油润滑对微动摩擦特性影响的研究

研究了钢摩擦副在油润滑工况下不同位移幅值对微动润滑摩擦特性的影响,分析了表面形貌。研究表明微动过程中表面之间的油介质会被驱除出接触区域,而滑动过程中表面之间的油介质始终保持在接触区域;润滑油的存在对接触区域起到了遮盖的作用,减少了氧化反应;由于油的流动性,在微动过程中容易再次渗透到接触区域,降低了表面摩擦与磨损。     

Influence of hyaluronic acid on the time-dependent friction response of articular cartilage under different conditions

Therapeutic lubricant injections of hyaluronic acid are a relatively recent treatment for osteoarthritis. Their efficacy, however, in vivo has been subject to much debate. Frictional properties of cartilage-cartilage contacts under both static and dynamic loading conditions have been investigated, using healthy cartilage and cartilage with a physically disrupted surface, with and without the addition of a therapeutic lubricant, hyaluronic acid. Most of the cartilage friction models produced typical time-dependent loading curves, with a rise in static friction with loading time. For the dynamic loading conditions the rise in friction with loading time was dependent on the spatial (and time) variation in the load on the cartilage plate. For sliding distances of 4 mm or greater, when the cartilage plate was unloaded during sliding, the dynamic friction remained low whereas, with shorter sliding distances, the dynamic friction increased with increasing loading time. Static friction was higher than dynamic friction (under the same tribological conditions). The 'damaged' cartilage models produced higher friction than healthy cartilage under equivalent tribological conditions. It was shown that hyaluronic acid was an effective boundary lubricant for articular cartilage under static conditions with both healthy and damaged cartilage surfaces. Hyaluronic acid was less effective under dynamic conditions. However, these dynamic conditions had low friction values with the control lubricant because of the effectiveness of the intrinsic biphasic lubrication of the cartilage. It was only under the tribological conditions in which the cartilage friction was higher and rising with increasing loading time because of depletion of the intrinsic biphasic lubrication, that the role of hyaluronic acid as an effective therapeutic lubricant was demonstrated.     

An investigation into the influence of frictionally generated surface temperatures on thermionic emission

Tribochemistry—including chemical reactions at sliding surfaces in contact—is an important factor in boundary lubrication and the formation of protective films. It is a complex subject quite different from conventional glassware studies and may involve effects of high temperatures produced by friction, the emission of charged particles and high pressure.In previous theoretical studies based on a general thermal model of sliding contact, results were presented for surface temperatures generated with pure metallic elements as well as ceramics. More recently, this model was extended to include thermionic emission of electrons.The current paper is motivated by the need to understand the connection between high surface temperatures and electron emission in sliding systems. The objectives are to examine theoretically the temperatures and resulting thermionic emission at the surface of selected sliding contact systems. Results are presented and discussed for 20 pure elements including 19 metals and 1 semi-conductor.The results of this investigation may be of value in examining and testing various film-forming hypotheses. For example, in the tribopolymerization concept of boundary lubrication, it is postulated that high surface temperatures are controlling for the surface polymerization of condensation-type monomers while the emission of low-energy electrons initiates polymerization of vinyl-type addition monomers.     

Molecular aspects of boundary lubrication

Recent molecular dynamics computer simulations of boundary lubrication, in which the lubricant and sliding solid surfaces are represented at an atomistic level, have given new insights into the mechanism of boundary lubrication. Combined with recent data from experiments on sliding surfaces, these simulations have forced us to modify our traditional view of lubrication in this regime. Stick-slip behaviour at low sliding velocities, discontinuous shear velocity profiles across the gap and lubricant states oscillating between solid-like and liquid-like extremes are some of the phenomena that occur in boundary lubrication. The Eyring model is discussed and directions for improvements proposed that would encompass stick-slip behaviour.     

Influence of temperature on the friction performance of gear oils in rolling–sliding and pure sliding contacts

The friction behaviour of five different gear oils in rolling–sliding and pure sliding contacts and how temperature influences their friction properties were investigated. It is found that increasing temperature decreases boundary friction with gear oils that contain friction modifiers while not for other gear oils, at all contact pressures investigated. In mixed lubrication region, temperature decreases friction at low contact pressures while increases friction at high contact pressures. The effect of slide–roll ratio on friction is significant in boundary lubrication region especially at higher temperature while less significant in mixed lubrication region at both low and high temperatures. The ranking of gear oils for friction in boundary and mixed lubrication regimes is similar both in rolling–sliding and pure sliding contacts, regardless of temperature. Copyright © 2013 John Wiley & Sons, Ltd.     

