Investigations of the copper isotope effect in oxygen-deficient YBa2Cu3O7−δ

We present data on the copper isotope effect (⁶³Cu-⁶⁵Cu), C_u =-nT_c/nm_Cu, for two isotopic pairs of oxygen-deficient YBa₂Cu₃O_7–, where varies between 0.06 and 0.52. _Cu is below 0.01 at =0.06 (fully oxygenated), it takes values between –0.14 and –0.34 in the 60 K plateau. Larger negative values of _Cu are observed away from the plateau. The dependence of _Cu is similar to that of the pressure effect dnT_c/dP.     

The critical curve in an antiferromagnetic superconductor with nonmagnetic impurities

The critical curve of a transition of the second kind in an antiferromagnetic superconductor (AFS) with nonmagnetic impurities has been studied. The AFS is described by using the mean-field model given by Nass, Levin, and Grest and assuming a one-dimensional electron band. We find that the points on the critical curve satisfy the thermodynamic stability condition for 0₁/₀5.04 and 0.49H_Q/₀1.64.Here ₁ is the inverse lifetime of a conduction electron for nonmagnetic impurity scattering,H _Q is the antiferromagnetic molecular field, ₀ is the zero-temperature order parameter of a superconductor in the absence ofH _Q and impurities. Further, ₁ and H_Q denote the values of these quantities for points on the critical curve. For ₁/₀>5.04 and H_Q/₀>1.64, the phase transition from the superconducting to the normal state is always of the second kind. Some thermal properties of the system near the critical curve have also been investigated and we find that these depends dramatically on the impurity concentration.     

An exact calculation of Price's law for the law of Lotka

Price's law asserts — in its simpliest version — that authors produce half of the papers made by the total ofN authors. More generally: the topN (0<<1) authors produce a fraction (0<<1) of the papers made by the total ofN authors and the Price's law says that . In this paper — using Lotka's law — we prove a mathematical relationship of in function of and the parameter (the mean number of papers per author) and investigate when . More-over our reasoning uses the theory of the 80/20 rule as developed in: L. EGGHE, On the 80/20-rule,Scientometrics, 10 (1986) 55–68, thereby also showing the relation betwwen the 80/20-rules (being an arithmetical form of measuring elitarism) and Price's law (being a geometric form of measuring elitarism).     

Tilted and Crossing Vortex Chains in Layered Superconductors

No Heading In presence of the Josephson vortex lattice in layered superconductors, small c-axis magnetic field penetrates in the form of vortex chains. In general, structure of a single chain is determined by the ratio of the London [] and Josephson [_J] lengths, = /_J. The chain is composed of tilted vortices at large s (tilted chain) and at small s it consists of crossing array of Josephson vortices and pancake-vortex stacks (crossing chain). We study chain structures at the intermediate s and found two types of phase transitions. For 0.6 the ground state is given by the crossing chain in a wide range of pancake separations a [2–3]_J. However, due to attractive coupling between deformed pancake stacks, the equilibrium separation can not exceed some maximum value depending on the in-plane field and . The first phase transition takes place with decreasing pancake-stack separation a at a = [1 – 2]_J, and rather wide range of the ratio , 0.4 0.65. With decreasing a, the crossing chain goes through intermediate strongly-deformed configurations and smoothly transforms into the tilted chain via the second-order phase transition. Another phase transition occurs at very small densities of pancake vortices, a [20 – 30]_J, and only when exceeds a certain critical value 0.5. In this case small c-axis field penetrates in the form of kinks. However, at very small concentration of kinks, the kinked chains are replaced with strongly deformed crossing chains via the first-order phase transition. This transition is accompanied by a very large jump in the pancake density.PACS numbers: 74.25.Qt, 74.25.Op, 74.20.De     

Phase relationships in Si3N4-AIN-MxOy systems and their implications for sialon fabrication

Phase relationships in Si₃N₄-AIN-M_xO_y systems involving -sialon, where M represents lithium, magnesium, calcium, yttrium, neodymium, samarium, gadolinium, dysprosium, erbium and ytterbium are outlined. Their implications for the formation and fabrication of single-phase -sialon and two-phase : sialon ceramics are discussed.     

