CO2 distribution in the atmosphere and noise survey after blow-out in alfina 1 well, Northern Latium, Italy

A water-dominated geothermal reservoir, with a gas cap (mainly CO₂) on the reservoir roof, was individualed in Torre Alfina zone, northern Latium, about 30 km south-east of Monte Amiata.The first exploratory well (Alfina 1), drilled in 1973, blew-out spontaneously so that no production casing could be inserted.After well shut-in several surface gas manifestations appeared which were considered of some risk to the environment.This paper describes the methods used to determine the degree of pollution and the total area involved.The study of the gas dispersion in the atmosphere, the noise resulting from production, and the meteorological conditions in the area, was used in drawing up a disposal plant project; this plant will be assembled on future wells as a safety measure where large quantities of fluids are involved.     

Thermodynamic evolution of the Los Azufres,Mexico, geothermal reservoir from 1982 to 2002

An investigation has been made of the response of the Los Azufres geothermal reservoir to 20 years of development, beginning in 1982. The simulator WELFLO was used to characterize the thermodynamic conditions of the reservoir fluids. The first response to exploitation consisted of a decrease in pressure and an increase in enthalpy. Small decreases in reservoir pressure associated with large increases in fluid enthalpy characterize the long-term response in the northern production area. In the southern production area, long-term changes include decreases in pressure and mass flow rate, increases in steam production and, in wells affected by injection, increases in both pressure and total mass flow rate. These changes reflect the effects of boiling, cooling and fluid mixing, processes resulting from large-scale fluid production.     

Isotopic (δO, δD) patterns in Los Azufres (Mexico) geothermal fluids related to reservoir exploitation

Isotopic patterns for the year 2000 in the Los Azufres geothermal reservoir were related to injection of a condensed steam–water–air mixture as well as to the occurrence of reservoir physical processes resulting from exploitation. Reservoir boiling and mixing of reservoir fluids with cooler fluids were the most important processes identified. Boiling takes place in two zones of the field. In the north, the boiling area includes wells AZ-13, AZ-28, AZ-48, AZ-43 and AZ-32, while, in the south, boiling affects wells AZ-16AD, AZ-22, AZ-18, AZ-26 and AZ-36. Mixing of reservoir fluids with cooler waters was identified in wells AZ-2, AZ-33, AZ-16 and AZ-46 located in the southern zone and in well AZ-4 in the north. The isotopic (oxygen-18 and deuterium) patterns of fluids collected in September 2000 show that the original convective process found in the unperturbed reservoir is still taking place, although mixing of reservoir and reinjected fluids is also indicated. According to N₂ data, the effects of reinjection on the physical and chemical characteristics of the reservoir fluids can be observed in the northern part of the field. Until now, however, only a steam phase, resulting from boiling and steam separation of the re-injected mixture, is evident in the fluids discharged by the northern wells.     

The Cerro Prieto IV (Mexico) geothermal reservoir: Pre-exploitation thermodynamic conditions and main processes related to exploitation (2000–2005)

The Cerro Prieto IV (CP IV) reservoir, located in the northeastern part of the Cerro Prieto (Mexico) geothermal field, was studied in order to define its pre-exploitation conditions and initial (2000–2005) response to exploitation. Bottomhole thermodynamic conditions were estimated by modeling heat and fluid flows using the WELLSIM program and well production data. Produced fluid chemical and isotopic data were also analyzed to investigate characteristic patterns of behavior over time, which were then compared against simulation results to obtain a conceptual model of the CP IV reservoir. According to the proposed model, two zones in the reservoir – separated by Fault H and producing fluids of different characteristics – were identified under pre-exploitation conditions. Wells in the area to the east-southeast (south block) produce very high-enthalpy fluids (≥2000 kJ/kg), with very low chloride (≤7000 mg/kg) and high CO₂ (>6‰ molar) and δD (<−94‰). In contrast, wells toward the west-northwest (north block) show moderate-enthalpy fluids (1400–1800 kJ/kg), with high chloride (∼12,000 mg/kg) and relatively low CO₂ (<6‰ molar) and δD (<−94‰). Dilution caused by cooler water entry, boiling due to steam gain, both occurring in the north block, and steam condensation in the south block were identified as the three main reservoir processes associated with exploitation. Also, it was found that the dynamics of the CP IV reservoir is controlled by the Fault H system.     

