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设计合成了两种新型的四苯基联苯二胺衍生物N'N-二苯基-N,N'-双(3-氟苯基)-[1,1'-联苯]-4,4'-二胺(m-FTPB)和N,N'-二苯基-N,N'-双(4-氟苯基)-[1,1'-联苯]-4,4'-二胺(p-FTPB),通过熔点测试、元素分析、FT-IR光谱和1H-NMR谱等手段对其分子结构进行了表征.考察了氟代位置对这类化合物的荧光性质和HOMO能级的影响,结果表明:F原子在四苯基联苯二胺分子苯基的邻、间、对位取代时,荧光发射峰依次发生红移:而F原子在间、对、邻位取代时,HOMO能级依次上升. 相似文献
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Morten Slyngborg Dennis Achton Nielsen Assoc. Prof. Peter Fojan 《Chembiochem : a European journal of chemical biology》2016,17(21):2083-2092
The self‐assembly of fibers from peptides has attracted a tremendous amount of attention due to its many applications, such as in drug‐delivery systems, in tissue engineering, and in electronic devices. Recently, the self‐assembly potential of the designer peptide RFFFR has been reported. Here it is experimentally verified that the peptide forms fibers that are entangled and form solid spheres without water inside. Upon dilution below the critical fiber concentration, the fibers untangle and become totally separated prior to dissolution. These structures readily bind thioflavin T, resulting in a characteristic change in fluorescent properties consistent with β‐sheet‐rich amyloid structures with aromatic/hydrophobic grooves. The circular dichroism spectroscopy data are dominated by a π→π* transition, thus indicating that the fibers are stabilized by π‐stacking. Contrary to what was expected, the dissolution of the spheres/fibers results in increasing fluorescence anisotropy over time. This is explained in terms of HomoFRET between phenylalanine residues with a T‐shaped π‐stacking mode, which was determined in another study to be the dominant mode through atomistic simulations and semiempirical calculations. Kelvin probe force microscopy measurements indicate that the spheres and fibers have a conductivity comparable to that of gold. Hence, these self‐assembled structures might be applicable in organic solid‐state electronic devices. The dissolution properties of the spheres further suggest that they might be used as drug‐delivery systems. 相似文献
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碳原子线的制备是从马铃薯淀粉为固态碳源以Fe(NO3)3为催化剂前驱体,高温裂解制得。它的磁滞回线呈"S"形,一般只有铁磁性物质的磁滞回线才表现出"S",但一般铁磁性物质在常温下的饱和磁矩很大,大约为300 emu/g是碳原子线的300倍,我们把碳原子线的这种磁学性质称之为类铁磁性。通过碳原子线的顺磁共振谱图计算得到每个碳原子有4.78个自由电子,说明碳原子线中有大量的未成对电子。 相似文献
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Samples of a rolled double-base propellant were exposed to acetone vapour and the rate of solvent uptake observed. The solvent was subsequently removed and dynamic mechanical and extensometer measurements were made on the dried samples. The percentage elongation at break and the ultimate tensile strengths of the samples after solvent treatment were considerably above that of the control samples. The solvent uptake modified the relaxation behaviour of the samples and consequently the values of Young's modulus within the temperature range 30°C to 60°C. The solvent uptake was found to be non-Fickian. Samples that had been thermally annealed prior to solvent vapour treatment were also examined. In general the behaviour was similar to that of unannealed samples but the scale of some of the changes and the rate of solvent uptake was modified. 相似文献
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为了将膨胀珍珠岩和硬泡聚氨酯两种不同的保温材料复合,首先需要对其进行改性,利用硅烷偶联剂KH550对膨胀珍珠岩颗粒进行表面处理,得到活性聚氨酯填充骨料.根据国内外相关规范,测定了成型保温板件的密度、抗压强度、导热系数等物理力学性能.随着膨胀珍珠岩添加量的增加,复合保温材料的密度及抗压强度都有很大的提高.当掺入不同类别的膨胀珍珠岩时,发现粒径较大的膨胀珍珠岩对复合材料抗压性能的提高优于粒径较小的,而在导热系数方面两者却相反.通过上述实验得出了膨胀珍珠岩掺入量以及加入不同种类膨胀珍珠岩对复合材料各性能的影响,通过实验结果确定最终优选方案.将上述两种材料复合,以合理的配比达到共同发挥两种材料各自的优势的目的,此种新型保温材料具有广泛的应用前景. 相似文献
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《国际聚合物材料杂志》2012,61(11):563-575
