Superconducting and Magnetic Properties of Zn-doped YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript>

The superconducting properties and AC/DC magnetic properties of YBa₂Cu_3−x Zn _x O_7−δ , (x=0.0, 0.01, 0.03, 0.05, 0.10 and 0.15) compounds were investigated. Samples were synthesized through solid-state reaction route. X-ray diffraction data confirms the single-phase orthorhombic/tetragonal crystallization for the studied samples. Thermo-Gravimetric Analysis (TGA) was done for pure and Zn-doped YBa₂Cu₃O_7−δ (YBCO) samples. Results reveal that at higher dopant levels the doped samples are more oxygen-deficient than the undoped ones. The superconducting properties of YBa₂Cu_3−x Zn _x O_7−δ system always enhance with addition of oxygen to Cu–O chains, which causes enhancement of superconducting carrier density together with orthorhombic structure. Zn substitution causes an overall reduction of superconducting condensation energy with systematic degradation of superconducting properties like T _c and J _c. This occurs via induced non-homogeneity of hole carrier density created by extended nature of perturbation on electronic structure in CuO₂ planes and its weak-link type behavior. AC susceptibility measurement reveals that Zn doping reduces the inter-granular couplings. Scanning Electron Microscope (SEM) images indicate that increment of average grain size with increasing of Zn concentration.     

Effect of Sintering Temperature on Magnetic and Electrical Properties of GdBaCo<Subscript>2</Subscript><Emphasis Type="Italic">O</Emphasis><Subscript>5 + <Emphasis Type="Italic">δ</Emphasis></Subscript>

In this study, we report the results of an investigation into the sintering temperature dependence of magnetic and transport properties for GdBaCo₂ O _{5 + δ} synthesized through a sol-gel method. The lowering of sintering temperature leads to the increase of oxygen content and the reduction of grain size. The increase of oxygen content results in the enhancement of magnetic interactions and the weakening of Coulomb repulsion effect, while the reduction of grain size improves the magnetoresistance effect. Metal-insulator transition accompanied with spin-state transition is observed in all samples.     

Effect of CdTe Addition on the Electrical Properties and AC Susceptibility of YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript> Superconductor

The effect of CdTe addition on YBa₂Cu₃O_7?δ (CdTe) _x (x = 0–0.10) has been studied. XRD patterns showed the presence of impurities including CdTe for x ≥ 0.05 wt%. The resistance versus temperature curves showed metallic behavior for all samples. The onset temperature T _{c onset} for all samples is between 90 and 92 K. The superconducting transition width, ΔT _c = 4 K for all samples except for x = 0.1 wt% where ΔT _c = 6 K. The superconducting transition determined by AC susceptibility measurement also showed little change in \(T_{\mathrm {c}\chi ^{\prime }}\) (between 89 and 92 K). However, the peak temperature T _p of the imaginary part of the susceptibility χ″, showed a drastic decrease for samples with x > 0.05 wt%. This indicated that the superconducting grains were strongly decoupled for x > 0.05 wt% due to the impurities as observed in the XRD pattern. The intergrain critical current density, J _c at T _p for the x = 0 sample is J _c (82 K) = 17 A cm^?2. These results can be useful in the fabrication of semiconductor/YBCO superconductor hybrid systems.     

Effect of Ba/Y Molar Ratio on Superconducting Properties of BaTiO<Subscript>3</Subscript>-Doped YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript><Emphasis Type="Italic">O</Emphasis><Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript> Films

YBa₂Cu₃ O _7?δ (YBCO) films with BaTiO₃ (BTO) nanostructures were prepared by using the precursor solutions with different cationic molar ratios of Y:Ba:Cu = 1.0:1.6–2.0:3.0 in the TFA-MOD process. These YBCO films were deposited on (00 l)-oriented LaAlO₃ single-crystal substrates using a spin coater. The high superconducting critical current density (J _C) (77 K, self-filed) of more than 10 MA/cm² for the final BTO-doped YBCO film was obtained. Moreover, the effect of different Ba/Y molar ratios in the precursor solution on superconducting properties of BTO-doped YBCO films was investigated. Compared with the BTO-doped YBCO film deposited by using the precursor solutions with Ba/Y molar ratio of 2.0, an enhancement of J _C in a magnetic field for the film from the solution with Ba/Y molar ratio of 1.9 was achieved. For Ba/Y molar ratios of 1.6 and 1.7, a reduction of J _C in a magnetic field occurred. The J _C enhancement may be mainly ascribed to the enhanced flux pinning by the Y₂Cu₂ O ₅ nanostructures with the optimal number dispersing in YBCO matrix.     