Analysis of the effect of the decomposition of char-forming heat-insulating materials on the free discharge of a gas mixture

The article presents results of a numerical solution of a nonsteady problem on the free discharge of a mixture of gases from a hemispherical volume with allowance for thermal decomposition of heat-insulating materials.Notation V volume - S area - t - P p - T - u v - Q q, dimensional and dimensionless time, pressure, temperature, TIM decomposition rate, and heat flux - adiabatic exponent - R gas constant - density - H specific enthalpy - c specific heat - thermal conductivity - , , _s dimensionless complexes - coefficient expressing the radiative properties of the gas medium and the heat-transfer surface - Stefan-Boltzmann constant Indices 0 initial state and scale factors - s surface - coke - M TIM material - P pyrolysis front - A ablation front - v volatile degradation products - adiabatic conditions - c completion of discharge Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 54, No. 5, pp. 787–793, May, 1988.     

Oriented mosaic model analysis of anisotropic thermoelectric properties of heterogeneous materials

Thermoelectric properties of heterogeneous materials are discussed in terms of a randomly oriented rectangular plate-like mosaic of anisotropic crystalline grains embedded in a homogeneous host material. Anisotropies in effective thermoelectric parameters and the values of thermoelectric parameters can be related to the mean orientation of the plate-like grains which, in turn, can be related to the orientation factor of Lotgering. They are also functions of various parameters such as dimension ratios , and of electrical resistivities, thermal conductivities, and the Seebeck coefficient, respectively, of grains to those of host medium. Use of f-dependent anisotropies in conjunction with relative magnitudes of electrical and thermal conductivities as well as of the Seebeck coefficient, allows , and to be estimated, which characterize the intergranular medium.     

Bone formation induced by calcium phosphate ceramics in soft tissue of dogs: a comparative study between porous α-TCP and β-TCP

Two kinds of tri-calcium phosphate ceramics (Ca/P = 1.50), -TCP and -TCP, which has the same macrostructure and microstructure, but different phase composition, were implanted in dorsal muscles of dogs. The samples were retrieved at 30, 45 and 150 days, respectively, after implantation, and were analyzed histologically. There were critically different tissue responses between -TCP ceramic and -TCP ceramic. Higher cell populations were observed inside the pores of -TCP than those of -TCP, bone tissue was found in -TCP at 45 and 150 days, but no bone formation could be detected in any -TCP implants in this study. On the other hand, the bone tissue in -TCP seemed to degenerate at 150 days. The results indicate that porous -TCP can induce bone formation in soft tissues of dogs; while the rapid dissolution of the ceramic and the higher local Ca²⁺, PO ₄ ^3- concentration due to the rapid dissolution of -TCP may resist bone formation in -TCP and the less rapid dissolution of -TCP may be detrimental to already formed bone in -TCP.     

Torsional load transfer from a rigid shaft to an elastic plane with a slit

A plane elastostatic problem for an elastic wedge loaded by a concentrated moment at its apex provides an example of violation of the Saint-Venant principle for apex angles 2 larger than . Considering the problem for a truncated wedge, Neuber demonstrated the method of construction of an applicable solution for any apex angles in the range 22, despite the failure of the Saint-Venant principle. In the present paper the particularly important case of the truncated-wedge problem is examined. The truncated wedge degenerates into a slitted elastic plane, while a rigid circular shaft, acted upon by a torsional moment, is inserted into the plane. The analytical solution of the mixed boundary-value problem is obtained. Numerical results turn out to be in complete agreement with Neuber's results for the slitted elastic plane.     

Structure of unidimensional temperature stresses

Using the structural approach, the temperature stresses are examined in a semiinfinite rod, insulated on the lateral faces and rigidly fixed at the end. A comparative analysis is made for three heat-transfer models.Notation k(t) heat flux relaxation function - (t) internal energy relaxation function - T rod temperature - ambient temperature - t time - x coordinate along the rod - _xx(x, t) stress - u(x, t) displacement - (x, t) deformation - c₀=(E/)^1/2 speed of sound in the rod under isothermal conditions - E elasticity modulus - density of the material - _t coefficient of thermal expansion - thermal-conductivity coefficient - a thermal-diffusivity coefficient - b thermal-activity coefficient - c_q=(a/_r)^1/2 velocity of heat propagation - _r heat flux relaxation time - (t) unique Heaviside function Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 33, No. 5, pp. 912–921, November, 1977.     

