Unexpected increase in indoor pollutants after the introduction of a smoke‐free policy in a correctional center

Correctional centers (prisons) are one of the few non‐residential indoor environments where smoking is still permitted. However, few studies have investigated indoor air quality (IAQ) in these locations. We quantified the level of inmate and staff exposure to secondhand smoke, including particle number (PN) count, and we assessed the impact of the smoking ban on IAQ. We performed measurements of indoor and outdoor PM_2.5 and PN concentrations, personal PN exposure levels, volatile organic compounds (VOCs), and nicotine both before and after a complete indoor smoking ban in an Australian maximum security prison. Results show that the indoor 24‐h average PM_2.5 concentrations ranged from 6 (±1) μg/m³ to 17 (±3) μg/m³ pre‐ban. The post‐ban levels ranged from 7 (±2) μg/m³ to 71 (±43) μg/m³. While PM_2.5 concentrations decreased in one unit post‐ban, they increased in the other two units. Similar post‐ban increases were also observed in levels of PN and VOCs. We describe an unexpected increase of indoor pollutants following a total indoor smoking ban in a prison that was reflected across multiple pollutants that are markers of smoking. We hypothesise that clandestine post‐ban smoking among inmates may have been the predominant cause.     

Biological and environmental exposure monitoring of volatile organic compounds among nail technicians in the Greater Boston area

Nail technicians are exposed to volatile organic compounds (VOCs) from nail products, but no studies have previously measured VOC biomarkers for these workers. This study of 10 nail technicians aimed to identify VOCs in nail salons and explore relationships between air concentrations and biomarkers. Personal and area air samples were collected using thermal desorption tubes during a work shift and analyzed using gas chromatography/mass spectrometry (GC/MS) for 71 VOCs. Whole blood samples were collected pre‐shift and post‐shift, and analyzed using GC/MS for 43 VOCs. Ventilation rates were determined using continuous CO₂ measurements. Predominant air VOC levels were ethyl methacrylate (median 240 µg/m³), methyl methacrylate (median 205 µg/m³), toluene (median 100 µg/m³), and ethyl acetate (median 639 µg/m³). Blood levels were significantly higher post‐shift than pre‐shift for toluene (median pre‐shift 0.158 µg/L and post‐shift 0.360 µg/L) and ethyl acetate (median pre‐shift <0.158 µg/L and post‐shift 0.510 µg/L); methacrylates were not measured in blood because of their instability. Based on VOCs measured in these seven nail salons, we estimated that emissions from Greater Boston area nail salons may contribute to ambient VOCs. Ventilation rates did not always meet the ASHRAE guideline for nail salons. There is a need for changes in nail product formulation and better ventilation to reduce VOC occupational exposures.     

Detection of human effluents by a MOS gas sensor in correlation to VOC quantification by GC/MS

Due to increasing interest in indoor air quality (IAQ) monitoring for demand controlled ventilation (DCV) aiming at improved perceived air quality, health, energy and cost saving, the objective of this study has been the development of a sensor module based on a single microelectromechanical-system (MEMS) metal oxide semiconductor (MOS) gas sensor for IAQ monitoring as close as possible to the human sensory impression in indoor environments. Based on the results of a statistical evaluation on human induced volatile organic compounds (VOCs) in the ambient air of indoor environments correlating with human presence and perceived air quality, the performance of differently doped SnO₂ thick film gas sensor materials has been investigated in laboratory and by means of field tests in order to find the most promising sensor material for IAQ monitoring based on the detection of changes of human induced VOCs in indoor air. Implementation of an empirical evaluation algorithm reversing proportionality of anthropogenic CO₂ production and other bio-effluent generation allows prediction of CO₂ equivalent units. Analytical instrumentation and reference sensors served to evaluate the effectiveness of the developed sensor module in real-life.     

