A model of corrosion fatigue crack growth in ship and offshore steels

A model describing corrosion fatigue crack growth rate da/dN has been proposed. The crack growth rate is assumed to be proportional to current flowing through the electrolyte within the crack during a loading cycle. The Shoji formula for the crack tip strain rate has been assumed in the model. The obtained formula for the corrosion fatigue crack growth rate is formally similar to the author's empirical formulae established previously. The different effects of ΔK and the fatigue loading frequency f on da/dN, in region I as compared to region II of the corrosion fatigue crack growth rate characteristics can be described by a change of one parameter only: the crack tip repassivation rate exponent.     

Small fatigue crack initiation and growth behavior of high-strength low alloy steel in various environments

Fatigue tests under rotating bending and reversed torsion were carried out in air, distilled water and 3% saltwater, using smooth specimens of high-strength low alloy steel (Cr-Mo steel). The initiation and growth behavior of small fatigue cracks in each environment were evaluated based on detailed observations, and the effects of corrosive environment were also discussed. The fatigue strength decreased with increasing aggressiveness of test environment. The decreases in corrosive environment were due to earlier fatigue crack initiation. From the observed locations at which small fatigue cracks began, it was considered that the crack initiation was primarily governed by hydrogen embrittlement in distilled water and also affected by corrosive dissolution in 3% saltwater. The validity of the application of linear fracture mechanics for small fatigue cracks was established. The growth rates of small fatigue cracks were higher than for large through cracks, and not accelerated by the corrosive environment. Moreover, fatigue life in the corrosive environment was estimated by using the crack growth characteristics in air.     

Role of crack tip mechanics in stress corrosion cracking of high-strength steels

This paper analyzes the effects of crack tip plastic strains and compressive residual stresses, created by fatigue pre-cracking, on environmentally assisted cracking of pearlitic steel subjected to localized anodic dissolution and hydrogen assisted fracture. In both situations, cyclic crack tip plasticity improves the behaviour of the steel. In the respective cases, the effects are supposed to be due to accelerated local anodic dissolution of the cyclic plastic zone (producing chemical crack blunting) or to the delay of hydrogen entry into the metal caused by residual compressive stresses, thus increasing the fracture load in aggressive environment.     

Mechanism of corrosion fatigue crack propagation in high strength steels

The crack propagation velocity in corrosion fatigue $\text{(d a/d N)}{}_{\mathrm{c}}$ were measured on the Ni-Cr-Mo steel quenched and tempered at 473 or 773 K.The steel with high sensitivity to delayed failure reveals the largest $\text{(d a/d N)}{}_{\mathrm{c}}$ under square load and the smaller $\text{(d a/d N)}{}_{\mathrm{c}}$ under positive saw tooth load. The frequency dependency of crack propagation characteristics indicates that the interaction between hydrogen atoms and the cyclic moving of triaxial position at crack tip acts an important role in the crack propagation mechanism, i.e. hydrogen concentration process controls the crack propagation of the steel.The steel with low susceptibility to delayed failure reveals, on the other hand, the largest $\text{(d a/d N)}{}_{\mathrm{c}}$ under the positive saw tooth load but the smallest $\text{(d a/d N)}{}_{\mathrm{c}}$ under the square load, i.e. the stress increasing time is important and the hydrogen invasion process is the controlling factor for the crack propagation.     

Correlation between electrochemical reactions with bare surfaces and corrosion fatigue crack growth in steels

The results of this preliminary correlation demonstrate the relationship between electrochemical reactions with bare metal surfaces and CF crack growth for steels in aqueous environments, and is very encouraging. These findings provide further support for the hypothesis of surface/electrochemical react control, and indicate the effectiveness of the in-situ fracture technique in providing unambiguous measurements of bare-surface reaction kinetics. For quantitative modeling, efforts will be needed to provide measurements of current and charge densities, and to address the issue of actual surface areas of cracks. Additional research is in progress and will be reported.     

