Chloride penetration and carbonation in concrete with rice husk ash and chemical activators

The use of industrial or agricultural by-product substitutions for cement has greatly contributed to sustainable development practices. The joint use of chemical activators has produced improvements in the mechanical properties of concrete but there are still few studies attempting to investigate the influence of activators on carbonation and chloride penetration. This study investigated the influence of chemical activators K₂SO₄, Na₂SO₄, Na₂SiO₃ on compressive strength, chloride penetration and carbonation of concrete mixtures with rice husk ash. Results indicate that the use of these activators has beneficial effects on initial strength and reduces chloride penetration. The mixture prepared with 20% rice husk ash and 1% K₂SO₄ as a chemical activator showed the lowest carbonation coefficients, which were in fact lower than the values found in the reference sample.     

Prediction of chloride permeability of concretes containing ground pozzolans by artificial neural networks

This research was to study the chloride penetration resistance of normal (W/B of 0.80, 0.62, 0.48) and high (W/B of 0.41, 0.35, 0.30) strength concretes containing ground pozzolans such as fly ash, bottom ash and rice husk ash using the rapid chloride penetration test and the immersion test methods. Furthermore, on the basis of this experimental data, an artificial neural network technique is carried out to derive an explicit artificial neural network formulation for the prediction of chloride permeability as a function of six input parameters: water to binder ratio, percent replacement, testing ages, pozzolans types, aggregate to cement ratio and the actual compressive strength. To verify the model, linear and non-linear regression equations are carried out and compared with the proposed artificial neural network prediction model. The results indicate that the incorporation of ground fly ash, ground bottom ash and ground rice husk ash substantially improve the workability and chloride permeability. The artificial neural network models have more accurate and precise prediction than linear and non-linear regression technique. Moreover, it is concluded that the artificial neural network models have a strong prediction capability of chloride penetration of concrete and can be easily expanded for the new additional database to re-train the network.     

Influence of 15 and 80 nano-SiO2 particles addition on mechanical and physical properties of ternary blended concrete incorporating rice husk ash

This study demonstrates the effects of SiO₂ nanoparticles as additives with two different sizes of 15 and 80?nm on compressive strength and porosity of rice husk ash (RHA) blended concrete. Up to 20% of ordinary Portland cement (OPC) was replaced by RHA with average particle size of 5 micron. Also, SiO₂ nanoparticles were added to the above mixture at four different weight percentages of 0.5, 1.0, 1.5 and 2.0 and cured in lime solution. The results indicated that compressive strength of Portland cement–nano SiO₂–rice husk ash (PC–NS–RHA) ternary blended concrete was considerably increased. Moreover, the total amount of porosity decreased to a minimum with respect to the control concrete. This improvement was observed at all the curing ages and replacement levels, but there was a gain in the optimal point with 20% of RHA plus 2% of 80?nm SiO₂ particles at 90 days of curing.     

Evaluation of bagasse ash as supplementary cementitious material

The utilization of waste materials in concrete manufacture provides a satisfactory solution to some of the environmental concerns and problems associated with waste management. Agro wastes such as rice husk ash, wheat straw ash, hazel nutshell and sugarcane bagasse ash are used as pozzolanic materials for the development of blended cements. Few studies have been reported on the use of bagasse ash (BA) as partial cement replacement material in respect of cement mortars. In this study, the effects of BA content as partial replacement of cement on physical and mechanical properties of hardened concrete are reported. The properties of concrete investigated include compressive strength, splitting tensile strength, water absorption, permeability characteristics, chloride diffusion and resistance to chloride ion penetration. The test results indicate that BA is an effective mineral admixture, with 20% as optimal replacement ratio of cement.     

