共查询到18条相似文献,搜索用时 218 毫秒
1.
2.
3.
印染污泥与木屑混燃特性及动力学 总被引:3,自引:0,他引:3
采用综合热重分析法,在不同升温速率及印染污泥与木屑不同比例混合条件下,对印染污泥、木屑及其混合物的燃烧特性进行了研究.结果表明,印染污泥的热重曲线存在4个明显的失重峰,分别与水分的析出、两个挥发分的析出以及固定碳的燃烧阶段相对应.混合试样燃烧过程中,污泥和木屑基本保持各自的挥发分析出特性,其燃烧曲线位于污泥和木屑燃烧曲线之间,且混合试样微熵热重曲线的变化趋势与组成比例较大的成分DTG曲线变化趋势较为接近.污泥与木屑混合后其综合燃烧特性指数SN有所增大,说明挥发分含量越高对应的燃烧特性越好;采用积分法(Coats-Redfern方程)计算得到各阶段燃烧反应的机理方程及相应的活化能参数,分析表明单一印染污泥燃烧的活化能较低,活化能的大小与试样的燃烧阶段是相对应的. 相似文献
4.
草类生物质热解特性及动力学的对比研究 总被引:2,自引:0,他引:2
我国长江中下游地区有大面积分布的芒属、芦苇、狼尾草,研究很少,应用少.为草类生物质能的开发与利用提供又一途径.对芒属、芦苇、狼尾草进行常压热重分析,同时与常见的稻草相比较,通过生物质热解失重率(TG)和失重速率(DTG)曲线,获得相关热解特性参数,采用生物质挥发分综合释放指数(D),并通过热分析数学方法求取生物质热解动力学参数.试验结果表明:草类生物质热解过程可以分为4个阶段,在563 K附近存在一个肩峰,失重都集中在460 K~673 K.挥发分综合释放指数则芒属>稻草>狼尾草>芦苇,活化能则芒属>稻草>狼尾草>芦苇,固体剩余物则芒属>狼尾草>稻草>芦苇,所以总体上看芒属的热解稳定性相对较差,芦苇的热解稳定性较好,同时采用二级反应动力学模型由Coats-Redfern法求的相应得活化能和频率因子.也为今后更好、更合理高效的利用这些草类提供实验数. 相似文献
5.
6.
几种生物质的TG-DTG分析及其燃烧动力学特性研究 总被引:13,自引:1,他引:12
采用热重分析技术对木屑、麦秆、玉米秆和玉米芯4种生物质的燃烧特性进行了研究,考察了其着火、燃尽特性和综合燃烧特性,研究了升温速率对生物质燃烧特性的影响,同时在热天平上对其进行了动力学试验研究.研究表明:生物质燃烧过程大致可以分为3个阶段,即水分析出阶段、挥发分析出燃烧阶段、固定碳燃烧与燃尽阶段:生物质具有着火温度低、燃尽温度低、燃尽率高等优点;随着升温速率的提高,着火温度、各试样挥发分最大释放速率、燃尽温度均呈升高趋势,燃烧特性随升温速率的提高而变好.采用一级反应动力学模型和积分法对生物质燃烧动力学参数的研究表明,生物质具有较低的活化能,有利于点燃. 相似文献
7.
选取石化污泥和烟煤,将两者按不同比例混合。采用热重分析法,在相同升温速率下,对各混合样品进行热解实验,探讨石化污泥与烟煤热解特性的差异及其共热解时石化污泥对烟煤热解过程的影响。结果表明:石化污泥与烟煤的热解过程和反应特征参数差异很大,主要表现在样品的挥发分析出温度区间、总失重率及失重速率上。同时,石化污泥的挥发分综合释放特性指数D远优于烟煤;在石化污泥和烟煤的共热解过程中,石化污泥的添加对烟煤的热解起到一定促进作用,当石化污泥掺入比例为10%时,混合物的热解特性最好。 相似文献
8.
《可再生能源》2021,39(9)
采用热重分析法对市政污泥、木屑及其不同比例的混合样品热解特性进行了分析,研究了升温速率和混合比例对热解过程的影响。对污泥和木屑进行单独热解时,木屑比污泥的反应活性更高;随着升温速率的增大,二者的挥发分析出指数D均有增大,但升温速率对污泥挥发分析出的影响更大;污泥与木屑共热解改善了污泥热解过程的综合热解释放特性,有利于热解反应的进行;随木屑添加比例的增加D值呈指数增长,在木屑添加比例为80%时,D达到最大值118.18×10-8,但仍低于理论值141.67×10-8,说明存在竞争作用。文章采用FWO(Flynn-Wall-Ozawa)和Starink方法,分别计算木屑添加比例为80%的共热解表观活化能。当转化程度α为0.1~0.8时活化能变化较小,α为0.9时活化能分别突增到761.64,786.12 kJ/mol。这说明共热解过程可分为150~520℃和520~1 000℃两个温度阶段,与污泥单独热解相比,降低了转化率达到90%时的终温。 相似文献
9.