三峡水库蓄水对库区降水量的影响分析

三峡大坝建成后库区水位上升,常年水面面积也将大幅增加,库区下垫面将发生变化,从而导致局地气候特征的变化。为了解三峡大坝对库区降水量的影响,基于三峡库区37个雨量站点1958-01-01~2008-12-31逐日有效降水量资料,采用气象诊断旋转正交经验函数(REOF)方法计算并分析了三峡库区和大坝南北部年均降水量、四季降水量的时空变化情况,并通过REOF模态图时间系数分析了建坝前后降水量的波动情况。结果发现,三峡水库运行后库区降水量存在一定的波动,三峡大坝在运行前45年与运行后6年的时间内,年均、四季整个库区与北部降水量差值波动幅度并不明显。     

Characteristics and management of the Sumikawa geothermal reservoir, northeastern Japan

The subsurface temperature gradually increases southward in the Sumikawa geothermal field and decreases sharply toward the north. The geothermal reservoir contains a two-phase zone between the cap rock and hot water zone. The target for production was designated in the deep zone, in the high temperature southern area. The production and reinjection areas have been separated to recover thermal energy efficiently during the recycling of reinjection fluid; the wells have been spaced as far apart as possible to reduce well interference. To improve productivity and injectivity, cold-water well stimulation was applied, and this experiment reduced the number of wells required for 50 MW_e power generation.     

Analysis of tracer test data, and injection-induced cooling, in the Laugaland geothermal field, N-Iceland

The Laugaland geothermal system in N-Iceland is hosted by low-permeability fractured basalt and its productivity is limited by insufficient recharge, even though substantial thermal energy is in-place in the 90–100 °C hot rocks of the system. The purpose of a 2-year reinjection experiment, completed in late 1999, was to demonstrate that some of this energy could be extracted economically through long-term reinjection. A comprehensive monitoring program was implemented as part of the project, including three detailed tracer tests. More than 1400 tracer samples were collected during the tests. Tracer return data indicate that the injected water travels through the area bedrock by two modes: first, along direct, small volume flow-paths, such as fractures or interbeds; second, by dispersion and mixing throughout a large volume of the reservoir. Based on the tracer test results, and assuming 15 l/s average future reinjection, the temperature of water produced is predicted to decline by 1–3 °C in 10 years. It can be asserted, in spite of measurement uncertainties, that the 2-year reinjection experiment did not cause a temperature decline greater than about 0.5 °C, conforming to predictions. It is estimated that future reinjection at 15 l/s will enable an increase in energy production amounting to about 24 GWh_th/year, which equals roughly of the average yearly energy production at Laugaland during the last decade. Reinjection has continued after the experiment and is already an important part of the management of the Laugaland geothermal system.     

Thermal and geochemical structure of the Uenotai geothermal system, Japan

The Uenotai geothermal area is located in southern Akita prefecture of northern Honshu Island. The Uenotai geothermal system is a liquid-dominated system with a central zone of aquifer boiling. The two-phase reservoir has evolved from liquid in the natural state due to exploitation. Gas composition of the vapor phase in the reservoir is nearly in equilibrium and correlates with the vapor fraction in the reservoir and with discharging steam quality. The marginal part of the Uenotai system has cooled with the drop in ground-water level. The chemical characteristics of the geothermal water indicate mixing of the immature high Cl source water with conductively heated or steam-heated shallow water or surface water, as well as boiling and steam gain.     