Effect of utilizing unground and ground normal and black rice husk ash on the mechanical and durability properties of high-strength concrete

The aim of the present study is to investigate the effects of utilizing different processings of normal rice husk ash (RHA) and black rice husk ash (BRHA) on the mechanical and durability properties of high-strength concrete (HSC). Mechanical and durability properties of HSC were evaluated on concrete mixes containing unground BRHA and RHA and ground BRHA and RHA, their average particles sizes being 165, 85, 67 and 24 µm, respectively. The replacement of ordinary Portland cement with the ashes was adopted at 20%. The results showed that incorporating any form of RHA and BRHA in HSC reduced the slump value. The surface areas of RHA and BRHA, not their carbon content, determined the dosage of superplasticizer needed to achieve a targeted slump value. Concrete with unground and ground RHA incorporated exhibited 30% higher compressive strength while unground BRHA produced 30% lower compressive strength than that of the control concrete. Incorporating unground and ground RHA showed a synergy between filler and pozzolanic effect and had insignificant difference in mechanical and durability properties of the concretes. Meanwhile, incorporating ground BRHA showed a dominant filler effect in the concrete. Overall, the improvement of splitting tensile strength and modulus of elasticity of both RHA and GBRHA concrete showed a similar trend to that of the compressive strength of RHA concrete. The durability of concretes with unground and ground RHA and ground BRHA incorporated showed better performance than that of the control concrete. The material with 20% ground BRHA as partial cement replacement in HSC of Grade 50 could be used without any reduction in the mechanical and durability properties. Use of unground BRHA is not recommended because it did not improve these properties.     

Properties of geopolymer with seeded fly ash and rice husk bark ash

In the present work, compressive strength of inorganic polymers (geopolymers) produced of seeded fly ash and rice husk bark ash has been investigated. Different specimens made from a mixture of fly ash and rice husk bark ash in fine and coarse form were subjected to compressive strength tests at 7 and 28 days of curing. The curing regime was different: one set of the specimens were cured at room temperature until reaching to 7 and 28 days and the other sets were oven cured for 36 h at the range of 40-90 °C and then cured at room temperature until 7 and 28 days. The results indicate that in both 7 and 28 days regimes, the highest strengths are related to the specimens by SiO₂/Al₂O₃ ratio equals 2.99 cured at 80 °C. For these specimens, those contained finer fly ash particles show more compressive strength. Thermogravimetric analysis and Fourier transform infrared spectroscopy both also are in agreement with the obtained results from compressive strength tests. In addition, SEM micrographs of the specimens show that the finer the particle size of the utilized ashes, the denser the microstructure which confirms the results obtained by the strength tests.     

Assessing the effect of biomass ashes with different finenesses on the compressive strength of blended cement paste

This study assesses the effect of biomass ashes with different finenesses on the compressive strength of blended cement paste. rice husk ash (RHA), palm oil fuel ash (POFA) and river sand (RS) were ground to obtain two finenesses: one was the same size as the cement, and the other was smaller than the cement. Type I Portland cement was replaced by RHA, POFA and RS at 0%, 10%, 20%, 30% and 40% by weight of binder. A water to binder ratio (W/B) of 0.35 was used for all blended cement paste mixes. The percentages of amorphous materials and the compressive strength of the pastes due to the hydration reaction, filler effect and pozzolanic reaction were investigated. The results showed that ground rice husk ash and ground palm oil fuel ash were composed of amorphous silica material. The compressive strength of the pastes due to the hydration reaction decreased with decreasing cement content. The compressive strength of the pastes due to the filler effect increased with increasing cement replacement. The compressive strengths of the pastes due to the pozzolanic reaction were nonlinear and were fit with nonlinear isotherms that increased with increasing fineness of RHA and POFA, cement replacement rate and age of the paste. In addition, the model that was proposed to predict the percentage compressive strength of the blended cement pastes on the basis of the age of the paste and the percentage replacement with biomass ash was in good agreement with the experimental results. The optimum replacement level of rice husk ash and palm oil fuel ash in pastes was 30% by weight of binder; this replacement percentage resulted in good compressive strengths.     

Properties of self-compacting concrete containing class F fly ash

An experimental program was carried out to study the properties of self-compacting concrete (SCC) made with Class F fly ash. The mixes were prepared with five percentages of class F fly ash ranging from 15% to 35%. Properties investigated were self-compactability parameters (slump flow, J-ring, V-funnel, L-box and U-box), strength properties (compressive and splitting tensile strength), and durability properties (deicing salt surface scaling, carbonation and rapid chloride penetration resistance).     

