Generation-IV reactors and nuclear hydrogen production

There are dozens of hydrogen production methods and techniques from many sources such as fossil fuels, renewable energy sources and nuclear energy in the literature. Thermo-chemical methods are more efficient at higher temperatures to produce large quantities of hydrogen. In this study, a comparative overview of Generation VI nuclear reactor types for major hydrogen production methods have been researched in the literature and suggestions have been carried out.This research work is addressing that both electric power cycle and hydrogen production based on nuclear technologies need to be developed. Generation IV nuclear reactors can provide hydrogen for a worldwide hydrogen economy. Both thermo-chemical and electrolysis (hybrid) processes in hydrogen production have a promising future, especially when integrated with Generation IV nuclear power plants. Efficient heat transfer is required for both high temperature thermodynamic cycles and the high temperature steam electrolysis. Hence, highly efficient heat exchanger designs are one of the key technologies for that purpose.     

Integrated hydrogen production options based on renewable and nuclear energy sources

Due to varied global challenges, potential energy solutions are needed to reduce environmental impact and improve sustainability. Many of the renewable energy resources are of limited applicability due to their reliability, quality, quantity, and density. Thus, the need remains for additional sustainable and reliable energy sources that are sufficient for large-scale energy supply to complement and/or back up renewable energy sources. Nuclear energy has the potential to contribute a significant share of energy supply with very limited impacts to global climate change. Hydrogen production via thermochemical water decomposition is a potential process for direct utilization of nuclear thermal energy. Nuclear hydrogen and power systems can complement renewable energy sources by enabling them to meet a larger extent of global energy demand by providing energy when the wind does not blow, the sun does not shine, and geothermal and hydropower energies are not available. Thermochemical water splitting with a copper–chlorine (Cu–Cl) cycle could be linked with nuclear and selected renewable energy sources to decompose water into its constituents, oxygen and hydrogen, through intermediate copper and chlorine compounds. In this study, we present an integrated system approach to couple nuclear and renewable energy systems for hydrogen production. In this regard, nuclear and renewable energy systems are reviewed to establish some appropriate integrated system options for hydrogen production by a thermochemical cycle such as Cu–Cl cycle. Several possible applications involving nuclear independent and nuclear assisted renewable hydrogen production are proposed and discussed. Some of the considered options include storage of hydrogen and its conversion to electricity by fuel cells when needed.     

An overview of the IAEA HEEP software and international programmes on hydrogen production using nuclear energy

Recent years have witnessed an increasing interest in hydrogen production using nuclear energy. A number of countries are actively exploring the option of nuclear hydrogen production and have established concrete roadmaps for near and far term achievements. This paper presents a summary of information presented at some IAEA technical meetings on status of nuclear hydrogen production including ongoing related R&D activities in Member States. The paper highlights, in addition, the IAEA hydrogen economic evaluation programme (HEEP) which has recently been developed under agreement and in collaboration with the BHABHA Atomic Research Centre (BARC). HEEP software can be used to perform the economics of the most promising processes for hydrogen production. Current processes considered in HEEP are: high and low temperature electrolysis, thermo-chemical processes including S-I process, conventional electrolysis and steam reforming. HEEP software is also suitable for comparative between nuclear and fossil energy sources, and for solely hydrogen production or cogeneration with electricity. The HEEP modelling includes various aspects of hydrogen economy including storage, transport, and distribution with options to eliminate or include specific details as required by the users.     

Biomass-based energy fuel through biochemical routes: A review

Energy demand is increasing continuously due to rapid growth in population and industrialization development. The development of energy sources is not keeping pace with spiraling consumption. Even developed countries are not able to compensate even after increasing the energy production multifold. The major energy demand is provided from the conventional energy sources such as coal, oil, natural gas, etc. Two major problems, which every country is facing with these conventional fuels, are depletion of fossil fuels and deterioration of environment.The present review article aims to highlight various biochemical processes for conversion of biomass into biological hydrogen gas and ethanol. The present discussion focuses on hydrogen production through various routes viz. fermentative, photosynthesis and biological water gas shift reaction. In addition, emphasis has been laid on ethanol as biomass-based energy fuel. The discussion has been focused on the technology for ethanol production from various biomass sources such as molasses, lignocellulosic feedstock and starch. Various biochemical processes and their major steps involved during the ethanol production from biomass have been discussed in detail.     

