Computational fluid dynamics (CFD) investigation of air flow and temperature distribution in a small scale bread-baking oven

Experimental and computational fluid dynamics (CFD) analyses of the thermal air flow distribution in a 3-zone small scale forced convection bread-baking oven are undertaken. Following industrial bread-making practise, the oven is controlled at different (constant) temperatures within each zone and a CFD model is developed and validated against experimental data collected within the oven. The CFD results demonstrate that careful selection of the flow model, together with implementation of realistic boundary conditions, give accurate temperature predictions throughout the oven. The CFD model is used to predict the flow and thermal fields within the oven and to show how key features, such as regions of recirculating flow, depend on the speeds of the impinging jets.     

Numerical investigation of coke oven gas (COG) injection into an ironmaking blast furnace (BF)

Blast furnace (BF) ironmaking is the predominating process for producing hot metal (HM). It consumes huge quantities of carbonaceous fuel materials and leads to massive CO₂ emissions. The injection of coke oven gas (COG) into the BF is considered a promising solution. It recovers the COG that is a kind of off-gas in the steelwork, and reuses the COG as an H₂-intensive fuel in the BF to partially replace the use of carbonaceous fuel materials. However, thus far, the technology is not widely adopted, mainly due to the lack of understanding regarding the effects of key operational parameters of COG injection on BF performance. In addition, the coupling effect of COG injection and BF operation particularly the control at furnace top is not clear, leading to the low utilization efficiency. In this work, a continuum-based BF process model is developed and validated to consider the injection of COG into a commercial scale BF through the tuyere. The model is validated by comparing the calculated key performance indicators with those measured in production. The impact of COG injection rate is studied and its coupling effects with top burden distribution have also been clarified. The simulation results show that an increased COG injection rate leads to improved BF performance, in terms of increased productivity and decreased consumption of carbonaceous fuel materials. However, the utilization efficiency of COG and the replacement ratio of carbonaceous fuel materials by COG is decreased. An optimum top burden distribution can be identified, which can improve the utilization efficiency of injected COG and achieve a relatively high replacement ratio. The findings from this work should be useful to guide production of BF with H₂-intensive fuel injection, which helps to save the use of carbonaceous fuel materials and reduce CO₂ emission.     

A numerical and experimental investigation of the modelling of microwave melting of frozen packed beds using a rectangular wave guide

The melting of frozen packed beds by microwave with rectangular wave guide has been investigated numerically and experimentally. It was performed for the two different layers, which consists of frozen and unfrozen layers. Based on the model combined the Maxwell and heat transport equations, the results show that the direction of melting against the incident microwave strongly depends on the structure of layered packed beds because the difference in the dielectric properties between water and ice.     

Recent progress and challenges in photocatalytic water splitting using layered double hydroxides (LDH) based nanocomposites

The worldwide energy demand is steadily increasing and estimated to be doubled by the year 2050 due to a continuous hike in economies and population. A large part of the global energy requirement procures using traditional energy sources such as fossil fuels, which are non-renewable. Also, their excessive consumption imparts negative impacts on the environment by CO₂, and CO emissions, which constantly increase the average global temperature. Therefore, the need for a more reliable, sustainable, inexpensive, renewable and environmentally-friendly form of energy is imperative. From these perspectives, hydrogen energy is emerging as one of the most promising alternatives to overcome rising energy demand with a zero-carbon footprint.Herein, various layered double hydroxides (LDH) nanocomposite owing to their attractive physicochemical properties and synergistic effect with other materials in the field of hydrogen production are reviewed. Why the class of LDHs materials is critical and their ideographic properties which make them promising materials in the field of water splitting via photocatalysis and electrocatalysis are also discussed. The synthetic methods of LDHs based nanocomposites fabrication are summarized. Various challenges and strategies from the viewpoint of a different method of hydrogen production through LDHs are reported. Additionally, multiple techniques like surface plasmon resonance (SPR), heterojunction formation, and doping with co-catalyst to increase the efficiency for photocatalytic hydrogen production are also presented. Hopefully, this review will help the readers explore highly efficient, inexpensive and stable LDH catalysts toward photocatalytic water splitting.     

