Interface chemical states of NiO/NiFe films and their effects on magnetic properties

Ta/NiOx/Ni81Fe19/Ta multilayers were prepared by rf reactive and dc magnetron sputtering. The exchange coupling field ( Hex) and the coercivity ( Hc) of NiOx/Ni81Fe19 as a function of the ratio of Ar to O2 during the deposition process were studied. The composition and chemical states at the interface region of NiOx/NiFe were also investigated using the X-ray photoelectron spectroscopy (XPS) and peak decomposition technique. The results show that the ratio of Ar to O2 has great effect on the nickel chemical states in NiOx film. When the ratio of Ar to O2 is equal to 7 and the argon sputtering pressure is 0.57 Pa, the x value is approximately 1 and the valence of nickel is + 2. At this point, NiOx is antiferromagnetic NiO and the corresponding Hex is the largest. As the ratio of Ar/O2 deviates from 7, the exchange coupling field ( Hex) will decrease due to the presence of magnetic impurities such as Ni +3 or metallic Ni at the interface region of NiOx/NiFe, while the coercivity ( Hc) will increase due to     

Deposition methods and properties of polycrystalline CdS thin films

CdS thin film was used as a suitable window layer for CdS/CdTe solar cell, and the properties of CdS thin films deposited by pulsed laser deposition (PLD), chemical bath deposition (CBD) and magnetron sputtering (MS) were reported. The experimental results show that the transmittances of PLD-CdS thin films are about 85% and the band gaps are about 2.38–2.42eV. SEM results show that the surface of PLD-CdS thin film is much more compact and uniform. PLD is more suitable to prepare the CdS thin films than CBD and MS. Based on the thorough study, by using totally PLD technique, the FTO/PLD-CdS(150 nm)/CSS-CdTe solar cell (0.0707 cm²) can be prepared with an efficiency of 10.475%.     

Fe_xPt_(100-x)薄膜的磁性能研究

用直流磁控溅射方法和原位退火工艺在玻璃基片上制备了FexPt100-x纳米膜.研究发现Fe含量对FePt纳米膜的磁特性有很大的影响.矫顽力和△H随Fe含量的增加而增大.当x=48时,矫顽力Hc达到了1040 kA/m,样品出现很好的有序化L10织构;△H取得最大值,颗粒间相互作用最小.FexPt1-x薄膜的矩形比S随着x的增加而增大,x>46时S值接近1,在一定程度上表明了此时读出信号强度较大;开关场分布SFD的变化情况刚好与此相反,Fe48Pt52获得的SFD值近似等于0.8,说明转变位置波动弱,来自转变的信号噪音低.     

南通通甲河表层沉积物活性铁的研究

为了评价通甲河表层沉积物中活性铁与氧化还原环境的关系,文章根据(2006-04-03~26)对南通通甲河表层沉积物的调查,研究了活性铁、氧化还原电位(Eh)、酸挥发性硫化物(AVS)、有机质(OM)等随时间的变化及其相互间的关系。得出:通过测定Fe3+/Fe2+值可以说明河流沉积环境的氧化还原特性,Fe3+/Fe2+的变化与Eh、AVS及OM之间存在着一定的关系。本河流段沉积物属还原态。     

XPS Studies of Magnetic Multilayers

NiOx/N81Fe19 and Co/AlOx/Co magnetic multilayers were fabricated by reactive RF/DC magnetron sputtering on clean glass substrates and oxidized Si (100) substrates, respectively. The exchange biasing field (Hex) between NiOx, and Ni81Fe19 as a function of NiOx, oxidation states was studied by X-ray photoelectron spectroscopy (XPS). The oxidation states and the oxide thickness of Al layers in magnetic multilayer films consisting of Co/AlOx/Co were also analyzed. It is found that the Hex of NiOx/Ni81Fe19 films only depends on Ni2+ but not on Ni3+ or Ni. The bottom Co can be completely covered by depositing an Al layer thicker than 2.0 nm. The oxide layer was Al2O3, and its thickness was 1.15 nm.     

