Mix design of concrete for prestressed concrete sleepers using blast furnace slag and steel fibers

The application of ground granulated blast furnace slag (GGBFS) and steel fibers in prestressed concrete railway sleepers was investigated in this study. The use of GGBFS was considered as an eco-friendly material aimed at reducing CO₂ emissions and energy consumption as well as to enhance the durability performance of railway sleepers. Steel fibers improves the durability and structural performance in terms of crack control and reduction of spalling and can replace shear reinforcement. The mix proportions of the concrete incorporating GGBFS (56% GGBFS) and GGBFS with steel fibers (56% GGBFS and 0.75% steel fibers) were determined through a series laboratory tests and a life cycle assessment. These mixes satisfied the requirements of the Korean Railway Standard and resulted in improved flexural capacity as well as less CO₂ emissions compared with current railway sleepers. Using these mixes, a total of ninety prestressed concrete sleepers were produced in a factory under the same manufacturing process as current railway sleepers, and their mechanical properties as well as durability performance were evaluated. The mix with partial replacement of Type III Portland cement by GGBFS showed an improved resistance to chloride ion penetration and freeze-thaw cycles compared with the concrete used for current railway sleepers. However, these mixes were more vulnerable to carbonation. The mix with GGBFS and steel fibers (mix BSF) showed a slightly better durability performance than the mix with GGBFS only (mix BS), including better carbonation and freeze-thaw resistances. The mix BSF showed decreased chloride ion penetration depth than mix BS but showed a slightly higher chloride ion diffusion coefficient.     

Alkali-silica reaction in concrete containing glass

The use of surplus waste glass in concrete has been avoided on the grounds that it is known to undergo harmful alkali-silica reaction (ASR). As part of a research project to develop draft specifications for glass in concrete, a major ASR testing programme was undertaken to establish appropriate use of glass in concrete which avoided harmful ASR. The British Standard for assessing ASR reactivity of aggregate—BS 812-123—was used. Testing was conducted on concrete mixes containing glass as either fine aggregate, filler aggregate, or as a Type II addition. Glass used as fine aggregate was found to produce significant expansion for both green and amber glass. GGBS and metakaolin had the effect of reducing this expansion considerably. Concrete containing powdered glass displayed much less expansion. A simple schematic model for the alkali-silica reaction of glass, based on glass dissolution mechanisms is proposed, and related to the test results.     

Effect of rice-husk ash on durability of cementitious materials

In this paper the effects of partial replacements of Portland cement by rice-husk ash (RHA) on the durability of conventional and high performance cementitious materials are investigated. Different percentages of RHA replacement levels, two RHAs (amorphous and partially crystalline optimized by dry-milling) and several water–cementitious materials ratio are studied. The following durability aspects were tested: air permeability, chloride ion penetration, alkali-silica expansion, sulfate and acid resistance. The results were compared with those of cementitious materials without RHA. It is concluded from the tested properties that the incorporation of both RHAs in concretes show different behaviors for air permeability and chloride ion penetration depending on the water/cementitious materials ratio used; in mortars, it reduces the mass loss of specimens exposed to hydrochloric acid solution and decreases the expansion due to sulfate attack and the alkali-silica reaction. The results of durability aspects due to physical or pozzolanic effects after the addition of both RHAs, and its chemical composition, in general indicate an enhanced performance, proving the feasibility of its rational utilization as a supplementary cementing material.     

Non-steady-state accelerated chloride penetration resistance of structural lightweight aggregate concrete

This study aims to characterise the chloride penetration resistance of structural lightweight aggregate concrete (LWAC) produced with different types, volumes and initial wetting conditions of lightweight aggregates (LWA), types of cement and contents of fly ash and silica fume, w/c ratios and curing conditions. A comprehensive experimental study was carried out involving three types of non-steady-state tests, which simulate different exposure conditions and penetration mechanisms. It is shown that the chloride penetration resistance is mainly affected by the cementitious paste and that high performance LWAC of 30–70 MPa can be produced. Regardless of the type of aggregate, we propose exponential relations to estimate the diffusion coefficient of chlorides. The volume and initial wetting condition of LWA had little influence on the chloride resistance. A long-term higher reduction of the diffusion coefficient was found in less dense LWAC. Reasonable correlations between the non-steady-state tests were obtained. Contrary to what is suggested in some European standards, the concrete strength cannot properly predict the durability behaviour of LWAC.     