Plasma steam methane reforming (PSMR) using a microwave torch for commercial-scale distributed hydrogen production

Although large-scale hydrogen production through conventional steam methane reforming (SMR) is available at an affordable cost, there is a shortage of hydrogen pipeline infrastructure between production plants and fueling stations in most places where hydrogen is needed. Due to the difficulties of transporting and storing hydrogen, onsite hydrogen production plants are desirable. Microwave plasma torch-based methods are among the most promising approaches to achieving this goal.The plasma steam methane reforming (PSMR) method discussed here has many benefits, including a high energy yield, a small carbon footprint, real-time fueling because of the short start-up time (<10 min), and the absence of expensive metal-based catalysts. Methane reforming and water gas shift reaction (WGSR) co-occur in the method advanced without a separate WGSR to achieve a high H₂ yield.This study examines an experimental investigation of commercial-scale hydrogen production through PSMR utilizing a microwave torch system. The optimum results obtained showed that the hydrogen production rate was 2247 [g(H₂)/h], and energy yield was 70 [g(H₂)/kWh] of the absorbed microwave power. An assessment of the results indicated a similar trend to that of simulated data (ASPEN Plus). The experimental results presented in this paper demonstrate the potential of a catalyst-free PSMR for commercial-scale hydrogen production.     

An experimental investigation of the dissipation mechanisms in the suction side boundary layer of a turbine blade

The present work is part of an extensive experimental activity carried out by the authors in recent years aimed at investigating the boundary layer transition phenomenon in turbine blades. The large scale of the cascade and the use of advanced LDV instrumentation and precision probe traversing mechanism resulted in high degree of spatial resolution and high accuracy of measurements. The main dissipation mechanism determining the profile losses in turbomachinery blades is the work of deformation of the mean motion within the boundary layer operated by both viscous and turbulent shear stresses. In the present paper, the local viscous and turbulent deformation works have been directly evaluated from the detailed measurements of boundary layer mean velocity and Reynolds shear stress. The results show the distributions and the relative importance of the viscous and turbulent contributions to the loss production, in relation with the boundary layer states occurring along the turbine profile.     

Comparative experimental investigation of oxyhydrogen (HHO) production rate using dry and wet cells

Hydroxy gas was produced by water electrolysis from dry and wet cells using stainless steel 316L electrode of 136.5 cm² surface area and 4 mm separation. Electrolytes as NaOH and KOH of different concentrations were used. This study investigates the effect of electrolyte concentration, cell connection, electric current, operating time, electrolyte temperature and voltage on HHO productivity of the cells. Different plate configurations were studied. Increases of applied current, electrolyte temperature, electrolyte concentration and voltage led to the increase of gas production. More gas was produced from wet cell as compared to dry cell for the same design. HHO production for the dry cell reaches its maximum values of 866, 985, 1040 and 1090 ml/min at 5, 10, 15 and 20 g/L of NaOH at currents of 14, 18, 20 and 21.3 A and attains stable after about 30 min but the temperatures were increased till 32, 38, 44 and 52 °C, respectively and remained constant after that. The production peak values for wet cell were 975, 1160, 1325 and 1375 ml/min at 5, 10, 15 and 20 g/L of NaOH and flow currents of 17.8, 23.5, 26 and 27 A and remains constant after 90 min. At 10, 15 and 20 g/L NaOH, the temperatures were increased till constant values of 35, 44, 50 and 58 °C, respectively. HHO productivities from dry and wet cells are 866 and 1160 ml/min with electrolyzer efficiency of 72.1 and 69.3% at 14 and 18 A and (5 and 10 gm NaOH/L), respectively.     

Theoretical and experimental investigation of biomass gasification process in a fixed bed gasifier

This investigation concerns the process of air biomass gasification in a fixed bed gasifier. Theoretical equilibrium calculations and experimental investigation of the composition of syngas were carried out and compared with findings of other researchers. The influence of excess air ratio (λ) and parameters of biomass on the composition of syngas were investigated. A theoretical model is proposed, based on the equilibrium and thermodynamic balance of the gasification zone.The experimental investigation was carried out at a setup that consists of a gasifier connected by a pipe with a water boiler fired with coal (50 kWth). Syngas obtained in the gasifier is supplied into the coal firing zone of the boiler, and co-combusted with coal. The moisture content in biomass and excess air ratio of the gasification process are crucial parameters, determining the composition of syngas. Another important parameter is the kind of applied biomass. Despite similar compositions and dimensions of the two investigated feedstocks (wood pellets and oats husk pellets), compositions of syngas obtained in the case of these fuels were different. On the basis of tests it may be stated that oats husk pellets are not a suitable fuel for the purpose of gasification.     

