我国热作模具钢性能数据集（续Ⅱ）

(2 )　 5Cr Mn Mo Si V钢5Cr Mn Mo Si V钢是无镍多元合金化热锻模钢 ,它在 4Cr Mn Mo Si V钢的基础上增加碳的含量 ,和含有少量钒所以比 5Cr Ni Mo钢具有更好的淬透性和强韧性 ,在 40 0 mm× 40 0 mm截面上可以完全淬透。与5Cr Ni Mo钢相比热疲劳性能几乎相当 ,除可切削性和高温伸长率较低及锻造变形抗力较高外 ,其冲击韧性和断裂韧性、高温强度、抗回火稳定性、热磨损性和抗氧化能力都有较大的提高。如要获得同样硬度其回火温度比 5Cr Ni Mo钢约高 1 0 0°C。适宜制作大型复杂的重载锤锻模。但是此钢的热强性和耐磨性同样不如高…     

Ni对0Cr16Ni4Mo钢组织与性能的影响

调整Ni元素在0Cr16Ni4Mo钢锭中的含量,采用力学性能测试及光学显微镜进行微观组织分析,研究不同Ni元素含量对0Cr16Ni4Mo马氏体不锈钢组织与性能的影响。实验结果表明:当Ni元素含量达到5.3%时,0Cr16Ni4Mo钢的屈服强度和抗拉强度优于Ni含量较少的坯料;当Ni元素含量达到5.3%时,热处理后钢的微观组织的主体为板条马氏体,铁素体几乎不存在;冲击试验结果表明,随着Ni元素的提高,材料微观组织中的铁素体数量得到一定程度的控制,有利于材料冲击韧性的提升。     

柽柳挥发油成分及无机元素的GC/M

采用GC/MS方法分析鉴定了用索氏提取法获得的柽柳挥发油中的26种成分,占挥发油总量的91.0%。4种主要成分为十六酸甲脂(29.20%)、十八碳二烯酸(20.88%)、9-十八碳烯酸甲酯(12.31%)和β-维生素E(7.65%),占挥发油的70.0%。采用ICP-MS法测定了微波消解法得到的柽柳无机元素样品中的无机元素成分,共检出27个元素,元素含量高低顺序为:K、Na、Ca、Mg、P、Ce、Fe、Al、La、B、Zn、Ni、Cu、Cr、Ga、Mn、V、Se、Ba、Pb、Sr、Mo、As、Th、Co、Cd、Hg,微量元素Ce、Fe、Zn、Ni、Cr含量较高。     

Mn含量对耐海水腐蚀不锈钢组织与性能的影响

借助XRD、SEM等研究了0%~0.6%的Mn对00Cr20Ni18Mo6V0.8Si 0.1耐海水腐蚀不锈试验钢力学性能的影响。结果表明:当Mn为0.2%时,抗拉强度(σb)最大为583MPa;延伸率(δ)最大为23.3%,硬度随Mn含量的增高也略微上升,但变化不是很明显。     

模具表面改性渗层组织性能研究

从模具钢、热加工工艺与表面处理组织性能的相互关系出发,选用5种材料,分别进行QPQ盐浴氮化和TD法盐浴渗钒,借助Olympus CMM55Z光学金相显微镜和宝棱显微硬度计等设备,研究材料渗层组织性能和显微硬度分布梯度,分析探讨模具的使用性能。结果表明:盐浴氮化中,Cr12MoV的耐磨性和抗冲击性能最突出,45Cr4Ni MoV的韧塑性和抗冲击性能优于W18Cr4V,42Cr Mo的综合性能最弱;盐浴渗钒中,160CrNi Mo覆层厚13μm,远高于其他试验材料,但中碳合金钢覆层效果不佳,为兼顾模具耐磨性、韧塑性和抗冲击性,宜选用中碳合金钢而非高碳合金钢进行渗碳、TD处理和后续热处理,这对提高模具使用寿命有重要价值。     

低层错能FeMnSiCrCu形状记忆合金的空蚀

对低层措能Fe—26Mn—6Si—7Cr—lCu形状记忆合金和0Crl3Ni5Mo不锈钢进行了空蚀试验。结果表明，Fe—26Mn—6Si—7Cr—lCu形状记忆合金杭空蚀性能优于0Crl3Ni5Mo不锈钢。空蚀过程中应变诱发马氏体转变是该形状记忆合金具有良好杭空蚀性能的主要原因。     