Fe/S/GaAs(100)界面形成研究

为了改善界面费米能级钉扎,运用CH3CSNH2／NH4OH对GaAs(100)表面进行钝化,并对界面的形成过程进行研究。结果表明,经高温退火处理后,S在GaAS(100)表面以Ga—S的形式存在,没有形成化合物;研究了Fe生长过程中的成键特性和电子态,Fe淀积到S／GaAs(100)表面,引起0．5 eV的能带弯曲,Fe与Ga、S发生较强的化学反应,而与As的反映被消弱。随着Fe覆盖度的增加,S原子停留在界面处,起到绝缘层的作用,而As和Ga则存在扩散和偏析现象,Fe在S／GaAs(100)表面以岛状形式生长。     

快速热处理的[Fe/Pt]n薄膜的结构和磁性

采用直流磁控溅射方法在Si基片上制备[Fe/Pt]_n薄膜,利用X射线荧光光谱仪(XRF)、X射线衍射仪(XRD)和振动样品磁强计(VSM)分析薄膜的组分、结构和磁性。研究结果表明：[Fe/Pt]_n薄膜经过600 ℃快速热处理,得到了L1₀-FePt薄膜。对于[Fe (x nm)/Pt (0.5 nm)]_n薄膜,当Fe层厚度为0.7 nm时,薄膜的有序度最大,平行膜面和垂直膜面的矫顽力均最高;对于不同调制周期的[Fe/Pt]_n薄膜,有序度随调制周期先增大后减小,平行膜面的矫顽力均高于垂直膜面的矫顽力,当调制周期为2.4 nm时,薄膜平行膜面的矫顽力最大。     

Magnetic reconnection structures in the boundary layer of an interplanetary magnetic cloud

An interplanetary magnetic diffusion region was detected by WIND during 0735-0850 UT on May 15, 1997 when the front boundary layer of a magnetic cloud passed through the spacecraft about 190 earth radii upstream of the earth. The main signals of magnetic reconnection processes are: (i) Flow reversal was detected at about 0810 UT. The counter-streaming flows have the speeds of about 65 and 41 km/s, respectively, with an angle of about 140 degree between them. (ii) Hall magnetic field was detected. The Hall fields -By and +By, perpendicular to the X-Z plane, with their magnitude up to -7.0 nT, are superposed upon a guide field about 12 nT. (iii) Alfvenic fluctuations are obviously intensified inside the reconnection region; at the front boundary of the reconnection region, a slow-mode-like discontinuity was detected.(iv) Ions are heated intensively inside the reconnection region, with their temperature three times higher than that ahead of the boundary layer; electrons are also heated, with a little enhan     

Microstructure and magnetic properties of granularFePt/(FePt)_(27)Ti_(73) films for ultrahigh-density recording media

1　INTRODUCTIONThe increasing demand for the areal density inmagnetic recording has driven the recording bit tosmaller dimensions, and it is necessary to decreasegrain size to 8 nm to achieve the areal density of155 Gb/cm2. However, with such small grainsize, the grain magnetization becomes thermallyunstable because of superparamagnetic limitation.In order to overcome the thermal instability, highanisotropy is most necessary because high magne tocrystalline anisotropy …     

Fe-N合金的结构和磁性

为开发新结构的磁性材料,采用机械球磨Fe和六方氮化硼(h-BN)混合粉末形成了Fe-N非晶合金和纳米晶合金.利用Mossbauer谱仪、X-射线衍射分析和振动样品磁强计研究了球磨参量对合金的形成机制和结构转变的影响.结果表明:随球磨时间的增加,首先形成非晶Fe-N合金,然后晶化成六方结构的ε-FexN合金,Fe-N合金晶化时还发生了电子相变.表征了Fe-N非晶和ε-FexN合金的磁性,得到ε-FexN合金磁性能随N含量的增加从铁磁转变为顺磁的变化规律,阐明了样品的饱和磁感应强度随球磨时间变化的规律和机制.可见采用六方氮化硼为氮源、高能球磨制作Fe-N合金是一种有效方法.     