Theoretical investigation of solvent effects on the selective hydrogenation of furfural over Pt(111)

It was well known that solvent effect plays a very important role in the catalytic reaction. There are many theoretical studies on the solvent effect in homogeneous catalysis while there are few theoretical studies on the solvent effect in the heterogeneous catalytic reaction and there has been no work to investigate the solvent effect on furfural transformation in heterogeneous catalysis. In the present work, both the density functional calculations and the microkinetic analysis were performed to study the selective hydrogenation of furfural over Pt(111) in the presence of methanol as well as toluene and compared with that in the gas condition. The present results indicated that the methanol can enhance the adsorption strength of furfural and other oxygen-containing reaction species due to its relatively strong polarity properties and this can be a main reason for solvent-induced high activity and selectivity. Another reason is that reaction paths study showed that the presence of methanol solvent makes the dehydrogenation of furfural less thermochemical due to the fact that furfural is more stabilized than that of dehydrogenation species, and methanol also has an inhibition effect on the dehydrogenation of furfural in the kinetic aspect, and further energetic span theory proves highest activity and selectivity for hydrogenation in methanol solvent of vapor, methanol and toluene. Moreover, microkinetic model simulation demonstrated that the activity and selectivity of hydrogenation in methanol is both higher than that in vapor and toluene. The much higher activity in methanol is due to the stabilized adsorbed reactants in the surface, which leads to a higher surface coverage of furfural. It might be proposed based on the present work that a solvent with relatively strong polarity may be favorable for the high selective hydrogenation of furfural.     

Parametric investigation of the soil–structure interaction effects on the dynamic behaviour of a shallow foundation supported wind turbine considering a layered soil

The proposed investigation is concerned with influential factors of soil–structure interaction issues for onshore wind turbines. Indeed, the awareness of these aspects encounters hardly a straightforward application in practical regulations and therefore is often neglected. However, with the rapid recent growth, the wind energy installations are expanding into regions where the soil conditions may be unfavorable. A consciousness raising of the significance of interaction between the wind turbine, its foundation and the underlying soil is lacking. This paper aims to fill this research gap. It involves a three‐blade wind turbine grounded on a layered half space. The layered soil is simplified as a horizontal layer over an homogeneous half space. However, the method can consider multilayered soil and different bottom conditions, such as rigid bedrock or flexible half space. The soil–structure system is modeled by means of a coupling between finite element and boundary element method. The analysis is carried out in frequency domain. At the first stage, the only foundation–soil system is investigated, and subsequently, the focus shifts to the whole turbine‐soil assembly. The effects of different parameters are systematically evaluated, in order to provide a range of values for which the soil–structure interaction has to be accounted for. The investigation highlighted the importance of the relative stiffness of structure and soil. Also, the ratio of the layer stiffness to the half space stiffness plays an important role. Copyright © 2014 John Wiley & Sons, Ltd.     

Theoretical calculation and experimental investigation on acoustic characteristics of a regenerator in thermoacoustic apparatus

An acoustic‐driven thermoacoustic device, which is used to investigate acoustic characteristics of a regenerator, was designed and manufactured. A model of the acoustic characteristics of the regenerator is discussed. The acoustic characteristics of the regenerator, such as acoustic impedance Ẑ_n, reflection coefficient , transmission loss TL, and phase angle between incident and reflected wave at x=0, were obtained by processing the experimental results with the correlation‐spectra analysis (the auto‐ and cross‐spectra) methods theoretically. Comparisons of acoustic characteristics between two cases, A (regenerator) and B (regenerator and two additional heat exchangers), are discussed. Different heating power influence on acoustic characteristics is also investigated. The results obtained will be helpful in further investigations on the regenerator model. © 2005 Wiley Periodicals, Inc. Heat Trans Asian Res, 34(8): 539–546, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20093     

Theoretical and experimental investigation of total equivalent temperature difference (TETD) values for building walls and flat roofs in Turkey

The aim of this study is to find time lag (TL), decrement factor (DF) and total equivalent temperature difference (TETD) values for multilayer walls and flat roofs of buildings using experimental and theoretical methods, and to compare the experimental results with theoretical ones. The TETD is a method for calculating cooling load due to heat gain from the walls or flat roofs, and it can be obtained using values of inside and outside air temperatures, solar radiation, TL and DF. The TL and DF depend on the highest and the lowest temperatures at the inner and outer surfaces of the walls or flat roofs, and the time periods involved in reaching these temperatures. Hence, two testing rooms each consisting of four multilayered walls and a flat roof, air conditioner, measuring elements are built to measure all required temperatures. The required temperatures, which are hourly inside and outside air temperatures, and surface temperatures of each structure layer, are measured in every minute during testing periods of the 2007 summer season of Gaziantep, Turkey. Hourly solar radiation values on the walls are computed using hourly measured solar radiation on a horizontal surface. The TL, DF and TETD values of eight different walls and two different flat roofs commonly used in Turkey are computed utilizing the measured temperature and solar radiation values. The computed values for the TL, DF and TETD are compared with theoretical results obtained numerically using periodic solution of one dimensional transient heat transfer problem for the same structures.     