Energy impact assessment for the reduction of carbon dioxide and formaldehyde exposure risk in air-conditioned offices

Treatment of fresh air in ventilation systems for air-conditioning consumes a considerable amount of energy and affects the indoor air quality (IAQ). In this study, energy impact on ventilation systems was examined against certain IAQ objectives for indoor formaldehyde exposure risk in air-conditioned offices of Hong Kong. Thermal energy consumptions for ventilation systems and indoor formaldehyde exposure concentrations based on some regional surveys of typical offices in Hong Kong were reviewed. The thermal energy consumptions of ventilation systems operating for CO₂ exposure concentrations between 800 ppmv and 1200 ppmv for typical office buildings and the corresponding formaldehyde exposure risks were evaluated. The results showed that, for a reference indoor environment at a CO₂ exposure concentration of 1000 ppmv, the average thermal energy saving of ventilation system for a unit increment of the acceptable formaldehyde exposure limit of 1 h (loss of life expectancy of 0.0417 day) was 280 MJ m⁻² yr⁻¹; and for a unit decrement of the exposure limit of 1 h, an additional average thermal energy consumption of 480 MJ m⁻² yr⁻¹ was expected. This study would be a useful source of reference in evaluation of the energy performance of ventilation strategies in air-conditioned offices at a quantified exposure risk of formaldehyde.     

深圳市新装修住宅室内空气质量调研分析

本文通过对深圳市新装修住宅室内空气质量进行现场测试和长期监测,总结了此类住宅的室内空气污染现状,对装饰装修所带来的室内空气污染规律进行了分析。调研结果显示,深圳市装修污染水平基本与全国平均水平一致,甲醛和TVOC超标率均高于60%;家具是住宅室内空气化学污染最主要的污染源,且由于其使用密度高,卧室和儿童房等功能房间污染程度最为严重;化学污染在装修后初期能够快速下降,但后期衰减缓慢,持续时间长;不同的污染物衰减过程有所差异,苯系物污染相比于甲醛污染衰减的更快一些。     

Comparison of strategies to improve indoor air quality at the pre-occupancy stage in new apartment buildings

Indoor air quality of new apartment buildings, which is known to cause Sick Housing Syndrome, has become a major concern among apartment residents as well as construction companies in Korea. Recently, the Indoor Air Quality Management Act, a regulation that limits concentration levels of formaldehyde and five volatile organic compounds in new apartment buildings, has been implemented. In this study, the effects of ventilation and decomposing agents were investigated and compared, which could be used at the pre-occupancy stage as solutions to high VOCs concentration levels in new apartment buildings. Six housing units were investigated under different conditions to assess the extent of the improvement in indoor air quality. The results demonstrate that ventilation is an effective way to control indoor air pollution caused by VOCs emissions, and the effect of decomposing agents on improving indoor air quality depends on the types of VOCs.     

马鞍山市大型商场室内空气质量研究

测试了马鞍山市某商场的甲醛浓度、二氧化碳浓度、微生物菌落数和温度、相对湿度、风速等环境参数,通过问卷调查了营业员和顾客对室内空气质量的评价,客观评价与主观评价的结果表明,商场内空气中主要污染物的浓度符合国家标准,但仍然存在空气质量方面的问题。     

Significant OH production under surface cleaning and air cleaning conditions: Impact on indoor air quality

We report measurements of hydroxyl (OH) and hydroperoxy (HO₂) radicals made by laser‐induced fluorescence spectroscopy in a computer classroom (i) in the absence of indoor activities (ii) during desk cleaning with a limonene‐containing cleaner (iii) during operation of a commercially available “air cleaning” device. In the unmanipulated environment, the one‐minute averaged OH concentration remained close to or below the limit of detection (6.5×10⁵ molecule cm^?3), whilst that of HO₂ was 1.3×10⁷ molecule cm^?3. These concentrations increased to ~4×10⁶ and 4×10⁸ molecule cm^?3, respectively during desk cleaning. During operation of the air cleaning device, OH and HO₂ concentrations reached ~2×10⁷ and ~6×10⁸ molecule cm^?3 respectively. The potential of these OH concentrations to initiate chemical processing is explored using a detailed chemical model for indoor air (the INDCM). The model can reproduce the measured OH and HO₂ concentrations to within 50% and often within a few % and demonstrates that the resulting secondary chemistry varies with the cleaning activity. Whilst terpene reaction products dominate the product composition following surface cleaning, those from aromatics and other VOCs are much more important during the use of the air cleaning device.     