Effect of Firing Temperature on the Structure and Superconducting Properties of YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">x</Emphasis></Subscript> Films

YBa₂Cu₃O_7−x (YBCO) films were prepared on LaAlO₃ single crystal substrate under various firing temperatures (750–800 °C) in the crystallization process by metalorganic deposition (MOD) method. The coating solution was made by mixing the fluorine-free precursor solution containing Y and Cu with Ba–fluorine precursor solution (Ba-TFA). The effect of firing temperature on the structure and superconducting properties of YBCO films was systematically investigated. The results indicated that YBCO-films were smooth, crack-free, exhibited good textures and retain high oxygen content according to the XRD and SEM images. Sample of YBCO-film fired at 780 °C showed highest superconducting properties including high critical transition temperature T _c=89 K, sharp transition temperature ΔT _c<1 K, and critical current density J _c=2.8 MA cm⁻², which are attributable to excellent in-plane textures and dense microstructures with good connectivity between the grains.     

Study of YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript> Superconductor/Graphene Oxide Composite

The aim of this research was to fabricate YBa₂Cu₃O_7?δ (YBCO) superconductor composite with graphene oxide nanosheets and to study the effect of the graphene oxide nanosheets on YBCO superconductor properties. For this purpose, the samples of pure superconductor and superconductor composite with 0.001, 0.01, and 0.1 wt.% graphene oxide were synthesized. First, graphite oxide was made by Hummer’s chemical method; after that, graphene oxide nanosheets were produced by bath-keeper ultrasonic. Then, different amounts of graphene oxide were added to the process of superconductor fabrication, which was made by solid-state reaction method. The samples were characterized and studied by Meissner effect test, XRD analysis, FESEM imaging, EDX measurement, and ac magnetic susceptibility. The critical current density (J_c) of samples was measured by four probes method. The results showed that by increasing the weight ratio of graphene oxide, J_c and T_c decrease.     

Fabrication and Analysis of Tri-layer YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript><Emphasis Type="Italic">O</Emphasis><Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript> Thick Films by Low-Fluorine MOD Method

Improving the thickness of superconducting layer in coated conductors is an effective way to enhance its critical current. In this work, tri-layer YBCO/YBCO/YDyBCO films were successfully deposited on buffered Hastelloy substrate using the multi-coating lowfluorine metal-organic decomposition (LF-MOD) method and the thickness of the films can be up to 2.4 μ m. The effects of high-temperature annealing time on microstructures and superconducting properties of the films were systematically studied. Energy dispersive X-ray spectroscopy (EDS) results reveal that there remains a large amount of F element in the upper layer of the film when the annealing time is too short. With increasing the annealing time, the fluoride-containing precursor converts to YBCO grains completely. But the coarsening of grains appeared, and the critical current density (J _c) of the film dropped slightly when the annealing time is too long. The cross-sectional scanning electron microscope (SEM) image and EDS plane analysis were applied to investigate the microstructure and element distribution of the final triple-layer YBCO films, respectively. The critical current of the final YBCO superconducting film could reach 316 A (77 k, self-field) for 1.2-cm-wide tapes with the optimal annealing conditions.     

Synthesis and Characterization of Ni<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Cu<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Bi<Subscript>3</Subscript> Superconductor

In this paper, we characterized the microstructure and superconducting properties of Cu-doped NiBi₃ samples. The polycrystalline Ni_1?x Cu _x Bi₃ (0 ≤ x ≤ 0.10) samples were prepared using a solid-state reaction method. The crystal structure and unit cell parameters were determined by Rietveld refinement of powder X-ray diffraction. The data showed that the main phase present corresponded to NiBi₃ without dependence on the Cu concentration, but with small quantities of Ni and Bi. The SEM and AFM measurements revealed that the main phase was inhomogeneous at microscopic level, with Bi richer regions in comparison to other regions. However, Raman spectroscopy results did not show significant changes in the spectra with Cu doping and in different regions of the samples. Another finding was that regardless of Cu doping, the superconducting transition temperature was 4.05–4.06 K.     