Evaluation of frictional properties of tribomaterials under sparse lubrication

Frictional properties of typical tribomaterials are evaluated under sparse lubrication conditions where lubricating oil is supplied but its amount is far from sufficient even for boundary lubrication. These conditions are provided by employing a mist oiling system which can continuously supply oil at constant, extremely low and quantitatively controlled rates. First, basic data on the properties of the oil mist are given and a quantitative determination of oil supply onto a sliding surface is described. Then frictional properties evaluated under stepwise increasing loads are presented for iron/steel, surface modification, ceramics and self-lubricating materials, and their characteristic behaviour is discussed.     

Tribochemistry of aluminium and aluminium alloy systems lubricated with liquids containing alcohol or amine additive types and some other lubricants — a review

The ability of a lubricating oil to reduce wear and prevent damage of interacting solids is a crucial factor controlling lubricant formulation. It is well known that friction produces local high temperatures. Many chemical reactions that are initiated by the friction process itself occur at much lower temperatures than those needed to provide the activation energy. Under boundary lubrication conditions, a clean surface exposed as a result of mechanical activity of the solid surface is extremely reactive, especially in the case of metals. This review mostly relates to the tribochemistry of aluminium, and discusses the tribological characteristics of alcohol‐ and amine‐type liquids used as either additives or lubricants to lubricate aluminium and its alloys under boundary friction conditions. Although tribochemical reactions during sliding are perceived in various ways, here the emphasis is on the negative‐ion‐radical action mechanism (NIRAM) approach. This review addresses the question as to how present knowledge of tribochemistry can be applied to the elucidation of the mechanisms of action by which the boundary lubricant compounds considered reduce aluminium‐on‐aluminium, steel‐on‐aluminium, and aluminium‐on‐steel wear. Also, information and a discussion on the tribological behaviour of other additives and/or lubricants in relation to the friction and wear of aluminium and its alloys are presented. A concise review of the most recent work on the tribochemistry of selected fluorinated alcohols is also included.     

On the effort to discriminate the principal function of tribofilm on friction under the boundary lubrication condition

Friction coefficient under boundary lubrication conditions is affected by many factors. In order to study the friction characteristic of tribofilm, friction coefficient of tribofilm formed on steel disk under the boundary lubrication conditions was separately measured under dry condition using a laboratory-made micro-tribometer to eliminate the hydrodynamic lubrication action of fluid. This paper introduces the approaching method to understand the friction characteristic of tribofilm. In this paper, sliding speed dependency of friction exerted by tribofilm was observed that could not be interpreted by the classical boundary lubrication mechanisms. The additives having long alkyl chain showed strong sliding speed dependency of friction.     

Friction, wear and structure of Cu samples in the lubricated steady friction state

Friction and wear of copper rubbed with lubrication in wide range of loads and sliding velocities were studied. The results of friction and wear experiments are presented as the Stribeck curve where the boundary lubrication (BL), mixed (ML) and elasto-hydrodynamic lubrication (EHL) regions are considered. The structural state of subsurface layers in different lubricant regions is studied by X-ray photoelectron spectroscopy, optical, transmission and scanning microscopy analysis. Dislocation density of dislocations in EHL and BL lubricant regimes was determined. Nanohardness at thin surface layers rubbed under different lubricant regimes is compared. The dominant friction and wear mechanisms in different lubrications regions are discussed.     