The associations of indoor environment and psychosocial factors on the subjective evaluation of Indoor Air Quality among lower secondary school students: a multilevel analysis

Subjective evaluation of Indoor Air Quality (subjective IAQ) reflects both building‐related and psychosocial factors, but their associations have rarely been studied other than on the individual level in occupational settings and their interactions have not been assessed. Therefore, we studied whether schools’ observed indoor air problems and psychosocial factors are associated with subjective IAQ and their potential interactions. The analysis was performed with a nationwide sample (N = 195 schools/26946 students) using multilevel modeling. Two datasets were merged: (i) survey data from students, including information on schools’ psychosocial environment and subjective IAQ, and (ii) data from school principals, including information on observed indoor air problems. On the student level, school‐related stress, poor teacher–student relationship, and whether the student did not easily receive help from school personnel, were significantly associated with poor subjective IAQ. On the school level, observed indoor air problem (standardized β = ?0.43) and poor teacher–student relationship (standardized β = ?0.22) were significant predictors of poor subjective IAQ. In addition, school‐related stress was associated with poor subjective IAQ, but only in schools without observed indoor air problem (standardized β = ?0.44).     

Field measurements of indoor air pollutant concentrations on two new ships

Indoor air quality (IAQ) on ships is important for the passengers’ comfort and the crew’s work efficiency, despite ships not being as common as vehicles and airplanes. The builders and operators need to be aware of the importance and present status of IAQ, but sufficient data and information are not available. In this study, we measured the pollutant concentrations on two different kinds of newly launched ships: a passenger ship and a chemical cargo ship. Although higher than in the passenger ship, the concentrations of most volatile organic compounds (VOCs) and formaldehyde in the cargo ship were lower than the recommended standards and acceptable with a few exceptions. The high CO and CO₂ concentrations in the kitchen, engine room, and engine control room were generally attributed to combustion sources. Overall, the IAQ of the cargo ship was worse than that of the passenger ship, and the concentrations of some pollutants surpassed the international criteria. For the passenger ship, the variation of IAQ was also investigated after 17 months. The observed data showed some differences in concentration variation according to the types of pollutants. To improve IAQ on ships, more data need to be collected and minimum requirements suggested.     

Indoor air quality and thermal comfort in temporary houses occupied after the Great East Japan Earthquake

Thermal conditions and indoor concentrations of aldehydes, volatile organic compounds (VOCs), and NO₂ were investigated in 19 occupied temporary houses in 15 temporary housing estates constructed in Minamisoma City, Fukushima, Japan. The data were collected in winter, spring, and summer in January to July 2012. Thermal conditions in temporary log houses in the summer were more comfortable than those in pre‐fabricated houses. In the winter, the indoor temperature was uncomfortably low in all of the houses, particularly the temporary log houses. Indoor air concentrations for most aldehydes and VOCs were much lower than the indoor guidelines, except for those of p‐dichlorobenzene, acetaldehyde, and total VOCs. The indoor p‐dichlorobenzene concentrations exceeded the guideline (240 μg/m³) in 18% of the temporary houses, and the 10^?3 cancer risk level (91 μg/m³) was exceeded in winter in 21% due to use of moth repellents by the occupants. Indoor acetaldehyde concentrations exceeded the guideline (48 μg/m³) in about half of the temporary houses, likely originating from the wooden building materials. Indoor NO₂ concentrations in the temporary houses were significantly higher in houses where combustion heating appliances were used (0.17 ± 0.11 ppm) than in those where they were not used (0.0094 ± 0.0065 ppm).     