Performance of TiO2 nanoparticles synthesized by microwave and solvothermal methods as photoanode in dye-sensitized solar cells (DSSC)

In this work, a direct comparison of the properties of the TiO₂ nanoparticles prepared by microwave and solvothermal methods were carried out and its performance as photoanode in dye-sensitized solar cells (DSSC) was analyzed. Though previously some works exist on the preparation of TiO₂ nanoparticles by solvothermal or microwave methods, they could not be compared directly as the experiment conditions such as choice of solvent, precursors and reaction temperatures were not virtually same. Herein, TiO₂ nanoparticles were synthesized by microwave and solvothermal methods using the same initial precursors and properties of the prepared nanoparticles were compared. From the X-ray diffraction pattern and Raman analysis, the prepared nanoparticles in both the cases were found to be of anatase phase. Optical properties and its carrier lifetime were studied using UV–Vis absorption, photoluminescence (PL) analysis and PL lifetime studies, respectively. Further, its morphology analyzed using scanning electron microscope (SEM) and transmission electron microscope (TEM) images, and SAED (selected area electron diffraction) patterns reveals the polycrystalline nature of the prepared nanoparticles. The surface area and the pore size distribution were studied using BET (Brunauer–Emmett–Teller) and BJH (Barrett–Joyner–Halenda) analysis, which revealed its mesoporous nature and uniform pore distribution. The chemical states of the prepared nanoparticles were further characterized using X-ray photoelectron spectroscopy. The DSSC was fabricated using the prepared TiO₂ nanoparticles as photoanodes. Further, the power conversion efficiency and the electron transport properties were analyzed.     

Characteristics and structural change of layered polysilane (Si6H6) anode for lithium ion batteries

Layered polysilane (Si₆H₆) has a graphite-like structure with higher capacity than crystalline silicon. The rate of increase of the thickness of a layered polysilane electrode after 10 charge-discharge cycles was smaller than that for a Si powder electrode, although the layered polysilane electrode has higher capacity. The structural changes of electrochemically lithiated and delithiated layered polysilane at room temperature were studied using scanning electron microscopy, X-ray diffraction and Raman spectroscopy. Layered polysilane became amorphous by insertion of lithium to 0 V, whereas insertion of lithium into crystalline silicon produces Li₁₅Si_4. Layered polysilane maintained an amorphous state during lithium insertion and deinsertion, whereas silicon changed between Li₁₅Si₄ and amorphous Li_xSi, which explains the smaller volume change of a layered polysilane electrode compared with a Si powder electrode.     

On the improvement of chemical conversion in a surface-wave microwave plasma reactor for CO2 reduction with hydrogen (The Reverse Water-Gas Shift reaction)

A novel surface-wave microwave discharge reactor configuration to generate syngas via gaseous CO₂ reduction with H₂ (non-catalytic Reverse Water-Gas Shift reaction) is studied in the context of power-to-chemicals concept. Improvement of CO₂ conversion to maximize CO production is explored by adding an external cylindrical waveguide downstream of the plasma generation system. A 2D self-consistent argon model shows that power absorption and plasma uniformity are improved in the presence of the waveguide. We show experimentally that CO₂ conversion is increased by 50% (from 40% to 60%) at the stoichiometric feed ratio H₂:CO₂ equal to 1 when using the waveguide. At higher H₂:CO₂ ratios, the effect of the waveguide on the reactor performance is nearly negligible. Optical emission spectroscopy reveals that the waveguide causes significant increase in the concentration of O atoms at a ratio H₂:CO₂ = 1. The effects of the operating pressure and cooling rate are also investigated. A minimum CO₂ conversion is found at 75 mbar and ratio H₂:CO₂ = 1, which is in the transition zone where plasma evolves from diffusive to combined operation regime. The cooling rates have significant impact on CO₂ conversion, which points out the importance of carefully designing the cooling system, among other components of the process, to optimize the plasma effectiveness.     

