On sliding friction and wear of polyetheretherketone (PEEK) composites at elevated temperatures

The friction and wear behaviour of polyetheretherketone (PEEK) composites, incorporating different amounts of short carbon fibres with different surface treatments, was studied under dry sliding conditions against smooth steel on a pin-on-disc apparatus at different temperatures. Wear of the composites was reduced considerably in all cases, but, whatever the surface treatment, wear increased with increasing temperature for all proportions off fibres. For minimum friction coefficient there was an optimum proportion of fibre volume fraction of about 10 vol.%. The effect of the fibre surface treatment was not significant for the tribological behaviour of the PEEK composites. To predict wear performance, a wear model proposed by Friedrich and Voss seemed to work properly, and, furthermore, a friction model was developed to predict the friction behaviour of PEEK composites with short carbon fibres.     

Effect of quartzite and granite in wear surfaces on dry sliding

Abstract

The wear surfaces abraded with quartzite and granite were subjected to scratch tests. Sharp and blunt indenters were used with various constant loads to produce controlled abrasive wear tracks. The characteristics of deformation mechanisms and material removal were further studied using a scanning electron microscope to determine the differences in the tribological behaviour between the quartzite and granite wear surfaces.

The results indicate that quartzite residues are more uniformly distributed as individual particles on the wear surfaces and therefore provide more stable frictional forces. In the case of granite the abrasive residues are rather non-uniformly collected into piles of abrasives.     

Friction and dry sliding wear behavior of carbon and glass fabric reinforced vinyl ester composites

Friction and dry sliding wear behavior of glass and carbon fabric reinforced vinyl ester composites have been presented. The results show that the coefficient of friction and wear rate increased with increase in load/sliding velocity and depends on type of fabric reinforcement and temperature at the interphase. The excellent tribological characteristics were obtained with carbon fiber in vinyl ester. It is believed that a thin film formed on counterface was seems to be effective in improving the tribological characteristics. The worn surfaces examined through SEM, showed higher levels of broken glass fiber in vinyl ester compared to carbon-vinyl ester composites.     

A study on friction and wear characteristics of nanometer Al2O3 /PEEK composites under the dry sliding condition

The friction and wear properties of the polyetheretherketone (PEEK) based composites filled with 5 mass% nanometer or micron Al₂O₃ with or without 10 mass% polytetrafluroethylene (PTFE) against the medium carbon steel (AISI 1045 steel) ring under the dry sliding condition at Amsler wear tester were examined. A constant sliding velocity of 0.42 m s⁻¹ and a load of 196 N were used in all experiments. The average diameter 250 μm PEEK powders, the 15 or 90 nm Al₂O₃ nano-particles or 500 nm Al₂O₃ particles and/or the PTFE fine powders of diameter 50 μm were mechanically mixed in alcohol, and then the block composite specimens were prepared by the heat compression moulding. The homogeneously dispersion of the Al₂O₃ nano-particles in PEEK matrix of the prepared composites was analyzed by the atomic force microscopy (AFM). The wear testing results showed that nanometer and micron Al₂O₃ reduced the wear coefficient of PEEK composites without PTFE effectively, but not reduced the friction coefficient. The filling of 10 mass% PTFE into pure PEEK resulted in a decrease of the friction coefficient and the wear coefficient of the filled composite simultaneously. However, when 10 mass% PTFE was filled into Al₂O₃/ PEEK composites, the friction coefficient was decreased and the wear coefficient increased. The worn scars on the tested composite specimen surfaces and steel ring surfaces were observed by scanning electron microscopy (SEM). A thin, uniform, and tenacious transferred film on the surface of the steel rings against the PEEK composites filled with 5 mass% 15 nm Al₂O₃ particles but without PTFE was formed. The components of the transferred films were detected by energy dispersive spectrometry (EDS). The results indicated that the nanometer Al₂O₃ as the filler, together with PEEK matrix, transferred to the counterpart ring surface during the sliding friction and wear. Therefore, the ability of Al₂O₃ to improve the wear resistant behaviors is closely related to the ability to improve the characteristics of the transfer film.     