Use of rice husk ash in sandcrete blocks for masonry units

Different mix proportions of sand, cement and rice husk ash (RHA) were studied for use in sandcrete blocks. Optimum water/(cement+RHA) ratios were determined at different mix proportions. Compressive strengths of various mix proportions at 7, 28 and 60 days were also determined. The optimum water/(cement+RHA) ratio increased with rice husk ash contents. Test results showed that up to 40% RHA could be added as a partial replacement for cement without any significant change in compressive strength at 60 days. Compressive strengths of various mix proportions were compared with British Statutory minimum compressive strengths of bricks for various walls and it was found that sandcrete blocks of 1∶5 mortar mixes with 40% RHA (by weight of cement) could be used in both load and non-load bearing walls.     

Application of rice husk ash in brick aggregate concrete to improve the permeability and resistance against acid and sulfate attack

Brick-aggregate-concrete with a greater permeability is susceptible to decay at a faster rate under the action of acid and sulfate. This study tries to improve the durability of brick aggregate concrete by the addition of rice husk ash, which has been termed brick-ash concrete in this paper. The permeability and sorptivity of stone-aggregate-concrete, brick-aggregate concrete, and brick-ash concrete samples with different percentages of rice husk ash and different water-to-binder ratios were investigated. The concrete samples were also exposed to 1.5 % hydrochloric acid and 5 % sodium sulfate along with periodic drying and wetting cycle and periodic observations in terms of compressive strength, weight loss, and ultrasonic pulse velocity test for 360 days. 5 % to 10 % rice husk ash can significantly improve the permeability and resistance to the harsh environment of brick aggregate concrete. Additionally, this study also presents the equations to predict the actual strength from ultrasonic pulse velocity values for the brick ash concrete specimen exposed to acid and sulfate environments.     

The combined benefits of CPF and RHA in improving the durability of concrete structures

The work presented is a laboratory study of controlled permeability formwork (CPF) applied to concrete where cement was partially replaced (10%, 15% and 20%) with Portuguese rice husk ash (RHA). Portuguese rice husk is a by-product which may be incinerated industrially. Various tests were carried out to evaluate the durability of concrete made with RHA at 10%, 15% and 20% replacement of cement by weight and cast with both the usual formwork and CPF. Tests carried out so far, reported in this paper, concern strength, absorption by capillarity and chloride ion penetration. Results lead to the conclusion that CPF enhances concrete performance even further when using partial cement replacement by RHA.     

The effect of mineral admixtures on the properties of high-performance concrete

The paper presents a laboratory study on the influence of two mineral admixtures, silica fume (SF) and fly ash (FA), on the properties of superplasticised high-performance concrete. Assessment of the concrete mixes was based on short- and long-term testing techniques used for the purpose of designing and controlling the quality of high-performance concrete. These include compressive strength, porosity, oxygen permeability, oxygen diffusion and chloride migration. Measurements were carried out after curing at 20% and 65% relative humidity up to the age of 1 yr. The results, in general, showed that mineral admixtures improved the properties of high-performance concretes, but at different rates depending on the binder type. While SF contributed to both short- and long-term properties of concrete, FA required a relatively longer time to get its beneficial effect. In the long term, both mineral admixtures slightly increased compressive strength by about 10%, but contributed more to the improvement of transport properties of concretes.     