Theoretical and experimental investigation of a heat pipe heat exchanger for energy recovery of exhaust air

Heat pipes and two-phase thermosyphon systems are passive heat transfer systems that employ a two-phase cycle of a working fluid within a completely sealed system. Consequently, heat exchangers based on heat pipes have low thermal resistance and high effective thermal conductivity, which can reach up to the order of (10⁵ W/(m K)). In energy recovery systems where the two streams should be unmixed, such as air-conditioning systems of biological laboratories and operating rooms in hospitals, heat pipe heat exchangers (HPHEs) are recommended. In this study, an experimental and theoretical study was carried out on the thermal performance of an air-to-air HPHE filled with two refrigerants as working fluids, R22 and R407c. The heat pipe heat exchanger used was composed of two rows of copper heat pipes in a staggered manner, with 11 pipes per row. Tests were conducted at different airflow rates of 0.14, 0.18, and 0.22 m³/h, evaporator inlet-air temperatures of 40, 44, and 50°C, filling ratios of 45%, 70%, and 100%, and ratios of heat capacity rate of the evaporator to condenser sections (C_e/C_c) of 1 and 1.5. For HPHE's steady-state operation, a mathematical model for heat-transfer performance was set and solved using MATLAB. Results illustrated that the heat transfer rate was in direct proportion with the evaporator inlet-air temperature and flow rate. The highest HPHE's effectiveness was obtained at a 100% filling ratio and (C_e/C_c) of 1.5. The predicted and experimental values of condenser outlet-air temperature were in good agreement, with a maximum difference of 3%. HPHE's effectiveness was found to increase with the increase in evaporator inlet-air temperature and number of transfer units (NTU) and with the decrease in airflow rate, up to 33% and 20% for refrigerants R22 and R407c, respectively. Refrigerant R22 was the superior of the two refrigerants investigated.     

Numerical analysis of the effect of boundary layer thickness on vortex structures and heat transfer in the wake behind a hill

This study presents a three‐dimensional numerical analysis of the effect of boundary layer thickness on vortex structures and heat transfer behind a hill mounted in a laminar boundary layer. When the thickness of the velocity boundary layer is comparable to the hill height, a hairpin vortex is formed symmetrically to the center of the spanwise direction in the wake. A secondary vortex is formed between the legs, and horn‐shaped secondary vortices appear under the concave parts of the hairpin vortex. When the boundary layer thickness increases, the legs and horn‐shaped secondary vortices move toward the center of the spanwise direction, and thus heat transport and heat transfer increase there. At this time, high‐turbulence areas generated locally move toward the center of the spanwise direction with an increase in the boundary layer thickness. With a further increase in the boundary layer thickness, steady streamwise vortices are formed downstream of the hill, but the heat transfer decreases. © 2009 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20261     

ENDOW (efficient development of offshore wind farms): modelling wake and boundary layer interactions

While experience gained through the offshore wind energy projects currently operating is valuable, a major uncertainty in estimating power production lies in the prediction of the dynamic links between the atmosphere and wind turbines in offshore regimes. The objective of the ENDOW project was to evaluate, enhance and interface wake and boundary layer models for utilization offshore. The project resulted in a significant advance in the state of the art in both wake and marine boundary layer models, leading to improved prediction of wind speed and turbulence profiles within large offshore wind farms. Use of new databases from existing offshore wind farms and detailed wake profiles collected using sodar provided a unique opportunity to undertake the first comprehensive evaluation of wake models in the offshore environment. The results of wake model performance in different wind speed, stability and roughness conditions relative to observations provided criteria for their improvement. Mesoscale model simulations were used to evaluate the impact of thermal flows, roughness and topography on offshore wind speeds. The model hierarchy developed under ENDOW forms the basis of design tools for use by wind energy developers and turbine manufacturers to optimize power output from offshore wind farms through minimized wake effects and optimal grid connections. The design tools are being built onto existing regional‐scale models and wind farm design software which was developed with EU funding and is in use currently by wind energy developers. Copyright © 2004 John Wiley & Sons, Ltd.     

Experimental investigation of wind effects on a standalone photovoltaic (PV) module

The pressure field on the upper and lower surfaces of a photovoltaic (PV) module comprised of 24 individual PV panels was studied experimentally in a wind tunnel for four different wind directions. The results show that the pressure distribution on the module surface is symmetric about its mid-plane for head-on wind (0° and 180°) and asymmetric at other wind directions. The inter-panel gap (which is essential in large PV modules) is found to influence module's surface pressure field. Pressure magnitudes on the module surface were increased with the module inclination angle, as expected. It is also observed that the mean pressure magnitudes on the PV module under smooth wind exposure are higher than those under open terrain wind exposure.