累积退火参数对Zr-Sn-Nb-Fe-Si合金耐腐蚀性能的影响

目前,有关累积退火参数对Zr-Sn-Nb-Fe-Si合金耐腐蚀性能的影响规律尚不清楚。通过改变Zr-0.5Sn-0.5Nb-0.3Fe-0.012Si合金管坯中间热处理制度制备了2种累积退火参数不同的包壳管,利用光学显微镜、扫描电子显微镜(SEM)和透射电子显微镜(TEM)分析了包壳管的晶粒组织和第二相,并对2种包壳管进行了水质为360℃/18.6 MPa/0.01 mol/L Li OH水溶液、400℃/10.3 MPa过热水蒸汽和360℃/18.6 MPa纯水的静态高压釜长期腐蚀试验。研究结果表明:累积退火参数不同的Zr-Sn-Nb-Fe-Si合金包壳管的晶粒组织和第二相分布、大小、成分相同。累积退火参数对Zr-Sn-Nb-Fe-Si合金的耐腐蚀性能没有显著影响。     

脉冲电流处理对冷轧态GH3030合金再结晶组织性能的影响

目的 探究不同工艺参数下脉冲电流处理对冷轧态GH3030合金静态再结晶组织的影响.方法 利用电子背散射衍射(EBSD),探究脉冲电流处理(EPT)和常规退火处理(CHT)对GH3030合金静态再结晶的影响.探究了两种热处理方式下不同退火温度和时间对冷轧态GH3030合金静态再结晶体积分数、晶粒尺寸以及硬度的影响,计算两种热处理方式下不同工艺参数的静态再结晶动力学方程与激活能.结果 与常规退火处理相比,脉冲电流处理可以快速提高冷轧态GH3030合金的静态再结晶体积分数,并且得到了尺寸更加均匀的晶粒,而脉冲电流处理的合金其硬度值均小于相同条件下常规退火处理的合金.根据静态再结晶动力学方程的结果可知,脉冲电流处理的合金再结晶激活能低于常规退火处理的合金,脉冲电流处理下发生完全再结晶所需时间远远少于常规退火处理下所需时间.结论 脉冲电流处理促进了冷轧GH3030合金静态再结晶行为,并且加速了再结晶晶粒的成核和长大,但脉冲电流处理对改善GH3030合金的硬度效果不明显.     

退火制度对TA18钛合金管材力学性能的影响

通过对TA18钛合金管材在不同工艺制度下的退火实验,得出去应力退火温度、保温时间等工艺参数对成品管材退火后力学性能的影响,并从理论上分析讨论了产生这种影响的原因,从而得到TA18钛合金管材的最佳退火制度。     

大规格铜镍合金无缝管材成品退火工艺研究

选用6个典型规格的铜镍合金无缝管材经拉拔生产后,按拟定的退火试验方案进行退火试验,退火后取样进行性能测试.通过检测拉伸强度、屈服强度和伸长率,以及布什硬度和洛氏硬度,并进行金相试验,观察合金是否由加工态组织变为单相再结晶α组织.结果表明:小于等于700℃的退火温度无法保证获得完全再结晶的单相α组织.退火温度大于730℃...     

研究CT20钛合金管材的冷轧工艺

研究了CT20低温钛合金管材的加工工艺及冷轧变形量、退火温度对管材力学性能的影响。结果表明：CT20合金对加工硬化不敏感,冷轧最大变形量应控制在45％以内;CT20合金管材通过不同温度热处理所获得的等轴、双态和片状组织的室温力学性能差别不大,20K低温下由于孪生变形的发生,片状组织的塑性最好,双态组织则介于片状和等轴组织之间,管材为等轴和双态组织时,冷成型性能优异;对管材进行＋两相区910℃×1h,FC的热处理,可获得综合性能优良的双态组织。     

锆合金耐腐蚀性能及氧化特性概述

归纳了研究锆合金腐蚀方面的一些重要结果,总结了合金元素、第二相、β固溶热处理、累积退火参数、中间退火以及最终退火热处理对锆合金显微组织及耐腐蚀性能的影响规律,讨论了锆合金氧化膜显微组织与腐蚀行为的关系,提出了如何提高锆合金抗腐蚀性能的一些措施.     

工艺参数对半固态Al-4Cu-Mg 合金力学行为的影响

在热模拟实验的基础上,研究了各工艺参数对半固态和供应态Al-4Cu-Mg合金变形力学行为的影响.研究结果表明:在液-固温度区间变形时,变形温度、应变速率对半固态和供应态Al-4Cu-Mg合金的流变应力峰值影响显著,对稳态流变应力影响较小.当变形温度超过某一临界值后,流变应力随变形温度的变化趋于稳定.在固相温度区间变形时,半固态与供应态材料流变应力的变化趋势基本一致,变形均为固相间的塑性变形.但供应态Al-4Cu-Mg合金的原始变形组织和半固态Al-4Cu-Mg合金的球状组织对变形的影响有所不同.     