AC Susceptibility and Superconducting Properties of Graphene Added YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">d</Emphasis></Subscript>

The effect of graphene (G) addition on YBa₂Cu₃O_7?δ(G)_x (x =?0 ? 0.03 wt%) has been studied using the X-ray diffraction method, scanning electron microscopy, electrical resistance versus temperature, transport critical current density J_c, and AC susceptibility measurements. XRD patterns showed single-phase YBa₂Cu₃O_7?δ (YBCO) for all samples. SEM micrographs showed filling of the voids between YBa₂Cu₃O_7?δ grains as graphene was added. The temperature-dependent electrical resistance curves showed metallic normal state behavior and onset transition temperature T_conset between 90 and 92 K for all samples. AC susceptibility measurement showed transition temperature \(T_{\mathrm {c} \chi ^{\prime }}\) between 90 and 93 K. \(T_{\mathrm {c} \chi ^{\prime }}\) was maintained or improved slightly as graphene was added. The x =?0.001 wt% showed the highest J_c, i.e., 2750 A cm^?2 at 77 K and 5570 mA cm^?2 at 30 K which was 13 and 40 times higher than that of the non-added YBCO, respectively. The peak temperature T_p of the imaginary part of the susceptibility χ^″ was around 78–82 K for all samples indicating grain coupling was not weakened as graphene was added.     

Improved Superconducting Properties of Thick YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript> Film by Adding Amino-Rich Polyethyleneimine in Precursor Solution

Polyethyleneimine (PEI) with an amount of –NH₂ groups used in precursor solution could effectively reduce Cu²⁺ volatilization during the pyrolysis process. Thermogravimetric analysis shows that the temperature window of low-temperature pyrolysis for precursor solution with PEI (PEI-YBCO) is widened significantly. The slower pyrolysis process can enrich Cu²⁺ and improve critical current density (J_c) of PEI-YBCO films. The highest J_c is 3.03 MA/cm² at 77 K when the amount of PEI is 0.5 g/10 mL and the film thickness is 400 nm. Then the thickness increases from 0.4 to 2.0 μm by changing the coating times. The J_c values of PEI-YBCO films decrease gradually with the thickness increase. However, the critical current (I_c) can be up to 197 A/cm (at 77 K, self-field) and J_c can still keep 1.68 MA/cm² at 1.2 μm.     

Influence of Oxygen on the Tribomechanical Properties of Single Crystals of YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript>

This paper reports a study on the mechanical and tribological properties of ab- and a (b) c?planes of YBa₂Cu₃O_7?δ single crystals. The single crystals were grown using a CuO-BaO self-flux method. The oxygenation effect on the mechanical and tribological properties of ab- and a (b) c?planes is reported. For the ab- plane, the hardness and elastic modulus were around 6 and 50 GPa, respectively. In this case, significant differences were not observed among the hardness and elastic modulus at different oxygenation states. However, the hardness and elastic modulus for as-grown and oxygenated YBa₂Cu₃O_7?δ single crystals were different from that of the a (b) c?plane, and were observed to be slightly higher for the as-grown than for the oxygenated samples. For as-grown and oxygenated samples, we observed hardness values around 4.7 and 2.0 GPa, respectively. Regarding the elastic modulus, the values were 75 and 40 GPa, respectively. The indentation fracture toughness values on the ab- plane for the as-grown and oxygenated YBa₂Cu₃O_7?δ single crystal were 3.7 ± 1.2 and 2.9 ± 1.2 MPa m^1/2, respectively. For the ab- plane, the scratch resistance of the as-grown sample was higher than that of the oxygenated sample and the scratches under load were deeper for the oxygenated sample. As regards the a (b) c?plane, the scar features were seemingly constant through all the scratch lengths and the scratches under load were deeper and larger for the oxygenated than that for the as-grown sample.     

Angular-Dependent Vortex Pinning Properties of YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">δ</Emphasis></Subscript>/Y<Subscript>2</Subscript>O<Subscript>3</Subscript> Quasi-Multilayers

A series of quasi-multilayers of YBa₂Cu₃O_7?δ (YBCO)/Y₂O₃ specifically 70 × (m YBCO/n Y₂O₃) were prepared on SrTiO₃ single crystal using pulsed-laser deposition (PLD) with a controlled deposition pulses of m = 40 and n = 2, 5, and 10 for YBCO and Y₂O₃, respectively. The x-ray diffraction patterns indicate that all the present quasi-multilayers exhibit good c-axis orientation. The angular dependence of critical current density (J _c ) on applied magnetic field directions are systemically measured to study the anisotropic vortex pinning performances for those quasi-multilayers. It is revealed that compared with the pure YBCO films, the quasi-multilayers with n = 2, i.e., a proper constituent pulse of Y₂O₃, exhibits the enhanced vortex pinning abilities in all angles between c-axis orientation and the applied magnetic field direction. As well, such a quasi-multilayer film (n = 2) shows the higher lift factor J _c (Θ)/ J _c (90°) and much better vortex pinning properties at high fields and high temperatures, showing promising potential for coated conductor application.     

