利用高黏度保护渣解决低碳钢铸坯表面夹渣缺陷

低碳钢铸坯在连铸过程中表面容易产生夹渣缺陷。通过增加保护渣中MgO、MnO、Al2O3等的含量,可在提高保护渣黏度的同时加大保护渣的表面张力以及钢-渣界面张力,有利于钢、渣分离。根据经验公式η1 300℃·Vc=0.1~0.35以及武钢炼钢总厂四分厂连铸机拉速为1.3 m/min的实际情况,将试验保护渣黏度设计值由0.13 Pa·s提高到国内外专家要求的最大值0.25 Pa·s,连铸坯轧制钢材表面夹渣率由50%大幅度下降到20.5%。为了进一步降低夹渣率,根据试验情况及国内外保护渣设计理念,再次将保护渣的黏度由0.25 Pa·s提高至0.45 Pa·s,同时引入含量2%的Li2O,以改善传热条件,保证良好的润滑效果,实现保护渣均匀地消耗凝固,为坯壳均匀形成创造更有利的条件。最终将钢材表面夹渣率降到0.35%,提高了连铸坯及轧材合格率,满足了客户需求。     

钢球用钢Φ380mm连铸圆坯表面裂纹原因分析及工艺改进

对Φ380mm高碳钢球钢连铸圆坯轧成钢材出现的表面裂纹进行了统计分析结果表明:抛丸检查后的连铸圆坯表面存在纵向裂纹,主要原因是钢液在结晶器中凝固时冷却不均产生的。通过将结晶器铜管锥度由0.45%/m调整为0.63%/m,1300℃保护渣粘度由0.60 Pa·s降到0.50 Pa·s,1300℃保护渣熔速由36s调整到49s,二冷比水量由0.30L/kg降到0.25L/kg,二冷段四面冷却改为八面冷却等措施,有效降低了大规格钢球钢铸坯及轧材的表面纵裂纹,轧材表面探伤合格率提高到95%以上。     

含钛铁素体不锈钢连铸过程保护渣性能演变对铸坯质量的影响

结合生产实践,研究了含钛铁素体不锈钢浇铸过程中保护渣的成分及性能演变规律,分析了保护渣性能变化对铸坯质量的影响作用.得到如下结论:在含钛铁素体不锈钢连铸过程中,保护渣中Δw(TiO2)为2.3％ ～11.4％.随着浇铸的进行,熔化温度由初始的1124℃提高至1240℃,黏度升高至0.431 Pa·s.TiO2含量增加是...     

0.12%~0.16%C铬钼钢连铸板坯表面纵裂的控制

12Cr2Mo,14CrMo和15CrMo钢的生产流程为铁水-110t BOF—LF—VD-300 mm×（1700~2400）mm板坯CC工艺。分析了钢中碳含量,Mn/S,结晶器倒锥度,结晶器冷却工艺和保护渣,浸入式水口插入深度等因素对连铸板坯表面纵裂的影响。通过将优化前3种钢的结晶器倒锥度1.10优化成12Cr2Mo钢1.20,14CrMo钢1.15,15CrMo钢1.10,浸入式水口的插入深度由原先的170~180 mm调整到140~150 mm,使用粘度较低的保护渣（碱度1.25,1300℃粘度0.129 Pa·s）,以增加渣液的流动性,连铸板坯表面纵裂缺陷得到了有效的控制,纵裂率由原先的8.9%降低到优化后的3.2%。     

Q420B铁塔角钢裂纹的成因分析和工艺优化

Q420B铁塔角钢（/%:0.12~0.17C,0.15~0.35Si,1.25~1.60Mn,≤0.035P,≤0.035S,0.06~0.09V）的生产流程为60 t转炉-LF-220 mm×290 mnm坯连铸-型钢轧制。铁塔角钢成品酸洗后发现部分批次出现裂纹和表面夹杂,分析表明,裂纹深度达1 mm,有夹杂物和氧化、脱碳现象。通过保护渣碱度从0.97降至0.79,粘度由0.236 Pa·s提高至0.450 Pa·s,连铸坯矫直温度从900℃提高至1 000℃,二冷比水量从0.9 L/kg降至0.7L/kg等工艺措施,铸坯的合格率由93%提高到97%,并有效地避免了角钢裂纹的形成。     

Q345E钢Φ800 mm铸坯表面网状裂纹的分析及控制措施

采用金相显微镜和扫描电镜分析了Q345E钢Φ800 mm铸坯(/%:0.15C,0.27Si,1.37Mn,0.009P,0.001S,0.03Nb,0.04V,0.030A1,0.008 ON)表面网状裂纹,得出结晶器壁和凝固坯壳之间保护渣膜厚度不均匀,使坯壳局部受挤压,产生凹坑,冷却速度降低,产生热应力裂纹。通过将保护渣碱度(CaO)/(SiO_2)从1.03提高到1.15,熔点从1 235℃降至1 210℃,1 300℃粘度从0.87 Pa·s提高到1.10 Pa·s,使Φ800 mm连铸坯表面凹坑和网状裂纹的发生率从原60.5%降至0.5%以下。     