Characterization of Fe3Si-based coatings on low silicon steel by pulsed Nd：YAG laser cladding

The Fe3Si based coating was produced on the Fe-1Si steel surface by a pulsed Nd:YAG (yttrium aluminum garnet) laser. Its phase constitution and microstructure were characterized by using X-ray diffraction (XRD),optical microscope (OM),and field emission scanning electron microscope (FESEM) with associated energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). The hyperfine structure of the coating was studied by Mssbauer spectra (MS) and the magnetic property was also measured at ...     

Modification of Fe3O4 Magnetic Nanoparticles by L-dopa or Dopamine as an Enzyme Support

Fe3O4 magnetic nanoparticles were prepared by co-precipitation of Fe2+ and Fe3+ in an ammonia solution,and its size was about 36 am measured by an atomic force microscope.Fe3O4 magnetic nanopanicles were modified by L-dopa or dopamine using sonication method.The analysis of FTIR clearly indicated the formation of Fe-O-C bond.Direct immobilization of trypsin(EC:3.4.21.4)on Fe3O4 magnetic nanoparticles with L-dopa and dopamine spacer was investigated using glutaraldehyde as a coupling agent.No significant changes in the size and magnetic property of the three kinds of magnetic nanoparticles linked with or without trypsin were observed.The existence of the spacer molecule on magnetic nanoparticles could greatly improve the activity and the storage stability of bound trypsin through increasing the flexibility of enzyme and changing the microenvironment on nanoparticles surface compared to the naked magnetic nanoparticles.     

Transport properties of LCMO granular films deposited by the pulsed electron deposition technique

By finely controlling the deposition parameters in the pulsed electron deposition process, granular La 2/3 Ca 1/3 MnO 3 (LCMO) film was grown on silicon substrates. The substrate temperature, ambient pressure in the deposition chamber and acceleration potential for the electron beam were all found to affect the grain size of the film, resulting in different morphologies of the samples. Transport properties of the obtained granular films, especially the magnetoresistance (MR), were studied. Prominent low-field MR was observed in all samples, indicating the forming of grain boundaries in the sample. The low-field MR show great sensitive to the morphology evolution, which reaches the highest value of about 40% for the sample with the grain size of about 250 nm. More interestingly, positive-MR (p-MR) was also detected above 300 K when low magnetic field applying, whereas it disappeared with higher magnetic field applied up to 1.5 and 2 Tesla. Instead of the spin- polarized tunneling process being commonly regarded as a responsible reason, lattice mismatch between LCMO film and silicon substrate appears to be the origin of the p-MR     

Effect of Cu doping and annealing treatment on the microstructure and magnetic properties of nanocrystalline single-phase Nd-Fe-B alloys

The effects of Cu addition and annealing treatment on the magnetic properties and microstructure of Nd12.3Fe81.7-xCuxB6 (x=0-1.2) ribbons melt-spun and annealed were systematically investigated by the methods of vibrating sample magnetometer (VSM), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Optimum magnetic properties were achieved by annealing melt-spun Nd12.3Fe81.5Cu0.2B6 ribbons at 550°C for 15 min, which only contained Nd2Fe14B phase. The remanence, coercive force, and maximum ...     

四氧化三铁磁流体的制备及性能分析

采用化学共沉淀法制备了Fe3O4磁流体。以阴离子表面活性剂油酸钠对磁性颗粒进行包覆,分析了pH值、温度和Fe2＋/Fe3＋比例等制备条件对Fe3O4磁流体的影响。运用磁天平、粒度测试仪对磁流体的粒径和磁化率进行了测定,并用傅里叶变换红外光谱仪（FT-IR）、透射电子显微镜（TEM）和振动样品磁强计（VSM）等对磁流体进行了表征。实验和分析结果表明,所制备的磁流体具有超顺磁性,粒径约为16 nm,饱和磁化强度在73.8 emu/g以上。     