Review of engineered tribological interfaces for improved boundary lubrication

Recent advances in smart surface engineering and coating technologies offer unique possibilities for better controlling friction and wear under boundary or marginally lubricated rolling, sliding or rotating contact conditions. Specifically, such coatings can be tailored to meet the increasingly multi-functional application needs of future engine systems by enabling them to operate in lower viscosity oils with reduced sulfur and phosphorous. Using these technologies, researchers have already pioneered the development of a variety of nano-composite and super-hard coatings providing longer tool life in demanding machining and manufacturing applications. The same technologies can also be used in the design and development of novel coating architectures providing lower friction and wear under boundary-lubricated sliding conditions. For example, such coatings can be tailored in a very special way that while one of the phases can favorably react with certain additives in engine oils to result in an ideal chemical boundary film; the other phases can provide super-hardness and hence resists wear and scuffing. Because of their very dense microstructure and high chemical inertness, these coatings can also provide superior protection against oxidation and corrosive attacks in aggressive environments. The use of solid lubricant coatings may also improve the tribological properties of sliding contact interfaces under boundary lubricated sliding conditions. When fluid and boundary films fails or is broken down, such coatings can carry the load and act as a back-up lubricant. Other smart surface technologies such as laser texturing and/or dimpling, laser-glazing and -shotpeening have also become very popular in recent years. In particular, laser texturing of control or coated surfaces have opened up new possibilities for further manipulation of the lubrication regimes in classical Stribeck diagrams. Controlling dimple size, shape, orientation, and density, researchers were able to modify both the width and the height of the boundary lubrication regimes and thus achieve lower friction and wear at sliding and rotating contact interfaces. Overall, smart surface engineering and coating technologies have matured over the years and they now become an integral part of advanced machining and manufacturing applications. They can also be used to meet the increasingly stringent and multi-functional application needs of demanding tribological applications. In this paper, selected examples of recently developed novel surface engineering and coating technologies are introduced, and the fundamental tribological mechanisms that control their friction and wear behavior under boundary lubrication regimes are presented.     

Temperature—friction characteristics of cylinder lubrication in large,slow, cross‐head marine diesel engines under boundary lubrication conditions

In large, slow, cross‐head marine diesel engines research has increasingly shown that the lubrication regime between piston rings and cylinder liner at top dead centre is of the boundary lubrication type due to the high gas pressure, low sliding speed, and high temperature. This means that the tribological properties of piston ring, cylinder liner, and cylinder lubricant in these types of engine under boundary lubrication conditions should be considered simultaneously when friction and wear between the piston ring and cylinder liner are studied. Until now there has been no standard method to evaluate boundary lubrication performance. There are a few traditional methods used in lubricant research, but their results are not correlated with service conditions. It is important to find a suitable method to evaluate the boundary lubrication performance of lubricants at the laboratory testing stage or before the engine testing stage. The important parameters, such as sliding speed, normal load, materials of the contacting pairs, and lubricant, need all to be controlled. In this paper a systematic experimental procedure, the ‘five times heating and cooling test’, is introduced to assess lubricant properties under boundary lubrication conditions. Most of the parameters mentioned above are controlled. The model contact, of pin‐on‐plate form, is made from the actual piston and liner materials used in a large‐bore, slow, cross‐head marine diesel engine. The temperature characteristics of different blends of lubricants are investigated under boundary lubrication conditions using a pin‐on‐plate reciprocating test rig. These blends of lubricants have the same additives but different base fluids; they nevertheless fulfil the physical and chemical requirements of a real marine diesel engine. The test temperature range is from room temperature to the working temperature of the top piston ring. The experiments show that there are different temperature—friction characteristics for lubricants with different bases and the same additive package and there are also different temperature—friction characteristics during heating up and cooling down for each blend. Single‐base lubricants have more promising temperature—friction characteristics than those of a blend of a high‐viscosity base and a low‐viscosity base at high temperature.     

Textured surfaces in sliding boundary lubricated contacts – mechanisms,possibilities and limitations

Abstract

The mechanisms of friction and wear in boundary lubrication are complex with influences from the surface roughness and hardness of surfaces, the lubricant and the wear products. Introduction of a texture on either surface can influence several important parameters. Wear particles can be collected or produced by the surface texture. A lubricating film can suffer or gain and the lubrication regime might change. This paper presents an overview of the tribological effects and important parameters of textured surfaces in sliding boundary lubricated contact, based on the experience of the authors and on published results. Examples of successful and less successful textured contacts are given and some recommendations regarding size, orientation and textured area fraction are presented.     

The lubrication effect of hyaluronic acid and chondroitin sulfate on the natural temporomandibular cartilage under torsional fretting wear

The aim of this study is to investigate the lubrication of hyaluronic acid (HA) and chondroitin sulfate (CS) on the condylar cartilage of the temporomandibular joint. The wear behaviour of bovine condyle cartilage was explored against a zirconia ball with different lubrications under torsional fretting mode. The worn cartilage morphologies were observed using scanning electron microscopy and hemotoxylin and eosin staining. The results indicated that HA or CS could significantly lower the friction torque and dissipated energy of fretting interface and reduce the damage of the articular cartilage surface compared to the control (phosphate‐buffered saline). The mixture (HA and CS) could provide better protection for the cartilage layer. Absence of good lubrication in overloading torsional fretting process caused excessive cartilage wear. High concentration and high molecular weight HA or CS acted as good boundary lubricants, and the lubrication effect of their mixture was better due to their synergistic function. Copyright © 2014 John Wiley & Sons, Ltd.     

Influence of different surface modification technologies on friction of conformal tribopair in mixed and boundary lubrication regimes

Moving machine assemblies are generally designed to operate in full film lubrication regime to ensure high efficiency and durability of components. However, it is not always possible to ensure this owing to changes in operating conditions such as load, speed, and temperature. The overall frictional losses in machines are dependent on the operating lubrication regimes (boundary, mixed or full-film). The present work is thus aimed at investigating the role of different surface modification technologies on friction of a sliding bearing/roller tribopair both in boundary and mixed lubrication regimes. A special test rig comprising of two bearings was built for the experimental studies. Tribological tests were conducted in a wide speed range to enable studies in boundary and mixed lubrication regimes. The influence of application of different surface modification technologies on both the sliding bearing and the roller surfaces on friction has been studied. The rollers used in these studies were provided with five different coatings (hard DLCs and a soft self-lubricating coating). Additionally, two uncoated rollers having different surface roughness were also studied. Uncoated bearings were used in all tribopairs except two. These two bearings were coated with DLC and phosphate coatings respectively and uncoated rollers were the mating counterparts. Friction measurements were made on the new as well as the previously run-in surfaces. It was found that the rollers with self-lubricating coating resulted in lowest boundary friction closely followed by the rollers with the hardest DLC coatings. The DLC coating applied on to the bearing showed lower boundary friction after running-in. Mixed friction has been found to be mainly dependent on the surface topography characteristics of both the original and the run-in surfaces of bearings and rollers. The harder DLC coatings and the phosphated bearing showed the lowest mixed friction due to an efficient running-in of the bearing surface.     

Grooved surface texturing by electrical discharge machining (EDM) under different lubrication regimes

The aim of the present research work was to investigate the effectiveness of grooved surface texturing with a rhombic geometry under different lubrication regimes. Tribological investigation under unidirectional sliding was focused on the effect of texturing parameters including pattern area density on the coefficient of friction under different lubrication regimes, achieved by varying sliding speed and lubricant viscosity. Grooved patterns with different textured area densities were produced on steel samples by electrical discharge machining. Results of this investigation showed that under boundary lubrication, textures resist sliding thus resulting in increased friction. The largest improvement of friction reduction was observed under hydrodynamic lubrication, for low‐viscosity oil when using the textured disc with 21% pattern area density. The reduction of the coefficient of friction if compared with the untextured surface was of approximately 24%. Examination of the sliding surfaces has not shown any quantifiable wear for the contact conditions studied.     

In Situ Studies of Cartilage Microtribology: Roles of Speed and Contact Area

The progression of local cartilage surface damage toward early stage osteoarthritis (OA) likely depends on the severity of the damage and its impact on the local lubrication and stress distribution in the surrounding tissue. It is difficult to study the local responses using traditional methods; in situ microtribological methods are being pursued here as a means to elucidate the mechanical aspects of OA progression. While decades of research have been dedicated to the macrotribological properties of articular cartilage, the microscale response is unclear. An experimental study of healthy cartilage microtribology was undertaken to assess the physiological relevance of a microscale friction probe. Normal forces were on the order of 50 mN. Sliding speed varied from 0 to 5 mm/s, and two probes radii, 0.8 and 3.2 mm, were used in the study. In situ measurements of the indentation depth into the cartilage enabled calculations of contact area, effective elastic modulus, elastic and fluid normal force contributions, and the interfacial friction coefficient. This work resulted in the following findings: (1) at high sliding speed (V = 1–5 mm/s), the friction coefficient was low (μ = 0.025) and insensitive to probe radius (0.8–3.2 mm) despite the fourfold difference in the resulting contact areas; (2) the contact area was a strong function of the probe radius and sliding speed; (3) the friction coefficient was proportional to contact area when sliding speed varied from 0.05 to 5 mm/s; (4) the fluid load support was greater than 85% for all sliding conditions (0% fluid support when V = 0) and was insensitive to both probe radius and sliding speed. The findings were consistent with the adhesive theory of friction; as speed increased, increased effective hardness reduced the area of solid–solid contact which subsequently reduced the friction force. Where the severity of the sliding conditions dominates the wear and degradation of typical engineering tribomaterials, the results suggest that joint motion is actually beneficial for maintaining low matrix stresses, low contact areas, and effective lubrication for the fluid-saturated porous cartilage tissue. Further, the results demonstrated effective pressurization and lubrication beneath single asperity microscale contacts. With carefully designed experimental conditions, local friction probes can facilitate more fundamental studies of cartilage lubrication, friction and wear, and potentially add important insights into the mechanical mechanisms of OA.     

The effect of cast iron graphites on friction and wear performance I: Graphite film formation on grey cast iron surfaces

Cast iron is assessed as a self-lubricating metal-base composite material. The formation of cast iron graphite films and the effective surface treatment of grey cast iron are discussed. It was found that the friction and wear behaviour of cast iron are influenced by the formation of a graphite surface layer. When cast iron surfaces are etched with Nital, they are found to be covered with a graphite film during the sliding friction process. This contributes to the protection of metallic contact points. The formation of graphite films during testing is assumed to be due to the non-elastic deformation of surface graphite. The effects of applied load, sliding velocity and lubricant are also discussed. The coefficient of friction increases with applied load and sliding velocity, and therefore lubrication becomes more important. These phenomena are discussed in terms of the formation of graphite films during the friction process.     

Non-ferrous coating/lubricant interactions in tribological contacts: Assessment of tribofilms

Use of low friction non-ferrous coatings for engine tribo-components exposed to boundary lubrication is becoming popular in automotive industries. The excellent tribological behaviour of some non-ferrous coatings also reduces dependence on some harmful components of lubricants. In this work, hydrogenated diamond like carbon (HDLC) and chromium nitride (CrN) coatings sliding against cast iron counterbody have been used to study the interaction with friction modifiers (Moly dimer and Moly trimer) and antiwear additive zinc dialkyldithiophosphate (ZDDP) under boundary lubrication condition. The tribological results of the non-ferrous coatings are compared with those of uncoated steel. Tribofilms are formed using a reciprocating pin-on-plate tribometer. The chemical analysis of the tribofilms has been accomplished using X-ray photoelectron spectroscopy (XPS). The XPS analysis shows that the friction modifiers form a low friction tribofilm on the non-ferrous coatings. No antiwear tribofilm derived from ZDDP was observed on the HDLC coating but a stable antiwear tribofilm was found on the CrN coating. Moly dimer together with ZDDP+Base Oil showed the lowest friction coefficient for the CrN coating while Moly trimer along with ZDDP+Base Oil gave the lowest friction for the HDLC coating. This study will investigate the generic differences between the tribofilms formed on the DLC and CrN coatings by two additive-containing oils.     

Influence of Surface Topography on the Tribological Behaviour of Aluminium Alloy 5182 with EDT Surface

Friction is one of the most important parameters in sheet metal forming. Friction conditions are influenced by the texture of the sheet surface, by the surface or coating of the tools and by the lubrication. The aluminium alloy AA 5182 with EDT surface has been studied and tested at various angles between rolling and sliding direction. The friction behaviour observed in experiments at different normal pressures based on Coulomb’s friction law are shown and discussed in this article. Moreover, local surface topography and lubricant distribution in the contact area are described.     

The load-carrying action of organolead dithiophosphates,dithiocarbamates and xanthates Part II: Polymer formation on sliding metals

The catalytic effects of organolead dithiophosphates, dithiocarbamates and xanthates on the polymerization of some unsaturated hydrocarbons under conditions of boundary lubrication were studied. Free radicals, produced in the contact zone as the decomposition products of organolead dithiocompounds, initiate polymer formation directly on the rubbing surface. The protective film on the sliding surface does not react with the surface to reduce wear. The results of four-ball tests in antiwear and extreme pressure regions are presented. The formation of friction polymer was confirmed by electron probe microanalysis and chemical analysis.