Study of a novel silica gel–water adsorption chiller. Part I. Design and performance prediction

A novel silica gel–water adsorption chiller is designed and its performance is predicted in this work. This adsorption chiller includes three vacuum chambers: two adsorption/desorption (or evaporation/condensation) vacuum chambers and one heat pipe working vacuum chamber as the evaporator. One adsorber, one condenser and one evaporator are housed in the same chamber to constitute an adsorption/desorption unit. The evaporators of two adsorption/desorption units are combined together by a heat-pipe heat exchanger to make continuous refrigerating capacity. In this chiller, a vacuum valve is installed between the two adsorption/desorption vacuum chambers to increase its performance especially when the chiller is driven by a low temperature heat source. The operating reliability of the chiller rises greatly because of using fewer valves. Furthermore, the performance of the chiller is predicted. The simulated results show that the refrigerating capacity is more than 10 kW under a typical working condition with hot water temperature of 85 °C, the cooling water temperature of 31 °C and the chilled water inlet temperature of 15 °C. The COP exceeds 0.5 even under a heat source temperature of 65 °C.     

Waste heat driven dual-mode, multi-stage, multi-bed regenerative adsorption system

Over the past few decades there have been considerable efforts to use adsorption (solid/vapor) for cooling and heat pump applications, but intensified efforts were initiated only since the imposition of international restrictions on the production and utilization of CFCs and HCFCs. In this paper, a dual-mode silica gel–water adsorption chiller design is outlined along with the performance evaluation of the innovative chiller. This adsorption chiller utilizes effectively low-temperature solar or waste heat sources of temperature between 40 and 95 °C. Two operation modes are possible for the advanced chiller. The first operation mode will be to work as a highly efficient conventional chiller where the driving source temperature is between 60 and 95 °C. The second operation mode will be to work as an advanced three-stage adsorption chiller where the available driving source temperature is very low (between 40 and 60 °C). With this very low driving source temperature in combination with a coolant at 30 °C, no other cycle except an advanced adsorption cycle with staged regeneration will be operational. The drawback of this operational mode is its poor efficiency in terms of cooling capacity and COP. Simulation results show that the optimum COP values are obtained at driving source temperatures between 50 and 55 °C in three-stage mode, and between 80 and 85 °C in single-stage, multi-bed mode.     

Experimental investigation of a novel multifunction heat pipe solid sorption icemaker for fishing boats using CaCl2/activated carbon compound–ammonia

The performance of a solid sorption icemaker is investigated. CaCl₂/activated carbon was used as compound adsorbent and ammonia was employed as adsorbate. The influence of operating conditions (cooling water temperature, mass recovery and heat pipe heat recovery, etc.) on the mass of ice, SCP (specific cooling power) and COP (coefficient of performance) was experimentally assessed. At the desorption temperature of 126 °C, cooling water temperature of 22 °C, ice produced temperature of −7.5 °C, 40 s of mass recovery and 2 min of heat pipe heat recovery, the mass of ice, SCP and COP values are 17.6 kg/h, 369.1 W/kg and 0.2, respectively.     

Study of a novel silica gel–water adsorption chiller. Part II. Experimental study

The prototype of a novel silica gel–water adsorption chiller is built and its performance is tested in detail. The experimental results show that the refrigerating capacity (RC) and COP of the chiller are 7.15 and 0.38 kW, respectively, when the hot water temperature is 84.8 °C, the cooling water temperature is 30.6 °C, and the chilled water outlet temperature is 11.7 °C. The RC will reach 6 kW under the condition of 65 °C hot water temperature, 30.5 °C cooling water temperature and 17.6 °C chilled water temperature. The results confirm that this kind of adsorption chiller is an effective refrigerating machine though its performance is not as fine as the prediction results. Also it is well effectively driven by a low-grade heat source. Therefore, its applications to the low-grade heat source are much attractive.     

Hybrid absorption heat pump with ammonia/water mixture – Some design guidelines and district heating application

An ammonia/water mixture can be used as an efficient working fluid in industrial-type heat recovery heat pumps and heat transformers. Several configurations of such systems are possible depending on the availability of the waste (thermal) and primary (thermal or electrical) energy sources. This article presents the configurations, the main thermodynamic and hydraulic parameters, and some design guidelines and operating experiences of a medium-temperature, ammonia/water-based compression/re-sorption heat recovery system for district domestic hot water production. In-field experiments have proven the advantages of the concept and its applicability limits in a particular economical environment, while hot water was produced at 55 °C with industrial cooling water at 36 °C as a waste heat source.     

A theoretical study of a novel regenerative ejector refrigeration cycle

There has been a demand for developments of the ejector refrigeration systems using low grade thermal energy, such as solar energy and waste heat. In this paper, a novel regenerative ejector refrigeration cycle was described, which uses an auxiliary jet pump and a conventional regenerator to enhance the performance of the novel cycle. The theoretical analysis on the performance characteristics was carried out for the novel cycle with the refrigerant R141b. Compared with the conventional cycle, the simulation results show that the coefficient of performance (COP) of the novel cycle increases, respectively, by from 9.3 to 12.1% when generating temperature is in a range of 80–160 °C, the condensing temperature is in a range of 35–45 °C and the evaporating temperature is fixed at 10 °C. Especially due to the enhanced regeneration with increasing the pump outlet pressure, the improvement of COP of the novel cycle is approached to 17.8% compared with that in the conventional cycle under the operating condition that generating temperature is 100 °C, condensing temperature is 40 °C and evaporating temperature is 10 °C. Therefore, the characteristics of the novel cycle performance show its promise in using low grade thermal energy for the ejector refrigeration system.     

Performance evaluation of a two-stage adsorption refrigeration cycle with different mass ratio

The performance of a two-stage adsorption chiller with different mass allocation between upper and bottom beds has been investigated numerically. It is found that the chiller can be driven effectively by the waste heat of temperature 55 °C with the heat sink at environment temperature. Results show that cooling capacity can be improved with the optimum allocation of adsorbent mass to the bottom beds than that to the upper beds. The improvement in Coefficient of Performance (COP) values, however, is less significant. It is also seen that the improvement in cooling capacity is more significant for the relatively higher heat source temperature. It is shown that the cooling capacity can be improved up to 20% if the heat source temperature is 80 °C and the average outlet temperature is fixed at 7 °C.     

A year-round dynamic simulation of a solar-driven ejector refrigeration system with iso-butane as a refrigerant

In this paper, the performance of the solar-driven ejector refrigeration system with iso-butane (R600a) as the refrigerant is studied. The effects that both the operating conditions and the solar collector types have on the system's performance are also examined by dynamic simulation. The TRNSYS and EES simulation tools are used to model and analyze the performance of a solar-driven ejector refrigeration system. The whole system is modelled under the TRNSYS environment, but the model of the ejector refrigeration subsystem is developed in the Engineering Equations Solver (EES) program. A solar fraction of 75% is obtained when using the evacuated tube solar collector. In the very hot environment, the system requires relatively high generator temperature, thus a flat plate solar collector is not economically competitive because the high amount of auxiliary heat needed to boost up the generator temperature. The results from the simulation indicate that an efficient ejector system can only work in a region with decent solar radiation and where a sufficiently low condenser temperature can be kept. The average yearly system thermal ratio (STR) is about 0.22, the COP of the cooling subsystem is about 0.48, and the solar collector efficiency is about 0.47 at T_e 15 °C, T_c 5 °C above the ambient temperature, evacuated collector area 50 m² and hot storage tank volume 2 m³.     

Study on an activated carbon fiber–ethanol adsorption chiller: Part I – system description and modelling

This article presents the transient modelling for a two-bed, activated carbon fiber (ACF)–ethanol adsorption chiller. This innovative adsorption chiller employs pitch based ACF of type A-20 as adsorbent which is a fibrous adsorbent having the advantages of fast adsorption rate, high porosity and ease of handling when compared with granular adsorbents and powdered adsorbents. Ethanol is used as refrigerant as it has no harm to environment, it is a non-toxic substance, moreover, ethanol has comparatively higher vapor pressure even at low temperature. This innovative system utilizes effectively low-temperature waste heat sources of temperature between 60 and 95 °C along with a coolant at 30 °C. We have found that, regardless of the initial mass distribution, the ACF–ethanol adsorption chiller is able to achieve the same cyclic-steady-state within three cycles or 1890 s.     

Experimental study on a continuous adsorption water chiller with novel design

A newly developed adsorption water chiller is introduced and tested. In the new adsorption refrigeration system, there are no refrigerant valves, the problem of mass transfer resistance resulting in pressure drop along refrigerant passage in conventional systems when methanol or water is used as refrigerant can be absolutely solved. Silica-gel–water is used as working pair and mass recovery-like process is adopted in order to use low temperature heat source ranging from 70 to 85 °C effectively. The experiment results demonstrate that the chiller (26.4 kg silica-gel in each adsorber) has a cooling capacity of 2–7.3 kW and COP ranging 0.2–0.42 according to different evaporating temperatures. Based on the experimental tests of the first prototype, the second prototype is designed and tested; the experimental data demonstrate that the chiller performance has been greatly improved, with a heat source temperature of 80 °C, a COP over 0.5 and cooling capacity of 9 kW has been achieved at evaporating temperature of 13 °C.     

Experimental investigation of silica gel–water adsorption chillers with and without a passive heat recovery scheme

We experimentally show that for the same heat exchanger inventory allocation, a four-bed adsorption chiller delivers a 12% higher ultimate cooling capacity than its two-bed counterpart. In addition it delivers a significantly improved quality of instantaneous cooling than a two-bed chiller at the same cooling capacity. The COP-enhancing feature of a passive heat recovery scheme that does not involve additional pumping action or valves is experimentally proven. It improves the COPs of a two-bed chiller and a four-bed chiller by as much as 38 and 25%, respectively, without any effect on their cooling capacities. The highest COPs achieved with a two-bed and four-bed chillers are 0.46±0.02 and 0.45±0.02, respectively. These are measured at a hot-water inlet temperature of 85 °C, cooling-water inlet temperature of 29.4 °C and chilled-water inlet temperature of 12.2 °C.     

A novel experimental investigation of a solar cooling system in Madrid

This paper reports novel experimental results derived through field testing of a part load solar energized cooling system for typical Spanish houses in Madrid during the summer period of 2003. Solar hot water was delivered by means of a 49.9 m² array of flat-plate collectors to drive a single-effect (LiBr/H₂O) absorption chiller of 35 kW nominal cooling capacity. Thermal energy was stored in a 2 m³ stratified hot water storage tank during hours of bright sunshine. Chilled water produced at the evaporator was supplied to a row of fan coil units and the heat of condensation and absorption was rejected by means of a forced draft cooling tower. Instantaneous, daily and period energy flows and energy balance in the installation is presented. System and absorption machine temperature profiles are given for a clear, hot and dry day's operation. Daily and period system efficiencies are given. Peak insolation of 969 W m⁻² (at 12:30 solar time on 08/08/03) produced 5.13 kW of cooling at a solar to cooling conversion efficiency of 11%. Maximum cooling capacity was 7.5 kW. Cooling was provided for 8.67 h and the chiller required a threshold insolation of 711 W m⁻² for start-up and 373 W m⁻² for shut-down. A minimum hot water inlet temperature to the generator of 65 °C was required to commence cold generation, whereas at 81 °C, 6.4 kW of cooling (18.3% of nominal capacity) was produced. The absorption refrigeration machine operated within the generation and absorption temperature ranges of 57–67 and 32–36 °C, respectively. The measured maximum instantaneous, daily average and period average COP were 0.60 (at maximum capacity), 0.42 and 0.34, respectively. Energy flows in the system are represented on a novel area diagram. The results clearly demonstrate that the technology works best in dry and hot climatic conditions where large daily variations in relative humidity and dry bulb temperature prevail. This case study provides benchmark data for the assessment of other similar prototypes and for the validation of mathematical models.     

The natural fluid nitrous oxide—an option as substitute for low temperature synthetic refrigerants

A theoretical investigation was performed concerning the coefficient of performance (COP) of cascade refrigerating systems using N₂O as refrigerant for the low temperature cascade stage and various natural refrigerants like ammonia, propane, propene, carbon dioxide and nitrous oxide itself for the high temperature stage. The basis of the comparison was a conventional R23/R134a-cascade refrigerating system for heat rejection temperatures of +55, +35 and +25 °C for air cooling, cooling tower water cooling and city water cooling, respectively. It can be stated that such an application of N₂O at the primary stage and ammonia or hydrocarbons as refrigerants at the secondary stage in refrigerating systems achieves similar COP-values compared to the R23/R134a-cascade refrigerating system, whereas CO₂ and N₂O in a transcritical cycle in general perform worse.An application of N₂O in a two-stage compression cycle with interstage injection and city water cooling at low and high interstage temperatures has a nearly equal COP as a conventional R23/R134a-cascade refrigerating system and is an interesting alternative for small laboratory refrigerating systems.     

Microchannel heat exchangers for charge minimization in air-cooled ammonia condensers and chillers

This paper presents experimental results from a prototype ammonia chiller with an air-cooled condenser and a plate evaporator. The main objectives were charge reduction and compactness of the system. The charge is reduced to 20 g/kW (2.5 oz/Ton). This is lower than any currently available air-cooled ammonia chiller on the market. The major contribution comes from use of microchannel aluminum tubes. Two aluminum condensers were evaluated in the chiller: one with a parallel tube arrangement between headers and “microchannel” tubes (hydraulic diameter D_h = 0.7 mm), and the other with a single serpentine “macrochannel” tube (D_h = 4.06 mm). The performances of the chiller and condensers are compared based on various criteria to other available ammonia chillers. This prototype was made and examined in the Air Conditioning and Refrigeration Center in 1998, at the University of Illinois at Urbana-Champaign.     

Forced convection adsorption cycle with packed bed heat regeneration: Cycle à adsorption à convection forcée avec régénération thermique du lit fixe

The convective thermal wave is part of a patented cycle which uses heat transfer intensification to achieve both high efficiency and small size from a solid adsorption cycle. Such cycles normally suffer from low power density because of poor heat transfer through the adsorbent bed. Rather than attempting to heat the bed directly, it is possible to heat the refrigerant gas outside the bed and to circulate it through the bed in order to heat the sorbent. The high surface area of the grains leads to very effective heat transfer with only low levels of parasitic power needed for pumping. The new cycle presented here also utilises a packed bed of inert material to store heat between the adsorption and desorption phases of the cycle. The high degree of regeneration possible leads to good coefficients of performance (COPs). Thermodynamic modelling, based on measured heat transfer data, predicts a COP (for a specific carbon) of 0.90 when evaporating at 5°C and condensing at 40°C, with a generating temperature of 200°C and a modest system regenerator effectiveness of 0.8. Further improvement is possible. Experimental heat transfer measurements and cycle simulations are presented which show the potential of the concept to provide the basis of a gas-fired air conditioner in the range 10–100 kW cooling. A research project to build a 10-kW water chiller is underway. The laboratory system, which should be operational by June 1997, is described.     

Thermostatic valve control using a non-azeotropic refrigerant, isobutane/propane mixtureRégulation d'un détendeur thermostatique utilisant un mélange d'isobutane et de propane comme frigorigène non azéotropique

This article describes the evaluation and comparison of a conventional R12 cross-charged thermostatic valve and an electronic expansion valve using a non-azeotropic refrigerant mixture (NARM); isobutane/propane mixture (CARE30). The superheat temperature setting on an expansion valve needs to compensate for the temperature glide associated with a non-azeotropic refrigerant as these can be of similar magnitude. It is also advisable to increase the superheat setting to make allowance for change in refrigerant composition as a result of preferential refrigerant/oil solubility. The majority of refrigeration systems operate at fixed evaporating temperatures, hence, once superheat setting is trimmed during commissioning, then there should be no further problems associated with evaporation of a non-azeotropic refrigerant provided the system is leak-tight. An R12 expansion valve with a factory superheat setting of 5°C tested over a wide range of evaporating temperatures proved satisfactory in operation with CARE30 after increasing the superheat temperature screw setting equivalent to 5°C.     

A minichannel aluminium tube heat exchanger – Part III: Condenser performance with propane

This paper reports heat transfer results obtained during condensation of refrigerant propane inside a minichannel aluminium heat exchanger vertically mounted in an experimental setup simulating a water-to-water heat pump. The condenser was constructed of multiport minichannel aluminium tubes assembled as a shell-and-tube heat exchanger. Propane vapour entered the condenser tubes via the top end and exited sub-cooled from the bottom. Coolant water flowed upward on the shell-side. The heat transfer areas of the tube-side and the shell-side of the condenser were 0.941 m² and 0.985 m², respectively. The heat transfer rate between the two fluids was controlled by varying the evaporation temperature while the condensation temperature was fixed. The applied heat transfer rate was within 3900–9500 W for all tests. Experiments were performed at constant condensing temperatures of 30 °C, 40 °C and 50 °C, respectively. The cooling water flow rate was maintained at 11.90 l min⁻¹ for all tests. De-superheating length, two-phase length, sub-cooling length, local heat transfer coefficients and average heat transfer coefficients of the condenser were calculated. The experimental heat transfer coefficients were compared with predictions from correlations found in the literature. The experimental heat transfer coefficients in the different regions were higher than those predicted by the available correlations.     

Split heat pipe type compound adsorption ice making test unit for fishing boats

In order to settle the problem of the corrosion between sea water and the steel adsorber for ammonia system, a split heat pipe type adsorption ice making test unit, which use compound adsorbent of CaCl₂ and activated carbon to improve the adsorption performance, is designed and constructed. For this test unit there is mass recovery function between two beds and the CaCl₂ in compound adsorbent per bed is 1.88 kg, and there is only one pump for the whole heating and cooling phase for adsorbers. Performances of this system are tested; the lowest evaporating temperature is as low as −42 °C. At the evaporating temperature of −35 and −25 °C, the cooling powers are 0.89 and 1.18 kW, respectively. At the evaporating temperature of −15 °C, its average cooling power is 1.37 kW, which corresponds coefficient of performance of refrigeration COP=0.41 and specific cooling power per kilogram CaCl₂ of each adsorber SCP=731 W kg⁻¹. The mass recovery process has improved SCP and COP for the system by 15.5 and 24.1%, respectively. Heat transfer performance is also improved by the split heat pipe construction; the average heat transfer coefficient for a whole cycle is 155.8 W m⁻² °C⁻¹.     

Thermodynamic limits to thermal regeneration in adsorption cooling cycles

Energy and exergy models for ideal adsorption cycles with isothermal beds and no mass recovery are developed to predict the limits to COP enhancement using thermal regeneration. The models are applied to compare the performance of zeolite–water and silica gel–water adsorbent–refrigerant pairs over a range of maximum bed temperatures. The thermodynamic consistencies of several alternate adsorption property assumptions are quantified. Differences in adsorption characteristics between zeolite–water and silica gel–water result in a significantly larger potential to enhance COP by implementing thermal regeneration for zeolite–water. Based on COP, the zeolite–water pair is preferred when both thermal regeneration and a high temperature thermal energy source (>150 °C) are used, while the silica gel–water pair is preferred when thermal regeneration is not used and/or a low temperature thermal energy source (<100 °C) is used.