固体自润滑涂层摩擦磨损特性研究

随着机械加工技术和空间技术的发展,固体润滑涂层在比较恶劣的润滑环境下能起到独特的润滑效果,得到高速发展和广泛应用.在综合国内外研究和报道的基础上,对一般固体润滑涂层和纳米固体润滑涂层的摩擦磨损特性的研究现状进行归纳,指出固体润滑涂层摩擦磨损研究的发展方向.     

Tribological behaviour of thermally sprayed silicon carbide coatings

SiC coatings have been successfully deposited using thermal spray detonation technique with a newly patented feedstock. Their tribological performance was compared to bulk SiC for dry and lubricated conditions (polyalphaolefin and 3.5 wt% NaCl solution). The lowest coefficient of friction (CoF=0.10) and wear-rate were detected with polyalphaolefin lubricant regardless of the test pair due to mixed fluid-film lubrication. Contradicting results were recorded under other test conditions. The coatings show low CoF of 0.20 in comparison to four times higher CoF of bulk SiC under dry sliding. Oppositely, SiC coatings in NaCl solution record five times higher CoF compared to bulk SiC CoF of 0.20. Such behaviour is associated with tribochemical reaction and tribo-corrosion mechanisms occurring in dry and NaCl sliding, respectively.     

Effect of sliding speed on friction and wear behaviour of nanocrystalline nickel tested in an argon atmosphere

The sliding speed dependence of the coefficient of friction (COF) and wear rate (W) of a nanocrystalline (nc) Ni with a grain size of 15 ± 3 nm and a hardness of 5.09 ± 0.11 GPa was compared to that of a microcrystalline (mc) Ni with a grain size of 20 ± 5 μm and a hardness of 1.20 ± 0.05 GPa. The sliding wear tests were performed in an argon environment under a constant normal load of 2 N using three different sliding speeds of 0.2 × 10⁻², 0.8 × 10⁻² and 3.0 × 10⁻² m/s. The lesser wear damage in the nc Ni at any given speed was attributed to its higher hardness and its greater elastic depth recovery ratio compared to the mc Ni. The mc Ni's COFs and wear rates were independent of the sliding speed over the relatively small range used. However, the same small increase in sliding speed caused an 86% reduction in the nc Ni's wear rate, from 3.44 × 10⁻³ to 0.47 × 10⁻³ mm³/m, and a 31% increase in its COF, from 0.49 ± 0.05 to 0.64 ± 0.06. A modified Archard equation was proposed to predict wear rates of Ni as a function of grain size and sliding speed. Increasing the sliding speed made it increasingly difficult for surface damage by plastic deformation to occur in the nc Ni, because the grain-boundary-induced deformation mechanisms are more difficult to operate at higher strain rates. At the highest speed, the smallest amount of debris was generated, which was not sufficient to form protective tribolayers leading to a high COF value.     

Studies on high temperature wear and its mechanism of Al-Si/graphite composite under dry sliding conditions

Wear behaviours of aluminum silicon alloy and Al-Si/graphite composite were investigated at ambient and elevated temperatures. The trend showed a decrease in wear rate with increase in temperature. The reduction in wear rate was mainly attributed to the formation of glazing layer and oxide layer at higher temperature. This was invariably observed in alloy and composites. In addition, the presence of graphite in composite offered better wear resistance for all temperatures under consideration. The wear due to oxidation was predominant during high temperature sliding.     

Dry sliding friction and casing wear behavior of PCD reinforced WC matrix composites

The friction and casing wear properties of PCD reinforced WC matrix composites were investigated using a cylinder-on-ring wear-testing machine against N80 casing steel counterface under dry sliding conditions. The results indicate that the friction and casing wear rate of PCD reinforced WC matrix composites are the lowest among the materials. As the applied load and sliding speed steadily increase, the friction coefficients of PCD reinforced WC matrix composites decrease. In addition, the casing wear rates increase with increasing load, but decline with sliding velocity. The dominant wear mechanism of the PCD composite is the micro-cutting wear, accompanied by adhesive wear.     

Sliding wear behaviour of ZrN and (Zr, 12 wt% Hf)N coatings

In the present study, the sliding wear resistances of ZrN and (Zr, 12 wt% Hf)N coatings deposited on a hardened AISI D2 tool steel by arc-physical vapor deposition (PVD) technique were examined by a ball-on-disc wear tester. Alloying of ZrN coating with 12 wt% Hf did not change the hardness significantly, but achieved an improvement on adhesion strength and dry sliding wear resistance against steel (AISI 52100-55HRC) and Al₂O₃ balls.     

