Activated carbon (AC) has been widely used in the prevention and control of air and water pollution due to its excellent adsorption ability. However, the adsorption capacity of AC for targeting organic compounds is reduced because of the competitive adsorption of water molecules. The current study proposes hydrophobic modification and regeneration of waste AC as a solution to these issues. Using waste AC as raw material, SiO2 particles were introduced to increase its surface roughness and micropores of AC. Nonpolar alkyl chain groups were grafted on the surface of AC to improve its hydrophobic performance, and high-temperature regeneration was used to increase its specific surface area. The experimental results showed that the water contact angle of AC increased from 30° (hydrophilic) to 142° (hydrophobic) after modification, and it maintained an angle of 139° even after high-temperature regeneration. The specific surface area of hydrophobic AC increased from 290 to 1075 m2 g?1 and the equilibrium adsorption capacity of hydrophobic AC for methylene blue is 425.4 mg g?1 after regeneration. AC-adsorbed methylene blue also has excellent hydrophobicity (145°) and high specific surface area (1250 m2 g?1) after being modified and regenerated by the same methods. After being exposed to air for 600 days, the modified AC still has good hydrophobicity (125°). This indicates that our method of hydrophobic modification combined with regeneration has great significance to the recovery and utilization of waste AC.
Molybdenum carbides/carbon composites (MCCs) with high specific surface area were prepared using the direct carbonization of a mixture of hydroxylpropyl cellulose, polyvinyl alcohol, K2MoO4 and K2CO3 at 900 °C in flowing Ar. X-ray diffraction pattern showed the formation of α-Mo2C with small amount of Mo3C2 in carbon matrix. The particle size of carbides in MCCs varied from ca. 50 nm to 5 μm by changing the precursor ratio. The BET specific surface areas of the synthesized MCCs could be controlled from 400 to 1200 m2/g depending on the amount of K2CO3 added during the preparation by increasing the microporosity. 相似文献
We report the preparation of hydroxyapatite in powdered form by aqueous reaction of calcium nitrate or hydroxide with phosphate
ion at room temperature. With a slow maturation step of 48 h avoiding heat, the resulting products show large specific surface
areas above 150 m2/g. The specific surface areas also depend on stirring speed with a maximum observed with gentle mixing. Ageing causes a decrease
in specific surface area which tends to stabilize near 100 m2/g following a 1 year period. The hydroxyapatite may be spray dried and conserve interesting physical properties for environmental
applications. 相似文献
Adsorption of phenol, hydroquinone, m-cresol, p-cresol and p-nitrophenol from aqueous solutions onto high specific area activated carbon cloth has been studied. The effect of ionization on adsorption of these ionizable phenolic compounds was examined by studying the adsorption from acidic, basic and natural pH solutions. Kinetics of adsorption was followed by in situ UV spectroscopy over a period of 90 min. First-order rate law was found to be valid for the kinetics of adsorption processes and the rate constants were determined. The highest rate constants were obtained for the adsorption from solutions at the natural pH. The lowest rate constants were observed in basic solutions. The rate constants decreased in the order p-nitrophenol approximately m-cresol>p-cresol>hydroquinone approximately phenol. Adsorption isotherms were derived at 30 degrees C and the isotherm data were treated according to Langmuir, Freundlich and Tempkin isotherm equations. The goodness of fit of experimental data to these isotherm equations was tested and the parameters of equations were determined. The possible interactions of compounds with the carbon surface were discussed considering the charge of the surface and the possible ionization of compounds at acidic, basic and natural pH conditions. 相似文献
Hollow carbon spheres (HCSs) have attracted tremendous interest in recent years due to their intriguing structure-induced physicochemical properties and significant potential for numerous applications. However, the preparation of HCSs with precise structural control using a simple and scalable strategy remains challenging. In this work, hollow carbon particles having a well-defined spherical morphology were successfully produced using a green, economical, and facile spray drying method together with a carbonization process. Kraft lignin was employed as the carbon precursor in place of lignosulfonate with potassium hydroxide (KOH) as an activation agent. The high specific surface area (1536.5–2424.8 m2 g?1) with micro-mesoporous structure of HCSs can be easily tuned by controlling the mass ratio of KOH to carbon precursor. The KOH-to-lignin mass ratios were utilized below 1.5, lower than those in previous studies typically used higher than 3, which was in accordance with green chemistry principles. In addition, these HCSs have applications as electrode materials in supercapacitors for energy storage devices. With the great achievements and continuous efforts in this important field, these results suggest that our approach will open a new path for the development of advanced carbon materials and high value-added utilization of Kraft lignin as a promising material for potential applications. 相似文献