BHA:Cr~(3+)晶体的生长和结构

本文报告了首次生长出较大尺寸的BHA:Cr~(3+)(BeO·3Al_2O_3:Cr~(3+))晶体,介绍了该种晶体生长的工艺条件,指出配料组份是晶体生长的关键因素,并初步测定了部分晶体结构.     

ZnWO_4∶Cr~(3+)激光晶体的发光特性

研究了ZnWO_4Cr~(3+)激光晶体的发光特性,其中~4T_2能级分裂为13550、14205、14706cm~(-1)三个能级,荧光谱的斯托克斯漂移为3567cm~(-1),ZnWO4∶Cr~(3+)晶体的最强荧光峰位于912nm,最佳激发峰在622nm,掺杂浓度在0.01％时,荧光发射最强。用532nm激发时仍有很强的荧光发射。     

660nm激光抽运LiTaO_3∶Cr~(3+)晶体的激光运转

利用 6 6 0nm的巨脉冲激光抽运一种新的激光晶体LiTaO3∶Cr3+ ,获得了 1mJ的 90 1 6nm巨脉冲激光输出。经BBO晶体倍频获得了 45 0 8nm的蓝绿激光输出。     

新型激光晶体Gd_3(In,Ga)_2Ga_3O_(12):Cr~(3+)的发光

本文首次报道了一种用熔盐法生长的新型终端声子激光晶体Gd_3(In,Ga)_2Ga_2O_(12):Cr~(3+)的光谱特性。根据室温吸收谱及荧光谱确定了该晶体的若干主要光谱参数。     

Mg_2SiO_4:Cr~(3+)晶体的生长及其特性

介绍了用提拉法生长的Mg_2SiO_4:Cr~(3+)单晶的生长、结构和形态特征,测定了该晶体的吸收谱和荧光谱。荧光谱电子振动边带在800～1400nm,吸收谱中有一定的Fe~(3+)吸收。     

连续可调谐Cr~(4+):YAG激光器

介绍了一种在1500um附近连续可调谐的Cr~(4+):YAG激光器,最大可调谐范围达160um。室温下,当吸收功率为5W时,得到了370mW的连续输出,激光器的抽运阈值为1.94W。     

Cr~(3+):LiGaW_2O_8晶体的光谱研究

研究了作者研制的Cr~(3+):LGT晶体的室温吸收和荧光光谱,用比较简捷的方法进行了能级、晶场强度和跃迁截面的计算分析,从光谱学观点可以认为这种晶体是一种较有潜力的终端声子可调谐激光材料。     

凸-ARR非稳腔中Cr~(4+)∶YAG调Q激光器的研究

在带抗共振环 (Anti resonantRing ,ARR)的非稳腔Nd∶YAG激光器中 ,采用Cr4+ ∶YAG作为被动调 Q 元件 ,获得单脉冲能量 >85mJ,脉宽 40ns和能量起伏 0 4%的高能量、高稳定调Q激光脉冲。同时对平 凸非稳腔和平 平介稳腔进行实验比较 ,并对腔型和实验结果进行了初步分析。     

Q-switched and Mode-locked Characteristics of Cr~(4+)∶YAG Crystal

The passively Q-switched and mode-locked(QML) characteristics in a diode-pumped Nd∶GdVO_4 laser with Cr~(4+)∶YAG saturable absorbers have been demonstrated. A maximum average output power of 710mW has been obtained in the QML laser. The maximum energy of a single Q-switched pulse is 52.5μJ, with the corresponding pulse width of 30ns and the peak power of 1.75kW, at the incident pump power of 7.75W. The repetition rates of the Q-switched envelope and the mode-locked laser pulse are 16.7kHz and 680MHz, respectively.     

双掺(Ce~(3+)、Nd~(3+)):YAG晶体对撞脉冲锁模的研究

一、引 言 新晶体双掺(Ce~(3+)、Nd~(3+)):YAG是一种具有高转换效率的激光增益介质~[1],它利用Ce~(3+)、Nd~(3+)的敏化途径提高激光效率。晶体中的Ce~(3+)离予通过辐射和非辐射二种方式向Nd~（3+）转     

Flashlamp-pumped Cr3+:GSAG laser

Flashlamp-pumped vibronic lasing has been demonstrated at room temperature with the garnet Cr³⁺: GSAG. Continuous wavelength tuning was observed from 765 to 801 nm in preliminary experiments. An energy output of 110 mJ/pulse was obtained at 784 nm with a slope efficiency of 0.12 percent. Wavelength dependent gain and loss data are presented and are discussed with reference to Cr³⁺: GSGG measurements.     

YGG:Cr~(3+)晶体的激光诱导荧光光谱研究

在10K→300K温度范围内测量了YGG:Cr~(3+)的激光诱导荧光光谱,测出了有关荧光谱线的分裂量。并导出了~4T_2与~2T_1到~2E的能级间距随温度的变化关系式。     

BHA:Cr~(3+)(BeO·3Al_2O_3:Cr~(3+))晶体的荧光特性

本文对新晶体BHA:Cr~(3+)(BeO·3Al_2O_3:Cr~(3+))的荧光谱进行了仔细辨认,发现晶体中存在着几种不同的发光中心。提出了不同Cr离子中心之间的能量传递模型。     

Cr3+→Nd3+ energy transfer and Nd3+ laser action studies of La3Ga5SiO14:Cr3+,Nd3+ co-doped crystal