Comparison of short period InAs/GaSb superlattices on GaSb and GaAs substrates

Type II superlattices (SLs) short period InAs(4ML)/GaSb(8ML) were grown by molecular-beam epitaxy on lattice-mismatched GaAs substrates and on GaSb substrates. A smooth GaSb epilayer was formed on GaAs substrates by inserting mulit-buffer layers including an interfacial misfit mode AlSb quantum dot layer and AlSb/GaSb superlattices smooth layer. SLs grown on GaAs substrates (GaAs-based SLs) showed well-resolved satellite peaks in XRD. GaSb-based SLs with better structural quality and smoother surface showed strong photoluminescence at 2.55 μm with a full width at half maximum (FWHM) of 20 meV, narrower than 31 meV of GaAs-based SLs. Inferior optical absorption of GaAs-based SL was observed in the range of 2―3 μm. Photoresponse of GaSb-based SLs showed the cut-off wavelength at 2.6 μm.     

用Sm2Fe17制备纳米粒子及磁性研究

采用直流电弧等离子体法在甲烷（CH4）、氢氩、氨气、氨氮气氛下制备了钐铁合金的多种纳米粉，在甲烷气氛下没有杉或铁的氧化物生成，但生成Fe3C；在氢氩和氨氮气氛下，有钐的氧化物，在纯甲烷气氛下的制备的样品矫顽力最大，在氨氮气氛下样品的饱和磁化程度和剩余磁化强度最高，而且矫顽力中等。分析了氨氮与氛下样品高温结晶前后结构和磁学性质的异同，发现再结晶过程中样品被氧化了，磁学性能急剧下降。     

Effect of silver growth temperature on the contacts between Ag and ZnO thin films

Highly c-axis oriented ZnO thin films were deposited on Si substrates by the pulsed laser deposition (PLD) method. At different growth temperatures, 200 nm silver films as the contact metal were deposited on the ZnO thin films. The growth temperatures have great influence on the crystal quality of Ag films. Current-voltage characteristics were measured at room temperature. The Schottky contacts between Ag and ZnO thin films were successfully obtained when silver electrodes were deposited at 150°C and 200°C. Ohmic contacts were formed while the growth temperatures were lower than 150°C or higher than 200°C. After analysis, the forming of Ag/ZnO Schottky contacts was shown to be dependent on the appearance of the p-type inversion layer at the interface between Ag and ZnO layers.     

钴基磁性纳米层状镁铝水滑石的制备及表征

采用改进的化学共沉淀制备钴基磁性流体(Co0.5Fe2.5O4),将磁性基质(Co0.5Fe2.5O4)与镁铝水滑石进行组装,合成出钴基磁性纳米层状镁铝水滑石．利用XRD、TEM、IR及振动样品磁强计等手段对制备的水滑石结构和磁学性能进行了表征,TEM分析结果表明,所制备的磁性镁铝水滑石为典型的层状结构,粒子的粒径20～60nm;XRD分析结果表明,磁性基质Co0.5Fe2.5O4的引入没有改变镁铝水滑石的层状结构且随着磁性基质含量的增多,磁性镁铝水滑石的特征衍射峰的衍射强度有所降低;磁学性能测试结果表明,磁性镁铝水滑石的比饱和磁化强度随磁性基质含量的增加而线性增加．同时研究了焙烧温度对水滑石物理性能的影响。     

Microstructure and AMR Properties of Permalloy Films Sputtered on (Ni_ (0.81)Fe_(0.19)_ (0.66)Cr_(0.34 )Buffer

1　IntroductionTheanisotropicmagnetoresistanceeffect (AMR)waswidelystudiedinthepastyearsbecauseofitspracticalapplicationinmagneticandelectronicdevices ,eg ,themagneticsensorsandreadouthead[1 3 ] .Ni0 .81Fe0 .19hasex cellentmagneticsoftness ,andwasgenerall…