Real-time air monitoring of occupational exposures to particulate matter among hairdressers in Maryland: A pilot study

Hairdressers are exposed to particulate matter (PM), a known air pollutant linked to adverse health effects. Still, studies on occupational PM exposures in hair salons are sparse. We characterized indoor air PM concentrations in three salons primarily serving an African/African American (AA) clientele, and three Dominican salons primarily serving a Latino clientele. We also assessed the performance of low-cost sensors (uRAD, Flow, AirVisual) by comparing them to high-end sensors (DustTrak) to conduct air monitoring in each salon over 3 days to quantify work shift concentrations of PM_2.5, respirable PM (RPM), and PM₁₀. We observed high spatial and temporal variability in 30-min time-weighted average (TWA) RPM concentrations (0.18–5518 μg/m³). Readings for the uRAD and AirVisual sensors were highly correlated with the DustTrak (R² = 0.90–0.99). RPM 8-hour TWAs ranged from 18 to 383 µg/m³ for AA salons, and 9–2115 µg/m³ for Dominican salons. Upper 95th percentiles of daily RPM exposures ranged from 439 to 2669 µg/m³. The overall range of 30-min TWA PM_2.5 and PM₁₀ concentrations was 0.13–5497 and 0.36-,541 μg/m³, respectively. Findings suggest that hairdressers could be overexposed to RPM during an 8-hour shift. Additional comprehensive monitoring studies are warranted to further characterize temporal and spatial variability of PM exposures in this understudied occupational population.     

Modeling the resiliency of energy‐efficient retrofits in low‐income multifamily housing

Residential energy efficiency and ventilation retrofits (eg, building weatherization, local exhaust ventilation, HVAC filtration) can influence indoor air quality (IAQ) and occupant health, but these measures’ impact varies by occupant activity. In this study, we used the multizone airflow and IAQ analysis program CONTAM to simulate the impacts of energy retrofits on indoor concentrations of PM_2.5 and NO₂ in a low‐income multifamily housing complex in Boston, Massachusetts (USA). We evaluated the differential impact of residential activities, such as low‐ and high‐emission cooking, cigarette smoking, and window opening, on IAQ across two seasons. We found that a comprehensive package of energy and ventilation retrofits was resilient to a range of occupant activities, while less holistic approaches without ventilation improvements led to increases in indoor PM_2.5 or NO₂ for some populations. In general, homes with simulated concentration increases included those with heavy cooking and no local exhaust ventilation, and smoking homes without HVAC filtration. Our analytical framework can be used to identify energy‐efficient home interventions with indoor retrofit resiliency (ie, those that provide IAQ benefits regardless of occupant activity), as well as less resilient retrofits that can be coupled with behavioral interventions (eg, smoking cessation) to provide cost‐effective, widespread benefits.     

Formaldehyde and acetaldehyde exposure mitigation in US residences: in‐home measurements of ventilation control and source control

Measurements were taken in new US residences to assess the extent to which ventilation and source control can mitigate formaldehyde exposure. Increasing ventilation consistently lowered indoor formaldehyde concentrations. However, at a reference air exchange rate of 0.35 h^?1, increasing ventilation was up to 60% less effective than would be predicted if the emission rate were constant. This is consistent with formaldehyde emission rates decreasing as air concentrations increase, as observed in chamber studies. In contrast, measurements suggest acetaldehyde emission was independent of ventilation rate. To evaluate the effectiveness of source control, formaldehyde concentrations were measured in Leadership in Energy and Environmental Design (LEED)‐certified/Indoor airPLUS homes constructed with materials certified to have low emission rates of volatile organic compounds (VOC). At a reference air exchange rate of 0.35 h^?1, and adjusting for home age, temperature and relative humidity, formaldehyde concentrations in homes built with low‐VOC materials were 42% lower on average than in reference new homes with conventional building materials. Without adjustment, concentrations were 27% lower in the low‐VOC homes. The mean and standard deviation of formaldehyde concentration was 33 μg/m³ and 22 μg/m³ for low‐VOC homes and 45 μg/m³ and 30 μg/m³ for conventional.     

