共查询到19条相似文献,搜索用时 125 毫秒
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微囊化载药高分子微球制备方法研究进展 总被引:4,自引:0,他引:4
本文综述了各种微囊化制备微球的方法和原理,并对微囊化微球技术的研究最新进展及其在纳米微球,磁性高分子微球、智能微球制备上的应用作了介绍。 相似文献
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《化工技术与开发》2018,(12)
本研究以共沉淀法制备的Fe3O4为核,采用溶胶-凝胶法,使用正硅酸乙酯(TEOS),在Fe3O4表面包覆一层Si O2,进而用硅烷偶联剂3-(异丁烯酰氧)丙基三甲氧基硅烷对Fe3O4@Si O2复合微球进行表面改性,制得表面含有双键核壳结构的Fe3O4@Si O2复合磁性微球。采用乳液聚合法,将复合磁性微球与功能单体甲基丙烯酸羟乙酯(HEMA)共聚,得到表面带有羟基的高分子磁性微球。对所制备的复合磁性微球用傅里叶红外光谱(FT-IR)、扫描电镜(SEM)以及X射线衍射(XRD)进行表征,结果表明,成功制备出了单分散性良好的功能性高分子羟基磁性微球。 相似文献
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考察了核壳式表面功能化磁性聚苯乙烯纳米微球的可控制备工艺。采用紫外可见吸收光谱、透射电子显微镜、原子力显微镜及在不同溶剂中的分散性实验,对表面羧基化的磁性聚苯乙烯纳米微球的结构与形态进行了表征。结果表明,改变外加晶核Fe2O3纳米颗粒数目,可有效实现磁性聚苯乙烯纳米微球的尺寸可控。 相似文献
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介绍了无机纳米材料的结构特性,对用于制备聚合物/无机纳米复合材料的直接分散法,插层复合法、溶胶-凝胶(sol-gel)法等3种方法及聚合物/无机纳米复合材料的性能进行了综述,并介绍了聚合物基纳米复合材料的现状和发展趋势。 相似文献
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Ayesha Kausar 《Polymer-Plastics Technology and Engineering》2019,58(6):579-596
This paper presents an overview of unique carbon nanostructure graphene nanoribbon (GNR). GNR is a thin elongated strip of sp2-bonded carbon atoms with a narrow width of ≤10 nm. The electronic, mechanical, thermal, chemical, and magnetic properties of GNR make it an attractive nanofiller in polymeric nanocomposite. Polyaniline, poly(methyl methacrylate), poly(vinylidene fluoride), poly(vinyl alcohol), polystyrene, polyethylene, epoxy, and polyamide have been explored with GNR so far. Despite of outstanding potential of polymer/GNR nanocomposite, not much research is found in this area. Few application areas of polymer/GNR nanocomposite discovered till now are related to sensor, supercapacitor, fuel cell, and electromagnetic interference shielding materials. 相似文献
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H. Sadeghi Nasrabadi M. R. Kalaee M. Abdouss M. Sheydaei S. Mazinani 《Journal of Inorganic and Organometallic Polymers and Materials》2013,23(4):950-957
In this study, polyethylenetetrasulfide/montmorillonite nanocomposite (PETS/nanoclay) is synthesized from ethylene dichloride and sodium tetrasulfide monomers by in situ polymerization method. The effect of phase-transfer catalyst (PTC) on polymerization kinetics in addition to the structure of resulting PETS containing nanoclay is investigated. The results show that surface-modified montmorillonites by methyl tallow bis-2-hydroxyethyl quaternary ammonium chloride could properly act as PTC. Therefore, it is demonstrated that the addition of nanoclay as PTC reduces the reaction time and increases the polymerization rate during the production of final nanocomposite. The samples were characterized using Fourier transform infrared and Raman spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), nuclear magnetic resonance spectroscopy besides energy-dispersive X-ray spectroscopy (EDS) combined with SEM (SEM–EDX). In addition, thermal behavior of nanocomposite was perused by differential scanning calorimetry and thermogravimetric analysis. XRD and AFM results show proper dispersion of clay in PETS matrix and SEM–EDX results demonstrate suitable distribution of clay in polymer matrix. PETS/nanoclay nanocomposite show a better thermal stability, and also higher glass transition and melt temperature compared to pure polysulfide polymer. The solubility of nanocomposite is also studied and results show that the solubility depends on solvent concentration in addition to reinforcement (nanoclay) deals. 相似文献
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Mohsen Ashjari Ali Reza Mahdavian Nadereh Golshan Ebrahimi Yasamin Mosleh 《Journal of Inorganic and Organometallic Polymers and Materials》2010,20(2):213-219
Recent studies on inorganic/polymer nanocomposites have shown enhancements in thermal, mechanical, and chemical properties
over the neat polymer without compromising density, toughness, and processibility. When nanoparticles are incorporated into
the polymer matrix, significant enhancements in thermal and mechanical properties of the nanocomposite are observed. The present
study is focused on the preparation and characterization of nanosize magnetite-reinforced PU composites, which induces magnetic
properties to a specific thermoplastic polyurethane elastomer. The nanocomposites are prepared and the effects of magnetite
content on thermal, mechanical, and magnetic properties of the nanocomposites are evaluated. Ultrasonication was used to disperse
