共查询到20条相似文献,搜索用时 203 毫秒
1.
氟碳铈精矿空气中焙烧的热分解研究 总被引:2,自引:0,他引:2
利用DTA、TG、XRD及化学分析等方法对山东微山的氟碳铈精矿在空气中焙烧的反应过程进行了研究。指出氟碳铈精矿的分解过程可分为两步,首先较低温度下,(Ce,La)CO_3F氧化分解为(Ce,La)O_(1+x),F_(1-x);随着焙烧温度的提高,(Ce,La)O_(1+x)F_(1-x)继续氧化分解,得到Ce_(0.75)Nd_(0.25)O_(1.875)和La_2O_3等,焙烧过程中部分脱氟,样品总失重率达19.54%。 相似文献
2.
3.
采用循环伏安法研究了LaF_3-LiF二元熔体及添加La_2(CO_3)_3的LaF_3~LiF熔体中,920~950℃下,La ̄(3+)在石墨电极上还原的阴极过程。结果表明:在LaF_3-LiF熔体中,电位在-0.85V左右(相对于石墨参比电极),La ̄(3-)离子在阴极还原析出;在添加La_2(CO_3)_3,的LaF_3-LiF三元熔体中,La(CO_3)_3,分解为La_2O_3,La_2O_3首先电解,然后LaF_3电解,均在阴极上析出镧。镧离子的电化学反应是简单的一步反应,即La ̄(3+)+3e→La。 相似文献
4.
按文献[1~4],L_p与(FeO_n)和R之间均有极值关系存在。本文得出从不同侧面反映的L_p极值关系式和曲线:(1)按CaO/SiO_2=0~0.9,0.91~1.9和>1.9三个区段划分的,用1/T、lg{(CaO)+0.7(mgO)}、lg(TFe)和lg(P_2O_5)表述的一次多项式;(2)按CaO/SiO_2=0~0.09,0.1~0.9,0.91~1.4,1.41~1.9和>1.9五个区段划分的,用1/T,(∑FeO)、(∑FeO) ̄2和lg(1+SiO_2)表述的非齐次多项式;(3)按∑FeO=13%~15%,16%~20%和30%~35%三个区段描述的L_p-R极值曲线。并发现L_p与(∑FeO)和R之间的极值关系存在一定规律。 相似文献
5.
6.
7.
8.
混合碳酸稀土热分解过程的研究 总被引:2,自引:0,他引:2
用DTA热分析技术研究混合碳酸稀土焙烧过程中的脱水过程,分解过程,用Freeman-Carroll法、Piloyan法和Kissinger法对其脱水及热分解的动力学参数进行计算,并对计算的结果进行比较和验证,得到了混合碳稀土脱水过程的反应活化能和反应级数分别为806.9J/mol、0.78,热分解过程的反应活化能和反应级数分别为8.529kJ/mol、0.95。用XRD分析方法研究了不同焙烧温度对焙烧产物的影响,论证高温下焙烧可能产生Ce0.75Nd0.25O1.875相。 相似文献
9.
西南稀土矿的矿石性质及分选工艺研究 总被引:2,自引:0,他引:2
研究了西南稀土矿的矿石性质及分选工艺.原矿风化强烈,产生大约20%的黑色风化物矿泥。-矿石中可工业利用的稀土赋存形式有矿物相和胶态相。矿物相稀土以氟碳铈矿为主,占96%以上,重选或重浮选联合工艺可得到REO30%,50%和60%的氟碳铈矿精矿,稀土回收率65%。胶态相稀土则吸附在Fe-Mn非晶质氧化物矿物上,用热盐酸浸出,氨水除杂,草酸沉淀回收稀土,稀土回收率74.3%,并副产铅。矿石和黑色风化物中稀土都强烈选择铈族稀土,∑CeO2在90%以上,且CeO2>La2O3>Nd2O3。 相似文献
10.
研究了用ICP-AES法测定锌合金中6种稀土元素(La2O3,CeO2,Pr6O11,Nd2O3,Sm2O3,Y2O3)的方法,采用正交设计实验对工作参数进行最佳化选择、基体匹配的方法消除基体影响,利用两点定标校正曲线法计算测量结果。在最佳实验条件下,本法测定杂质元素检出限0.1 ̄0.8μg/g,相对标准偏差2.6% ̄5.6%,回收率91.6% ̄106.3%。方法简便、快速,可以满足科研生产的需要 相似文献
11.
12.
13.
<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic 相似文献
14.
正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field, 相似文献
15.
《China Nonferrous Metals Monthly》2014,(10)
正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF 相似文献
16.
《China Nonferrous Metals Monthly》2014,(10)
正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure 相似文献
17.
《China Nonferrous Metals Monthly》2014,(10)
正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year, 相似文献
18.
《China Nonferrous Metals Monthly》2014,(12)
正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform. 相似文献
19.
正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness. 相似文献
20.
正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully. 相似文献