Strength and mechanical behavior of soil–cement–lime–rice husk ash (soil–CLR) mixture

This study presents results of geotechnical investigations on treated silty sand soil with cement, lime and rice husk ash (CLR) and cement-lime (CL) admixture. Consolidated undrained triaxial test and unconfined compressive test were performed to estimate the potential of CLR and CL. The study investigates the influence of the amount of CLR%, main effective stress and curing days on soil strength, deformation, post peak behavior and brittleness. The percentages of the additives of CLR and CL varied from 2.5 to 12.5 % by dry weight of the soil with dry densities of 14.5 kN/m³ and the curing times of 3, 7, 28 and 60 days were examined. From the results, the stress–strain response is strongly influenced by the CLR contents and effective confining pressure. Strength and post peak strength of the CLR–soil are greatly improved by an increase in binder content. An increase of the effective cohesion c′ (kPa) and effective friction Φ′ (degree) is observed with increasing the CLR content, consistently. Brittle behavior observed at lower confining pressures and high CLR content. For both CLR and CL additives, linear trend was observed for variation of the q _u (kPa) with respect to the additives percentages. RHA was also found to be effective in increasing the shear strength of CLR–soil mixture.     

Properties of self-compacting concrete prepared with recycled glass aggregate

The effects of recycled glass (RG) cullet on fresh and hardened properties of self-compacting concrete (SCC) were investigated. RG was used to replace river sand (in proportions of 10%, 20% and 30%), and 10 mm granite (5%, 10% and 15%) in making the SCC concrete mixes. Fly ash was used in the concrete mixes to suppress the potential alkali-silica reaction. The experimental results showed that the slump flow, blocking ratio, air content of the RG–SCC mixes increased with increasing recycled glass content. The compressive strength, tensile splitting strength and static modulus of elasticity of the RG–SCC mixes were decreased with an increase in recycled glass aggregate content. Moreover, the resistance to chloride ion penetration increased and the drying shrinkage of the RG–SCC mixes decreased when the recycled glass content increased. The results showed that it is feasible to produce SCC with recycled glass cullet.     

Effect of ground fly ash and ground bagasse ash on the durability of recycled aggregate concrete

This research aims to study the effect of ground fly ash (GFA) and ground bagasse ash (GBA) on the durability of recycled aggregate concrete. Recycled aggregate concrete was produced with recycled aggregate to fully replace crushed limestone in the mix proportion of conventional concrete (CON) and GFA and GBA were used to partially replace Portland cement type I at the rate of 20%, 35%, and 50% by weight of binder. Compressive strength, water permeability, chloride penetration depth, and expansion by sulfate attack on concretes were investigated.The results reveal that the use of GFA and GBA to partially replace cement in recycled aggregate concrete was highly effective in improving the durability of recycled aggregate concrete. The suitable replacement of GFA or GBA in recycled aggregate concrete to obtain the suitable compressive strength, low water permeability, high chloride penetration resistance, and high sulfate resistance is 20% by weight of binder.     

Non-steady-state accelerated chloride penetration resistance of structural lightweight aggregate concrete

This study aims to characterise the chloride penetration resistance of structural lightweight aggregate concrete (LWAC) produced with different types, volumes and initial wetting conditions of lightweight aggregates (LWA), types of cement and contents of fly ash and silica fume, w/c ratios and curing conditions. A comprehensive experimental study was carried out involving three types of non-steady-state tests, which simulate different exposure conditions and penetration mechanisms. It is shown that the chloride penetration resistance is mainly affected by the cementitious paste and that high performance LWAC of 30–70 MPa can be produced. Regardless of the type of aggregate, we propose exponential relations to estimate the diffusion coefficient of chlorides. The volume and initial wetting condition of LWA had little influence on the chloride resistance. A long-term higher reduction of the diffusion coefficient was found in less dense LWAC. Reasonable correlations between the non-steady-state tests were obtained. Contrary to what is suggested in some European standards, the concrete strength cannot properly predict the durability behaviour of LWAC.     

A study on durability properties of high-performance concretes incorporating high replacement levels of slag

This paper presents an experimental study of combined effects of curing method and high replacement levels of blast furnace slag on the mechanical and durability properties of high performance concrete. Two different curing methods were simulated as follows: wet cured (in water) and air cured (at 20°C and 65% RH). The concretes with slag were produced by partial substitution of cement with slag at varying amounts of 50–80%. The water to cementitious material ratio was maintained at 0.40 for all mixes. Properties that include compressive and splitting tensile strengths, water absorption by total immersion and by capillary rise, chloride penetration, and resistance of concrete against damage due to corrosion of the embedded reinforcement were measured at different ages up to 90 days. It was found that the incorporation of slag at 50% and above-replacement levels caused a reduction in strength, especially for the early age of air cured specimens. However, the strength increases with the presence of slag up to 60% replacement for the 90 day wet cured specimens. Test results also indicated that curing condition and replacement level had significant effects on the durability characteristics; in particular the most prominent effects were observed on slag blended cement concrete, which performed extremely well when the amount of slag used in the mixture increased up to 80%.     