The mechanism of continuous dissolution of the lamellar structure in aged Al 22 at% Zn alloy

The mechanism of continuous dissolution was studied using transmission electron microscopy, X-ray diffraction and hardness measurements. The metastable phase was identified in the first stage of dissolution nucleating at the - boundaries. Interface dislocations at the - boundaries forming a perpendicular net in the 110 directions were identified as of screw character and of Burgers vector b=1/2a 110. During dissolution a change of shape of precipitates occurs leading to their fragmentation and to a change of the direction of boundaries into 110 directions.     

Mössbauer studies of α″-Fe16N2 and α′-Fe8N films

Conversion-electron Mössbauer spectra of epitaxial -Fe₁₆N₂ and -Fe₈N films have been studied and their differences are discussed in detail. The Mössbauer spectrum of -Fe₁₆N₂ can be decomposed into three subspectra, which correspond to the 4d, 8h and 4c sites. The Mössbauer spectrum of -Fe₈N can be fitted using four spectra based on a nitrogen-atom-random-distribution model. The average hyperfine field is larger (3%) for -Fe₁₆N₂ than for -Fe₈N, which is approximately consistent with a 4.1% enhancement of the magnetic moments for -Fe₁₆N₂. The iron moments tend to locate in the film plane for -Fe₁₆N₂ and to arrange perpendicularly to the film plane for -Fe₈N.     

Change in the structure of alloy VT22 with the combined action of ultrasonic radiation and thermal cycling treatment

A study is made of the structure of alloy VT22 with thermal cycling treatment (TCT) and also with TCT and prior ultrasonic irradiation (USI) by the methods of metallography, electron microscopy, and hardness measurements. It is shown that TCT for annealed specimens promotes recrystallization, fragmentation, and spheroidization of and phases.It is established that TCT of specimens quenched to phase previously treated with ultrasonic radiation leads to formation of -phase platelets of considerably smaller dimensions and more strongly fragmented compared with -phase platelets after TCT for unirradiated specimens.Translated from Problemy Prochnosti, No. 10, pp. 47–49, October, 1990.     

A transmission electron microscopic study of the Bethany iron meteorite

The Bethany iron meteorite which is a part of the Gibeon shower is a fine octahedrite with zoned plessite fields of various sizes. The optically irresolvable microstructural details inside the plessitic fields have been studied by transmission electron microscopy, and the crystallographic relationships between the primary kamacite () and the parent taenite (), and between the and particles in the coarse plessite, have been examined using electron diffraction. In the case of primary kamacite the orientation-relationship with was close to the Nishiyama-Wasserman relationship, whereas, for the plessitic , the orientation-relationship with was close to Kurdjumov-Sachs. It was also found that the (111) and (110) planes were not strictly parallel. Additionally, measurements of the composition profile through the zoned plessite have been made using STEM microanalysis technique, and related to microstructure.     

Microstructure and properties of supersaturated ZA27 alloy during natural ageing

The decomposition of the supersaturated solid solution of ZA27 alloy at room temperature has been investigated by X-ray diffraction, TEM and mechanical properties testing. Based on the results obtained, both continuous precipitation and cellular reaction occur during the decomposition process. The continuous precipitation follows the sequence: ₁ + spherical GP zones ₂ + elliptical GP zones ₃ + R + . The cellular reaction can be written: + + . The properties of the alloy depend on the microstructure. After 1 month of ageing, a series of changes of microstructure have taken place. The properties of the alloy are: _b=500 MPa, =13%,H _v=148.     

Studies of the dielectric constant in solid H2,4He,and Ne

Measurements of the static dielectric constant and of the resulting polarizability _CM defined by the Clausius-Mosotti relation are reported for several molecular solids under conditions of quasiconstant density. The range of measurements was between 0.4 and about 15 K, and pressures up to about 1 kbar were used. In solid H₂, the changes of as a function of ortho concentration are reported at 4.2 and 12 K, from which it is concluded that [(ortho)–(para)]/0.005, which is approximately 2 1/2 times larger than in the liquid phase. Furthermore the temperature change of _CM is studied for various densities at comparable ortho concentrationsX. Particular attention is paid to the orientational order-disorder transition in solid H₂ withX0.65, where _CM shows an abrupt change that appears to be a function ofX, density, and thermal history. In general _CM is lower in the ordered (cubic) phase than in the disordered (hexagonal) phase. The temperature change of _CM in almost pure para-H₂, measured between 4 and 0.4 K, is presented and is compared with other recently reported experiments. It is concluded that the mechanism that produces the change of _CM withT and at the order-disorder phase transition is not understood. In solid Ne, measurements of _CM are reported for one sample assumed to be at zero pressure and one where the density is quasiconstant. There is a strong temperature dependence in _CM for the former above 5 K (in agreement with previous findings), while for the latter _CM appears to be constant within the uncertainties introduced by strain-induced hysteresis effects. The sample of solid⁴He, investigated between its melting point at 4.3 and 0.8 K at constant density, shows a very weak temperature dependence of _CM, which is also consistent with previously reported measurements.Research supported by a grant of the U.S. Army Research Office (AROD) and from a contract with the Office of Naval Research. A preliminary account of this research was given inBull. Am. Phys. Soc. 20, 672 (1975).     

