共查询到19条相似文献,搜索用时 600 毫秒
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室温固化环氧胶粘剂的研究现状与发展趋势 总被引:18,自引:1,他引:17
本文综述了双组分室温固化环氧树脂胶粘剂的发展过程与研究现状,介绍了近年来国内外几种性能优异的室温固化环氧胶粘剂,指出双组分室温固化型环氧胶的发展趋势是耐高温、高强度、高耐久性及快速固化。 相似文献
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室温固化环氧结构胶粘剂的现状及发展 总被引:6,自引:0,他引:6
本文描述了室温固化环氧树脂结构胶粘剂的历史和四个发展阶段。通过近年来国外一些公司生产的一些室温固化环氧树脂结构胶粘剂性能的分析指出今后室温固化型环氧树脂结构胶粘剂的发展方向是耐高温、高强度和缩短固化时间。 相似文献
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Y. Okamoto 《The Journal of Adhesion》1990,32(4):227-235
Anaerobic adhesives are single-component acrylic adhesives which cure rapidly at or below room temperature when air is excluded, but they remain in an uncured stage over a long time when they are exposed to an adequate supply of air. Thus, anaerobic adhesives are widely used in retaining compounds for nuts and bolts, in sealants, and for impregnation. Recently, anaerobic adhesives have also been used in electrical and electronic applications because of their fast room temperature cure capability and their convenience.1 相似文献
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Y. Okamoto 《The Journal of Adhesion》1990,32(4):237-244
Anaerobic adhesives are single-component acrylic adhesives which cure rapidly at or below room temperature when air is excluded, but they remain in an uncured stage over a long time when they are exposed to an adequate supply of air. Thus, anaerobic adhesives are widely used in retaining compounds for nuts and bolts, in sealants, and for impregnation. Recently, anaerobic adhesives have also been used in electrical and electronic applications because of their fast room temperature cure capability and their convenience. 相似文献
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Y. Okamoto 《The Journal of Adhesion》2013,89(4):227-235
Anaerobic adhesives are single-component acrylic adhesives which cure rapidly at or below room temperature when air is excluded, but they remain in an uncured stage over a long time when they are exposed to an adequate supply of air. Thus, anaerobic adhesives are widely used in retaining compounds for nuts and bolts, in sealants, and for impregnation. Recently, anaerobic adhesives have also been used in electrical and electronic applications because of their fast room temperature cure capability and their convenience.1 相似文献
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在环氧胶黏剂体系中,中温潜伏性固化剂以其优异的潜伏性和相对较低的固化温度而成为研究热点,符合当下提倡的绿色、环保、"低碳生活"理念。详细介绍了双氰胺、咪唑、酸酐、有机酰肼、BF3-胺络合物、微胶囊六种中温潜伏性固化剂及其改性方法。它们的改性方法主要是:通过改性活化或者加入活性促进剂降低双氰胺、酸酐、有机酰肼等高温固化剂的固化温度;通过改性钝化咪唑的固化活性,延长室温储存期;将BF3等路易斯酸室温固化的固化剂与胺络合降低其固化活性,提高室温储存期;将活性固化剂用壁材包裹形成微胶囊使其在室温时稳定,较高的温度时壁材破裂释放出活性固化剂,迅速固化。 相似文献
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Jianwei Fang Liqiang Wan Linxiao Wang Ruye Bie Yu Zhang Farong Huang 《Polymer Engineering and Science》2021,61(10):2437-2444
Polytriazole adhesives are a new type of adhesives with excellent heat resistance, but the lap shear strength at room temperature is not ideal, which is about 15 MPa. In order to improve its adhesion performance at room temperature, a series of urethane-modified polytriazole (UPTA) adhesives were successfully synthesized via 1, 3-dipolar cycloaddition reaction between azides, and alkynes. Firstly, an alkynyl-terminated urethane monomer di(but-3-yn-1-yl) (1,3-phenylenebis(methylene)) dicarbamate (DBPMD) was synthesized and characterized. Then DBPMD was reacted with biphenyl dibenzyl azide (BPDBA) and N′,N′,N′,N′-tetrapropargyl-p,p′-diaminodiphenyl methane (TPDDM) to prepare UPTA adhesives. Curing behavior, thermal properties, bonding performance, and resistance to damp heat aging of UPTA adhesives were studied. The results show that the introduction of urethane group has almost no effect on the curing behavior. The glass transition temperature (Tg) and the 5% thermal weight loss temperature (Td5) gradually decreased with the increased proportion of DBPMD added. Tg of UPTA adhesives ranged from 185 to 215°C and Td5 of UPTA adhesives were all above 300°C, which indicated its outstanding thermal stability. The lap shear strength at room temperature of UPTA adhesives increased first and then decreased with the increasing amount of DBPMD, which ranged from 13.9 to 19.9 MPa. The highest lap shear strength of UPTA adhesives can reach 19.9 MPa, which was 31.8% higher than PTA adhesive. The lap shear strength retention rate of UPTA adhesives at 180°C was all over 75%. Lap shear strength retention rate of UPTA adhesives under 168 h damp heat aging time was all over 80%. UPTA adhesives have good bonding performance, heat resistance, and damp heat aging resistance, which can meet many complex construction requirements. 相似文献
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