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对铬酸溶液中铬酐含量与波美度关系作连接曲线及拟合曲线图,并将铬酐含量和波美度关系换算成公式,进行相对和绝对误差分析。为了减少误差,对铬酐含量在100-400g/L范围内的铬酸溶液和波美度关系作连接曲线,再进行曲线拟合、公式化。结果表明,得到的公式完全适用于实际生产中通过量波美度来了解镀铬溶液中铬酸含量的换算。 相似文献
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电镀铬一般均沿用铬酐硫酸溶液,这种溶液虽有其独特之处,但电流效率很低,深镀能力较差。我们参考一些国内外有关资料介绍的快速镀铬工艺,进行了试验,采用硼酸、氧化镁作添加剂,使电流效率提高到20~30%,生产效率比一般镀铬提高约两倍,分散能力显著好转。现介绍如下: 相似文献
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不锈钢表面处理应用技术简介(Ⅱ) 总被引:1,自引:0,他引:1
4 不锈钢着色4.1 化学着色奥氏体镍铬钢 1Cr18Ni8Ti可着彩色 ,而铁素体和马氏体不适合着彩色。4 .1.1 工艺流程零件→抛光 (机械抛光、化学抛光和电解抛光 )→清洗→酸洗(10 %硫酸、10 %盐酸、室温时间 5~ 10min ,只用于机械抛光 )→清洗→着彩色→清洗→固膜→清洗→干燥。4 .1.2 着色铬酐 2 5 0 (2 0 0~ 4 0 0 )g/L ,硫酸 4 90 (35 0~ 70 0 )g/L ,温度 70~90℃ ,处理时间不同依次出现蓝色→蓝灰色→黄色→紫色→绿色。影响着色膜的因素有 :(1)材料成分 以 18 8型镍铬奥氏体不锈钢着色最鲜艳 ,其他品种则较差 ;(2 )… 相似文献
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1 存在的问题低铬钝化工艺中铬酐含量仅为传统高铬钝化的 2 %左右 ,而所获得的膜层质量与高铬钝化的膜层质量相当 ,其环境效益和经济效益较为突出。就军绿色、橄榄及黑色钝化工艺而言 ,虽然铬酐含量高于低铬钝化 ,但比传统的高铬钝化低得多 ,而且膜层的耐蚀性有明显提高。因此 ,应广泛推广低铬钝化工艺。但是 ,低铬钝化工艺在生产实践中体现诸多优越性的同时 ,也存在不足。(1)酸度问题。如蓝白色钝化 ,虽然铬酐的含量低 ,但其他酸的浓度并不低 (HNO3 2 0~ 4 0ml/L ,H2 SO410~ 15ml/L ,HCl 5~ 10ml/L ,pH值 0 .5左右… 相似文献
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不良电沉积铜镀层需要退除再重新电镀,经渗碳后的保护铜层也要进行去铜处理,所以,铜镀层的退镀在表面处理工艺中是必不可少的。传统的除铜处理,无论是化学方法,还是电化学方法大多都离不开铬酐,而铬酐是剧毒物质,对环境的污染和人体健康的威胁是不容忽视的。由于铬... 相似文献
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为了提高黄铜制品的防腐能力,为表面涂漆打下良好底层,黄铜制品在机械加工以后都将进行表面钝化处理。按传统的钝化工艺,黄铜制品须在铬酐含量高达300g/L的强酸性溶液中进行钝化处理,需要消耗大量的、昂贵的、产生严重污染的铬酐。所以,不但成本很高,而且给废水处理在技术上和经济上造成很大负担。基于这种情况,国内近年来有关单位都在研究和应用无铬或超低铬钝化新工艺,力争消除或减轻环境污染。 相似文献
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Tzu‐Chiao Wei Hsin‐Ping Wang Ting‐You Li Chun‐Ho Lin Ying‐Hui Hsieh Ying‐Hao Chu Jr‐Hau He 《Advanced materials (Deerfield Beach, Fla.)》2017,29(35)
Organic–inorganic hybrid perovskite materials exhibit a variety of physical properties. Pronounced coupling between phonon, organic cations, and the inorganic framework suggest that these materials exhibit strong light–matter interactions. The photoinduced strain of CH3NH3PbBr3 is investigated using high‐resolution and contactless in situ Raman spectroscopy. Under illumination, the material exhibits large blue shifts in its Raman spectra that indicate significant structural deformations (i.e., photostriction). From these shifts, the photostrictive coefficient of CH3NH3PbBr3 is calculated as 2.08 × 10?8 m2 W?1 at room temperature under visible light illumination. The significant photostriction of CH3NH3PbBr3 is attributed to a combination of the photovoltaic effect and translational symmetry loss of the molecular configuration via strong translation–rotation coupling. Unlike CH3NH3PbI3, it is noted that the photostriction of CH3NH3PbBr3 is extremely stable, demonstrating no signs of optical decay for at least 30 d. These results suggest the potential of CH3NH3PbBr3 for applications in next‐generation optical micro‐electromechanical devices. 相似文献
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通过系统地测量(La2/3Ca1/3)(Mn(3-x)/3Fex/3)O3(x=0、0.1、0.2、0.3的体系样品的电阻率-温度关系以及一定温度下磁电阻率与磁场的关系,发现随x的变化其磁电阻率峰和电阻率峰均发生位移,磁电阻率峰值增大,并伴生磁电阻率峰展宽效应.作者认为由于Fe的替代,引起体系中Mn3+/Mn4+比率及磁矩的变化,加之外场对磁有序结构的调制作用,从而影响了Mn3+-O-Mn4+的双交换作用,最终导致磁电阻行为发生变化. 相似文献
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Isothermal sections of the Ni-Cr-Al-W system have been investigated at 75 at % Ni and temperatures of 1523 and 1273 K, by means of phase compositional analysis, X-ray diffraction and microscopical examination. The alloys studied lay in the range 2.5 to 10 at % Cr, 12.5 to 20 at% Al, 2.5 to 6.25 at % W, The phases formed were, and the bcc solid solution based on tungsten (designated
2). The maximum extent of the region was found to be 3 at % each of chromium and tungsten. Preferential partitioning of tungsten to occurred. Study of an Ni-10Cr-12.5Al-2.5W alloy aged at 1273 and 1073 K, after quenching from 1573 K, showed that changes in and compositions and lattice parameters occur as a function of ageing time. 相似文献
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V. V. Shvartsman S. G. Prutchenko E. D. Politova S. Yu. Stefanovich 《Inorganic Materials》2000,36(7):729-733