The effects of saline aqueous corrosion on fatigue crack growth rates in 316 grade stainless steels

A study of fatigue crack propagation rates of 316 grade stainless steels in air and in an aqueous saline environment was carried out in an attempt to assess the fatigue properties encountered when such materials are used as surgical implants. The effects of variables such as temperature, pH, oxygenation level, bulk electrode potential, mean stress, frequency and stress waveform on the Paris crack growth law parameters were determined. Corrosion fatigue effects were observed in the aqueous saline environment, and a mechanism to describe this effect is proposed.     

Double influence of hydrogen on fatigue crack growth in heat-resistant steels

We investigate fatigue crack growth in cast heat-resistant steel pipes of reforming furnaces in a vacuum, in air, and in gaseous hydrogen in the temperature range 20 – 800°C. It is shown that the character and intensity of hydrogen-induced effects depend on temperature and loading amplitude. For the crack resistance threshold, we discovered the phenomenon of temperature inversion of these effects. Namely, the value of K _th in hydrogen increases with temperature up to 400°C and then decreases. Under high-amplitude loading, the influence of hydrogen manifests itself only in the acceleration of crack growth. The ambiguity in the influence of hydrogen on the plastic strain resistance of the material at the crack tip is analyzed on the basis of well-known physical concepts of the influence of hydrogen on the processes of generation and displacement of dislocations. The effects discovered in this work are explained by the realization of different fracture mechanisms and different types of hydrogen-induced effects under different conditions. Thus, at low temperatures (up to 400°C) and high K, one observes a decrease in the tearing strength; the case of low temperatures and low K is characterized by the shear fracture mechanism and the strengthening effect of hydrogen; for high temperatures ( 400°C) and low K, the shear fracture mechanism is combined with a decrease in the plastic strain resistance under the influence of hydrogen.Karpenko Physicomechanical Institute, Ukrainian Academy of Sciences, L'viv. Translated from Fiziko-Khimicheskaya Mekhanika Materialov, Vol. 30, No, 4, pp. 7–15, July – August, 1994.     

Effect of heat treatment on fatigue crack growth in chain steels

Abstract

The influence of tempering temperature, stress ratio, and prior strain on fatigue crack propagation in a low-alloy chain steel has been investigated. At small stress ratios (R=0·1) tempering above 400°C is beneficial, resulting in higher threshold levels and slower growth rates in the initial growth regime. Thereafter, crack growth is independent of tempering temperature, as it is over the entire growth period under a high mean stress (R=0·5). Prior strain produces a slower growth and higher thresholds at R= 0·1. Intergranular fracture is common and is a function of stress intensity range and tempering temperature. It is concluded that residual stress effects, rather than microstructural effects, account for the experimental observations. In particular, the existence of a tensile residual stress during initial growth and a crack closure stress greater than the minimum applied stress level are proposed.

MST/672     

Effects of corrosive environments on near-threshold fatigue crack growth behavior of T1-6A1-4V

The near-threshold fatigue crack growth behavior of Ti-6A1-4V alloy has been investigated in low O₂ steam (< 1 ppm), high O₂ steam (40ppm), and boiling water with various concentrations of Nad and/or Na₂₂SO₄. At load ratio (R) of 0.5, high O₂ steam increased the crack propagation rates in the threshold region, relative to low O₂ steam. However, at R = 0.8, the near-threshold crack growth rates in low and high O₂ steam were comparable. Values of threshold stress intensity range, ΔK_th, slightly increased with an increase in the concentration of NaCl in the solution. Varying solution pH from 5.0 to 10.0 in a 0.1 g NaCl plus 0.1 g Na₂SO₄ per 100ml H₂O solution had no effect on the rates of near-threshold crack propagation. Increasing the hydrazine level from 30 to 10⁷ ppb in the same salt solution also did not change the resistance to crack growth. Comparing the present results with the previous data on 403 stainless steel, the near-threshold crack propagation rate performance in Ti-6Al-4V alloy is superior to that in 403 steel in both the steam and salt solution environments.     

The significance of stress corrosion cracking in corrosion fatigue crack growth studies

A model is proposed to account for interactions between fatigue and stress corrosion crack propagation mechanisms in appropriate corrosion fatigue conditions. Tests on an alloy steel, and both wrought and cast aluminium alloys, are reported. Despite the use of very simple coefficients in the equations derived, encouraging results are obtained.