Indoor air quality in Portuguese schools: levels and sources of pollutants

Indoor air quality (IAQ) parameters in 73 primary classrooms in Porto were examined for the purpose of assessing levels of volatile organic compounds (VOCs), aldehydes, particulate matter, ventilation rates and bioaerosols within and between schools, and potential sources. Levels of VOCs, aldehydes, PM_2.5, PM₁₀, bacteria and fungi, carbon dioxide (CO₂), carbon monoxide, temperature and relative humidity were measured indoors and outdoors and a walkthrough survey was performed concurrently. Ventilation rates were derived from CO₂ and occupancy data. Concentrations of CO₂ exceeding 1000 ppm were often encountered, indicating poor ventilation. Most VOCs had low concentrations (median of individual species <5 μg/m³) and were below the respective WHO guidelines. Concentrations of particulate matter and culturable bacteria were frequently higher than guidelines/reference values. The variability of VOCs, aldehydes, bioaerosol concentrations, and CO₂ levels between schools exceeded the variability within schools. These findings indicate that IAQ problems may persist in classrooms where pollutant sources exist and classrooms are poorly ventilated; source control strategies (related to building location, occupant behavior, maintenance/cleaning activities) are deemed to be the most reliable for the prevention of adverse health consequences in children in schools.     

Identification of the major HOx radical pathways in an indoor air environment

OH and HO₂ profiles measured in a real environment have been compared to the results of the INCA‐Indoor model to improve our understanding of indoor chemistry. Significant levels of both radicals have been measured and their profiles display similar diurnal behavior, reaching peak concentrations during direct sunlight (up to 1.6×10⁶ and 4.0×10⁷ cm^?3 for OH and HO₂, respectively). Concentrations of O₃, NO_x, volatile organic compounds (VOCs), HONO, and photolysis frequencies were constrained to the observed values. The HO_x profiles are well simulated in terms of variation for both species (Pearson's coefficients: p_OH=0.55, p_HO2=0.76) and concentration for OH (mean normalized bias error: MNBE_OH=?30%), HO₂ concentration being always underestimated (MNBE_HO2=?62%). Production and loss pathways analysis confirmed HONO photolysis role as an OH precursor (here up to 50% of the production rate). HO₂ formation is linked to OH‐initiated VOC oxidation. A sensitivity analysis was conducted by varying HONO, VOCs, and NO concentrations. OH, HO₂, and formaldehyde concentrations increase with HONO concentrations; OH and formaldehyde concentrations are weakly dependent on NO, whereas HO₂ concentrations are strongly reduced with increasing NO. Increasing VOC concentrations decreases OH by consumption and enhances HO₂ and formaldehyde.     

An integrated modeling tool for simultaneous analysis of thermal performance and indoor air quality in buildings

To analyze the thermal performance and indoor air quality (IAQ) in building simultaneously and quickly, we have developed an integrated modeling tool to simulate the dynamic indoor multi-parameters distributions and concentrations. The tool can take the parameters including indoor temperature, indoor humidity, and pollutant concentrations (e.g., volatile organic compounds (VOC) CO₂, particulate matter (PM)), as well as the heating/cooling load of heating, ventilating, and air-conditioning (HVAC) system into account. It couples a new zonal approach based on room air age. This paper presents the basic concept and flow chart in developing the modeling tool, and demonstrates the tool's application in a hypothetical health care building. The tool could be used for design of HVAC system with IAQ control devices and for the simultaneous analysis of thermal performance and IAQ in buildings.     