Convolutional Neural Network-Based Regression for Predicting the Chloride Ion Diffusion Coefficient of Concrete

The durability performance of reinforced concrete (RC) building structures is significantly affected by the corrosion of the steel reinforcement due to chloride penetration, thus, the chloride ion diffusion coefficient should be investigated through experiments or theoretical equations to assess the durability of an RC structure. This study aims to predict the chloride ion diffusion coefficient of concrete, a heterogeneous material. A convolutional neural network (CNN)-based regression model that learns the condition of the concrete surface through deep learning, is developed to efficiently obtain the chloride ion diffusion coefficient. For the model implementation to determine the chloride ion diffusion coefficient, concrete mixes with w/c ratios of 0.33, 0.40, 0.46, 0.50, 0.62, and 0.68, are cured for 28 days; subsequently, the surface image data of the specimens are collected. Finally, the proposed model predicts the chloride ion diffusion coefficient using the concrete surface image data and exhibits an error of approximately 1.5E−12 /s. The results suggest the applicability of proposed model to the field of facility maintenance for estimating the chloride ion diffusion coefficient of concrete using images.     

Performance of ground clay brick in ASR-affected concrete: Effects on expansion, mechanical properties and ASR gel chemistry

The effects of ground clay brick (GCB) on alkali-silica reaction (ASR) expansion as well as on mechanical properties of ASR-affected concrete are investigated. Crushed red clay brick originated from demolished masonry was ground in a laboratory ball mill and replaced for portland cement at levels of 15% and 25% by weight in concrete mixes produced with alkali reactive sand. ASR expansion, compressive strength, flexural strength, and modulus of elasticity of the concrete mixes were evaluated. Effect of GCB on ASR gel chemistry was also studied on Pyrex glass-paste specimens using SEM/EDS (scanning electron microscope equipped with energy dispersive X-ray spectroscopy). The results indicate that GCB effectively reduces ASR expansion in concrete: associated cracking and loss on mechanical properties are also significantly reduced. SEM study suggests that GCB alters alkali silica gel chemistry thus resulting in a less expansive product.     

Chemical additives to control expansion of alkali-silica reaction gel: proposed mechanisms of control

Calcium chloride, lithium chloride, and acetone have previously been shown to affect expansion caused by alkali-silica reaction (ASR), a deleterious reaction occurring between reactive siliceous minerals present in some aggregate and the strongly alkaline pore solution in concrete. Here, the effect of these chemical additives was examined by transmission soft X-ray microscopy and a quantitative elemental analysis, using ICP-OES. In examining the effect of calcium chloride on ASR gels, the formation of a calcium silicate product, believed to be non-expansive, was identified by X-ray microscopy. Additionally, the elemental analysis results suggest that the concentration of calcium ions in the pore solution, which is dependent upon the solubility of the chemical additive and the percent addition, relative to the concentration of silica species in solution is an important parameter for effective control of expansion associated with ASR. In examining the effect of lithium chloride, quantitative elemental analysis showed silica dissolution in solutions of 0.7 M NaOH + 0.1 M LiCl, but with silicon present in slightly lower concentrations than in 0.7 M NaOH solutions alone. However, X-ray microscopy showed less evidence of repolymerization of the dissolved silica into an expansive gel in the presence of lithium chloride as compared to the reaction of the ASR gel in alkaline (0.7 M NaOH) solutions without lithium. With acetone, the results, including X-ray images showing the formation of repolymerized gel in 0.7 M NaOH solution containing 10% v/v acetone, indicate that the use of acetone as a chemical additive may not be as effective as once believed in preventing expansion caused by ASR. It is proposed that any reduction in expansion by use of acetone is temporary and diminishes over time.     