最终再结晶退火温度对锡磷青铜带材组织、性能的影响

本文在研究温度对 QSn6.5-0.1合金再结晶退火后组织、性能影响的基础上,绘制了再结晶全图,讨论了形变强化前原始晶粒大小对形变强化和低温退火强化的影响。结果表明,降低最终再结晶退火温度,获得细小的原始组织是提高合金性能的有效途径。最终再结晶退火温度由600℃降为450℃,晶粒直径可以减少55μm,强度提高50MPa,再经过轧制变形和低温退火后可获得吏显著的强化效果。     

Zr-4板材的高温变形特征及其理论研究

在200℃至600℃的不同温度条件下,对Zr-4合金板材消除应力态和完全再结晶态的拉伸变形特征、机理以及与力学性能的关系进行了分析讨论。     

Al-Mg-Mn和Al-Mg-Mn-Sc-Zr合金的再结晶

研究了Al-Mg-Mn和Al-Mg-Mn-Sc-Zr合金冷轧后在不同退火温度下合金的组织和性能的变化.结果表明,与不添加钪和锆的合金相比,复合添加0.4%Sc(质量分数)和Zr能使Al-Mg-Mn合金的再结晶开始温度提高120℃左右.添加微量Sc和Zr合金没有明显再结晶终了温度,在接近熔点时显微组织仍是加工态纤维组织.Sc,Zr复合添加形成的纳米级的二次Al3(Sc,Zr)相质点,对位错和亚晶界有强烈的钉扎作用,再结晶难以形核和长大,从而有效地抑制冷轧后退火过程中的再结晶.     

冷拉拔管棒材的残余应力测试与分析

用电阻应变片法测试了管棒材拉拔、矫和退火过程中产品表面残余应力,了管棒材残余应力随工艺参数变化的规律,结果表明,用不同变形方法生产管材,其表面残佟尖力相差很大。对制品采用去应力低温退火,在金属内部完成回复过程是减小制品残余应力最有效的措施。     

退火处理对AZ31镁合金表面Ni-Mo-P镀层组织与耐腐蚀性能的影响

为了进一步提高镁合金表面Ni-Mo-P镀层的耐蚀性,采用0M、XRD和浸泡试验等方法,研究了退火处理对AZ31镁合金表面Ni-Mo-P镀层组织与腐蚀性能的影响。结果表明:AZ31镁合金阳极氧化-化学镀Ni-Mo-P镀层表面为“胞状”组织,随着退火温度的升高或退火时间的延长,AZ31镁合金阳极氧化-化学镀Ni-Mo-P镀层的胞状组织逐渐细化,但镀层厚度降低,同时,非晶态Ni-Mo-P镀层组织逐渐向晶态转变,350℃退火1.0h具有较高的非晶化程度,退火处理后的Ni-Mo-P镀层由Mg、MgO、Mg2SiO4、Ni和Ni3P组成;退火使AZ31镁合金阳极氧化-化学镀Ni-Mo-P镀层耐蚀性降低,350℃退火1.0 h镀层具有相对较好的耐蚀性,这与镀层的厚度和非晶化程度有关。     

Corrosion of Zr + 2.5% Nb Alloy Hardened by Thermal and Thermomechanical Treatment

We study the effect of fast high-frequency hardening, subsequent annealing at various temperatures, and also certain thermomechanical treatments on the corrosion resistance of Zr + 2.5% Nb alloy. We show that annealing in the -region exerts the most favorable influence on the restoration of the corrosion resistance of this alloy after fast high-frequency hardening from the -region (the temperature range of existence of the -phase of zirconium) and subsequent thermomechanical treatment. We determine the temperature and time parameters of annealing to attain the high corrosion resistance of Zr + 2.5% Nb alloy and study the kinetics and mechanism of its corrosion.     

Sensitization induced stress corrosion failure of AISI 347 stainless steel fractionator furnace tubes

Austenitic stainless steel tubes are used as furnace tubes in petrochemical industries mainly because of their corrosion resistance and mechanical strength. AISI 347 grade stainless steel is used as furnace heater tubes in the fractionator of hydrocracker unit. Even though this stainless steel is stabilized with the addition of niobium thus preventing sensitization related corrosion failures, operational and maintenance errors may result in premature failures if conditions prevail. The present work reports the premature failure of AISI 347 grade fractionator furnace tubes after nearly 8 years of service. The failure occurred after shutdown. Carbonaceous deposits were found on the inner walls of the tube and circumferential cracks were found beneath the deposit. The service exposed 347 SS alloy tube was in the sensitized condition as confirmed by microstructure and double loop electrochemical potentiodynamic reactivation test. The tube material got sensitized possibly by localized overheating at the carbon layer deposited site. During shutdown of hydrocracker unit polythionic acid formation occurred possibly due to errors in shutdown procedures. Sensitized alloy 347 tube undergone polythionic acid induced intergranular stress corrosion cracking (PASCC).     