Evaluation on potential for assessing indoor formaldehyde using biosensor system based on swimming behavior of Japanese medaka (oryzias latipes)

In order to develop an early-warning biosensor system for predicting the impact on health of long-term and low-level exposure to indoor chemical compounds, e.g. volatile organic compounds (VOCs), we evaluated the potential for assessing indoor air quality using the biosensor system based on the swimming behavior of Japanese medaka (oryzias latipes) as an indicator of indoor air quality in the beginning. As a technology to dissolve chemical compounds into water efficiently, a micro bubble generator was introduced. The test chemical was formaldehyde which is a representative of chemical compounds existing indoors. The result of the measuring solubility of formaldehyde was that formaldehyde concentration in water was raised to 0.12 mg/L when 1.0 mg/m³ of formaldehyde in air was bubbled for approximately 44 h. The correlation between the 0.1 mg/L of formaldehyde in water, which is roughly equivalent to 0.83 mg/m³ of formaldehyde in air, and the swimming activities of medaka was investigated. The fish showed abnormal behavior compared to one under a control treatment, e.g. the body movement distance decreased and the duration time near the upper water column increased significantly. It was verified that it is possible to detect concentrations of formaldehyde of 0.83 mg/m³ in indoor air using this proposed biosensor system.     

Response of consumer and research grade indoor air quality monitors to residential sources of fine particles

The ability to inexpensively monitor PM_2.5 to identify sources and enable controls would advance residential indoor air quality (IAQ) management. Consumer IAQ monitors incorporating low‐cost optical particle sensors and connections with smart home platforms could provide this service if they reliably detect PM_2.5 in homes. In this study, particles from typical residential sources were generated in a 120 m³ laboratory and time‐concentration profiles were measured with 7 consumer monitors (2‐3 units each), 2 research monitors (Thermo pDR‐1500, MetOne BT‐645), a Grimm Mini Wide‐Range Aerosol Spectrometer (GRM), and a Tapered Element Oscillating Microbalance with Filter Dynamic Measurement System (FDMS), a Federal Equivalent Method for PM_2.5. Sources included recreational combustion (candles, cigarettes, incense), cooking activities, an unfiltered ultrasonic humidifier, and dust. FDMS measurements, filter samples, and known densities were used to adjust the GRM to obtain time‐resolved mass concentrations. Data from the research monitors and 4 of the consumer monitors—AirBeam, AirVisual, Foobot, Purple Air—were time correlated and within a factor of 2 of the estimated mass concentrations for most sources. All 7 of the consumer and both research monitors substantially under‐reported or missed events for which the emitted mass was comprised of particles smaller than 0.3 μm diameter.     

Factors controlling volatile organic compounds in dwellings in Melbourne,Australia

This study characterized indoor volatile organic compounds (VOCs) and investigated the effects of the dwelling characteristics, building materials, occupant activities, and environmental conditions on indoor VOC concentrations in 40 dwellings located in Melbourne, Australia, in 2008 and 2009. A total of 97 VOCs were identified. Nine VOCs, n‐butane, 2‐methylbutane, toluene, formaldehyde, acetaldehyde, d‐limonene, ethanol, 2‐propanol, and acetic acid, accounted for 68% of the sum of all VOCs. The median indoor concentrations of all VOCs were greater than those measured outdoors. The occupant density was positively associated with indoor VOC concentrations via occupant activities, including respiration and combustion. Terpenes were associated with the use of household cleaning and laundry products. A petroleum‐like indoor VOC signature of alkanes and aromatics was associated with the proximity of major roads. The indoor VOC concentrations were negatively correlated (P < 0.05) with ventilation. Levels of VOCs in these Australian dwellings were lower than those from previous studies in North America and Europe, probably due to a combination of an ongoing temporal decrease in indoor VOC concentrations and the leakier nature of Australian dwellings.