超高强水泥基材料的力学及耐久性能

超高强水泥基材料作为一种高性能建筑材料,在建筑工程领域已得到了广泛的关注和应用。简要介绍了超高强水泥基材料的发展历史、制备的基本途径和性能实现的基本原理,并且对近年来国内外学者关于超高强水泥基材料力学性能和耐久性能的研究进展进行了综述。综述内容包括:超高强水泥基材料的抗压强度、抗折强度、弹性模量、泊松比、应力应变曲线,以及超高强水泥基材料的抗渗、抗冻性能和碱骨料反应风险。在对已有文献的综述基础上,简要分析了纤维及养护制度对超高强水泥基材料性能的影响,并提出了超高强水泥基材料工程化的关键措施。     

Doubling the service life of concrete structures. II: Performance of nanoscale viscosity modifiers in mortars

A new approach for increasing the service life of concrete structures is evaluated in a series of mortar specimens. The new approach consists of employing nanoscale viscosity modifiers to increase the viscosity of the concrete pore solution and concurrently and proportionally decrease the diffusion rates of deleterious ions such as chlorides and sulfates. In part I of this series, viscosities of bulk solutions of the admixtures in water and electrical conductivities of admixture solutions also containing potassium chloride were examined to verify the viability of this new technology. In the current paper, these studies are extended to quantifying the performance of one of these admixtures in mortars by measuring the penetration depth of chloride ions in cylindrical specimens exposed to a 1 mol/L chloride ion solution for up to 1 year. While significant reductions in the 1 year penetration depth are produced when the viscosity modifier is utilized via conventional addition to the mixing water, the best performance is achieved when a solution of the viscosity modifier is utilized to pre-wet fine lightweight aggregates that are then added to the mortar mixture. A scaling function appropriate for radial diffusion was used to estimate the relative effective diffusion coefficients. Compared to a reference mortar, the best mixture reduced the effective diffusion coefficient by a factor of 2.7, consistent with the overall objective of doubling concrete service life.     

Benefits of internal curing on service life and life-cycle cost of high-performance concrete bridge decks – A case study

This paper investigates the impact of internal curing on the service life of high-performance concrete (HPC) bridge decks by using analytical models to predict the times to onset of corrosion, onset of corrosion-induced damage, and failure of decks. Three bridge deck design options were compared: (i) normal concrete deck; (ii) HPC deck with supplementary cementing materials (SCM); and (iii) HPC deck with SCM and internal curing. It was found that the use of internal curing can extend the service life of high-performance concrete bridge decks by more than 20 years, which is mainly due to a significant reduction in the rate of penetration of chlorides in concrete as a result of reduced early-age shrinkage cracking and reduced chloride diffusion. Compared to normal concrete, HPC with SCM and internal curing was predicted to add more than 40 years to the service life of bridge decks in severe environmental conditions. Life-cycle cost reductions of 40% and 63% were estimated when conventional HPC and internally-cured HPC were used in bridge decks instead of normal concrete, respectively, despite the fact that the in-place unit cost of internally-cured HPC can be 4% higher than that of conventionally-cured HPC, which in turn can be up to 33% higher than that of normal concrete. This is due to a longer service life and less frequent maintenance activities offered by low-permeability HPC bridge decks.     

Study of reinforced concrete slabs after three years of cathodic protection under severe conditions

The objective of this study is to determine the influence of cathodic protection on the properties of concrete cover in concrete slabs. To accelerate deterioration, the slabs were subjected to freezing and thawing cycles and sprayed with sodium chloride solution. Cathodic protection was applied to the reinforcements for three years. Then, the test pieces underwent physico-chemical analysis. Scanning electron microscopy and X-ray spectrometry were used to study the reinforcement-concrete interface, in particular for detecting alkali-silica reaction due to the alkalization. Carbonation depths, chloride penetration profiles and examinations of the reinforcements showed the good condition of the concrete cover and the beneficial effect of the cathodic protection of embedded steel.     

The effect of meta-halloysite on alkali–aggregate reaction in concrete

Damage to concrete structures may occur as a result of internal effects. Alkali silica reaction (ASR) is a long term reaction between alkalis and reactive aggregate present in the concrete. The reaction product is sodium–potasium–calcium silica gel, able to absorb water, resulting in the expansion and cracking of concrete. The key problem is to find the right method for mitigating the internal damage. This paper presents the results of an investigation into the effectiveness of calcined halloysite (meta-halloysite) in improving the resistance to alkali-silica reaction (ASR). The pozzolanic reactivity of meta-halloysite was also evaluated using Thermo-Gravimetric Analysis. Microstructures of mortar bars were observed by Scanning Electron Microscopy coupled with Energy Dispersive X-ray Spectroscopy (EDS) to investigate the location and chemical composition of ASR gel. The results from this study showed satisfactory level of pozzolanic reactivity when cement was partially replaced by meta-halloysite. It was demonstrated that a 20% addition of meta-halloysite are able to mitigate ASR and lower expansion of mortar bars with reactive aggregate to a safe level of not more than 0.1% at 14 days. Microstructural observations of the specimens containing meta-halloysite indicated the presence of a calcium–alkali–silicate–hydrate gel. But fewer reaction products and with different composition than those forming in the pastes without mineral additives are present.     

