $0.80 per liter, biomass’ payback period was 4.1 years with a capital cost of $1800/kW compared to wind's 6.1 years due to its higher initial cost of $3300/kW and solar's 13.5 years due to its high initial cost of $9100/kW. A biomass system would reduce annual energy costs by $63 729 per year, and mitigate GHG emissions by over 98% to 10 t CO2 from 507 t CO2. Diesel price increases to $1.20 or $2.00/l will decrease the payback period in years dramatically to 1.8 and 0.9 for CHP, 3.6 and 1.8 for wind, and 6.7 and 3.2 years for solar, respectively. 相似文献
20.
We analyze policies to promote renewable sources of electricity. A portfolio standard (RPS) raises electricity prices and primarily reduces gas-fired generation. A knee of the cost curve exists between 15% and 20% goals for 2020 in our central case, and higher natural gas prices lower the cost of greater reliance on renewables. A renewable energy production tax credit lowers electricity price at the expense of taxpayers, which limits its effectiveness in reducing carbon emissions, and it is less cost-effective at increasing renewables than a portfolio standard. Neither policy is as cost-effective as a cap-and-trade policy for achieving carbon emission reductions. 相似文献