Water－Aromatic Liquid－Liquid－Vapour Equilibrium Calculation Using a Cubic Equation of State

Ｗａｔｅｒ－ＡｒｏｍａｔｉｃＬｉｑｕｉｄ－Ｌｉｑｕｉｄ－ＶａｐｏｕｒＥｑｕｉｌｉｂｒｉｕｍＣａｌｃｕｌａｔｉｏｎＵｓｉｎｇａＣｕｂｉｃＥｑｕａｔｉｏｎｏｆＳｔａｔｅＧｕａｎｇｈｕａＧａｏ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｃａｌＥｎｇｉｎｅｅｒｉｎｇ...     

Exergetic analysis of carbon dioxide vapour compression refrigeration cycle using the new fundamental equation of state

The purpose of this paper is to present exergy charts for carbon dioxide (CO₂) based on the new fundamental equation of state and the results of a thermodynamic analysis of conventional and trans-critical vapour compression refrigeration cycles using the data thereof. The calculation scheme is anchored on the Mathematica platform. There exist upper and lower bounds for the high cycle pressure for a given set of evaporating and pre-throttling temperatures. The maximum possible exergetic efficiency for each case was determined. Empirical correlations for exergetic efficiency and COP, valid in the range of temperatures studied here, are obtained. The exergy losses have been quantified.