Chloride diffusion in concrete containing nano-TiO2 under coupled effect of scouring

The advantage of concrete containing nano-TiO₂ in resisting the coupled effects of chloride diffusion and scouring with respect to pure concrete was studied in this paper. Because of the movement in exposed concrete surface induced by scouring and the deterioration in concrete microstructure caused by chloride salt accumulation, an increasing mutual accelerative effect between the chloride diffusion and the scouring abrasion was experimental observed, which agreed with the theoretical simulation results. Benefited from the improvement in microstructure and porosity compared with the pure concrete, concrete containing 1% nano-TiO₂ in the weight of cement showed a better impermeability as well as the abradability. Correspondingly, a better performance in resisting the coupled effects of chloride diffusion and scouring was founded for the concrete containing nano-TiO₂ compared to the pure concrete, and this advantage increased upon the time.     

Effect of ground fly ash and ground bagasse ash on the durability of recycled aggregate concrete

This research aims to study the effect of ground fly ash (GFA) and ground bagasse ash (GBA) on the durability of recycled aggregate concrete. Recycled aggregate concrete was produced with recycled aggregate to fully replace crushed limestone in the mix proportion of conventional concrete (CON) and GFA and GBA were used to partially replace Portland cement type I at the rate of 20%, 35%, and 50% by weight of binder. Compressive strength, water permeability, chloride penetration depth, and expansion by sulfate attack on concretes were investigated.The results reveal that the use of GFA and GBA to partially replace cement in recycled aggregate concrete was highly effective in improving the durability of recycled aggregate concrete. The suitable replacement of GFA or GBA in recycled aggregate concrete to obtain the suitable compressive strength, low water permeability, high chloride penetration resistance, and high sulfate resistance is 20% by weight of binder.     

Use of natural zeolite as a supplementary cementitious material

Natural zeolite, a type of frame-structured hydrated aluminosilicate mineral, is used abundantly as a type of natural pozzolanic material in some regions of the world. In this work, the effectiveness of a locally quarried zeolite in enhancing mechanical and durability properties of concrete is evaluated and is also compared with other pozzolanic admixtures. The experimental tests included three parts: In the first part, the pozzolanic reactivity of natural zeolite and silica fume were examined by a thermogravimetric method. In this case, the results indicated that natural zeolite was not as reactive as silica fume but it showed a good pozzolanic reactivity. In the second part, zeolite and silica fume were substituted for cement in different proportions in concrete mixtures, and several physical and durability tests of concrete were performed. These experimental tests included slump, compressive strength, water absorption, oxygen permeability, chloride diffusion, and electrical resistivity of concrete. Based on these results, the performance of concretes containing different contents of zeolite improved and even were comparable to or better than that of concretes prepared with silica fume replacements in some cases. Finally, a comparative study on effect of zeolite and fly ash on limiting ASR expansion of mortar was performed according to ASTM C 1260 and ASTM C 1567. Expansion tests on mortar prisms showed that zeolite is as effective as fly ash to prevent deleterious expansion due to ASR.     

Exploitation of poor Greek kaolins: Durability of metakaolin concrete

In this paper the effect of metakaolin on concrete durability is investigated. A Greek kaolin of low kaolinite content was thermally treated at defined conditions and the produced metakaolin was finely ground. In addition, a commercial metakaolin of high purity was used. Eight mixture proportions were used to produce high performance concrete, where metakaolin replaced either cement or sand in percentages 10% or 20% by weight of the control cement content. Durability of metakaolin concrete was evaluated by means of resistance to chloride penetration, air permeability, sorptivity, porosity and pore size distribution. Metakaolin concrete exhibits significantly lower chloride permeability, gas permeability and sorptivity. The addition of metakaolin refines the pore system of concrete, leading to a decreased mean pore size and improved uniformity of the pore size distribution. The produced metakaolin, derived from the poor Greek kaolin, imparts similar behavior to that of the commercial metakaolin, with respect to the concrete durability.     