Structure and hydrology of the Ogiri field, West Kirishima geothermal area, Kyushu, Japan

The geothermal system in the West Kirishima area is controlled by a system of faults and fractures oriented along two main directions, northwest to southeast and east–northeast to west–southwest. The Ginyu fault extends through the Ogiri field in the Ginyu area, which is one of the east–northeast to west–southwest striking faults in this area. This fault is the reservoir target for developing the geothermal resources in the Ogiri field. The Ginyu fault is a near planar fracture with a uniform temperature of 232°C and has near-neutral pH, chloride fluids. Based on the results of a detailed analysis of the Ginyu fault, all production wells drilled in the Ogiri field intersected the Ginyu fault reservoir successfully, securing steam production for a 30 MW_e power plant. A typical fracture-type geothermal model for the Ogiri field was developed on the basis of the geology, electric and geophysical logs, fluid chemistry, and well test data.     

Analysis of reservoir pressure and decline curves in Serrazzano zone, Larderello geothermal field

An estimate of reserves in the Serrazzano reservoir was obtained from mass balance studies and production decline curve analyses.The Serrazzano reservoir consists of a geometrically well-defined structural high of permeable formations separated from the other productive regions of the Larderello field.Deep drilling began in the 1930s and was limited to a small area exhibiting natural manifestations. After the second World War the area of drilling was extended to about 20 km². Currently the drilling area is about the same. Even though the reservoir has been producing steam since the 1930s, a systematic collection of production data did not begin until after 1953.Data on average reservoir pressures were not available for the material balance calculations made in the study reported here. Calculated bottom hole pressures of shut-in wells were taken therefore to represent local static reservoir pressures. These pressures were used to calculate an “average reservoir pressure” which was graphed as a function of cumulative production. The reservoir pressure history corresponding to the first half of current cumulative production is not known. Data for the second half indicate a linear relationship between “reservoir pressure” and cumulative production.The conventional straight-line p/z vs cumulative production material balance relationship is known to be correct, of course, for closed single-phase gas reservoirs. The validity of this linearity for stream-producing systems with boiling water has not been proved. Regardless of this, the following observations were made: a line connecting the available data points extrapolated back to zero production indicates an initial reservoir pressure approximating at least 40 atm. Extrapolating the same data to zero reservoir pressure indicates the total initial steam in place to be about 170 × 10⁶ tons.An empirical type-curve matching technique was applied to the production decline curves of wells in the reservoir. The curve for each well was extrapolated to infinite production time to obtain an estimate of total past and future production. Summing these values for all producing wells in the reservoir, an estimated total production (past and future) of 200 × 10⁶ tons was obtained.The agreement between the estimated total production applying material balance principles and decline curve analyses is remarkably good. Although these results may be useful, further field and theoretical work are necessary to prove their validity.     

Takigami geothermal system, northeastern Kyushu, Japan

The Takigami geothermal reservoir is bounded by a system of faults and fractures oriented along two main directions, north to south and east to west. The Noine fault has a large vertical displacement and trends north to south, dividing the subsurface characteristics of resistivity, permeability, temperature and reservoir depth. The Takigami geothermal fluid has a near neutral pH and is of the Na–Cl type, with a chloride content ranging from 400 to 600 ppm. The southwestern part of the area has the highest subsurface temperature, up to 250°C. The deep fluid originates from the southwest, and flow is mainly to the north and partly to the east along faults and fractures, decreasing in temperature with increasing lateral flow.     