Effect of Low Temperature Annealing on the Magnetic Properties of Ga<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>As/GaAs Superlattices

We have studied the effect of low-temperature (LT) annealing on the properties of Ga_1?xMn _x As/GaAs superlattices (SLs). One SL contained GaAs layers doped by Be (which acts as a p-type dopant), while the GaAs layers of the other SL were undoped. The Be-doped SL exhibited a coercive field (H_C) three times larger than the undoped SL, and showed a much more robust remanent magnetization (M_r). While the effect of LT annealing on the undoped SL was relatively minor, magnetic properties of the Be-doped SL changed significantly after annealing. The coercive field of the Be-doped SL was reduced about three times, becoming comparable to that of the undoped SL. After annealing the temperature dependence of M_r in the Be-doped SL also became similar to the undoped SL. We discuss the effect of LT annealing on the magnetic properties of the two SL systems in terms of inter-diffusion of carriers, and of the reduced sensitivity to annealing characteristic of capped structures.     

Enhanced Superconductivity in Double-Doping Cu<Subscript>0.15</Subscript>TaSe<Subscript>2−<Emphasis Type="Italic">x</Emphasis></Subscript><Emphasis Type="Italic">S</Emphasis><Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>

Superconducting Cu _x TaSe₂(x=0.05, 0.15) and Cu_0.15TaSe_2?x S _x (x=0, 0.5, 1, 1.5) single crystals have been systematically fabricated by a chemical vapor transport method. It is found that the double doping in TaSe₂, i.e., the simultaneous intercalation of Cu and substitution of Se by S, can substantially enhance the superconducting transition temperature. Transport property measurements give evidence of the coexistence and competition of charge density wave state and superconductivity in Cu _x TaSe₂ which provide meaningful information to understand the complex electronic states in this system. The parallel shift and the fan-shape broadening behaviors are observed in the superconducting transition curves under magnetic fields of Cu_0.15TaSeS and TaSeS, respectively, indicating an increase of coherence length and suppression of superconducting fluctuation induced by copper intercalation.     

Sintering mechanisms in YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7−<Emphasis Type="Italic">x</Emphasis></Subscript> superconducting ceramics

The densification of ceramic compacts of YBa₂Cu₃O_7−x (123) was studied with a vertical dilatometer. The runs effected under isothermal conditions (ISO) covered the 920–970^∘C range and were performed under static air atmosphere. Also, controlled heating rate (CHR) runs, from about 800 to 1050^∘C, were conducted at 5^∘C/min under either flowing oxygen or static air. The ISO data could be satisfactorily fitted by the solution-precipitation (SP) model giving an activation enthalpy of 221 kJ/mol. Furthermore, the CHR data for 920–970^∘C was also fitted with the same model giving 207 kJ/mol as the activation energy. From analysis of CHR data, the initial stage sintering is driven by solid state sintering between 827–894^∘C (823–908^∘C in O₂). Then, in the interval 902–920^∘C (914–934^∘C in O₂) the intermediate stage driven by grain growth (GG), competes with the rearrangement process associated to the presence of a liquid phase. This last process applied because the next sintering stage in the range 922–970^∘C (938–990^∘C in O₂ flow) could be fitted by the SP model with an activation enthalpy of 207 kJ/mol (229 kJ/mol in O₂). In the range 972–995^∘C (990–1014^∘C in O₂), the solid state (GG) intermediate stage mechanism and/or viscous flow competes with the SP process.     

Lanthanum Concentration Effect of Magnetocaloric Properties in La<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>MnO<Subscript>3−<Emphasis Type="Italic">δ</Emphasis></Subscript>

Magnetocaloric properties of La _x MnO _3?δ films in the composition range 0.75 ≤ x ≤ 1 near phase transition from a ferromagnetic to a paramagnetic state were investigated. For x > 0.75 composition, it is showed that the increasing of La concentration improves magnetocaloric properties. It is also showed that post-annealing films in O ₂ improves magnetocaloric effect. The magnetocaloric properties are affected by Mn ⁺³/Mn ⁺⁴ ratios, which can be varied either by changing La concentration or varying the oxygen content in the La _x MnO _3?δ system. Moreover, La _x MnO _3?δ films can be used as a working material of an apparatus based on the active magnetic regenerator cycle that cools hydrogen gas.     

