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The application of comminution technology such as the high-pressure grinding rolls (HPGRs), which is able to generate a high density of cracks in the ore particles, is favourable for leaching processes. Extraction of metallic values by the heap leach process, can take place on the particles with partial exposure of mineral grains, if it can provide sufficient surface front for chemical attack by leaching solution. The aim of this study was to assess the benefits of high crack density in the ore particles produced using the HPGR and how it could diminish due to inadequate percolation of the leaching agent.A zinc ore was comminuted using HPGR at three different pressure settings and with a cone crusher for the control experiment. Subsamples from the (+23/−25, +14/−16, +5.25/−6.75 mm) size fractions were characterized and packed into leach reactors. The reactors were stopped from time to time to investigate the progress of crack and micro-crack growth and its effect on metal extraction using the X-ray computed tomography (CT). The results are validated with those obtained using traditional techniques such as SEM and QEMSCAN. Investigation of the leach reactors residue indicated significant changes in the particle size distribution (PSD) of initial feed toward the fine size fraction. The residues from the reactors leaching the material prepared using the HPGR product contained more fine particles than the reactors, which were fed by cone crusher product. These differences were up to 10.3%. 相似文献
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Mohammad Soleimani Jochen PetersenReza Roostaazad Soheil HosseiniS. Mohammad Mousavi Alireza Najafi Akhtarolmolouk Kazemi Vasiri 《Minerals Engineering》2011,24(1):64-69
In this study, the Geocoat™ technology was used for the extraction of zinc from a mineral concentrate obtained from the Kooshk mine (Yazd, Iran) by a culture dominated by the mesophilic bacterium Acidithiobacillusferrooxidans in a packed column bioreactor. A low grade sphalerite ore was used as support for the concentrate coating. During the 100 days of leaching pH, Fe3+, Fetotal, microbial population density and zinc extraction were measured. The final zinc extraction from concentrate and low grade support was 97% and 78%, respectively, and it was found that leaching from the support does not proceed significantly before leaching from the coating is completed. 相似文献
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《Minerals Engineering》2007,20(7):694-700
The leaching of low-grade oxide zinc ore and simultaneous integrated selective extraction of zinc were investigated using a small-scale leaching column and laboratory scale box mixer-settlers. Di-2-ethylhexyl phosphoric acid (D2EHPA) dissolved in kerosene was used as an extractant. The results showed that it was possible to selectively leach zinc from the ores by heap leaching. The zinc concentration of the leach liquor in the first leaching–extraction circuit was 32.57 g/L, and in the 16th cycle the zinc concentration was 8.27 g/L after the solvent extraction. The leach liquor was subjected to solvent extraction, scrubbing and selective stripping for the enrichment of zinc and the removal of impurities. The pregnant zinc sulfate solution produced from the stripping cycle was suitable for zinc electrowinning. 相似文献
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Sílvia M.C. Santos Remígio M. Machado M. Joana N. Correia M. Teresa A. Reis M. Rosinda C. Ismael Jorge M.R. Carvalho 《Minerals Engineering》2010,23(8):606-615
Atmospheric leaching of a sphalerite concentrate in sulphate and chloride media was performed and the effect of several variables, such as solid/liquid ratio and oxidant (Fe(III)) concentration were investigated. The behaviour of minor elements, such as Cu, In, As, Sb, Bi, Sn and Pb, was also studied under different conditions. The results showed that using a solid/liquid ratio of 5% (w/v) it was possible to leach 95% of zinc after 2 h, with a solution of 0.5 M H2SO4 and Fe2(SO4)3 at 80 °C. The minor elements As, Sb and Bi were also completely leached whereas copper leaching was favoured by the use of chloride medium. The oxidation of Fe(II) during the leaching tests was studied and an improvement of 20% zinc extraction was observed in an oxygenated system. Cross-current leach tests using two/three stages and a solid/liquid ratio of 10% (w/v) were performed to achieve 90% of zinc extraction. The electron microprobe analysis of the leaching residues showed no change on the sphalerite composition after the leaching, which indicates that the leaching of sphalerite involves the break down of the sulphide structure. 相似文献
