粉煤灰和矿渣粉对水下不分散混凝土性能的影响研究

本试验研究了粉煤灰和矿渣粉复掺时对水下不分散混凝土性能的影响,分析二者不同掺量复掺时对混凝土流动性、抗分散性、力学性能以及抗氯离子渗透性的影响规律.研究表明,与掺合料单掺相比,粉煤灰和矿渣粉复掺时混凝土流动性降低,但是抗分散性和抗氯离子渗透性明显改善,同时二者复掺时能起到“叠加效应”,使早期强度和后期强度均较高.     

等28d抗压强度条件下粉煤灰和矿渣对C50混凝土后期性能的影响

在28 d抗压强度相近的前提下,制备了纯水泥混凝土、大掺量粉煤灰混凝土、大掺量矿渣混凝土,测定了不同混凝土的后期抗压强度、抗氯离子渗透性,以及胶凝材料的化学结合水、硬化浆体中的Ca(OH)2含量.结果表明:含大掺量矿物掺合料的混凝土的后期强度和抗氯离子渗透性均明显高于纯水泥混凝土;大掺量矿渣混凝土的后期强度高于同掺量的大掺量粉煤灰混凝土;复合胶凝材料的后期水化程度增长率明显高于纯水泥;复合胶凝材料硬化浆体中后期Ca(OH)2含量明显低于纯水泥硬化浆体.     

掺钢渣-矿渣-粉煤灰复合微粉混凝土性能研究

研究了由钢渣-矿渣-粉煤灰制备的复合微粉对混凝土强度、收缩性能和氯离子渗透性能的影响。结果表明：在同水胶比下,复合微粉等量取代水泥后,混凝土7d强度低于普通混凝土的强度,当复合微粉掺量小于45％时,其28d及以后强度高于普通混凝土。在同水胶比下,复合微粉等量取代水泥后,可有效降低混凝土的干燥收缩,且混凝土的抗氯离子渗透性能显著提高。     

矿渣微粉、粉煤灰水泥基材料的性能试验研究

研究了矿渣微粉、粉煤灰单掺以及矿渣微粉与粉煤灰双掺对砂浆和净浆（W／B=035）的流动度、强度的影响。结果表明：①随着掺合料的不断增加，无论是矿渣微粉、粉煤灰单掺还是矿渣微粉与粉煤灰双掺，都能改善砂浆和净浆的流动度；②对砂浆和净浆的强度而言，矿渣微粉单掺要比粉煤灰单掺以及矿渣微粉与粉煤灰双掺的效果好；③在本试验掺量范围内，随着矿物掺合料的增多，粉煤灰单掺的强度逐渐下降，矿渣微粉单掺的强度逐渐上升；④双掺时，在掺合料总量相同的情况下，矿渣微粉比例越大，砂浆和净浆的流动度变小，而强度会升高。     

粉煤灰高强混凝土氯离子扩散性能的试验研究

采用NT BUILD492测试方法研究粉煤灰对高强混凝土的氯离子渗透性能的影响.测试了水泥-粉煤灰体系净浆的相容性、水胶比为0.28的混凝土的抗压强度以及氯离子渗透性.结果表明,掺加粉煤灰可以降低净浆的超塑化剂饱和点掺量.56d时掺粉煤灰的混凝土的抗压强度已超过基准混凝土.粉煤友取代水泥降低了氯离子扩散系数,在后期尤为明显.试验数据拟合得出,氯离子扩散系数与养护龄期有很好的相关性.而且,粉煤灰取代量20%时,氯离子扩散系数最小、线形相关性最好,相关指数达到0.998.     

粉煤灰和矿渣双掺对混凝土性能影响的研究

研究了粉煤灰和矿渣对混凝土性能的影响.结果表明,粉煤灰和矿渣等量取代水泥能改善混凝土的流动性,达到减水效果.粉煤灰和矿渣微粉复合使用,能显著改善混凝土的流动性,提高混凝土的中、后期强度,且可发挥二者的优势互补效应.     

复掺粉煤灰和超细矿渣对高性能混凝土力学与耐久性能的影响研究

将活性矿物掺入混凝土中可以有效提高其使用性能.基于此,制备了不同粉煤灰和超细矿渣配比的高性能混凝土试件,测试了高性能混凝土的抗压强度、劈裂抗拉强度、抗折强度、抗氯离子渗透能力,分析了单掺和复掺粉煤灰和超细矿渣对混凝土力学与耐久性能的影响.结果表明:粉煤灰和矿渣掺入可以有效提高混凝土的力学性能;当粉煤灰和矿渣掺量分别为1...     

大掺量"矿渣微粉+粉煤灰"中低强高性能混凝土配制技术与性能研究

为了生产具有中低强度等级的高性能混凝土，采用了在普通硅酸盐水泥混凝土基础上大掺量复合掺加“矿渣微粉 粉煤灰 高效减水剂”的技术路线，简称“三掺”高性能混凝土。本文通过较系统的配合比设计与试验，最终得出“三掺”高性能混凝土的系列配合比。性能研究结果表明：“三掺”高性能混凝土的工作性、水化热和耐久性都优于普通粉煤灰混凝土；其早期强度稍低，后期力学性能与普通粉煤灰混凝土一致。     

复合矿物掺合料对砂浆抗酸雨侵蚀性能的影响

研究了粉煤灰、矿渣微粉双掺对水泥砂浆的强度以及抗模拟酸雨侵蚀性能的影响.试验发现:随着粉煤灰、矿渣微粉总掺量的增加,砂浆强度逐渐下降;粉煤灰、矿渣微粉双掺对水泥砂浆试件在模拟酸雨条件下的强度发展有改善作用.     