Fluid-rock interaction processes in the Te Kopia geothermal field (New Zealand) revealed by SEM-CL imaging

Scanning electron microscopy-cathodoluminescence (SEM-CL) imaging of hydrothermal quartz exposed by weathering in the Te Kopia geothermal field (New Zealand) has revealed a history of crystal growth, dissolution, overprinting and fracturing that cannot be detected using other observational techniques (e.g. transmitted or reflected light microscopy, back-scattered electron imaging or secondary electron imaging). The crystals initially grew as CL-dark quartz, at least 350 m below their present location on the Paeroa Fault scarp, in a neutral pH, 215±10 °C liquid reservoir (inferred from the analysis of primary liquid fluid inclusions: mean T_h of 213 °C; 0.2–0.4 wt.% NaCl_eq.). Relict quartz–adularia–illite alteration occurs at the surface, in the vicinity of the quartz crystals, and in drillcores from the nearby TK-1 exploration well. Repeated movement on the Paeroa Fault uplifted pyroclastic rocks hosting the quartz crystals, but also provided pathways for “pulses” of hot fluids to move through the system. Quartz precipitation occurred at the edge of the crystals as the reservoir fluids cooled, as indicated by micron-scale alternating CL-dark/CL-bright quartz growth bands, which contain fluid inclusions with T_h values of 210±40 °C. Pressure fluctuations were the likely cause of dissolution, marked by corroded crystal edges, with subsequent precipitation of quartz into open space. SEM-CL imaging shows that the quartz crystals contain healed fractures, which trapped low salinity fluids with T_h values of 201±6 °C. Low-pH fluids in the near-surface setting also rounded the quartz crystals, and coated them with kaolinite and CL-grey amorphous “silica residue”.     

Research on the thermal waters of the western plain of romania

A study was made of two geothermal areas of the Western Plain of Romania in order to improve our knowledge of the thermal aquifers. In the first area. Oradea-Satu Mare, the results of isotope and chemical analyses of the hyperthermal waters, along with the geological, hydrogeological and geothermal information, lead to hypotheses on the genesis of the waters, the age and exchange mechanisms, and recharge, of the various aquifers. The Pontian aquifer, which is the most important of the region, is shown to have a complicated hydrodynamics, and the thermal waters seem to originate from a mixing between a very old, meteoric water and a syngenetic saline fluid. Two different types of thermal waters were identified in the second area. Arad-Timisoara; these differences are worth further study in view of future exploitation. The thermal waters in the Pontian reservoir in the northern part of this area have a low salinity and relatively fast circulation. The fluids in the southern part have a higher temperature but are found at deeper levels; they also show a high salinity and modest flow-rate and seem to have no natural recharge.     

The thermal and geochemical structure of the broadlands-ohaaki geothermal system, new zealand

Fifty two wells have been drilled into the Broadlands-Ohaaki geothermal system, New Zealand, in the course of its development. Fluid samples collected from these wells and measured temperatures indicate that boiling is common within the East and West Bank production zones, separated at the surface by the Waikato River. Steam-heated waters form over the top of the system, above zones of boiling, and are also present on the margins of the system. They are C0₂-rich, and are responsible for dilution of the deep chloride fluids, particularly on the margins of the system. Thermal inversions are common on the margins of the system, associated with the steam-heated waters. The eastern portion of the East Bank and margins of the West Bank have cooled since peak thermal conditions, possibly due to dilution, as indicated by comparing fluid inclusion data with temperatures now present. However, fluid inclusion Th and Tm data indicate that boiling and dilution patterns similar to those now present have existedsince inclusion formation. The hydrothermal alteration of the silicic volcanics comprises an assemblage of quartz—albite—illite—adularia—calcite—chlorite—pyrite; epitode and wairakite are rare, and pyrrhotite, sphalerite and galena are generally confined to the margins of the system. Kaolin, Camontmorillonite, cristobalite and siderite are also present on the margins of the system to depths of 600–1200 m, and are related to the presence of the C0₂-rich, steam-heated waters. The deep production fluids originate from a parent (preboiled) fluid with a temperature of 300°C and CO₂ content of 0.6 mol. Excess enthalpy (i.e. two phase feed zone) discharges are not suitable for the calculation of activity ratios in the reservoir liquid and assessment of mineral—fluid equilibria; this is probably due to non-equilibrium distribution of gas species between liquid and vapor. However, an assessment of mineral—fluid equilibria is possible from the compositions of liquid feed wells. Based on these data, the reservoir fluids are now slightly undersaturated with respect to calcite and are in equilibrium with K-mica, pyrite and chlorite. The common presence of adularia and calcite in veins and open spaces may be due to a shift in mineral—fluid equilibria caused by extensive boiling and gas loss in fractures as compared to formation fluid. In contrast, the marginal steam-heated waters are in equilibrium with pyrite-pyrrhotite. Their lower pH values make them more undersaturated with respect to calcite and K-feldspar than the chloride fluids, due mainly to the lower temperatures and concentration of CO₂, resulting in interstratified illite-smectite and even kaolinite ± siderite stability. Dilution and cooling of the boiling fluids by the steam-heated waters has caused their shift to K-mica stability; the resulting deposition of illite in fractures of the East Bank may be responsible for the lower permeabilities here, causing excess enthalpy conditions.Steam-heated waters are common in geothermal systems throughout the world; recognition of dilution patterns helps in deducing the overall geochemical structure of each system. Knowledge of the distribution of steam-heated waters will also assist in locating upflow zones, and also allows their potential for casing corrosion and production-induced incursion to be assessed.     