Q235B和Q345B钢中厚板表面纵裂纹的成因分析和工艺优化

Q235B钢（/%:0.14~0.17C,0.30~0.60Mn,0.010~0.040Als）和Q345B钢（/%:0.15~0.18C,1.30~1.60Mn,0.010~0.040Als）100 mm厚板的生产流程为铁水预处理-120 t转炉-LF-200 mm板坯连铸-轧制工艺。通过分析得出中厚板表面纵裂纹源于铸坯裂纹。通过保护渣碱度由1.16提高至1.26,1300℃黏度由0.80Pa·s提高至0.97 Pa·s,软搅拌时间不低于10 min,拉速控制在1.0 m/min左右,液面上下波动≤5 mm,保持结晶器锥度9.0 mm,钢水过热度20~25℃,二冷水为0.662 L/kg等工艺措施,使Q235B和Q345B钢中厚板纵裂率由2.17%下降至1.08%,板材综合合格率由原94.78%提高到98.16%。     

Q345E钢0800 mm铸坯表面网状裂纹的分析及控制措施

采用金相显微镜和扫描电镜分析了Q345E钢Φ800 mm铸坯（/%:0.15C,0.27Si,1.37Mn,0.009P,0.001S,0.03Nb,0.04V,0.030A1,0.008 ON）表面网状裂纹,得出结晶器壁和凝固坯壳之间保护渣膜厚度不均匀,使坯壳局部受挤压,产生凹坑,冷却速度降低,产生热应力裂纹。通过将保护渣碱度（CaO）/（SiO₂）从1.03提高到1.15,熔点从1 235℃降至1 210℃,1 300℃粘度从0.87 Pa·s提高到1.10 Pa·s,使Φ800 mm连铸坯表面凹坑和网状裂纹的发生率从原60.5%降至0.5%以下。     

高强度低合金钢保护渣黏度和结晶温度的优化

连铸时结晶器保护渣的黏度、结晶温度会对钢坯质量产生较大影响,采用旋转柱体法、黏温曲线分析法并结合扫描电子显微镜,研究了马鞍山钢铁股份有限公司3种不同保护渣的黏度、结晶温度。结果表明,马钢二炼钢厂生产Q420B铁塔用角钢的结晶器保护渣1 300℃时黏度0.298 Pa.s,结晶温度约1 180℃,为三者中最低。为降低卷渣情况和提高钢材质量,将黏度提高到0.35 Pa.s左右,并适当调节碱度使结晶温度升高,生产中卷渣及裂纹情况得到了较好的控制。     

中高锰钢液与精炼渣的反应行为研究

基于某钢厂中高锰钢现行精炼渣组分,设计了碱度为2～10的6组实验渣系,在1 600℃下采用高温电阻炉将不同Mn含量(0.80%、5.50%、10.81%、19.82%)的中高锰钢与实验渣系进行渣-钢平衡实验。采用FactSage计算了熔渣碱度对SiO₂活度的影响,不同MnO含量下渣中MgO溶解度及CaO-SiO₂-Al₂O₃液相区。结果表明,中高锰钢中的Mn会被精炼渣中的SiO₂氧化生成MnO;渣碱度提高会抑制MnO的生成,但当碱度达到4之后,MnO的生成量基本稳定;钢液中Mn含量会明显促进MnO生成;随着渣中MnO含量的增加,熔渣中MgO的溶解度降低,渣系的液相区逐渐扩大,使熔渣的熔化性质得到改善。     

China's Major Non-ferrous Metals Imports & Exports

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Zinc Production by Province in 2014

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80% of Chinese Firms Purchasing Overseas Mines Ended up in the Red

<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic     

Copper Processing Profit Dropped Sharply,Copper Consumption Will Face Impact in the Second Half of the Year

正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field,     

Central Geological Prospecting Fund Newly Added 16.47 Million Tonnes of Bauxite in 2013

正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF     

Manufacturers of Copper Tube for Central Air Conditioner Use Face Mounting Pressure in the Final Quarter of the Year

正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure     

Xinjiang Ranks No.1 in Production of Primary Aluminum in China

正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year,     

Shenhuo Coal Industry and Electricity Power Completed800,000 t/a Aluminum Project in Xinjiang

正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform.     

Guangdong Metal Transaction Center has Become the Second Largest Precious Metal Transaction Platform Nationwide

正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness.     

Seven Rare Earth Projects Involving Close to 3 Billion Yuan Investment Landed In the HighTech Zone

正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully.