共查询到20条相似文献,搜索用时 62 毫秒
1.
ICP-MS测定两种一枝黄花中12种微量元素 总被引:1,自引:0,他引:1
为确定两种一枝黄花中微量元素的差异,建立了微波消解-ICP-MS法,测定加拿大一枝黄花与一枝黄花中Ca、Mg、P、Fe、Mn、Ni、Cu、Zn、Se、Cr、Hg和Pb12种微量元素。方法的加标回收率为95.2%~107.1%,相对标准偏差在2.5%~8.9%之间,检出限在0.002~0.057μg.L-1之间,该方法具有良好的准确度和精密度。分析结果表明,加拿大一枝黄花与一枝黄花均含有Ca、Mg、P、Mn和Fe元素,前者中Ca、Cr、Mn、Zn、Pb、Ni含量较高,而后者中的Mg、P、Fe、Cu、Se含量较高。 相似文献
2.
3.
准确测定螺旋藻、茶多酚中9种人体必需微量元素的含量。采用电感耦合等离子体-质谱法(ICP-MS)进行测定。结果证明该法灵敏度高、结果准确、检出限低、具有良好的精密度和准确度,是测定螺旋藻、茶多酚中微量元素的有效方法。 相似文献
4.
Simultaneously determination of 42 trace elements in varies plant reference materials by different digestion techniques ICP-MS was evaluated. The digestion techniques was compared with that using different reagents. Using of HF will improve recovery of the rare earth element and Be, Ti, Sb, U etc and the disadvantage is As, B, Hg will volatilize due to drive HF using HNO3. But it can be avoided with using nebulizer and spray chamber of resistant HF in ICP-MS. 相似文献
5.
6.
7.
ICP-MS法测定地衣和鸡蛋粉中9种微量元素及其不确定度的评定 总被引:1,自引:0,他引:1
用硝酸和高氯酸混合酸消解样品 ,ICP MS法同时测定地衣和鸡蛋粉中Mn、Cu、Zn、Sr、Cd、Fe、Pb、As和Se9种微量元素的含量。在优化实验下 ,测得检出限为 (ng/L) :55Mn2 ,6 3Cu4 ,56 Fe4 ,6 6 Zn9,88Sr1,114 Cd2 ,2 0 8Pb5 ,75As12 ,80 Se6 0。用国家一级标准物质甘兰GBW0 85 0 4验证方法的准确度 ,测定值与标准值吻合较好。并对不确定度的评定程序举例说明 相似文献
8.
9.
《仪器仪表与分析监测》2015,(4)
采用电感耦合等离子体质谱法同时测定地表水中砷、锑、铅、镉、铊、铍、钴、钒8种金属元素含量。对质谱干扰和非质谱干扰进行了校正。外标法定量,8种元素在一定的质量浓度范围内与其信号强度呈线性关系,各元素标准曲线的相关系数均大于0.999,方法检出限为0.000 2~0.12μg/L,实际水样加标回收率为91.0%~105%,相对标准偏差为1.23%~5.69%(n=6)。 相似文献
10.
Human feces were collected in acid-washed plastic containers for three consecutive days from 30 subjects of Zhenjiang area, the fecal samples for the three-days period were pooled, weighed and homogenized, then dried, ground and ashed at 相似文献
11.
ICP-MS测定饮用水中痕量元素 总被引:2,自引:0,他引:2
ICP-MS技术目前在我国地面水测定中应用还较少,本文通过对饮用水中微量元素的检出限、精密度、加标回收及对标准内控样品的测定,说明用ICP-MS测定饮用水中痕量元素具有干扰少、检出限低、测定快速、能同时测定多种元素等优点。 相似文献
12.
Blood rare earth elements (REEs) were determined by inductively coupled plasma mass spectrometry (ICP-MS) in 112 children aged 7-10 years randomly. Samples are from the area containing rare earth ore and the control area in Xunwu County, Jiangxi province. Seen from fifteen kinds of REEs, eleven kinds of REEs increased in children's blood in rare earth ore area, and total light REEs content was 0.85 times higher and total heavy REEs content was 0.50 times higher than that in the control area. The blood REEs content would be higher if living a long time in the environment with high concentration of REEs. 相似文献
13.
14.
15.
16.
Human liver samples were obtained in autopsy from 16 subjects died suddenly, who were healthy, normal before death and lived in 4 different areas with different dietary types in China. To determine 48 micro quantity elements in human liver by inductively coupled plasma mass Spectrometry (ICP-MS),samples were microwave digested using HNO3 and H2O2 . Rhenium was used as an internal standard element standard. Reference materials of GBW(E) 080193 bovine liver and GBW09101 human hair were analysed by the described method. The analytical values of two standard reference materials showed close agreement with the reference values. The method is simple ,rapid, sensitive and accurate. 相似文献
17.
A method of analysis trace element chloride in cleaning products by Inductively Coupled Plasma-Mass Sepctrometry (ICPMS) was studied. It has good precision (RSD<5%). The LOD is 0.06 μg/L (n=7). The recovery is 93.7%-110.0%. 相似文献
18.
19.
The application of inductively coupled plasma mass spectrometry (ICP-MS) for determination of boron in water and urine samples was described. The detect limit (3σ) was 0.057 μg/L. The precision of the method was less than 2%. Multi-elements including Cr, Cu, Cd, Ba, Sr, Mn, Co, Tl, Li, Pb, Ca, Fe, K, Na, Mg, P, Si and Zn could be measured simultaneously. The method was successfully used in practice. 相似文献
20.
高分辨电感耦合等离子体质谱法测定煤质样品中49种痕量元素 总被引:1,自引:0,他引:1
Various trace elements, especially potential toxic trace elements such as As, Cd, Cr, Cu, Hg, Pb, Ni, Se, Tl, Zn, would be concentrated in processing of coal. Determination of these elements in coal is very important for identification of coal quality. A method is developed for determination of 49 trace elements in coal by high resolution inductively coupled plasma mass spectrometry (HR-ICPMS). Microwave acid digestion and low-temperature airproof acid digestion for sample preparation were investigated. It is shown that the low-temperature airproof acid digestion method is of lower blank, and more suitalbe for the coal sample preparation. The on-line internal standard (Rh) sample introduction is applied to compensate matrix effects in measurement by ICPMS. The method gives low detection limits (0.002-1.60 μg/g) and better relative standard deviations (0.60%-4.78%) for the determined 49 elements in coal. 相似文献