Physical and pozzolanic action of mineral additions on the mechanical strength of high-performance concrete

Pozzolans play an important role when added to Portland cement because they usually increase the mechanical strength and durability of concrete structures. The most important effects in the cementitious paste microstructure are changes in pore structure produced by the reduction in the grain size caused by the pozzolanic reactions pozzolanic effect (PE) and the obstruction of pores and voids by the action of the finer grains (physical or filler effect). Few published investigations quantify these two effects. Twelve concrete mixtures were tested in this study: one with Portland cement (control), nine mixtures with 12.5%, 25% and 50% of replacement of cement by fly ash, rice husk ash and limestone filler; two with (12.5+12.5)% and (25+25)% of fly ash and rice husk ash. All the mixtures were prepared with water/binder ratios of 0.35, 0.50, and 0.65. The compressive strength for the samples was calculated in MPa per kg of cement. The remaining contents of calcium hydroxide and combined water were also tested. The results show that the pozzolanic and physical effects have increased as the mineral addition increased in the mixture, being higher after 91 days than after 28 days. When the results for the same strength values are compared (35 and 65 MPa), it was observed that the filler effect (FE) increased more than the pozzolanic effect. The PE was stronger in the binary and ternary mixtures prepared with rice husk ash in proportions of 25% or higher.     

Production of sustainable fibre-reinforced concrete incorporating waste chopped metallic film fibres and palm oil fuel ash

The consumption of waste materials is one of the essential concerns of waste management strategies in many parts of the world. With the advances in concrete technology, the utilisation of waste materials in the sustainable construction has developed increasingly widespread because of technological, economic and ecological advantages. This paper presents the workability and mechanical properties of concrete incorporating waste chopped metallic film (WCMF) fibres and palm oil fuel ash (POFA). Waste plastic results in waste discarding disaster and consequently causes significant harms to the environment. WCMF fibres were prepared by recycling metallic–plastic films used for food packaging. Six concrete mixes containing 0–1.25% WCMF fibres with a length of 20 mm were made of ordinary Portland cement (OPC). Further, six concrete mixes with the same fibre content were made, where 20% POFA substituted OPC. The combination of WCMF fibres and POFA decreased the workability of concrete mixes. The inclusion of WCMF fibres to OPC and POFA concrete mixes decreased the compressive strength. However, at the curing period of 91 days, the POFA-based mixes obtained higher compressive strength values than those of OPC-based mixtures. The positive interaction between WCMF fibres and POFA consequently enhanced the flexural and tensile strengths, impact resistance, thereby increasing energy absorption capacity and ductility of concrete composites. It revealed that WCMF fibres acted as a bridge arrester and improved the load-transfer capacity of the concrete specimens. The study showed that the utilisation of WCMF fibres in the production of sustainable concrete is a beneficial, affordable and feasible solution.     

Concrete durability presented by acceptable chloride level and chloride diffusion coefficient in concrete: 10-year results in marine site

Generally, concrete with high resistance to the marine environment should have high compressive strength, a low chloride diffusion coefficient (D _C), and a high acceptable chloride level (Ac). Considering all parameters simultaneously, this study evaluated the degree of fly ash concrete durability based on 10-year results in a marine site. Based on the concrete durability (Ac/D _C, as compared to cement concrete with a W/B ratio of 0.45) and compressive strength, the degree of concrete durability proposed in this study indicates that fly ash concretes with a W/B ratio of 0.45 and 15–35 wt % fly ash replacement exhibit high-quality performance in a marine site.