Optimization of annealing treatment and comprehensive properties of Cu-containing Ti6Al4V-xCu alloys

The Ti6Al4V-Cu alloy was reported to show good antibacterial properties, which was promising to reduce the hazard of the bacterial infection problem. For the purpose of preparing Ti6Al4V-Cu alloy with satisfied comprehensive properties, it’s important to study the heat treatment and the appropriate Cu content of the alloy. In this study, high Cu content Ti6Al4V-xCu (x = 4.5, 6, 7.5 wt%) alloys were prepared, and firstly the annealing heat treatments were optimized in the α+β+Ti₂Cu triple phase region to obtain satisfied tensile mechanical properties. Then the effect of Cu content on the tribological property, corrosion resistance, antibacterial activity and cytotoxicity of the Ti6Al4V-xCu alloys were systematically studied to obtain the appropriate Cu content. The results showed that the optimal annealing temperatures for Ti6Al4V-xCu (x = 4.5, 6, 7.5 wt%) alloys were 720, 740 and 760 °C, respectively, which was resulted from the proper volume fractions of α, β and Ti₂Cu phases in the microstructure. The additions of 4.5 wt% and 6 wt% Cu into the medical Ti6Al4V alloy could enhance the wear resistance and corrosion resistance of the alloy, but the addition of 7.5 wt% Cu showed an opposite effect. With the increase of the Cu content, the antibacterial property was enhanced due to the increased volume fraction of Ti₂Cu phase in the microstructure, but when the Cu content was increased to 7.5 wt%, cytotoxicity was presented. A medium Cu content of 6 wt%, with annealing temperature of 740 °C make the alloy possesses the best comprehensive properties of tensile properties, wear resistance, corrosion resistance, antibacterial property and biocompatibility, which is promising for future medical applications.     

Annealing behavior of a modified 5083 aluminum alloy

The annealing behavior of a modified 5083 aluminum alloy was studied in the temperature range of 125–375 °C with different holding times. The results shown that the annealing temperature was more sensitive to the mechanical and corrosion resistance properties compared with the annealing holding time. The mechanical and corrosion resistance properties depend on annealing treatment due to different dislocation configuration in the matrix and the second phase interface, annealing temperature and time have been optimized for both of those properties improvement.     

包铝镁合金的工艺特点及应用前景

传统的镁及镁合金存在着表面耐蚀性能差、冷加工性能不理想等缺点。采用包覆轧制的方法制备包铝镁板Al/Mg/A1层状复合材料,并对其进行适当的扩散退火处理,可有效地改善镁合金的室温塑性低、耐腐蚀性能差等缺点,且显著地提高了镁合金产品的应用与发展,扩大了镁合金的开发应用领域及应用前景等。     

氢气气氛中热处理对Ni-W合金镀层组织和性能的影响

研究了在氢气气氛中,不同的热处理温度对Ni-W合金镀层表面状态、相结构及显微硬度和耐蚀性的影响。结果表明,镀态的Ni-W合金镀层存在一种未知相(2θ≈41.4°),热处理过程中这一未知相消失,同时镀层中析出NiW、Ni_4W等沉淀相。随着热处理温度的升高,镀层的晶粒度逐渐增大,镀层在热处理过程中形成的孔隙逐渐增多。当热处理温度达到1 000℃后,镀层表面出现明显的裂纹,同时镀层中可还原形成单质W。Ni-W合金镀层的显微硬度经热处理后显著增大,热处理温度为500℃时镀层的显微硬度最大,同时镀层具有与镀态Ni-W合金相近的耐蚀性,热处理温度进一步升高后镀层的耐蚀性降低。     

低锡量镀锡板开发及关键工艺研究

根据市场需求开发了一种镀锡量为0.5g/m2的低锡量镀锡板。为保证耐蚀性及焊接性能,研究了电镀锡工艺参数及软熔工艺参数对镀锡层、锡铁合金层及耐蚀性的影响,确定了生产此种低锡量镀锡板的最优工艺参数,采用电化学及中性盐雾试验进行了耐蚀性分析。结果表明:电镀工艺第一道次和最后一道次均采用大电流冲击,中间道次小电流电镀可以明显提高镀层的均匀性;软熔温度越高越有利于促进锡-铁合金层的生成,当软熔温度240℃,软熔高度4200mm时表面质量和耐蚀性最好。     

Elasto-Plastic FEM Analysis of Residual Stress in Spun Tube

The residual stress distribution of Hastelloy C corrosion-resistant alloy tubes after power spinning was simulated with the elasto-plastic finite element method combining with the element birth and death technique, the influences of spinning parameters on the distribution of the residual stress were investigated in detail, and the formation mechanism of residual stress during tube spinning was discussed. Based on the calculation of the residual stress, the reasons for annealing cracks on the spun tube during interpass heat treatment were explored. The simulation results and the characteristics of annealing cracks show that the circumferential residual tensile stress is a main factor to cause the annealing cracks.