Cr20Mn10Ni4Si3N钢的ESCA和AES研究

用x光电子能谱(ESCA)和俄歇电子能谱(AES)结合氩离子轰击刻蚀技术来获得抗唆合不锈钢Cr20Mn10Ni4Si3N的组成元素在表层的随深度分布情况,并描述了Si、Mn、Ni、Cr、Fe、O、C等组成元素的表面化学状态;与普通使用的不锈钢1Cr18Ni9Ti作了比较。元素Mn在表层相当厚的深度范围内呈氧化物形态,在富氧层中富集,很可能由此对材料的抗唆性作出了贡献。观察到表面Cr的价电子密度下降及Cr LMM Auger峰的双峰结构,能量间隔约5eV;表层Cr原子的外壳层电子态也许经历了一个轨道杂化再分布过程,使得其抗氧化能力有所降低。添加Mo及进一步添加Si使表面富氧层变薄,对提高钢的耐蚀作用是有益的。     

Minipal4便携X射线荧光光谱仪现场快速测定水系沉积物中多种元素

直接使用粉末样品,用Minipal 4便携式能量色散X射线荧光光谱仪现场测定水系成积物样品中的Cu、Zn、AS、Ba、Ni、Co、Mo、Mn等元素,方法简便、快速,把采到的样品再送到实验室内进行测量,两者的分析结果基本符合;精密度试验结果,除Mo以外,各组分的RSD(n=12)均小于5%,能满足矿山和野外现场快速测定的要求。     

硬质合金刀具车削Cr12Mn5Ni4Mo3Al不锈钢的试验研究

使用硬质合金刀具YW2进行Cr12Mn5Ni4Mo3Al不锈钢的干车削试验。分析了切削速度对车削力及表面粗糙度的影响,并采用扫描电子显微镜(SEM)观察刀具的磨损形貌。研究结果表明:使用硬质合金刀具YW2干车削Cr12Mn5Ni4Mo3Al不锈钢时,在小进给量和小背吃刀量切削的条件下,车削三向力的大小顺序为:径向力轴向力切向力;受积屑瘤的影响,表面粗糙度呈现出随车削速度的变化先减小后增大的变化趋势;硬质合金刀具后刀面磨损较轻微,而沿刀尖周围出现了较严重的粘结现象,前刀面上出现了较严重的划痕现象,低速时,前刀面还出现了贝壳状的剥落现象。     

我国热作模具钢性能数据集(续XⅢ)

(14)5Cr4Mo3SiMnVAl钢(012Al) 5Cr4Mo3SiMnVAl钢系属基体钢,是一种空冷硬化型的热作和冷作模具兼容的钢种,已列入GB1299标准.该钢也是在4Cr3Mo3V钢的基础上重新调整合金元素,添加Si、Mn、Al等元素进一步合金化.与3Cr2W8V钢相比不含钨,但钼、铬、锰、钒、硅及铝的含量明显提高.     

Wear Mechanism of Cemented Carbide Tool in High Speed Milling of Stainless Steel

Adhesion of cutting tool and chip often occurs when machining stainless steels with cemented carbide tools. Wear mechanism of cemented carbide tool in high speed milling of stainless steel 0Cr13Ni4 Mo was studied in this work. Machining tests on high speed milling of 0Cr13Ni4 Mo with a cemented carbide tool are conducted. The cutting force and cutting temperature are measured. The wear pattern is recorded and analyzed by high?speed camera, scanning electron microscope(SEM) and energy dispersive X?ray spectroscopy(EDS). It is found that adhesive wear was the dominant wear pattern causing tool failure. The process and microcosmic mechanism of the tool's adhesive wear are analyzed and discussed based on the experimental results. It is shown that adhesive wear of the tool occurs due to the wear of coating, the a nity of elements Fe and Co, and the grinding of workpiece materials to the tool material. The process of adhesive wear includes both microcosmic elements di usion and macroscopic cyclic process of adhe?sion, tearing and fracture.     

Investigation of abrasive wear resistance and wear mechanism of composite alloys

The abrasive wear resistance of composite alloys comprising hard tungsten carbide and soft CuNiMn matrix under different wear conditions has been investigated and compared with CrMo cast iron. It was found that Yz-composite alloy with hard cast angular tungsten carbide has greater wear resistance than CrMo cast iron under two-body wear conditions, but lower resistance than Cr-Mo cast iron under three-body wear conditions. It was found that under three-body wear conditions selective wear of the matrix and digging or fragmentation of tungsten carbide particles dominate in Yz-composite alloy, and microcutting and deformed ploughing is dominant under two-body wear conditions. The abrasive wear resistance of composite alloys under two-body wear condition is independent of bulk hardness, but is closely related to the microhardness of tungsten carbide.     

铁素体不锈钢激光熔覆层组织和性能研究

采用无碳合金粉末和低碳合金粉末对铁素体不锈钢进行激光表面熔覆处理,借助光学显微镜(Optical microscope,OM)、扫描电子显微镜(Scanning electron microscopy,SEM)、能谱分析仪(Energy dispersive spectrometry,EDS)、X射线衍射仪(X-ray diffractometry,XRD)、显微硬度仪、摩擦磨损试验仪、电化学工作站对熔覆层显微组织、化学成分、硬度、耐磨性和耐蚀性进行评价。结果表明,两种激光熔覆层均无裂纹、气孔等宏观缺陷,显微组织主要由等轴晶、包状晶、树枝晶和枝间共晶组成。无碳熔覆层与低碳熔覆层均含有α-Fe、Fe-Cr合金相、Cr单质相以及Cr_(9.1)Si_(0.9)、Fe_(9.7)Mo_(0.3)、Fe_(10.8)Ni、Fe_(19)Mn等金属间化合物。此外,低碳熔覆层还产生了间隙化合物Cr_7C_3以及马氏体相C_(0.055)Fe_(1.945)。低碳熔覆层硬度为750 HV0.5,显著高于母材硬度250 HV0.5;无碳熔覆层硬度为650 HV0.5,其热影响区发生软化。激光熔覆层相对于母材具有更为稳定的摩擦特性以及优异的耐磨性和耐蚀性,其中低碳熔覆层耐磨性和耐蚀性均优于无碳熔覆层。     

铸态贝氏体中锰钢化学成分设计及其性能研究

主要研究铸态锰钢加入适量Mo、V、Ti、RE等元素的显微组织和力学性能。研究结果表明:当化学成分(质量分数)设计为1.0%C,4%Mn,1%Si,钼铁加入量为总重量的1%,钛铁为0.8%,钒铁为0.6%,稀土硅为0.3%,可获得贝氏体组织,并具有较好的综合力学性能,而且在非强烈冲击工况下具有高抗磨性。     

沉积温度对脉冲真空弧源沉积类金刚石薄膜性能的影响

利用脉冲真空弧源沉积技术在Cr17Ni14Cu4不锈钢和Si(100)基体上制备了类金刚石(DLC)薄膜,研究了基体沉积温度对DLC薄膜的性能和结构的影响。研究表明,随着沉积温度由100 ℃提高到400 ℃,DLC薄膜中sp3 键质量分数减少,sp2键质量分数增多,薄膜复合硬度逐渐降低。当DLC薄膜沉积温度达到400 ℃时,薄膜中C原子主要以sp2键形式存在,与沉积温度为100 ℃时制备的DLC薄膜相比,薄膜复合硬度降低50%。DLC薄膜具有优异的耐磨性,摩擦因数低,随着沉积温度由100 ℃提高到400 ℃,Cr17Ni14Cu4不锈钢表面沉积的DLC薄膜耐磨性降低。沉积温度为100 ℃时,Cr17Ni14Cu4不锈钢表面沉积的DLC薄膜后,耐磨性大幅度提高。DLC薄膜与不锈钢基体结合牢固。     

Erosive and erosive-corrosive wear behaviour of cast nitrogenated stainless steels

Corrosive-erosive and erosive wear in cast low nickel nitrogenated austenitic stainless steels is higher than that in a standard CF8 grade steel. Niobium addition (I wt.%) to such (FeCrNiMnN) stainless steels, however, improves their resistance to both corrosive-erosive and erosive wear.     

Fretting and fretting corrosion behavior of novel micro alloyed rail steels

The fretting behavior of two novel rail steels of composition Cu–Ni and Cr–Cu–Ni has been studied and compared with that of C–Mn and Cu–Mo rail steels. The rail steels were fretted in dry condition and in 3.5% NaCl solution. All the four rail steels exhibited similar fretting behavior in dry condition. The morphological features of the wear scar surface indicated delamination process as the main wear mechanism. The wear damage in 3.5% NaCl was lower compared to that in dry condition for all the rail steels due to lubricating effect of the solution. Fretting in presence of 3.5% NaCl resulted in lower wear volume for Cu–Ni and Cr–Cu–Ni rail steels. The friction coefficient for Cr–Cu–Ni rail steel was lower than that of C–Mn, Cu–Mo and Cu–Ni rail steels. Scanning electron microscopy (SEM) showed better adherence of tribo-electro-chemical layers formed on Cu–Ni and Cr–Cu–Ni rail steel than the C–Mn and Cu–Mo rail steels. This has been related to the improved fretting corrosion behavior of Cu–Ni and Cr–Cu–Ni rail steels.     

热处理工艺参数对G13Cr4Mo4Ni4V钢晶粒度及性能的影响

采用不同的热处理工艺对G13Cr4Mo4Ni4V钢进行处理,采用金相显微镜、洛氏硬度计、冲击试验机分别对晶粒度、硬度及冲击功进行测试分析.结果表明,随着淬火温度的升高及保温时间的延长,G13Cr4Mo4Ni4V钢的晶粒度级别降低,硬度升高,冲击功降低.