以粤西地区生物质稻草、玉米秆、玉米芯、荔枝条及龙眼枝为研究对象,采用TG-DSC实验技术和差减微分法Freeman-Carroll,对其热解特性曲线和机理进行分析并计算热解特性参数及动力学参数。结果表明:试样稻草、荔枝条及龙眼枝均出现1个明显DTG峰,玉米芯出现3个明显DTG峰;玉米秆的半纤维素热解生成的"活性中间产物"再次以几乎相等的热解速率(即等DTG值)发生二次热解生成气体析出,导致在其2个DTG峰之间出现1个近似水平平滑的肩状峰;玉米芯、荔枝条及龙眼枝在高温热解区段出现DSC吸热峰;玉米秆低温段的挥发分初始析出温度、峰值温度以及半峰温度宽度均最小;草本类生物质较木质类生物质易于热分解;玉米秆和玉米芯热解的质量变化所占比例、挥发分综合释放特性指数、活化能及频率因子均随热解温度区段的升高而逐渐增大。 相似文献
10.
11.
《International Journal of Hydrogen Energy》2019,44(30):15863-15870
Pyrolysis experiments of sawdust with KOH and K2CO3 catalysts were carried out under different heating rate in nitrogen atmosphere using thermogravimetric analyzer. The distributed activation energy model (DAEM) was used to analyze pyrolysis kinetics of sawdust. The results showed that both KOH and K2CO3 had strong catalytic effect on sawdust pyrolysis, which reduced the pyrolysis temperature of sawdust and increased the yield of char. There was only one main peak in DTG curve, which means that the pyrolysis behavior of cellulose and hemicellulose in sawdust was greatly changed. The catalytic performance of KOH was found to be more excellent in sawdust pyrolysis. Also KOH could catalyze the pyrolysis of sawdust at low temperature. The kinetic analysis results showed that the two kinds of catalysts could reduce the activation energy of sawdust pyrolysis and maintain a similar catalytic trend, but KOH had a more stable catalytic performance. 相似文献
12.
13.
A. González M. Penedo E. Mauris M.J. Fernández-Berridi L. Irusta J. Iruin 《Biomass & bioenergy》2010,34(11):1573-1577
In this work, the pyrolysis of different Cuban biomass such as: sugar cane bagasse, coffee, residue of tobacco and sawdust of pine has been studied. The pyrolysis was carried out at different temperatures in a small furnace placed at the injection port of a gas chromatograph coupled to a Fourier transform infrared spectrometer (Py-GC/FTIR). Thermogravimetric analysis (TGA) was also carried out using a thermobalance. For tobacco residue, pyrolysis yield of charcoal and liquid products decreases with pyrolysis temperature (300–600 °C). When the pyrolysis is carried out at 300 °C charcoal yield is similar for tobacco residue, sawdust of pine and husk of coffee (≈40%) while for husk of coffee and sugar cane bagasse the charcoal yield is lower but the yield of the liquid product is higher. 相似文献
14.
猪粪热解特性及其动力学研究 总被引:1,自引:0,他引:1
在程序控温热重分析仪上进行了不同升温速率(10,20,30,50℃/min)的猪粪热解失重试验,获得了猪粪热解特性参数;采用分布活化能模型(DAEM)进行动力学分析,计算得到整个热解过程的活化能和频率因子的分布规律。结果表明,猪粪热解过程呈现失水干燥段、热解过渡段、挥发分析出段和碳化段,升温速率对猪粪的热解有一定的影响,表现为随升温速率的升高,DTG曲线向高温侧移动;动力学分析表明,猪粪热解活化能在52~113 kJ/mol变化,低于锯末、稻壳、稻秆、椰壳热解的活化能,说明猪粪较其他生物质易受热分解;同时猪粪热解的活化能和频率因子之间存在动力学补偿关系,但整个热解过程中这种补偿关系呈分段趋势。 相似文献
15.
Solar pyrolysis of pine sawdust, peach pit, grape stalk and grape marc was conducted in a lab-scale solar reactor for producing fuel gas from these agricultural and forestry by-products. For each type of biomass, whose lignocellulose components vary, the investigated parameters were the final temperature (in the range 800°C–2000 °C) and the heating rates (in the range 10–150 °C/s) under a constant sweep gas flow rate of 6 NL/min. The parameter influence on the pyrolysis product distribution and syngas composition was studied. The experimental results indicate that the gas yield generally increases with the temperature and heating rate for the various types of biomass residues, whereas the liquid yield progresses oppositely. Gas yield as high as 63.5wt% was obtained from pine sawdust pyrolyzed at a final temperature of 2000 °C and heating rate of 50 °C/s. This gas can be further utilized for power generation, heat or transportable fuel production. 相似文献
16.
17.
18.
Baofeng Wang Lirong Li Jinjun Zhang 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2016,38(10):1370-1376
Effect of pine sawdust on the removal of arsenic and sulfur during Shanxi Tuanbo-2 coal pyrolysis was investigated. Results showed that adding pine sawdust could increase the removals of arsenic and sulfur during Shanxi Tuanbo-2 coal pyrolysis, and when the ratio of the pine sawdust was 50%, the arsenic removal was the highest; at this ratio, the total sulfur removal also was the highest. Adding pine sawdust also increased pyritic sulfur and organic sulfur removal. Furthermore, results also indicated that adding pine sawdust made arsenic associated with sulfates and monosulfides and arsenic in stable forms escape more easily. 相似文献