Ultrasonic attenuation of longitudinal and shear waves in the normal and superconducting states of niobium

Ultrasonic attenuation measurements of both longitudinal and shear waves in the normal and superconducting states were made on niobium single crystals. Frequencies between 50 and 450 M H z were employed. Independent of the mode, frequency, and crystal studied, a deviation of the attenuation ratio _s/_n from BCS behavior was observed. The dependence of _s/_n on frequency and crystal purity are interpreted in terms of a model which assumes a difference in electron mean-free path due to phonon scattering in the normal and superconducting states.Research sponsored in part by NASA Grant 36-006-003 and by the Air Force Office of Scientific Research, Office of Aerospace Research, United States Air Force, under ASOSR Grant No. 68-1479B.     

Vibrational properties of wood along the grain

The dynamic Young's modulus (E_L) and loss tangent (tan _L ) along the grain, dynamic shear modulus (G_L) and loss tangent (tan _S) in the vertical section, and density () of a hundred spruce wood specimens used for the soundboards of musical instruments were determined. The relative acoustic conversion efficiency ( ) and a ratio reflecting the anisotropy of wood (, (E_L/G_L)(tan _S/tan _L)) were defined in order to evaluate the acoustic quality of wood along the grain. There was a positive correlation between and , and the variation in was larger than that in . It seemed logical to evaluate the acoustic quality of spruce wood by a measure of . By using a cell wall model, those acoustic factors were expressed with the physical properties of the cell wall constituents. This model predicted that the essential requirement for an excellent soundboard is smaller fibril angle of the cell wall, which yields higher and higher . On the other hand, the effects of chemical treatments on the and of wood were clarified experimentally and analyzed theoretically. It was suggested that the and of wood cannot be improved at the same time by chemical treatment.     

A Method for Calculating Thermal Radiation Properties of Multilayer Films from Optical Constants

A calculation method for the incident angle dependence of the solar absorptance _S and the temperature dependence of the total hemispherical emittance _H of multilayer films is proposed. The method is based on calculation of _S and _H from optical constants in the wavelength region from 0.25 to 100 m for thin polymer films and deposited metal. In this paper we provide values of _S in the incident angle region from 0 to 90° and _H in the temperature range from 173.15 to 373.15 K for two-layer samples of aluminum-deposited polyimide film. The results obtained for _S and _H by the present method are compared with experimental results measured by both spectroscopic and calorimetric methods. The calculated results of _S and _H agree well with the experimental results.     

Microstructures of titanium-aluminides produced by laser surface alloying

The microstructures of Ti-Al layers (from 43–80 at %Al) produced by laser surface alloying of titanium substrate with a powder feed technique have been investigated. The laser processing parameters were; 1.8 kW laser power, 3 mm beam diameter, 7 mm s^–1 traverse speed, and values of powder flow rates of aluminium ranging from 0.07–0.11 g s^–1. The microstructures were dendrites of ₂ and interdendritic regions of ₂+ in the Ti-43 at %Al alloy; dendrites of either ₂ or ₂+ with interdendritic in the Ti-50 at %Al alloy; dendrites of ₂+ with interdendritic in the Ti-55 at %Al alloy; single phase in the Ti-60 at %Al alloy and TiAl₃ dendrites and Al solid solution in the interdendritic regions in the Ti-80 at %Al alloy. The microstructures were fine and comparable to those produced by other methods of rapid solidification processing. The microstructures of the Ti-50 and Ti-55 at %Al alloys were in agreement with the existence of the peritectic reactions:L + andL + , in the Ti-Al system.