Review on effective parameters in electrochemical hydrogen storage

Today, energy has become one of the most important concerns of developing countries. The use of non-renewable energy sources, as well as the production of pollution, has led to growing efforts to replace fossil fuels, which are the most important energy sources in the modern world. Hydrogen as a clean fuel has attracted a lot of attention in recent years. Various methods have been reported for the production and storage of hydrogen. According to their advantages and disadvantages, it can be said that electrochemical hydrogen storage method is superior to other methods in terms of cost, safety, and optimum condition. The electrochemical hydrogen storage is done in a variety of techniques, and in recent years, the chronopotentiometry method has become one of the most popular methods for scientists. In chronopotentiometry technique, several parameters such as the reference electrode, the counter electrode, the working electrode, electrolyte, and current density are important. In this review, we investigated the articles that have been done in this regard from 2000 to 2020. This review can help scientists to better understand the electrochemical hydrogen storage system.     

Hydrogen versus synthetic fossil fuels

The fuels most considered for the post petroleum and natural gas era, hydrogen (gaseous and liquid) and synthetic fluid fossil fuels, have been compared by taking into account production costs, utilization efficiencies and environmental effects. Three different cost bases have been used for hydrogen depending on the primary energy sources used in its production. The results show that hydrogen is a much more cost effective energy carrier than synthetic fossil fuels. In addition to its environmental and efficiency benefits, hydrogen causes resource conservation, savings in transportation and capital investment, and reduction in inflation.     

Using next generation nuclear power reactors for development of a techno‐economic model for hydrogen production

Nuclear and hydrogen are considered to be the most promising alternatives energy sources in terms of meeting future demand and providing a CO?‐free environment, and interest in the development of more cost‐effective hydrogen production plants is increasing—and nuclear‐powered hydrogen generation plants may be a viable alternative. This paper is a report on investigating the application of new generation nuclear power plants to hydrogen production and development of an associated techno‐economic model. In this paper, theoretical and computational assessments of generations II, III+, and IV nuclear power plants for hydrogen generation scenarios have been reported. Technical analyses were conducted on each reactor type—in terms of the design standard, fuel specification, overnight capital cost, and hydrogen generation. In addition, a theoretical model was developed for calculating various hydrogen generation parameters, and it was then extended to include an economic assessment of nuclear power plant‐based hydrogen generation. The Hydrogen Economic Evaluation Program originally developed by the International Atomic Energy Agency was used for calculating various parameters, including hydrogen production and storage costs, as well as equity, operation and maintenance (O&M), and capital costs. The results from each nuclear reactor type were compared against reactor parameters, and the ideal candidate reactor was identified. The simulation results also verified theoretically proven results. The main objective of the research was to conduct a prequalification assessment for a cogeneration plant, by developing a model that could be used for technical and economic analysis of nuclear hydrogen plant options. It was assessed that high‐temperature gas‐cooled reactors (HTGR‐PM and PBR200) represented the most economical and viable plant options for hydrogen production. This research has helped identify the way forward for the development of a commercially viable, nuclear power‐driven, hydrogen generation plant.     

A comprehensive review on PEM water electrolysis

Hydrogen is often considered the best means by which to store energy coming from renewable and intermittent power sources. With the growing capacity of localized renewable energy sources surpassing the gigawatt range, a storage system of equal magnitude is required. PEM electrolysis provides a sustainable solution for the production of hydrogen, and is well suited to couple with energy sources such as wind and solar. However, due to low demand in electrolytic hydrogen in the last century, little research has been done on PEM electrolysis with many challenges still unexplored. The ever increasing desire for green energy has rekindled the interest on PEM electrolysis, thus the compilation and recovery of past research and developments is important and necessary. In this review, PEM water electrolysis is comprehensively highlighted and discussed. The challenges new and old related to electrocatalysts, solid electrolyte, current collectors, separator plates and modeling efforts will also be addressed. The main message is to clearly set the state-of-the-art for the PEM electrolysis technology, be insightful of the research that is already done and the challenges that still exist. This information will provide several future research directions and a road map in order to aid scientists in establishing PEM electrolysis as a commercially viable hydrogen production solution.     

Hydrogen production through renewable and non-renewable energy processes and their impact on climate change

The urbanization and increase in the human population has significantly influenced the global energy demands. The utilization of non-renewable fossil fuel-based energy infrastructure involves air pollution, global warming due to CO₂ emissions, greenhouse gas emissions, acid rains, diminishing energy resources, and environmental degradation leading to climate change due to global warming. These factors demand the exploration of alternative energy sources based on renewable sources. Hydrogen, an efficient energy carrier, has emerged as an alternative fuel to meet energy demands and green hydrogen production with zero carbon emission has gained scientific attraction in recent years. This review is focused on the production of hydrogen from renewable sources such as biomass, solar, wind, geothermal, and algae and conventional non-renewable sources including natural gas, coal, nuclear and thermochemical processes. Moreover, the cost analysis for hydrogen production from each source of energy is discussed. Finally, the impact of these hydrogen production processes on the environment and their implications are summarized.     