Energy transfer between Cr³⁺ and Nd³⁺ ions has been investigated in the 4.2-300-K temperature range by using steady-state and site-selective time-resolved laser spectroscopy. Radiative and nonradiative energy transfer has been studied from the time-resolved emission spectra and the donor fluorescence decays. The transfer efficiency was calculated as a function of temperature by using the Cr³⁺ lifetimes of the single doped and co-doped samples. Laser experiments were carried out in a diffusive cavity by pumping a co-doped rod 54 mm long and 5 mm in diameter with xenon flashlamps. The laser spectral emission shows a complex structure which varies as a function of pump energy. The temporal evolution of the laser spectrum is discussed in terms of a simple four-level spectral rate-equation laser model which takes into account the existence of two main broad Nd³⁺ site distributions with a large spectral overlap     

Li-La磷酸盐激光玻璃Cr~(3+)→Nd~(3+)敏化

本文对Li-La磷酸盐玻璃单掺Cr~(3+)离子及双掺Cr~(3+)、Nd~(3+)离子的光谱性质进行了研究,测定了玻璃的吸收光谱、荧光光谱和荧光寿命。Li-La磷酸盐玻璃中Cr~(3+)→Nd~(3+)的能量转移效率为38％,最适当的钕离子浓度为2×10~(21)cm~(-3),Cr_2O_3含量≥0.1wt％。     

Excited-state absorption studies of Cr4+ ions in severalgarnet host crystals

An experimental study of saturable absorption and excited-state absorption (ESA) in several inorganic saturable absorbers, Cr⁴⁺ :YAG, Cr⁴⁺:GGG, and Cr⁴⁺:YSGG, is presented. We provide the theoretical background of absorption characteristics in saturable absorbers that exhibit ESA, with some new results: approximate analytical solutions are proposed for the optical transmission in the case of a slow absorber, and for various light intensity conditions of spatially or temporally Gaussian beams in fast and slow absorbers. Experimentally, partial bleaching of the first excited state itself could be observed in Cr⁴⁺:YAG at λ=1064 nm, yielding the higher excited-state lifetime as τ*=(0.55±0.1) ns. The regular transmission bleaching curve was measured in Cr⁴⁺:GGG, for the first time in this material, yielding σ_ga=(58±5)×10^-1 cm², and σe_s=(13±2)×10^-19 cm² at λ=1064 nm, ESA spectra were measured for the three materials between ~700 and 900 nm. All three exhibit crossing between saturable absorption at longer wavelengths and inverse saturable absorption at shorter wavelengths     

用闪光灯泵浦Cr3+:GSAG和Cr3+:GSGG的斜率效率、腔结构、色心及其可调谐性

Cr3+:Gd3Sc2Al3O12(GSAG)和Cr3+:Gd3Sc2Ga3O12(GSGG)属弱场石榴石晶体,室温下,能输出脉冲可调谐激光。我们用2英寸长的Cr3+:GSAG 激光棒得到了200mJ的多模输出,其可调谐范围为700～800nm。     

灯泵浦Cr~(3 ):LiCaAlF晶体可调谐Q开关激光器

报道了闪光灯泵浦掺铬氟化铝钙锂（ＣｒＬｉＣＡＦ）可调谐、Ｑ开关激光器的实验结果。调谐范围为７３０～８５０ｎｍ，峰值波长为７８０ｎｍ。激光最大输出能量为１．６２Ｊ，斜率效率为０．８％，阈值为５０．４Ｊ。ＫＤ＊Ｐ晶体电光调Ｑ，单脉冲半宽度为４８ｎｓ，峰值功率为１．３×１０６Ｗ。     

Infrared cross-section measurements for crystals doped withEr3+, Tm3+, and Ho3+

The absorption and emission cross sections of the transition between the ground spin-orbit multiplet and the lowest excited multiplet were measured for Er³⁺, Tm³⁺, and Ho³⁺ ions in a variety of crystalline hosts. The materials that were investigated include LiYF₄, BaY₂F₈, Y ₃Al₅O₁₂, LaF₃, KCaF₃ , YAlO₃, and La₂Be₂O₅. The absolute magnitudes of the emission cross sections were determined from the absorption spectra, with the aid of the principle of reciprocity. The calculated radiative emission lifetimes derived from these measured cross sections agree well with the measured emission decay times for most materials. The potential use of these rare-earth-doped materials in pulsed laser applications requires that the ground state exhibit adequate splitting to minimize the detrimental effects of the ground state thermal population, and also that the emission cross section be sufficiently large to permit efficient extraction energy. The systems based on Ho³⁺ in the eightfold coordinated sites of LiYF₄, BaY₂F₈, and Y₃Al₅O₁₂ appear to be the most promising     

LiCaAlF6:Cr3+: a promising new solid-statelaser material

LiCaAlF₆:Cr³⁺ (Cr³⁺:LiCAF) exhibits an intrinsic (extrapolated maximum) slope efficiency of 67%. For comparison, the intrinsic slope efficiencies of BeAl₂O ₄:Cr³⁺ (alexandrite), Na₃Ga₂Li₃F₁₂:Cr³⁺ and ScBO₃:Cr³⁺ were found to be 65, 28, and 26%, respectively. The tuning range of LiCaAlF₆:Cr³⁺ was determined to be at least 720-840 nm. The conventional spectroscopic properties, such as the absorption, emission, and emission lifetimes as a function of temperature, are reported as well