活性掺和料再生集料混凝土研究

用矿渣微粉、钢渣微粉、粉煤灰和再生集料配制出28d强度大于50MPa,坍落度为200mm的活性掺和料再生集料混凝土,并对矿渣微粉再生集料混凝土、钢渣再生混凝土和粉煤灰再生集料混凝土的特性进行分析,其中掺矿渣40%,应用全部再生集料配制的混凝土90d强度达到61.5MPa     

乙苯,苯乙烯的生产及合成乙苯,苯乙烯催化剂的研究进展

苯乙烯是重要的石油化工原料。本文介绍了国内外苯乙烯生产的发展概况，合成乙苯，苯乙烯所用的催化剂种类，并就苯乙烯生产及催化剂的发展趋势提出了自己的观点。     

Synthesis and characterization of homopolymers and copolymers of various acrylates and acrylonitrile

Various homopolymers and copolymers of methyl acrylate, ethyl acrylate, butyl acrylate, and acrylonitrile in different feed ratios were synthesized. These were characterized by IR, ¹³C-NMR, DSC, DTA, and TGA. Spectroscopic characterization helped in differentiating copolymers of different mol ratios. Thermal analysis revealed different degradation patterns for homopolymers and copolymers. The temperature and energy changes associated with various phase transitions were dependent on the chemical composition of homo- and copolymers, as expected. © 1993 John Wiley & Sons, Inc.     

生物质气化及生物质与煤共气化技术的研发与应用

总结了生物质原料的特点及生物质单独气化的缺点;介绍了国内外生物质气化技术及生物质与煤共气化技术的研发与应用现状;分析了在此领域国内外的发展趋势与前景;概括了开展生物质与煤共气化技术研发的意义。     

Electronic structures and reactivities of monometallic and bimetallic clusters of Au and Cu

The variation of the Au 4f binding energy of Au clusters with the cluster size has been established by measuring the binding energies of clusters whose size distributions were independently determined by HREM and STM. The binding energy increases significantly when the cluster size is less than 2 nm. Au-Cu bimetallic clusters of the composition Cu₃Au have been deposited for the first time on carbon substrates. The shifts in the core level binding energies of the bimetallic clusters show the effect of alloying in the case of large clusters, but show effects of both alloying and cluster size in the case of the small clusters. The interaction of CO with Cu₃Au clusters is stronger than with a bulk Cu metal. The interaction of CO with small Cu clusters also seems to be stronger than with bulk Cu or with large Cu clusters.     

钾盐资源及钾肥供需情况分析及预测

阐述了国内外钾盐资源及钾肥生产现状,对国内外钾盐的供需形势进行了分析及预测,从资源、原材料、国际市场三方面提出了解决我国钾盐短缺的措施。     

Kinetics and Mechanism of Oxidation of Mono- and Polyacetals

Abstract

Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70°C, 15–16 hr) leads to the formation monoethers of the corresponding glycols with 68–90% selectivity. Salts of metals and complexes with crown-ethers have increased the reaction rate significally. Ozone have reacted with acetals with formation similar products. The mechanisms of intermediate stages have been proposed.     

Comparison of the Adhesion and Cohesion of Triblock and Random Copolymers of Styrene and Butadiene

A substantially greater detachment energy is required to strip a polyethylene tereph-thalate (Mylar) film from a styrene-butadiene-styrene (SBS) triblock copolymer compared to that for peeling from a random styrene-butadiene (SBR) copolymer. This is true even though the intrinsic interaction between the Mylar and each elastomer is expected to be similar because of their virtually identical chemical composition. It is proposed that this difference in peel strength (between the SBS and SBR) is a consequence of the much higher dissipative capacity of the former elastomer. Another manifestation of this is the higher cohesive tear strength of the SBS compared to the SBR. Extents of energy dissipation within each elastomer during detachment of the Mylar adherend are consistent with the hypothesis that the average maximum stress experience before detachment is some similar fraction of each elastomer's tensile strength.     

Wetting properties of homopolymers and copolymers of pentafluorostyrene and methylacrylate and homopolymer blends

Polypentafluorostyrene (PPFS), polymethylacrylate (PMA), and poly(pentafluorostyrene-co-methylacrylate), poly(PFS-co-MA) were prepared and the wetting characteristics of polymer blends of PPFS and PMA were compared with that of poly(PFS-co-MA) via contact angle measurements. The critical surface tension of polypentafluorostyrene was found to be 22.6 dyne/cm, which is comparable to the value reported for polytrifluoroethylene (22 dyne/cm). The critical surface tension of poly(PFS-co-MA) is not linearly related to its composition. The polymer blends of PPFS and PMA exhibit significant surface enrichment of the fluoropolymer. The harmonic-mean method¹ was employed to determine surface tensions of these polymers and many known polymers. It is found that the method produces useful surface tension data provided the contact angle values are derived from testing liquids of dissimilar polarity.     

责任和责任心的涵义与结构

责任是人应主动承担的角色义务和对其因过失所造成后果应承担的责罚.有两层涵义:一是义务;二是后果.责任心是个体自觉做好分内事务和履行道德义务的心理倾向,是个性心理品质成分中自我特征维度上的重要内容.责任心具有两个方面的涵义:一是角色分内职责;二是角色道德义务.责任心是一种通过责任认知、责任个性和责任适应的动态形式表现出来的静态品质,责任心是责任心过程结构与责任心关系结构相互制约、相互影响的统一体.     

二甲基二烯丙基氯化铵和丙烯酰胺的合成及应用

用复合引发体系(过硫酸盐-偶氮类引发剂)和脂肪胺类氧化还原体系引发,在实验室获得了单体转化率≥98%,特性粘数高于13.6 dL/g的阳离子共聚物PDA,探讨了控制聚合物分子量的影响因素.