Review of hydrogen technologies based microgrid: Energy management systems,challenges and future recommendations

With the significant development of renewable energy sources in recent years, integrating energy storage systems within a renewable energy microgrid is getting more attention as a promising future hybrid energy system configuration. Recently, hydrogen systems are being considered a promising energy storage option that utilised electrolysers to produce and store hydrogen when energy is surplus and re-supply it into microgrids using fuel cells in energy shortage scenarios. To control the energy flow within such hybrid energy systems, designing an energy management system should be considered a critical task, that allows the technical and economic optimal operation of microgrids. This study presents a comprehensive review and analysis of different energy management systems for hydrogen technologies-based microgrids, including the strategies’ objectives, constraints and techniques as well as the optimisation methods and simulation tools. In addition, an insightful discussion of the existing challenges and suggestions for the future research direction has been given.     

Cyanobacterial hydrogen production - A step towards clean environment

Environmental pollution and exhaustive depletion of non-renewable energy sources demand the exploration of alternate energy sources. Hydrogen has been crowned as future fuel by virtue of its immense potential. Many microorganisms mediate hydrogen production. Cyanobacteria are excellent biological means of hydrogen production. This review highlights the significant progress achieved in cyanobacterial hydrogen production methods. The role of key enzymes catalyzing hydrogen production and the various parameters influencing the path of increased hydrogen productivity has been discussed.Recent approaches towards enhanced hydrogen production like genetic engineering, alteration in nutrient and growth conditions, entrapment in reverse micelles, combined culture and metabolic engineering have been emphasized. Improvisation in hydrogen production methods mediated by microbes will pave the path for commercialization of molecular hydrogen as environmental friendly energy source.     

Updated hydrogen production costs and parities for conventional and renewable technologies

This paper provides first a review of the production costs of hydrogen from conventional, nuclear and renewable sources, reported in the literature during the last eight years. In order to analyze the costs on a unified basis, they are updated to a common year (2009), taking into account the yearly inflation rates. The study also considers whether the hydrogen has been produced in centralized or distributed facilities. From these data, the expected future costs for conventional production of hydrogen are calculated considering several scenarios on carbon emission taxations. Based on these estimations, together with the predicted future costs (2019–2020 and 2030) for hydrogen from alternative sources, several hydrogen cost-parity analyses are exposed for renewable and nuclear energies. From the comparison between these alternative technologies for hydrogen production and the conventional ones (steam methane reforming and coal gasification), several predictions on the time-periods to reach cost parities are elaborated.     

Advances in hydrogen production by thermochemical water decomposition: A review

Hydrogen demand as an energy currency is anticipated to rise significantly in the future, with the emergence of a hydrogen economy. Hydrogen production is a key component of a hydrogen economy. Several production processes are commercially available, while others are under development including thermochemical water decomposition, which has numerous advantages over other hydrogen production processes. Recent advances in hydrogen production by thermochemical water decomposition are reviewed here. Hydrogen production from non-fossil energy sources such as nuclear and solar is emphasized, as are efforts to lower the temperatures required in thermochemical cycles so as to expand the range of potential heat supplies. Limiting efficiencies are explained and the need to apply exergy analysis is illustrated. The copper–chlorine thermochemical cycle is considered as a case study. It is concluded that developments of improved processes for hydrogen production via thermochemical water decomposition are likely to continue, thermochemical hydrogen production using such non-fossil energy will likely become commercial, and improved efficiencies are expected to be obtained with advanced methodologies like exergy analysis. Although numerous advances have been made on sulphur–iodine cycles, the copper–chlorine cycle has significant potential due to its requirement for process heat at lower temperatures than most other thermochemical processes.     

Single-atom catalysts for photocatalytic hydrogen evolution: A review

The application of hydrogen energy is significant to meet the challenge of fossil energy depletion and carbon emission limitation. The photocatalytic hydrogen evolution has been considered as a green and clean strategy for obtaining hydrogen. However, due to the high cost and limited efficiency, photocatalysis is only considered as one of the candidate methods for hydrogen production. Recently, several researchers have devoted to develop the single-atom catalysts (SACs) as promising cocatalysts and found great potential applications that are distributed across the fields of energy and environmental science. SACs exhibit several advantages, including abundant active sites, efficient photo-generated carrier recombination, atom-economic reaction mechanism, etc. In this synthetic review, we have summarized the advances of SACs in photocatalytic hydrogen evolution. Firstly, the synthesis strategies and characterization methods of SACs have been introduced. Then, the approaches for immobilizing prepared SACs on various supports have been elucidated. Finally, the photocatalytic activity of representative SACs-loaded supports has been analyzed, as well as the modification routes for enhancing performance. The review aims to record the development and applications of SACs in the field of photocatalytic hydrogen evolution. More studies are still required to clarify the mechanism of SACs based photocatalytic reactions, thus guiding the design of SACs-support system.     