Alkali-silica reactivity criteria for concrete aggregates

In this study, the suitability of the threshold alkali level, TAL, the kinetic parameter, In k, and the microstructural disorder coefficient, Cd, of the aggregates, taken as alkali-silica reactivity criteria, was assessed using different typologies of Italian natural ASR-susceptible aggregates of known field performance. The TAL, In k, and Cd were determined using a modified version of the RILEM AAR-3 concrete prism expansion test, the ASTM C1260 mortar-bar expansion test, and the infrared spectroscopy test, respectively. It was found that the three reactivity criteria are all appropriate for discriminating between reactive and innocuous aggregates. However, the TAL proves to be a more suitable criterion for interpreting the field performance data of the aggregates investigated. There exists a linear relationship between TAL and In k, or between TAL and Cd, which provides a rapid means of estimating the threshold alkali levels of ASR-susceptible aggregates from the results of the ultra-accelerated mortar-bar test and/or the infrared spectroscopy test. A TAL-based classification of the degree of reactivity of the aggregates, as well as some modifications of the reactivity domains established by the infrared spectroscopy method are also proposed.     

再生粗骨料硅烷浸渍处理对混凝土介质传输性能的影响

由于残余砂浆的存在,再生粗骨料的物理力学指标远不及天然骨料,致使再生混凝土力学和耐久性能较差;此外,水分及有害离子侵入混凝土内部是引起混凝土材料性能劣化的主要原因。本试验用质量分数为8wt%的硅烷乳液浸渍强化再生粗骨料,通过抗压强度、毛细吸水和抗氯离子侵蚀试验对硅烷浸渍前后不同骨料质量取代率(0%、30%、50%)的再生混凝土介质传输性能进行了研究,最后利用SEM对再生混凝土内部的微观结构进行分析。试验结果表明,硅烷浸渍处理再生粗骨料的吸水率显著降低,由其制备的混凝土强度稍有所下降;再生混凝土毛细累积吸水量明显减少,且抗氯盐侵蚀性能显著提高,其中骨料质量取代率为50%的再生混凝土浸渍处理后氯离子扩散系数降低了37.5%。研究表明,硅烷浸渍处理再生粗骨料是提高再生混凝土耐久性的有效途径。      

A modified colorimetric method to determine the chloride profile from the ponding test

The ponding test has been used in recent years to evaluate the durability of concrete. However, the process of collecting the powder from various depths for the chloride analysis is difficult and exhausting. This paper presents a simplified procedure for measuring the chloride diffusion coefficient of concrete and the chloride profile using the modified colorimetric method (MCM). The MCM uses a depth of penetration approach and the surface chloride content to determine the chloride profile. The depth of penetration of chloride at 0.01% concentration is obtained from the colorimetric penetration depth by using regression analysis. The results show that the chloride diffusion coefficients and the profiles obtained from the MCM are very close to those yielded by conventional ponding. The MCM is a rapid and accurate method to determine the chloride profile of concrete during ponding tests.     

Compressive strength and durability properties of ceramic wastes based concrete

This paper presents an experimental study on the properties and on the durability of concrete containing ceramic wastes. Several concrete mixes possessing a target mean compressive strength of 30 MPa were prepared with 20% cement replacement by ceramic powder (W/B = 0.6). A concrete mix with ceramic sand and granite aggregates were also prepared as well as a concrete mix with natural sand and coarse ceramic aggregates (W/B = 0.5). The mechanical and durability performance of ceramic waste based concrete are assessed by means of mechanical tests, water performance, permeability, chloride diffusion and also accelerated aging tests. Results show that concrete with partial cement replacement by ceramic powder although it has minor strength loss possess increase durability performance. Results also shows that concrete mixtures with ceramic aggregates perform better than the control concrete mixtures concerning compressive strength, capillarity water absorption, oxygen permeability and chloride diffusion. The replacement of cement and aggregates in concrete by ceramic wastes will have major environmental benefits.