Scaling in the reservoir in Kizildere geothermal field, Turkey

At Kizildere geothermal field, the fluid in the reservoir is hot pressurized water at 200°C containing about 2% CO₂ dissolved in the fluid by weight. During production, as the pressure decreases this gas is released into the vapor phase. When the reservoir fluid loses its dissolved CO₂ the equilibrium of the dissolved solids is destroyed and deposition occurs, either in the reservoir or in the well. Scaling in the well can be cleaned mechanically but it is more or less impossible to clean the reservoir. Thus the gas must be kept dissolved in the water until it reaches the well. At Kizildere the wells are cleaned every six months of production. After cleaning it has been observed that some of the wells regain their original production values and others do not. Well KD-14 was deepened and incrustation noted on the cuttings coming from the reservoir. On closing the wells some of them retain their well-head pressure at a constant value, whereas in others a pressure build-up continues at the well-head. Normally the static WHP are around 5 – 6 kg/cm². However, after closure of the master-valve in wells KD14 and KD15 the WHP continued to increase until all the water column in the well was changed by the gas. This phenomenon occurs because of the presence of free gas in the reservoir.     

Detailed study of sulfide scaling at la courneuue nord, a geothermal exploitation of the Paris Basin, France

The fluid of the Dogger aquifer is always used through a closed loop formed by the production well, the heating plant and the injection well. After two or three years of exploitation of the geothermal doublets in the northern part of the Paris basin, scaling and plugging problems have appeared in some cases. The results of the detailed study carried out at La Courneuve Nord, a typical site of this area, are presented.The drawdrown of production rate, scaling in the heat exchanger and the increase of injection pressure required a rapid decision for workover operations on the wells. These cleaning operations and joint research studies allowed us to identify the cause of the plugging as well as to locate these deposits and to estimate their importance. Iron sulfide was found from the base of the production well casing all the way to the injection well casing. The thickness of this scale induces hydraulic pressure loss along the casings. Moreover, part of this sulfide is carried away by the fluid and fills up the bottom of the open hole injection well. After the cleaning operations, the hydraulic properties of the reservoir seem to be recovered.Chemical and mineralogical analyses of theses deposits identified the presence of a large variety of iron sulfide (mackinawite, pyrite, pyrrhotite) and a typical corrosion product (Fe₂(OH)₃Cl). Biochemical and bacteriological studies show a very high content of micro-organisms. At the end of the workover operations, several geophysical logs gave information on the corrosion of the casing as well as the residual scale. A balance of the iron content is calculated, between the volume of deposits and the iron removed by the corrosion of the casing.A chemical model, TPDEGAZ, is used to calculate the evolution of the saturation indexes of the fluid with respect to iron sulfide phases. The effects of parameters such as pressure, temperature, degassing and addition of iron by corrosion are simulated. The results of the observation and modeling approaches are compared.     