The structural, nonlinear optical, and dielectric properties of (1-x)PbZrO3 ·xtCdTiO3 solid solutions were studied. The phase relations in the composition rangesx = 0–0.3 and 0.85-1.0 were established. The results suggest that the ferrielectric ordering in CdTiO3 persists up to 730 K. 相似文献
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E. A. Filonova A. N. Demina E. A. Kleibaum L. Ya. Gavrilova A. N. Petrov 《Inorganic Materials》2006,42(4):443-447
We have revealed the formation of a continuous series of orthorhombic LaMn1 ? y FeyO3 solid solutions (0<y<1); La1 ? x SrxFeO3 solid solutions in the composition range 0 < x ≤ 0.8, with an orthorhombic structure at 0 < x ≤ 0.6 and a cubic structure at 0.6 < x ≤ 0.8; and a tetragonal SrMn1 ? y FeyO3 phase in the range 0.6 ≤ y ≤ 1. The composition stability limits of the perovskite phase La1 ? x SrxMn1 ? y FeyO3 have been determined, and the 1100°C isotherm of the La2O3-SrO-Mn3O4-Fe2O3 system in air has been constructed. 相似文献
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Cao C Qin W Zhang J Zhang J Wang Y Jin Y Wei G Wang G Wang L 《Journal of nanoscience and nanotechnology》2008,8(3):1384-1387
Tm3+/Er3+/Yb3+ tri-doped yttrium fluoride (YF3) phosphors were prepared by a facile hydrothermal method. X-ray topographic analysis found that the phosphors were crystallized products. Their sizes and morphologies were characterized by scanning electron microscopy (SEM, Hitachi S-4800), which indicated that most of the YF3 phosphors were hundreds of nanometers in size. Up-conversion (UC) spectra were recorded under 980-nm diode laser excitation at room temperature with a fluorescence spectrometer (Hitachi F-4500). Plenty of UC emissions of Tm3+ and Er3+ were observed from ultraviolet to red. For Tm3+ ions, a five-photon process (approximately 291 nm and approximately 347 nm), a four-photon process (approximately 362 nm and approximately 452 nm), and a three-photon process (approximately 475 nm) were identified in the UC spectra. The UC emissions from the Er3+ were: approximately 380 nm, approximately 408 nm, approximately 521 nm, approximately 537 nm, and approximately 652 nm. Therefore, cyan-white light can be observed by the naked eye at 980-nm excitation, even under low excitation power density. By comparing the UC spectra of the phosphors annealed at different temperatures, we found that the intensity of the UC luminescence increased as annealing temperature increased. Furthermore, the spectral dependencies on Tm3+ doped concentrations were studied. The energy transfer processes and fluorescence dynamics in the tri-doped system are currently being investigated. 相似文献
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高合金钢热冲孔冲头寿命关系到模具与产品成本、生产效率、自动化设备的使用,因此,应注重冲头的选材、材料制备与冲头制造工艺。 用 3 Cr3Mo3 VNb 作为高合金钢热冲孔冲头,为提高模具寿命,在材料制备上,优化了成分,采用电渣重熔冶炼,减少杂质,毛坯锻造两次,用大锻造比锻造,冲头热处理用真空炉,三次回火,热处理硬度取 HRC42 ~ 46 ,冲头表面处理采用镀铬工艺,开展了热冲孔工艺试验。 结果表明,用3 Cr3Mo3 VNb 可使冲孔冲头寿命平均达到 800 件以上。 相似文献
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The shrinkage phenomenon during the reaction-sintering of PMN-PZT from low-temperature pre-reacted 3PbO + MgNb2O6 + PZT powder mixtures has been studied. It was assumed that the pre-reaction treatment leads to the formation of a pyrochlore phase containing very active MgO small particles, and that the strong shrinkage occurring up to 800 °C took place by the diffusion of Mg2+ cations into the pyrochlore phase particles, thus controlling the reaction-sintering shrinkage phenomenon. Above that temperature the densification was enhanced by a liquid-phase sintering process. The ceramics sintered at 1050 °C for 2 h showed 96% of the theoretical density, and the dielectric constant of such a sintered ceramic showed a maximum value of 17 000 at 1 kHz. It was also found that the dielectric constant decreased with increasing grain size. Although the role of PZT in enhancing the dielectric constant of otherwise low-purity PMN ceramics is not clear, the increase in K is assumed to be a solid-solution effect. The presence of impurities and the PbO stoichiometry could be influencing the not too high dielectric constant value of PMN-PZT ceramics. 相似文献