the nanoparticles and break up any large clumps and aggregates and followed by mechanical mixing. The magnetic nanocomposites
were characterized by FT-IR spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and vibrating
sample magnetometry (VSM). Characterization of the magnetic nanocomposite by FT-IR showed a successful incorporation of magnetite
nanoparticles into the polymeric matrix. TGA and magnetometry of the magnetic nanocomposites revealed the amount of magnetite
that was incorporated into the polymeric phase. Finally, the corresponding magnetization behavior of the nanocomposites was
studied. 相似文献
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In this study, polymer‐grafted magnetic nanoparticles containing chromium(III) ions incorporated onto Fe3O4/mercaptopropanoic acid‐poly(2‐hydroxyethyl acrylate) was prepared via a simple and in situ method. The obtained magnetic nanocomposite exhibited high catalytic activity and excellent selectivity in direct hydroxylation of benzene in the presence of hydrogen peroxide under solvent‐free condition. The magnetic catalyst could be also separated by an external magnet and reused seven times without any significant loss of activity/selectivity. Due to the Lewis acidity of the Fe3+ groups in the structure of magnetic nanoparticles, the high efficiency of this catalyst is possibly due to the synergetic effect of Cr3+ and Fe3+ groups in the structure of magnetic nanocomposite. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40383. 相似文献
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聚丙烯/蒙脱土纳米复合材料的研究进展 总被引:3,自引:0,他引:3
对聚丙烯(PP)/蒙脱土(MMT)纳米复合材料的国内外研究进展进行综述,介绍了PP/MMT纳米复合材料的制备原理和制备方法。包括原位插层聚合法、聚合物溶液插层法、聚合物熔融插层法、溶胶一凝胶法,重点介绍了聚合物熔融插层法的研究进展。聚合物熔融插层法具有操作简单、无需处理过多溶剂的优点,避免了环境和能源问题,更易于工业化。最后对PP/MMT纳米复合材料的未来发展进行了展望。 相似文献
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M. A. Ramazanov F. V. Hajiyeva A. M. Maharramov Luca Di Palma Diana Sannino Makoto Takafuji 《Polymer-Plastics Technology and Engineering》2018,57(5):449-458
In this study, we report about the preparation of magnetic polymer nanocomposites on the basis of isotactic polypropylene and magnetite Fe3O4 nanoparticles. The structure and composition of polymer nanocomposite materials have been studied by scanning electron microscopy, atomic force microscopy, and X-ray dispersive analysis. The magnetic properties of polymer nanocomposites based on PP+Fe3O4have been investigated. It is found that not significant adhesion and agglomeration of nanoparticles occur, by increasing the nanoparticle content in polymer matrix up to 40%, and therefore they act as single-domain nanoparticles. The samples of nanocomposites based on PP+Fe3O4, with up to 40% content of Fe3O4, exhibit superparamagnetic properties. It was also found out that the magnetic polymer nanocomposite material based on PP+Fe3O4 is able to absorb ultrahigh frequency electromagnetic waves in the frequencies range from 0.1 to 30?GHz. The increase in Fe3O4 concentration from 5 to 40% at the 400?µm thicknesses of the films leads to an increase in absorption of electromagnetic waves of high frequency from 15 to 22.7%. 相似文献
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Facile fabrication of nanocomposite microspheres with polymer cores and magnetic shells by Pickering suspension polymerization 总被引:3,自引:0,他引:3
Chaoyang Wang Chengjin Zhang Yu Li Yunhua Chen Zhen Tong 《Reactive and Functional Polymers》2009,69(10):750-754
Pickering suspension polymerization was used to prepare magnetic polymer microspheres that have polymer cores enveloped by shells of magnetic nanoparticles. Styrene was emulsified in an aqueous dispersion of Fe3O4 nanoparticles using a high shear. The resultant Pickering oil-in-water (o/w) emulsion stabilized solely by magnetic nanoparticles was easily polymerized at 70 °C without stirring. Fe3O4 nanoparticles act as effective stabilizers during polymerization and as building blocks for creating the organic–inorganic hybrid nanocomposite after polymerization. The fabricated magnetic nanocomposites were characterized by FTIR, XRD, TGA, DSC, GPC, XPS and SEM. The structures of the polymer core and the nanoparticle shell were analyzed. We investigated the effects on the products of the weight of Fe3O4 nanoparticles used to stabilize the original Pickering emulsions. Pickering suspension polymerization provides a new route for the synthesis of a variety of hybrid nanocomposite microspheres with supracolloidal structures. 相似文献