Dry sliding friction and wear properties of Al-25Zn-3Cu-3Si alloy

Friction and wear properties of Al-25Zn-3Cu-3Si alloy were investigated over a range of pressure and sliding speed using a pin-on-disc test machine. The friction coefficient of the alloy increased with sliding speed, but decreased with increasing pressure up to 1.5 MPa, above which the trend reversed. However, the temperature and wear volume of the alloy increased continuously with increasing pressure and sliding speed. A fine-grained layer and a region with flow lines were observed underneath the surface of the wear samples. The formation of these regions was related to smearing of wear particles and heavy deformation of surface material, respectively.     

Abrasive wear mechanisms of fluoropolymer based composite coatings on aluminum substrates

Experimental studies on wear performance and wear mechanisms of fluoropolymer based composite, non-stick coatings on aluminum substrates were carried out by using particular wear testing methods, i.e. the “mechanical tiger paw (MTP) Test” and the “Nord Test”. Both are supposed to simulate household abrasive operating conditions in a laboratory environment. It was found that the wear process involved in the MTP Test was an accelerated one, but that in the Nord Test was decelerated due to a transition from severe three-body abrasion to milder two-body sliding wear. In addition, both effects of the microstructure of the coatings and of the surface treatment of the substrates were discussed.     

The role of triboparticulates in dry sliding wear

In this paper, wear processes and mechanisms for wear transitions with sliding time and temperature during sliding of a nickel-based alloy, N80A, in oxygen at temperatures to 250°C are discussed. Transitions in wear from high rates to low rates with sliding time were always observed at all the temperatures investigated. The transitions in wear were usually accompanied by transitions in contact resistance between the rubbing surfaces from nearly zero to positive high values. It was found that wear debris particles were heavily involved in the wear processes. The transitions in wear and contact resistance with sliding time mainly resulted from the development of wear-protective layers following the compaction of wear debris particles on the rubbing surfaces. The adhesion of triboparticulates to each other and to the rubbing surfaces played an important role in the rapid decrease in wear rate with sliding time and with increase in temperature. Processes involved in the development of the wear-protective particle layers and mechanisms for the wear transitions have been described on the basis of experimental observations. The importance of triboparticulates in wear and its implications for wear protection are discussed.     

On the effect of counterface material and aqueous environment on the sliding wear of various PEEK compounds

Polyetheretherketone (PEEK) compounds containing carbon fibres (CF), glass fibres (GF), PTFE, and graphite, respectively, were exposed to unidirectional sliding against various counterparts (100Cr6, X5CrNi18-10, alumina, and bronze). Some of these tests were repeated in water. The stainless steel revealed the best results under dry conditions, whereas alumina was the best counterpart in water. The compound containing GF plus PTFE performed best under dry conditions. Under wet conditions, CF were superior to GF, which react very susceptibly to water. The aqueous environment usually accelerated the compound wear. Only in case of CF containing compounds sliding against alumina, the water lubrication reduced the wear rate.     

Triboelectrochemical investigation of the friction and wear behaviour of TiN coatings in a neutral solution

Triboelectrochemical techniques use an electrochemical set-up (mainly of the three-electrode type) for controlling the potential of the surface of a conducting material subjected to rubbing in a tribometer. In this way it is possible to carry out friction and wear tests in electrolytic solutions under well-defined chemical conditions determined by the applied electrode potential. In addition, triboelectrochemical techniques offer the possibility of following in-situ and in real time the kinetics of electrochemical oxidation reactions (corrosion) by the simple measure of an electrical current. In the present study triboelectrochemical experiments were carried out on sputter deposited TiN coatings sliding against alumina in a borate solution (pH 8.4). The surface of selected worn coatings was characterised by X-ray photoelectron spectroscopy (XPS) and the topography by scanning electron microscopy (SEM). Results show that the rate of wear critically depends on the prevailing (electro)chemical conditions which determine the chemical surface state of the TiN coating. The behaviour is attributed to the lubricating properties of surface oxide films having a thickness in the nanometre range.     