Antimicrobial polymers based on poly(ethylene-alt-maleic anhydride) (PEMA) were prepared. Amination of poly(ethylene-alt-maleic anhydride) using diamines of different chain lengths such as ethylenediamine (EDA) and hexamethylenediamine (HMDA) afforded terminal amino groups on the polymers. Antimicrobial polymers were obtained by immobilization of benzaldehyde and its derivatives, which include 4-hydroxybenzaldehyde and 2,4-dihydroxybenzaldehyde onto amine-terminated polymers. The antimicrobial activity of the prepared polymers were examined against different types of microorganisms including Gram-positive and Gram-negative bacteria as well as some fungi. The obtained results revealed that the antimicrobial activity increased with increasing the number of phenolic hydroxyl group and with increasing the spacer length. 相似文献
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插层改性水滑石及其对聚丙烯力学和阻燃性的影响 总被引:1,自引:0,他引:1
通过离子交换法制备了十二烷基磺酸钠、酒石酸氢钠、衣康酸改性的水滑石和十二烷基磺酸钠/衣康酸、十二烷基磺酸钠/酒石酸氢钠协同改性的水滑石(LDHs),通过熔融插层法制备得到了LDHs/PP复合材料。采用红外光谱(FTIR)、X射线衍射(XRD)、热重分析(TGA)对水滑石的结构和性能进行了分析表征,研究了LDHs/PP复合材料的力学性能和阻燃性。结果表明:上述几种单一和复合有机酸及盐改性剂都能不同程度地扩大水滑石的层间距;采用酸/盐协同改性的水滑石不仅有机基团含量较高,而且层间距大,显著提高PP的弯曲强度和阻燃性,表明酸和盐复合改性水滑石有显著协同作用及改性水滑石与PP基体相容性好。 相似文献
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Capucine Jourdain de Muizon Sridévi M. Ramanoudjame Lucie Esteoulle Claude Ling Germain Brou Dr. Nicolas Anton Thierry Vandamme Dr. Marc-André Delsuc Dr. Dominique Bonnet Prof. Bruno Kieffer 《Chembiochem : a European journal of chemical biology》2021,22(4):657-661
Conjugation of the bioactive apelin-17 peptide with a fluorocarbon chain results in self-organization of the peptide into micelles. Fluorine NMR spectroscopy studies show that the fluoropeptide‘s micelles are monodisperse, while proton NMR indicates that the peptide moiety remains largely disordered despite micellization. A very fast exchange rate is measured between the free and micellar states of the peptide which enables the number of molecules present in the micelle to be estimated as 200, in agreement with values found by dynamic light scattering measurements. 相似文献
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聚合物/无机半导体复合纳米纤维性能研究 总被引:1,自引:1,他引:1
利用高压静电纺丝技术结合自组装方法,成功制备了硫化镉/聚环氧乙烷复合纳米纤维,并用X-射线光电子能谱、透射电子显微镜等)研究了复合材料表界面微观结构对纤维形态的影响,从而揭示微观结构和纤维光学性能之间的关系,以便为进一步的器件制备奠定前期基础。 相似文献
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聚乙烯耐环境应力开裂性能的改进 总被引:5,自引:0,他引:5
研究了4种粒状或粉状改性剂(LLDPE、CPE、SBS、EVA)对HDPE的耐环境应力开裂(ESCR)性能的共混改性,探讨了改性机理。结果表明,LLDPE主要通过改变晶体形态和降低结晶度改性,而CPE、SBS、EVA则主要通过加强晶区间连接改性,后者对ESCR的改性效果更显著。 相似文献
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Roberto Milani Mario Gleria Silvia Gross Roger De Jaeger Ahmed Mazzah Leon Gengembre Martine Frere Charafeddine Jama 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(3):344-351
In this paper we describe a two-step surface modification process of poly(ethylene-co-vinyl alcohol) by exploiting hexachlorocyclophosphazene and poly(dichlorophosphazene) as coupling agents. Part of the P–Cl
groups of the chlorophosphazenes is first reacted with the surface hydroxylic groups of the substrate to form covalent P–O–C
bonds, the remaining being utilized for successive substitution reactions with different nucleophiles (i.e. 2,2,2-trifluoroethanol,
heptadecafluorononanol and 4-hydroxyazobenzene). Modified surface properties, such as hydrophobicity improvement with fluorinated
alcohols and photochromic features with the azobenzene derivative, were verified by contact angle measurements and UV–Vis
spectroscopy, respectively, while changes in surface composition were demonstrated through XPS spectroscopy. 相似文献
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没食子酸丙酯-富马酸酯衍生物的合成与性能 总被引:5,自引:2,他引:5
没食子酸丙酯分别与5种富马酸单酯酰氯反应,制得了5种相应的3,4 二羟基 5 (反 β 烷氧羰基丙烯酰氧基)苯甲酸丙酯,这些新化合物同时具有良好的抗氧化和抗菌活性。 相似文献