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论述了常规法浸出、高温高酸浸出、硫化锌精矿直接加压浸出几种湿法炼锌工艺除铁过程的特点。指出硫化锌精矿直接加压浸出是一种能简化电锌生产工艺流程、降低单位产品能耗物耗、提高金属回收率的全湿法炼锌新工艺。 相似文献
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Acidithiobacillus ferrooxidans at 30 °C and Sulfobacillus thermosulfidooxidans at 47 °C were selected from a preliminary screening of various acidophiles for their ferric iron reduction capacities during anaerobic, autotrophic growth on sulfur. The selected cultures were used with a polymetallic sulfide ore under anoxic conditions to demonstrate enhanced solubilization of iron during leaching in shaken flasks and enhanced removal of iron from laboratory ore-leaching columns, compared to leaching with continuous aeration. Ore-associated, ferric iron-rich precipitates, which were formed under previously oxidizing conditions, were a potential influence on extraction of target metals and percolation through ore columns and were available as the source of ferric iron for anaerobic sulfur oxidation. Over twice as much iron was removed by moderate thermophiles when anoxic phases were introduced during the leaching. Enhanced removal of iron and some improvement in extraction of base metals from ore fragments were also demonstrated with a selected “Sulfolobus”-like strain during growth and leaching with alternating periods of aeration and anoxic conditions at 70 °C. 相似文献
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《Minerals Engineering》2006,19(5):478-485
Electric arc furnaces (EAF) generate about 10–20 kg of dust per metric ton of steel, which constitute a hazardous waste, known as EAF dust. This dust contains a remarkable amount of non-ferrous metals, which include zinc, cadmium, lead, chromium and nickel that could be recovered, reducing the environmental impact of the leachable toxic metals, and generating revenue. In this paper, different alkaline leaching techniques were tested in order to dissolve the zinc present in an EAF dust: (i) conventional agitation leaching; (ii) pressure leaching; (iii) conventional leaching following a microwave pretreatment and (iv) leaching with agitation provided by an ultra-sonic probe. Temperature and sodium hydroxide concentration were the variables tested. The highest zinc recovery from the EAF dust, containing about 12% of zinc, was about 74%. This was achieved after 4 h of leaching in a temperature of 90 °C and with a sodium hydroxide concentration of 6 M of the leaching agent. 相似文献
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以含铅锌烟尘为原料, 采用机械活化-硫酸浸出的湿法冶炼工艺分离铅锌烟尘中的金属铅及锌。着重研究了机械活化前后不同的硫酸浓度、液固比、浸出温度、浸出时间等工艺条件对原料中Zn浸出率及Pb入渣率的影响。实验结果表明, 机械活化前, H2SO4直接浸出铅锌烟尘的最佳工艺参数为H2SO4浓度175 g/L、液固比7∶1、浸出温度60 ℃、浸出时间60 min。在最佳工艺条件下, Zn浸出率达92.47%, Pb入渣率为90.30%。原料机械活化30min后, 最佳工艺条件变为H2SO4溶液浓度150 g/L、液固比5∶1、浸出温度50 ℃、浸出时间40 min。此时Zn浸出率达91.52%及Pb入渣率为95.36%。机械活化后铅锌烟尘的Zn浸出率及Pb入渣率对 H2SO4溶液浓度、液固比、浸出温度、浸出时间的依赖性明显降低。 相似文献
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为研究高炉瓦斯泥硫酸浸出锌过程的动力学,以河北某高炉瓦斯泥为原料进行了硫酸浸出试验,分别考察了浸出温度、硫酸浓度对浸出过程锌浸出率的影响。随着浸出温度的升高和硫酸浓度的增加,锌浸出率逐渐提高,浸出速率降低。采用Avrami动力学模型对锌浸出过程进行模拟,结果表明,浸出过程符合n=0.160 4的Avrami动力学模型,反应表观活化能为10.02 kJ/mol,说明浸出过程受扩散控制,因此要提高浸出效率,应加强扩散效应。提高硫酸浓度或升高反应温度,加速了溶液中的反应过程和传质过程,锌浸出率提高。试验结果为湿法浸出过程动力学以及固废资源化利用后续研究和生产实践提供了一定的理论依据。 相似文献
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本文叙述了焙烧球料渗滤浸出的研究结果。重点讨论了各工艺参数对铀浸出率的影响,并测定了焙烧球料的机械强度对渗滤浸出操作的适应性。试验结果表明,在最佳浸出条件下,铀的浸出率可达97.8%,和搅拌浸出的结果相同。焙烧球料的机械强度也能满足渗滤浸出操作要求。 相似文献
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A pH dependent leaching test (CEN/TS 14429) and a percolation leaching test (CEN/TS 14405) developed in CEN/TC 292 have been used for the first time to characterise the release behaviour of different sulphidic mining wastes. Geochemical speciation modeling using LeachXS Orchestra provides another type of partitioning between mineral and sorptive phases than is currently practised in the mining industry. Comparing new leaching test data for seven tailings and two waste rock samples with model predictions gives new insights into release behaviour. In leaching, mineral transformations on the surface of waste rock or tailings particles, rather than bulk mineral composition, dictate release, which implies that mineralogical examinations are not necessarily relevant from a leaching perspective. Kinetic aspects of release from sulphidic waste can be addressed by testing material in different stages of oxidation or exposure to atmospheric conditions. 相似文献
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对铅冶炼难处理复杂氧化锌烟尘碱洗渣进行了"中性浸出—酸浸"工艺试验研究。结果表明,碱洗渣中性浸出时,锌、镉的浸出率先随浸出温度、液固比、搅拌速度和时间的增加而提高,后增速变缓;中浸渣酸浸时,液固比对锌、铟的浸出率无明显影响。锌、铟的浸出率随初始酸度、浸出温度和时间的增加先增加后变缓。中性浸出最佳条件为:温度338K、液固比5∶1、搅拌速度400r/min、浸出时间1h,此条件下,锌、镉的浸出率分别为80.3%和76.3%。中浸渣酸浸最佳条件为:初始酸度100g/L、浸出时间2h、浸出温度363K、液固比5∶1,在该条件下,锌、铟的浸出率分别为97.1%和85.5%。 相似文献
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