Nanoconfinement effects on hydrogen storage properties of MgH2 and LiBH4

To find a solution to efficiently exploit renewable energy sources is a key step to achieve complete independence from fossil fuel energy sources. Hydrogen is considered by many as a suitable energy vector for efficiently exploiting intermittent and unevenly distributed renewable energy sources. However, although the production of hydrogen from renewable energy sources is technically feasible, the storage of large quantities of hydrogen is challenging. Comparing to conventional compressed and cryogenic hydrogen storage, the solid-state storage of hydrogen shows many advantages in terms of safety and volumetric energy density. Among the materials available to store hydrogen, metal hydrides and complex metal hydrides have been extensively investigated due to their appealing hydrogen storage properties. Among several potentials candidates, magnesium hydride (MgH₂) and lithium borohydride (LiBH₄) have been widely recognized as promising solid-state hydrogen storage materials. However, before considering these hydrides ready for real-scale applications, the issue of their high thermodynamic stability and of their poor hydrogenation/dehydrogenation kinetics must be solved. An approach to modify the hydrogen storage properties of these hydrides is nanoconfinement. This review summarizes and discusses recent findings on the use of porous scaffolds as nanostructured tools for improving the thermodynamics and kinetics of MgH₂ and LiBH₄.     

Prospects for the production of green hydrogen: Review of countries with high potential

The article provides a review of the current hydrogen production and the prospects for the development of the production of “green” hydrogen using renewable energy sources in various countries of the world that are leaders in this field. The potential of hydrogen energy in such countries and regions as Australia, the European Union, India, Canada, China, the Russian Federation, United States of America, South Korea, the Republic of South Africa, Japan and the northern countries of Africa is considered. These countries have significant potential for the production of hydrogen and “green” hydrogen, in particular through mining of fossil fuels and the use of renewable energy sources. The quantitative indicators of the production of “green” hydrogen in the future and the direction of its export are considered; the most developed hydrogen technologies in these countries are presented. The production of “green” hydrogen in most countries is the way to transition from the consumption of fossil fuels to the clean energy of the future, which will significantly improve the environmental situation, reduce greenhouse gas emissions and improve the energy independence of the regions.     

Application of laser fusion to the radiolytic production of hydrogen

A preliminary conceptual design of a plant to produce hydrogen by laser-fusion-induced steam radiolysis has been developed. It consists of a suppressed ablation lithium wetted wall cavity surrounded by pure and borated steam regions in which fusion neutrons deposit a substantial fraction of their energy, causing nuclear heating in the steam and structural materials, as well as radiolysis of water molecules. Coupled photon-neutron transport calculations have been performed to determine the energy deposited in the different regions of the reactor, and subsequently the amount of hydrogen and nuclear heating generated for various sets of reactor dimensions. The results of these calculations have been used to perform an economic analysis based on scaled costs of the corresponding component systems of proposed laser fusion power plants and hydrogen-generating or handling facilities. The production costs of hydrogen and electric power produced by the laser fusion hydrogen/electric plant considered have been estimated. It has been found that within the uncertainty of these estimates, and for laser fusion output parameters reasonably expected for a first-generation reactor, the computed hydrogen and electric power production costs are not competitive with current prices of natural gas and oil, and electrical power generated by alternate means. However, with an extension of the expected range of output values to significantly higher pellet gains, hydrogen production could become economically attractive.     

A figure of merit assessment of the routes to hydrogen

The efficient use of primary energy sources, which can be used for hydrogen production, is addressed by a consideration of four key measures, which reflect the ability of different sources and processing routes to meet underlying needs and the practical demands of energy on a large scale. The measures considered are carbon dioxide emission reduction, primary energy availability, land use implications and hydrogen production costs. Fourteen pathways to hydrogen are considered involving fossil fuels and nuclear energy as well as the range of renewable sources, and including additional strategies for carbon sequestration.The overall comparison of routes, based on simple figures-of-merit, shows a clear division between those using renewable energies and those associated with the traditional ‘high energy density’ primary sources. Emerging from the work is a clearer view of the implications of following a particular production path, the limitations of certain technologies and the research challenges which must be met in addressing future fuel options and global warming.