Microstructure and Magnetic Properties of Sn<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Ni<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript>2</Subscript> Thin Films Prepared by Flash Evaporation Technique

An effort was made to develop semiconductor oxide-based room temperature dilute magnetic semiconductor (DMS) thin films based on wide band gap and transparent host lattice with transition metal substitution. The Sn\(_{\mathrm {1}-x}\)Ni\(_{x}\textit {O}_{\mathrm {2}}\) (\(x\,= \mathrm {0.00, 0.03, 0.05, 0.07, 0.10, and \,0.15}\)) thin film samples were prepared on glass substrates by flash evaporation technique. All the samples were shown single phase crystalline rutile structure of host SnO\(_{\mathrm {2}}\) with dominant (110) orientation. The Ni substitution promotes reduction of average crystallite size in SnO\(_{\mathrm {2}}\) as evidenced from the reduction of crystallite size from 40 (SnO\(_{\mathrm {2}}\)) to 20 nm (Sn\(_{\mathrm {0.85}}\)Ni\(_{\mathrm {0.15}}\textit {O}_{\mathrm {2}}\)). In the energy dispersive spectra as well as X-ray photoelectron spectra of all the samples show, the chemical compositions are close to stoichiometric with noticeable oxygen deficiency. The crystalline films were formed by coalescence of oval-shaped polycrystalline particles of 100 nm size as evidenced from the electron micrographs. The energy band gap of DMS films decreases from 4 (SnO\(_{\mathrm {2}}\)) to 3.8 eV (x \(=\) 0.05) with increase of Ni content. The magnetic hysteresis loops of all the samples at room temperature show soft ferromagnetic nature except for SnO\(_{\mathrm {2}}\) film. The SnO\(_{\mathrm {2}}\) films show diamagnetic nature and it converts into ferromagnetic upon substitution of 3 % Sn\(^{\mathrm {4+}}\) by Ni\(^{\mathrm {2+}}\). The robust intrinsic ferromagnetism (saturation magnetization, 21 emu/cm\(^{\mathrm {3}}\)). Further increase of Ni content weakens ferromagnetic strength due to Ni-O antiferromagnetic interactions among the nearest neighbour Ni ions via O\(^{\mathrm {2-}}\) ions. The observed magnetic properties were best described by bound magnetic polarons model.     

Properties of YBaCuFe<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Ni<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript>5</Subscript> (0 < <Emphasis Type="Italic">x</Emphasis> ≤ 0.3) solid solutions

YBaCuFe_{1 – x}Ni_xO₅ solid solutions are shown to exist for x 0.3. Data are presented on the lattice parameters, thermal stability, thermal expansion, electrical conductivity, thermoelectric power, magnetic susceptibility, and dielectric properties of the solid solutions. Ni substitution for Fe notably increases the electrical conductivity of the solid solutions, reduces their thermoelectric power and thermal expansion, and shifts the antiferromagnetic—paramagnetic phase transition and dielectric anomalies in YBaCuFe_{1 – x}Ni_xO₅ to lower temperatures.Translated from Neorganicheskie Materialy, Vol. 40, No. 12, 2004, pp. 1515–1519.Original Russian Text Copyright © 2004 by Chizhova, Klyndyuk, Bashkirov, Petrov, Makhnach.     

Photoluminescent properties and Hall coefficient of Cu<Subscript>1−<Emphasis Type="Italic">y</Emphasis></Subscript>In<Subscript>1+<Emphasis Type="Italic">y</Emphasis></Subscript>Se<Subscript>2+δ</Subscript>

The photoluminescence spectra and Hall coefficient of CuInSe_2+δ and Cu_1?y In_1+y Se₂ alloys have been measured. The results, combined with structural data, have been used to identify dominant defect species and determine their energies at different deviations from stoichiometry in the alloys.     

Microhardness of the YbAg<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>In<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Cu<Subscript>4</Subscript> alloy system

We report Vickers microhardness measurements on flux grown single crystals of the YbAg_xIn_{1 − x}Cu₄ alloy system. Although sample dependent, the microhardness exhibits a clear concentration dependence: in general, it decreases with x. The lattice parameter as a function of x exhibits a similar behavior. For x < 0.5, where the lattice parameter is almost constant, the microhardness exhibits a weak enhancement. Similar concentration dependence of the lattice parameter, resistivity and microhardness allows us to conclude that the microhardness reflects the evolution of the YbAg_xIn_{1 − x}Cu₄ alloy system towards more metallic character with increasing x.