Coating thickness effect on initial wear of nitrogen-doped amorphous carbon in nano-scale sliding contact: Part II—theoretical modeling

This is the second paper of a two-part report. In the first paper, empirical data on the wear particle generation in carbon nitride coatings subjected to repeated sliding contact with a spherical diamond counter-face is reported. The effect of coating thickness on the wear particle generation is also discussed in the first paper. In this paper, a simplified theoretical expression, combining the Coffin-Manson equation with the analytical solution of a proposed elastic perfectly-plastic indentation model, is introduced. The expression successfully correlates critical number of friction cycles for wear particle generation N_c to coating thickness h, contact pressure P and radius of spherical asperity on the tip of the diamond pin R. With this expression, the lifespan of sliding components can be predicted.The theoretical results computed for diamond pin with a specific asperity radius value of 250 nm were compared with the experimental results reported in the first paper. The theoretical model successfully predicts the maximum lifespan of a component, N_c, in repeated sliding applications. The influences of various contact pressures and asperity radii on the maximum lifespan were also assessed using the model.     

Effect of porosity on dry sliding wear of Al-Si alloys

Porosity adversely affects the pressure tightness (ability of a system to hold pressure), mechanical properties and wear resistance of components. The amount of porosity and the size and shape of pores have a great impact on material removal during wear. Al-Si alloy with different porosity levels was prepared using powder metallurgy technique. Dry sliding wear behavior was investigated against AISI 52100 bearing steel ball. It was found that the wear rate gradually rises with surface porosity, then drops as porosity and pore size reach critical levels. A model was developed to explain the relationship between porosity and pore size.     

Influence of the normal force,abrasive slurry concentration and abrasive wear modes on the coefficient of friction in ball-cratering wear tests

The purpose of this work is to study the influence of the normal force (N), abrasive slurry concentration (C) and abrasive wear modes on the coefficient of friction in ball-cratering wear tests. Experiments were conducted with balls of AISI 52100 steel, an AISI H10 tool-steel specimen and abrasive slurries prepared with black silicon carbide (SiC) particles+distilled water. The tangential (T) and normal loads were monitored throughout the tests and the results have shown that: (i) the coefficient of friction behavior was independent of the normal force and (ii) both the concentrations of abrasive slurries and the subsequent action of the abrasive wear modes, generally, did not affect the behavior or magnitude of the coefficient of friction.     

Friction and dry sliding wear behaviour of cermets

The friction and wear behaviour of cermets/steel rubbing pairs were investigated. Friction and wear tests were carried out using three different crèmets on the base of tungsten, titanium and chromium carbides under dry sliding conditions against steel disk (0.45% C). Sliding wear tests were carried out using modified block-on-ring equipment at a sliding speed of 2.2 m/s and normal load 40 N.It is shown that wear resistance and coefficient of friction depend on the type and chemical composition of the cermets. The WC–Co cermets have the highest wear resistance. The wear rate of WC–Co and TiC–NiMo cermets increased with increasing binder content in the cermets. The wear of Cr₃C₂–Ni cermets is more complicated and depends on the composition of cermets. The wear of WC–Co cermets is caused mainly by preferential removal of the cobalt binder, followed by fracture of the intergranular boundaries and fragmentation of the carbide grains. The main wear mechanism in the TiC–NiMo cermets is polishing (micro-abrasion) and adhesion, resulting in a low wear rate. The main wear mechanism of Cr₃C₂–Ni cermets involves thermal cracking and fatigue-related crushing of large carbide grains and carbide framework and also adhesion.     

Coating thickness effects on initial wear of nitrogen-doped amorphous carbon in nano-scale sliding contact: Part I—in situ examination

This paper, the first of a two-part series, presents the empirical data obtained from in situ examination on the generation of wear particles on carbon nitride coatings by a spherical diamond counter-face during repeated sliding contacts. In particular, the effect of coating thickness, varying from 1 to 500 nm, on the generation of wear particles was examined.Based on the in situ examination, the shape transition maps for generated wear particles were obtained for carbon nitride coatings of various thickness. The results show that the critical number of friction cycles, Nc, for the transition from “no observable wear particles” to “wear particle generation” generally increased with increasing coating thickness. It was noted that up to 20 friction cycles, the maximum Hertzian contact pressure, P_max, for “no observable wear particles” regime can be increased from 1.39Y to 1.53Y if silicon was coated with carbon nitride coating thicker than 10 nm, where Y is defined as the yield strength of silicon.