The use of gas chemistry to evaluate boiling processes and initial steam fractions in geothermal reservoirs with an example from the olkaria field, Kenya

A method has been developed to evaluate boiling processes in the producing aquifer of “high-enthalpy” geothermal wells using data on the concentrations of CO₂, H₂S and H₂ in steam discharged. The extent to which water and steam are separated in the producing aquifer is evaluated as well as the amount of enhanced evaporation due to heat flow from the rock to the boiling water. Further, the initial steam fraction in the reservoir fluid is calculated. Results are presented for the Olkaria geothermal field, Kenya, to demonstrate the use of our method. They show that the initial steam fraction in the reservoir is very small: up to 0.25% of the mass, or about 10% by volume. Segregation of water and steam in the producing aquifers is rather extensive for some of the wells. Thus, water which has boiled and yielded steam into wells amounts to more than two times the mass of the fluid discharged from the well. The larger part of the exploited steam ( ) is generated by flow of heat from the rock to the boiling water.     

Temperature evaluation of the Bugok geothermal system, South Korea

Using a variety of chemical geothermometers and statistical analysis, we estimate the temperature of a possible deeper geothermal reservoir at Bugok, Southern Korea. Shallow thermal aquifers (down to about 400 m depth) are under exploitation in this area; the temperatures (up to 78 °C) of the produced fluids are the highest found in South Korea. Based on hydrochemical data and occurrence, the groundwaters at Bugok can be classified under three groups: Na-SO₄ thermal groundwaters (CTGW) occurring in the central (about 0.24 km²) part of the area; Ca-HCO₃ cold groundwater (SCGW) found in shallow peripheral parts of the CTGW; the intermediate-type groundwater (STGW). The CTGW type is typical of the Bugok thermal waters; they have the highest discharge temperatures and contain very high concentrations of Na (75.1–101.0 mg/L), K (2.9–6.9 mg/L) and SiO₂ (62.0–84.5 mg/L) and are rich in sulfates.The major ion composition of the CTGW suggests that these waters are in partial equilibrium with rocks at depth. The application of various alkali-ion geothermometers yields temperature estimates in the 88–198 °C range for the thermal reservoir. Multiple-mineral equilibrium calculations indicate a similar but narrower temperature range (from about 100 to 155 °C). These estimates for CTGW are significantly higher than the measured discharge temperatures. Considering the heat losses occurring during the ascent of the waters, one can infer the presence of a deeper (around 1.8 km) thermal reservoir in the Bugok area that could be developed for district heating or other direct applications of geothermal heat.     

Experimental study of sand control in a natural gas hydrate reservoir in the South China sea

Gas hydrate is considered to be one of the most promising energy sources of the 21st century, however, with the deepening of research on hydrate resources and the acceleration of trial exploitation processes, it has become apparent that sand production is one of the key factors restricting hydrate exploitation. Here we focus on the key issues of sand production in natural gas hydrate reservoirs in the Liwan Sea area in the northern part of the South China Sea. Innovative systematic studies of the mode of hydrate sand production using a multi-channel hydration acoustic wave monitoring system were conducted. The results show that a hydrate formation composed of very fine silt is prone to excessive sand production requirement. When the production pressure difference is only 1 MPa, the sand output already accounts for 19% of total liquid production, making sand production an important issue under these conditions. Finally, using filter screens with different pore sizes, hydrate reservoir sand control simulations were carried out. The results were analysed to determine properties such as: sand yield, permeability, sand content, and productivity. The design criterion for the filter screen of the fine sand particles in hydrate formations was finally obtained as D₅₀ = 11d₅₀ (where D₅₀ is median grain size of the gravel, and d₅₀ is the median grain size of the formation).